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GB1498199A - Fungicidal agents - Google Patents

Fungicidal agents

Info

Publication number
GB1498199A
GB1498199A GB13349/75A GB1334975A GB1498199A GB 1498199 A GB1498199 A GB 1498199A GB 13349/75 A GB13349/75 A GB 13349/75A GB 1334975 A GB1334975 A GB 1334975A GB 1498199 A GB1498199 A GB 1498199A
Authority
GB
United Kingdom
Prior art keywords
formula
group
compound
prepared
reacting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB13349/75A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Novartis AG
Original Assignee
Ciba Geigy AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CH457274A external-priority patent/CH590608A5/en
Application filed by Ciba Geigy AG filed Critical Ciba Geigy AG
Publication of GB1498199A publication Critical patent/GB1498199A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D213/00Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
    • C07D213/02Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
    • C07D213/04Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
    • C07D213/60Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D213/78Carbon atoms having three bonds to hetero atoms, with at the most one bond to halogen, e.g. ester or nitrile radicals
    • C07D213/81Amides; Imides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D239/00Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
    • C07D239/02Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
    • C07D239/24Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
    • C07D239/28Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, directly attached to ring carbon atoms
    • C07D239/30Halogen atoms or nitro radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/04Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
    • C07D307/18Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/24Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D307/00Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/68Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D309/00Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/16Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D309/28Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D327/00Heterocyclic compounds containing rings having oxygen and sulfur atoms as the only ring hetero atoms
    • C07D327/02Heterocyclic compounds containing rings having oxygen and sulfur atoms as the only ring hetero atoms one oxygen atom and one sulfur atom
    • C07D327/06Six-membered rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D333/00Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D333/38Carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Furan Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Pyridine Compounds (AREA)
  • Pyrane Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

1498199 Heterocyclic amides CIBA-GEIGY AG 1 April 1975 [2 April 1974 10 Feb 1975] 13349/75 Heading C2C Novel compounds of Formula (I) wherein R 1 represents a halogen atom or an alkyl or alkoxy group of 1 to 4 carbon atoms, R 2 represents a hydrogen or halogen atom, an alkyl group of 1 to 3 carbon atoms or an alkoxy group of 1 to 4 carbon atoms, R 5 represents a hydrogen or halogen atom or an alkyl group of 1 to 3 carbon atoms, and R 6 represents a hydrogen atom or a methyl group and the total number of carbon atoms in the substituent groups R 1 , R 2 , R 5 and R 6 on the phenyl ring does not exceed 8; X represents the group R 3 represents the group (wherein each of R<SP>1</SP>, R<SP>11</SP> and R<SP>111</SP> represents a hydrogen atom or a methyl or ethyl group); and R 4 represents an unsubstituted or halosubstituted furyl, tetrahydrofuryl, pyridyl, or pyrimidyl group; but excluding the compounds N - (1<SP>1</SP> - methoxycarbonylethyl) - N - (furan- (2<SP>11</SP>) - carbonyl) - 2,6 - dimethylaniline and N - (1<SP>1</SP> - methoxycarbonylethyl) - N - (furan- (2<SP>11</SP>) - carbonyl) - 2,3,6 - trimethylaniline) are used in fungicidal compositions. They may be prepared either by (a) acylating a compound of Formula (II) with a compound of formula or an acid halide, or anhydride thereof or by (b) reacting a compound of Formula IV with butyl lithium or sodium hydride to give the corresponding alkali metal salt and then reacting this salt with a compound of formula where Hal is a halogen atom. The enantiomeric D-form of the compounds of Formula (I) in which X = -CH(CH 3 )- may be prepared by reacting the racemic compound of Formula (VI) with a nitrogen-containing, optically active base to give the corresponding salt, followed by fractional crystallization and liberation of the acid of Formula VI which is enriched with the optical D-antipode. The D-form of the ester of Formula II may then be prepared in conventional manner from the D-form of the acid of Formula VI. The D-form of the amide of Formula II may be prepared by reacting the D-form of the acid with the amine of formula HN(R<SP>11</SP>)(R<SP>111</SP>). The D-form of the compound of Formula (I) may then be prepared as in step (a) above. The D-form of the compound of Formula VI may also be prepared by replacing the hydroxy group in the naturally occurring L(+) lactic acid by halogen and reacting this product further with the aniline of Formula VII with reversal of the configuration.
GB13349/75A 1974-04-02 1975-04-01 Fungicidal agents Expired GB1498199A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH457274A CH590608A5 (en) 1974-04-02 1974-04-02 N-Furoyl-N-aryl-alanine esters - prepd. e.g. by reacting N-aryl-alanine esters with 2-furoic acid or its derivs.
CH159175A CH603041A5 (en) 1974-04-02 1975-02-10 N-Furoyl-N-aryl-alanine esters

