GB1431511A - Purification of acrylonitrile - Google Patents
Purification of acrylonitrileInfo
- Publication number
- GB1431511A GB1431511A GB66874A GB66874A GB1431511A GB 1431511 A GB1431511 A GB 1431511A GB 66874 A GB66874 A GB 66874A GB 66874 A GB66874 A GB 66874A GB 1431511 A GB1431511 A GB 1431511A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acrolein
- acrylonitrile
- cyanhydrin
- hydrogen cyanide
- purification
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/32—Separation; Purification; Stabilisation; Use of additives
- C07C253/34—Separation; Purification
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1431511 Purification of acrylonitrile BP CHEMICALS INTERNATIONAL Ltd 19 Dec 1974 [7 Jan 1974] 00668/74 Heading C2C Acrylonitrile that has been produced by the vapour phase reaction of acrolein or a substance giving rise to acrolein under the reaction conditions, molecular oxygen and ammonia at elevated temperature in the presence of a catalyst, and that contains acrolein and hydrogen cyanide as by-products, is purified by treating with an ammonium, alkalimetal or alkaline earth metal salt of a weak aliphatic carboxylic acid to cause the acrolein and hydrogen cyanide to react to form acrolein cyanhydrin, and separating the acrylonitrile from the acrolein cyanhydrin by distillation. The salt is preferably an acetate, propionate, butyrate or stearate and may be used as a solid or aqueous or organic solution; in examples, aqueous ammonium acetate is used.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB66874A GB1431511A (en) | 1974-01-07 | 1974-01-07 | Purification of acrylonitrile |
| CA217,057A CA1019346A (en) | 1974-01-07 | 1974-12-30 | Process for the purification of acrylonitrile |
| FR7500199A FR2256914A1 (en) | 1974-01-07 | 1975-01-06 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB66874A GB1431511A (en) | 1974-01-07 | 1974-01-07 | Purification of acrylonitrile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1431511A true GB1431511A (en) | 1976-04-07 |
Family
ID=9708432
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB66874A Expired GB1431511A (en) | 1974-01-07 | 1974-01-07 | Purification of acrylonitrile |
Country Status (3)
| Country | Link |
|---|---|
| CA (1) | CA1019346A (en) |
| FR (1) | FR2256914A1 (en) |
| GB (1) | GB1431511A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5606094A (en) * | 1995-01-10 | 1997-02-25 | Baker Hughes Incorporated | Acrolein scavengers |
| US6325945B2 (en) | 1999-07-01 | 2001-12-04 | E. I. Du Pont De Nemours And Company | Process of making a polyester or polyol |
| US6331264B1 (en) | 1999-03-31 | 2001-12-18 | E. I. Du Pont De Nemours And Company | Low emission polymer compositions |
| WO2004063145A1 (en) * | 2003-01-03 | 2004-07-29 | The Standard Oil Company | Process for recovering acrylonitrile or methacrylonitrile |
-
1974
- 1974-01-07 GB GB66874A patent/GB1431511A/en not_active Expired
- 1974-12-30 CA CA217,057A patent/CA1019346A/en not_active Expired
-
1975
- 1975-01-06 FR FR7500199A patent/FR2256914A1/fr not_active Withdrawn
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5606094A (en) * | 1995-01-10 | 1997-02-25 | Baker Hughes Incorporated | Acrolein scavengers |
| US5760283A (en) * | 1995-01-10 | 1998-06-02 | Baker Hughes Incorporated | Acrolein scavengers |
| US6331264B1 (en) | 1999-03-31 | 2001-12-18 | E. I. Du Pont De Nemours And Company | Low emission polymer compositions |
| US6325945B2 (en) | 1999-07-01 | 2001-12-04 | E. I. Du Pont De Nemours And Company | Process of making a polyester or polyol |
| WO2004063145A1 (en) * | 2003-01-03 | 2004-07-29 | The Standard Oil Company | Process for recovering acrylonitrile or methacrylonitrile |
| US7250527B2 (en) | 2003-01-03 | 2007-07-31 | Ineos Usa Llc | Process for recovering acrylonitrile or methacrylonitrile |
| EA009177B1 (en) * | 2003-01-03 | 2007-12-28 | ИНЕОС ЮЭсЭй ЭлЭлСи | Process for recovering acrylonitrile or methacrylonitrile |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1019346A (en) | 1977-10-18 |
| FR2256914A1 (en) | 1975-08-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |