GB1548431A - Polyamides - Google Patents
PolyamidesInfo
- Publication number
- GB1548431A GB1548431A GB3922076A GB3922076A GB1548431A GB 1548431 A GB1548431 A GB 1548431A GB 3922076 A GB3922076 A GB 3922076A GB 3922076 A GB3922076 A GB 3922076A GB 1548431 A GB1548431 A GB 1548431A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- mol
- isophthalic
- polyamides
- diamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004952 Polyamide Substances 0.000 title abstract 2
- 229920002647 polyamide Polymers 0.000 title abstract 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 abstract 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 2
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 abstract 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- -1 aliphatic diamine Chemical class 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000004985 diamines Chemical class 0.000 abstract 1
- 150000001991 dicarboxylic acids Chemical class 0.000 abstract 1
- 150000003951 lactams Chemical class 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 238000006068 polycondensation reaction Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/36—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from amino acids, polyamines and polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Polyamides (AREA)
Abstract
Polyamides are prepared by polycondensation of a) a diamine of the dicycane type, b) a polyamide-forming dicarboxylic acid which comprises from 85 to 100 mol % of isophthalic acid and optionally terephthalic acid, and c) an omega -amino acid or a lactam thereof having more than 9 carbon atoms or an aliphatic diamine/dicarboxylic acid salt or mixture (in each case in a molar ratio of 1:1), in particular of a) (4,4'-diamino-3,3'-dimethyldicyclohexyl) methane, b) isophthalic/terephthalic acid (95:5 mol) and c) laurolactam while observing the conditions defined in the Claim. The resultant copolyamides are glass-clear (transparent), have excellent dimensional stability and have excellent stability to boiling water.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1228775A CH624970A5 (en) | 1975-09-22 | 1975-09-22 | Process for the preparation of glass-transparent polyamide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1548431A true GB1548431A (en) | 1979-07-18 |
Family
ID=4381599
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3922076A Expired GB1548431A (en) | 1975-09-22 | 1976-09-22 | Polyamides |
Country Status (6)
| Country | Link |
|---|---|
| CH (1) | CH624970A5 (en) |
| DE (1) | DE2642244C2 (en) |
| FR (1) | FR2324672A1 (en) |
| GB (1) | GB1548431A (en) |
| IT (1) | IT1066199B (en) |
| PL (1) | PL102928B1 (en) |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4255559A (en) | 1978-10-18 | 1981-03-10 | Ciba-Geigy Corporation | Transparent copolyamide from 1,10-disubstituted-1,10 diamine |
| US4264762A (en) | 1978-10-24 | 1981-04-28 | Basf Aktiengesellschaft | Glass-clear nylons from 3,3'-dimethyl PACM |
| US4355177A (en) | 1978-10-18 | 1982-10-19 | Ciba-Geigy Corporation | Substituted 11-amino-undeca-4,8-dienal and 11-amino-undecanal derivatives and processes for their preparation |
| US4368090A (en) | 1979-12-06 | 1983-01-11 | Chemische Werke Huls Ag | Method of using copolyether ester amides as thermoplastic adhesives for heat sealing textiles |
| US4460790A (en) * | 1978-10-18 | 1984-07-17 | Ciba-Geigy Corporation | Substituted 1,11-diaminoundecanes, processes for producing them, and their use |