Publications (1)

Publication Number Publication Date
GB1498199A true GB1498199A (en) 1978-01-18

Family

ID=25688094

Family Applications (2)

Application Number Title Priority Date Filing Date
GB13349/75A Expired GB1498199A (en) 1974-04-02 1975-04-01 Fungicidal agents
GB1333275A Expired GB1448810A (en) 1974-04-02 1975-04-01 Fungicidal n-substituted furoic amide derivatives

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB1333275A Expired GB1448810A (en) 1974-04-02 1975-04-01 Fungicidal n-substituted furoic amide derivatives

Country Status (31)

Country Link
JP (3) JPS6042202B2 (en)
AR (2) AR205189A1 (en)
AT (2) AT345614B (en)
AU (1) AU465906B2 (en)
BG (2) BG24651A3 (en)
CA (2) CA1050558A (en)
CH (1) CH603041A5 (en)
CS (2) CS183788B2 (en)
DD (3) DD118510A5 (en)
DE (2) DE2513732A1 (en)
DK (2) DK141995B (en)
EG (2) EG11640A (en)
ES (2) ES436174A1 (en)
FI (2) FI750921A7 (en)
FR (2) FR2265747B1 (en)
GB (2) GB1498199A (en)
HU (2) HU173317B (en)
IE (2) IE41140B1 (en)
IL (2) IL46989A (en)
IT (2) IT1049394B (en)
LU (2) LU72175A1 (en)
NL (2) NL7503755A (en)
NO (2) NO141340C (en)
OA (2) OA04918A (en)
PH (2) PH11792A (en)
PL (2) PL98627B1 (en)
RO (3) RO73181A (en)
SE (2) SE418086B (en)
SU (4) SU682096A3 (en)
TR (2) TR18508A (en)
YU (2) YU39026B (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4291049A (en) 1978-02-02 1981-09-22 Montedison S.P.A. Acyl anilines exerting a fungicidal action
US4328236A (en) 1979-10-04 1982-05-04 Basf Aktiengesellschaft Isoxazolyl carboxanilides, and their use for combating fungi
EP0061836A3 (en) * 1981-03-19 1983-01-05 Imperial Chemical Industries Plc Amide derivatives, processes for preparing them, their use as fungicides and pesticidal compositions containing them
US8541342B2 (en) 2007-06-06 2013-09-24 Bayer Cropsciene Ag Fungicidal substance combinations
US8658564B2 (en) 2007-06-06 2014-02-25 Bayer Cropscience Ag Fungicide active ingredient combinations

