GB1305367A - - Google Patents
Info
- Publication number
- GB1305367A GB1305367A GB1952671*[A GB1952671A GB1305367A GB 1305367 A GB1305367 A GB 1305367A GB 1952671 A GB1952671 A GB 1952671A GB 1305367 A GB1305367 A GB 1305367A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acetic acid
- vinyl acetate
- mixture
- tray
- head
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 15
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 abstract 6
- 239000000203 mixture Substances 0.000 abstract 5
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 4
- 239000007788 liquid Substances 0.000 abstract 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- 238000004821 distillation Methods 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 150000002739 metals Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 238000010992 reflux Methods 0.000 abstract 1
- QEVHRUUCFGRFIF-MDEJGZGSSA-N reserpine Chemical compound O([C@H]1[C@@H]([C@H]([C@H]2C[C@@H]3C4=C(C5=CC=C(OC)C=C5N4)CCN3C[C@H]2C1)C(=O)OC)OC)C(=O)C1=CC(OC)=C(OC)C(OC)=C1 QEVHRUUCFGRFIF-MDEJGZGSSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1305367 Vinyl acetate SOC ITALIANA RESINE SpA 8 June 1971 [1 July 1970] 19526/71 Heading C2C In a method of separating vinyl acetate from mixtures with ethyl acetate the liquid mixture is supplied to a distillation column part way between the head and base and extractive liquid acetic acid is supplied part way between the liquid mixture introduction and the head, and the distillation is carried out with a ratio by weight of acetic acid to vinyl acetate of 5:1 to 20:1 and with a reflux ratio of 2 to 7:1, and the vinyl acetate is recovered at the top and acetic acid and ethyl acetate at the base. A column of between 15 to 50 theoretical trays may be used and the mixture introduced at between the fifth and thirtieth tray, and the acetic acid between the tenth and fortieth tray. The mixture treated may be that prepared by the oxidation of ethylene in acetic acid using palladium or other rare metals as catalyst.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2685070 | 1970-07-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1305367A true GB1305367A (en) | 1973-01-31 |
Family
ID=11220367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1952671*[A Expired GB1305367A (en) | 1970-07-01 | 1971-06-08 |
Country Status (5)
| Country | Link |
|---|---|
| CH (1) | CH542811A (en) |
| DE (1) | DE2132299A1 (en) |
| FR (1) | FR2098139A5 (en) |
| GB (1) | GB1305367A (en) |
| NL (1) | NL7108885A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022083396A1 (en) * | 2020-10-20 | 2022-04-28 | 天津大学 | Method for producing vinyl acetate |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4925533A (en) * | 1989-03-06 | 1990-05-15 | Lloyd Berg | Separation of vinyl acetate from ethyl acetate by extractive distillation with acids or acid amides |
| DE19825254C1 (en) * | 1998-06-05 | 1999-11-11 | Celanese Gmbh | Working up crude liquid vinyl acetate containing acetic acid, water and ethyl acetate |
-
1971
- 1971-06-08 GB GB1952671*[A patent/GB1305367A/en not_active Expired
- 1971-06-28 NL NL7108885A patent/NL7108885A/xx unknown
- 1971-06-29 DE DE19712132299 patent/DE2132299A1/en active Pending
- 1971-06-29 CH CH951271A patent/CH542811A/en not_active IP Right Cessation
- 1971-06-30 FR FR7123996A patent/FR2098139A5/fr not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022083396A1 (en) * | 2020-10-20 | 2022-04-28 | 天津大学 | Method for producing vinyl acetate |
| JP2023531171A (en) * | 2020-10-20 | 2023-07-21 | 天津大学 | Method for producing ethylene acetate |
| US11939286B2 (en) * | 2020-10-20 | 2024-03-26 | Tianjin University | Method for producing vinyl acetate |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2098139A5 (en) | 1972-03-03 |
| CH542811A (en) | 1973-10-15 |
| NL7108885A (en) | 1972-01-04 |
| DE2132299A1 (en) | 1972-01-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PLNP | Patent lapsed through nonpayment of renewal fees |