| GB2170209A (en) * | 1985-01-07 | 1986-07-30 | Inventa Ag | Copolyamides |
| AU612416B2 (en) * | 1987-10-21 | 1991-07-11 | Atochem | Transparent polyamides, process for their manufacture |
| US7133209B2 (en) | 2003-02-25 | 2006-11-07 | Degussa Ag | Transparent molding composition for optical applications |
| US8044171B2 (en) | 2006-01-31 | 2011-10-25 | Ems-Chemie Ag | Polyamide molding compound and its use for producing transparent, hot-steam-sterilizable molded parts and extrudates |
| US8268956B2 (en) | 2006-12-08 | 2012-09-18 | Ems-Chemie Ag | Transparent mold made of a polyamide molding material |
| US8383244B2 (en) | 2011-06-17 | 2013-02-26 | Ems-Patent Ag | Semiaromatic molding compounds and uses thereof |
| US8404323B2 (en) | 2010-03-12 | 2013-03-26 | Ems-Patent Ag | Impact-resistant modified polyamide moulding compound and container formed therefrom |
| US8507598B2 (en) | 2007-12-21 | 2013-08-13 | Ems-Patent Ag | Transparent polyamide moulding compound |
| US8586662B2 (en) | 2007-11-16 | 2013-11-19 | Ems-Patent Ag | Filled polyamide molding materials |
| US8604120B2 (en) | 2010-07-30 | 2013-12-10 | Ems-Patent Ag | Polyamide moulding compound for producing moulded articles with a soft-touch surface and also corresponding moulded articles |
| US9109115B2 (en) | 2013-03-15 | 2015-08-18 | Ems-Patent Ag | Polyamide moulding compound and moulded articles produced herefrom |
| US9133322B2 (en) | 2012-10-02 | 2015-09-15 | Ems-Patent Ag | Polyamide moulding compounds and use thereof in the production of moulded articles |
| US9453106B2 (en) | 2012-05-23 | 2016-09-27 | Ems-Patent Ag | Scratch-resistant, transparent and tough copolyamide moulding compounds, moulded articles produced therefrom and uses thereof |
| US9963591B2 (en) | 2012-12-18 | 2018-05-08 | Ems-Patent Ag | Polyamide molding material and moldings manufactured from same |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2635085A1 (en) * | 1976-08-04 | 1978-02-09 | Bayer Ag | POLYAMIDE |
| DE2726262A1 (en) * | 1977-06-10 | 1978-12-21 | Bayer Ag | COPOLYAMID |
| US4258177A (en) * | 1978-10-18 | 1981-03-24 | Ciba-Geigy Corporation | Transparent copolyamide from 1,10-disubstituted C10 diamine |
| US4258176A (en) * | 1978-10-18 | 1981-03-24 | Ciba-Geigy Corporation | Transparent copolyamide from 1,10-disubstituted C11 diamine |
| DE2936759C2 (en) * | 1979-09-12 | 1987-03-26 | Hüls AG, 4370 Marl | Transparent copolyamides |
| DE3168062D1 (en) * | 1980-12-12 | 1985-02-14 | Dynamit Nobel Ag | Transparent polyamide resistant to boiling water and sterilization |
| GB8710748D0 (en) | 1987-05-07 | 1987-06-10 | Rennie Sa | Metal coating powders |
| FR2706474B1 (en) * | 1993-06-11 | 1995-08-25 | Atochem Elf Sa | Transparent polyamide compositions without hot deformation. |
| CH689422A5 (en) | 1995-02-01 | 1999-04-15 | Inventa Ag | Transparent copolyamides, their preparation and Formkoerper from the transparent copolyamides. |
| CA2162429A1 (en) * | 1995-02-01 | 1996-08-02 | Hans Dalla Torre | Colorless, transparent copolyamides, their preparation, and molded articles made from these copolyamides, their blends or alloys |
| DE10009756B4 (en) * | 2000-03-01 | 2004-03-25 | Ems-Chemie Ag | Colorless, highly transparent polyamide blends with improved stress crack resistance |
| DE102006045269A1 (en) | 2005-11-09 | 2007-05-31 | Ems-Chemie Ag | Metallic coated Lichtreflektierbauteile based on thermoplastic molding compositions |