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5845433B2 (en) * 1975-02-10 1983-10-08 チバ・ガイギ− アクチエンゲゼルシヤフト 2↓-Production method of furancarboxylic acid anilides
US4147792A (en) * 1977-02-04 1979-04-03 Ciba-Geigy Corporation Fungicidal compositions
CH629939A5 (en) * 1977-03-29 1982-05-28 Ciba Geigy Ag MICROBICIDAL AGENT.
DE2724785A1 (en) * 1977-05-27 1978-12-14 Schering Ag FURANCARBONIC ANILIDES, FUNGICIDALS CONTAINING THESE COMPOUNDS AND THE PROCESS FOR THEIR PREPARATION
CH637368A5 (en) * 1978-10-27 1983-07-29 Ciba Geigy Ag ANILINE DERIVATIVES AND Pesticides Manufactured From Them.
DE2961993D1 (en) * 1978-10-31 1982-03-11 Bayer Ag Substituted n-propargyl anilines, process for their preparation and their use as fungicides
CH641760A5 (en) * 1978-11-27 1984-03-15 Ciba Geigy Ag PEST CONTROL.
CH639940A5 (en) * 1978-12-05 1983-12-15 Ciba Geigy Ag Substituted N-alkoxycarbonylethyl-N-acylanilines, microbicides containing them, and process for the preparation of the compounds
DE2948734A1 (en) * 1978-12-07 1980-06-19 Ciba Geigy Ag PEST CONTROL
MA19111A1 (en) * 1979-10-26 1981-12-31 Ciba Geigy Ag HOMOSERIN DERIVATIVES, PROCESS FOR THEIR PREPARATION AND THEIR USE AS MICROBICIDES
DE3013908A1 (en) * 1980-04-11 1981-10-22 Basf Ag, 6700 Ludwigshafen 2- (N-ARYL-, N-ISOXAZOLYLCARBONYL) -AMINOBUTYROLACTONE, METHOD FOR THE PRODUCTION THEREOF AND FUNGICIDES CONTAINING THEM
MA19215A1 (en) * 1980-07-25 1982-04-01 Ciba Geigy Ag NOVEL ARYLAMINE DERIVATIVES, PROCESS FOR THEIR MANUFACTURE AND USE AS MICROBICIDES.
DE3030736A1 (en) 1980-08-14 1982-03-25 Basf Ag, 6700 Ludwigshafen N-DISUBSTITUTED ANILINE DERIVATIVES, THEIR PRODUCTION, THEIR USE AS MICROBICIDES AND AGENTS THEREFOR
DE3133418A1 (en) * 1981-08-24 1983-03-10 Basf Ag, 6700 Ludwigshafen THIAZOLYL AND ISOTHIAZOLYLCARBONIC ACID ANILIDES, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE AS FUNGICIDES
JPH0326906U (en) * 1989-07-26 1991-03-19
DE4011172A1 (en) * 1990-04-06 1991-10-10 Degussa COMPOUNDS FOR CONTROLLING PLANT DISEASES
DE4304172A1 (en) 1993-02-12 1994-08-25 Bayer Ag Fungicidal active ingredient combinations
US5723491A (en) * 1994-07-11 1998-03-03 Novartis Corporation Fungicidal composition and method of controlling fungus infestation
DE4429014A1 (en) 1994-08-16 1996-02-22 Basf Ag Process for the preparation of cyclic amines
PE32799A1 (en) 1996-12-25 1999-04-09 Agrogene Ltd NEW DERIVATIVE OF AMINOBUTIRIC ACID FOR THE PROTECTION OF FUNGAL DISEASES
DE10347090A1 (en) 2003-10-10 2005-05-04 Bayer Cropscience Ag Synergistic fungicidal drug combinations
DE10349501A1 (en) 2003-10-23 2005-05-25 Bayer Cropscience Ag Synergistic fungicidal drug combinations
DE102004049761A1 (en) 2004-10-12 2006-04-13 Bayer Cropscience Ag Fungicidal drug combinations
ATE484194T1 (en) 2005-06-09 2010-10-15 Bayer Cropscience Ag ACTIVE INGREDIENTS COMBINATIONS
DE102005026482A1 (en) 2005-06-09 2006-12-14 Bayer Cropscience Ag Active substance combination, useful e.g. for combating unwanted phytopathogenic fungus, comprises herbicides e.g. glyphosate and active substances e.g. strobilurin, triazoles, valinamide and carboxamide
DE102006023263A1 (en) 2006-05-18 2007-11-22 Bayer Cropscience Ag Synergistic drug combinations
EP2489265A3 (en) 2006-09-18 2012-10-24 Basf Se Pesticidal mixtures comprising an anthranilamide insecticide and a fungicide
KR20090108734A (en) 2007-02-06 2009-10-16 바스프 에스이 Insecticide mixture
RU2339635C1 (en) * 2007-06-26 2008-11-27 Государственное образовательное учреждение высшего профессионального образования "Российский химико-технологический университет им. Д.И. Менделеева "(РХТУ им. Д.И. Менделеева) Pyridylmethylanilides of heterocyclic acids, possessing fungicidal activity
DE102007045920B4 (en) 2007-09-26 2018-07-05 Bayer Intellectual Property Gmbh Synergistic drug combinations
AU2010272872B2 (en) 2009-07-16 2014-08-28 Bayer Intellectual Property Gmbh Synergistic active substance combinations containing phenyl triazoles
EP2910126A1 (en) 2015-05-05 2015-08-26 Bayer CropScience AG Active compound combinations having insecticidal properties
CN115557887B (en) * 2022-11-10 2024-11-01 南京林业大学 Ugi reaction-based synthesis of trifluoromethyl pyridine derivative and biological activity research thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3959481A (en) * 1969-02-13 1976-05-25 Uniroyal Method of protecting plants from fungal diseases using furan-3-carboxamide derivatives
JPS5345364A (en) * 1976-10-06 1978-04-24 Daiahoiru Kk Device for controlling extrusion molding die bolt

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4291049A (en) 1978-02-02 1981-09-22 Montedison S.P.A. Acyl anilines exerting a fungicidal action
US4328236A (en) 1979-10-04 1982-05-04 Basf Aktiengesellschaft Isoxazolyl carboxanilides, and their use for combating fungi
EP0061836A3 (en) * 1981-03-19 1983-01-05 Imperial Chemical Industries Plc Amide derivatives, processes for preparing them, their use as fungicides and pesticidal compositions containing them
US4432784A (en) * 1981-03-19 1984-02-21 Imperial Chemical Industries Plc Biologically active heterocyclic compounds
US4506084A (en) * 1981-03-19 1985-03-19 Imperial Chemical Industries Plc Aminonitrile intermediates
US8541342B2 (en) 2007-06-06 2013-09-24 Bayer Cropsciene Ag Fungicidal substance combinations
US8658564B2 (en) 2007-06-06 2014-02-25 Bayer Cropscience Ag Fungicide active ingredient combinations

Also Published As

Publication number Publication date
YU82875A (en) 1982-05-31
ATA244675A (en) 1978-01-15
DK135875A (en) 1975-10-03
FR2265748A1 (en) 1975-10-24
OA04918A (en) 1980-10-31
SU743561A3 (en) 1980-06-25
SU628812A3 (en) 1978-10-15
DE2513732C2 (en) 1988-04-14
FI63567C (en) 1983-07-11
IL46988A (en) 1977-12-30
SE419218B (en) 1981-07-20
AU7964075A (en) 1975-10-09
IE41777B1 (en) 1980-03-26
DK141168B (en) 1980-01-28
YU39026B (en) 1984-02-29
FI63567B (en) 1983-03-31
FR2265747A1 (en) 1975-10-24
IT1049394B (en) 1981-01-20
NL160821B (en) 1979-07-16
IE41140L (en) 1975-10-02
NO142714B (en) 1980-06-23
NO141340B (en) 1979-11-12
LU72175A1 (en) 1977-02-01
RO84021A (en) 1984-05-12
LU72174A1 (en) 1976-03-02
CS183789B2 (en) 1978-07-31
JPS50135226A (en) 1975-10-27
FR2265748B1 (en) 1978-02-03
DK135975A (en) 1975-10-03
PH13072A (en) 1979-11-23
CS183788B2 (en) 1978-07-31
CA1050558A (en) 1979-03-13
NO142714C (en) 1980-10-01
SU626690A3 (en) 1978-09-30
YU82775A (en) 1982-08-31
IE41777L (en) 1975-10-02
DE2560591C2 (en) 1989-06-08
EG12263A (en) 1978-12-31
OA04916A (en) 1980-10-31
AR205189A1 (en) 1976-04-12
ATA244875A (en) 1977-09-15
FR2265747B1 (en) 1977-04-15
ES436174A1 (en) 1977-04-16
JPS6042202B2 (en) 1985-09-20
NL7503754A (en) 1975-10-06
GB1448810A (en) 1976-09-08
NO751084L (en) 1975-10-03
JPS50135225A (en) 1975-10-27
RO84021B (en) 1984-06-30
IL46989A0 (en) 1975-06-25
TR18339A (en) 1977-05-10
NO751086L (en) 1975-10-03
SE7503518L (en) 1975-10-03
DE2513732A1 (en) 1975-10-16
FI750921A7 (en) 1975-10-03
HU172935B (en) 1979-01-28
AT345614B (en) 1978-09-25
CH603041A5 (en) 1978-08-15
DK141995B (en) 1980-08-04
DK141995C (en) 1980-12-15
DE2513788B2 (en) 1977-06-30
RO79677A (en) 1982-08-17
SU682096A3 (en) 1979-08-25
AR224602A1 (en) 1981-12-30
PL97786B1 (en) 1978-03-30
DE2513788A1 (en) 1975-10-09
CA1050546A (en) 1979-03-13
TR18508A (en) 1977-03-04
AU7964175A (en) 1976-09-30
DD124733A5 (en) 1977-03-09
HU173317B (en) 1979-04-28
DK141168C (en) 1980-07-14
DD118785A5 (en) 1976-03-20
DD118510A5 (en) 1976-03-12
EG11640A (en) 1977-10-31
ES436175A1 (en) 1977-04-16
YU40259B (en) 1985-12-31
JPS5345364B2 (en) 1978-12-06
IL46989A (en) 1978-06-15
PH11792A (en) 1978-07-05
JPS53135964A (en) 1978-11-28
BG24651A3 (en) 1978-04-12
RO73181A (en) 1982-10-11
NO141340C (en) 1980-02-20
FI750920A7 (en) 1975-10-03
BG26356A3 (en) 1979-03-15
PL98627B1 (en) 1978-05-31
SE7503517L (en) 1975-10-03
AT343407B (en) 1978-05-26
SE418086B (en) 1981-05-04
IL46988A0 (en) 1975-06-25
NL160821C (en) 1979-12-17
AU465906B2 (en) 1975-10-09
JPS5740829B2 (en) 1982-08-30
IT1048806B (en) 1980-12-20
NL7503755A (en) 1975-10-06
IE41140B1 (en) 1979-10-24

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PS Patent sealed [section 19, patents act 1949]
704A Declaration that licence is not available as of right for an excepted use (par. 4a/1977)
PCNP Patent ceased through non-payment of renewal fee