| DE102006057957B4 (en) * | 2006-12-08 | 2017-03-23 | Ems-Chemie Ag | Transparent molded body made of a polyamide molding compound and its use |
| DE102008002599A1 (en) | 2008-06-24 | 2009-12-31 | Evonik Degussa Gmbh | Component with cover layer of a PA613 molding compound |
| DE102008046682A1 (en) | 2008-09-10 | 2010-03-11 | Basf Se | Thermoplastic molded mass, useful to produce molded body, fiber and film, comprises polyamide made of units derived from dicarboxylic acids and cycloaliphatic diamines, and units derived from further polyamide-forming monomer and additives |
| DE102009035974A1 (en) | 2009-08-04 | 2011-02-17 | Basf Se | Thermoplastic molded mass, useful to prepare e.g. foils, comprises amorphous polyamide from units derived from aliphatic dicarboxylic acid, tetraalkyl substituted cycloaliphatic diamine and further polyamide forming monomer, and additives |
| DE102010051726A1 (en) | 2010-11-19 | 2012-05-24 | Basf Se | Thermoplastic molding composition useful for preparing molding, fiber and film, comprises amorphous polyamide constructed from units derived from aliphatic dicarboxylic acid and units derived from bicyclic aliphatic diamine, and additives |
| DE102010051708A1 (en) | 2010-11-19 | 2012-05-24 | Basf Se | Thermoplastic molding composition useful for preparing molding, fiber and film, comprises amorphous polyamide constructed from e.g. units derived from aliphatic dicarboxylic acid and dialkyl-substituted cycloaliphatic diamine, and additive |
| EP2881438A1 (en) | 2013-12-05 | 2015-06-10 | LANXESS Deutschland GmbH | Polyamide compositions |
| EP4008743B1 (en) | 2020-12-04 | 2024-09-04 | Ems-Chemie Ag | Water vapour-resistant transparent polyamides |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2512606A (en) * | 1945-09-12 | 1950-06-27 | Du Pont | Polyamides and method for obtaining same |
| US2516585A (en) * | 1948-12-21 | 1950-07-25 | Du Pont | Synthetic linear polyamides containing intralinear cyclic groups and process for obtaining same |
| US2696482A (en) * | 1951-07-19 | 1954-12-07 | Du Pont | Transparent synthetic linear polyamide and process for producing same |
| IL24111A (en) * | 1964-08-24 | 1969-02-27 | Du Pont | Linear polyamides |
| DE1595354C3 (en) * | 1966-10-18 | 1978-12-07 | Basf Ag | Process for the production of polyamides |
| BE792063A (en) * | 1971-12-02 | 1973-05-29 | Bayer Ag | TRANSPARENT COPOLYAMIDES |
| US3840501A (en) * | 1972-07-05 | 1974-10-08 | Phillips Petroleum Co | Copolyamides of 2,2-bis(4-aminocyclohexyl)propanes and a mixture of alkane dicarboxylic acids |
| US3842045A (en) * | 1972-07-05 | 1974-10-15 | Phillips Petroleum Co | Amorphous polyamides from bis(4-aminocyclohexyl)methane and a mixture of straight chain dicarboxylic acids |
| DE2405985A1 (en) * | 1974-02-08 | 1975-08-21 | Hoechst Ag | Thermoplastic amorphous polyamide mould compsns - rendered non-combustible by incorporating red phosphorus |
-
1975
- 1975-09-22 CH CH1228775A patent/CH624970A5/en not_active IP Right Cessation
-
1976
- 1976-09-20 IT IT5135976A patent/IT1066199B/en active
- 1976-09-20 DE DE19762642244 patent/DE2642244C2/en not_active Expired
- 1976-09-21 PL PL19255176A patent/PL102928B1/en unknown
- 1976-09-21 FR FR7628354A patent/FR2324672A1/en active Granted
- 1976-09-22 GB GB3922076A patent/GB1548431A/en not_active Expired
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4255559A (en) | 1978-10-18 | 1981-03-10 | Ciba-Geigy Corporation | Transparent copolyamide from 1,10-disubstituted-1,10 diamine |
| US4355177A (en) | 1978-10-18 | 1982-10-19 | Ciba-Geigy Corporation | Substituted 11-amino-undeca-4,8-dienal and 11-amino-undecanal derivatives and processes for their preparation |
| US4460790A (en) * | 1978-10-18 | 1984-07-17 | Ciba-Geigy Corporation | Substituted 1,11-diaminoundecanes, processes for producing them, and their use |
| US4484004A (en) * | 1978-10-18 | 1984-11-20 | Ciba-Geigy Corporation | Substituted 1,11-diaminoundecanes, processes for producing them and their use |
| US4487947A (en) * | 1978-10-18 | 1984-12-11 | Ciba-Geigy Corporation | Substituted 1,11-diaminoundecanes, processes for producing them, and their use |
| US4264762A (en) | 1978-10-24 | 1981-04-28 | Basf Aktiengesellschaft | Glass-clear nylons from 3,3'-dimethyl PACM |
| US4368090A (en) | 1979-12-06 | 1983-01-11 | Chemische Werke Huls Ag | Method of using copolyether ester amides as thermoplastic adhesives for heat sealing textiles |
| GB2170209A (en) * | 1985-01-07 | 1986-07-30 | Inventa Ag | Copolyamides |
| AU612416B2 (en) * | 1987-10-21 | 1991-07-11 | Atochem | Transparent polyamides, process for their manufacture |
| US7133209B2 (en) | 2003-02-25 | 2006-11-07 | Degussa Ag | Transparent molding composition for optical applications |
| US8044171B2 (en) | 2006-01-31 | 2011-10-25 | Ems-Chemie Ag | Polyamide molding compound and its use for producing transparent, hot-steam-sterilizable molded parts and extrudates |
| US8268956B2 (en) | 2006-12-08 | 2012-09-18 | Ems-Chemie Ag | Transparent mold made of a polyamide molding material |
| US8586662B2 (en) | 2007-11-16 | 2013-11-19 | Ems-Patent Ag | Filled polyamide molding materials |
| US8507598B2 (en) | 2007-12-21 | 2013-08-13 | Ems-Patent Ag | Transparent polyamide moulding compound |
| US8404323B2 (en) | 2010-03-12 | 2013-03-26 | Ems-Patent Ag | Impact-resistant modified polyamide moulding compound and container formed therefrom |
| US8604120B2 (en) | 2010-07-30 | 2013-12-10 | Ems-Patent Ag | Polyamide moulding compound for producing moulded articles with a soft-touch surface and also corresponding moulded articles |
| US8383244B2 (en) | 2011-06-17 | 2013-02-26 | Ems-Patent Ag | Semiaromatic molding compounds and uses thereof |
| US9453106B2 (en) | 2012-05-23 | 2016-09-27 | Ems-Patent Ag | Scratch-resistant, transparent and tough copolyamide moulding compounds, moulded articles produced therefrom and uses thereof |
| US9133322B2 (en) | 2012-10-02 | 2015-09-15 | Ems-Patent Ag | Polyamide moulding compounds and use thereof in the production of moulded articles |
| US9963591B2 (en) | 2012-12-18 | 2018-05-08 | Ems-Patent Ag | Polyamide molding material and moldings manufactured from same |
| US9109115B2 (en) | 2013-03-15 | 2015-08-18 | Ems-Patent Ag | Polyamide moulding compound and moulded articles produced herefrom |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2324672B1 (en) | 1978-05-12 |
| IT1066199B (en) | 1985-03-04 |
| DE2642244C2 (en) | 1983-07-07 |
| PL102928B1 (en) | 1979-05-31 |
| FR2324672A1 (en) | 1977-04-15 |
| DE2642244A1 (en) | 1977-03-31 |
| CH624970A5 (en) | 1981-08-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| 429A | Application made for amendment of specification (sect. 29/1949) | ||
| 429H | Application (made) for amendment of specification now open to opposition (sect. 29/1949) | ||
| 429D | Case decided by the comptroller ** specification amended (sect. 29/1949) | ||
| SPA | Amended specification published | ||
| PE20 | Patent expired after termination of 20 years |
Effective date: 19960921 |