GB1284326A - Process for preparation of cresol and acetone from cymene hydroperoxide - Google Patents
Process for preparation of cresol and acetone from cymene hydroperoxideInfo
- Publication number
- GB1284326A GB1284326A GB2866270A GB2866270A GB1284326A GB 1284326 A GB1284326 A GB 1284326A GB 2866270 A GB2866270 A GB 2866270A GB 2866270 A GB2866270 A GB 2866270A GB 1284326 A GB1284326 A GB 1284326A
- Authority
- GB
- United Kingdom
- Prior art keywords
- cresol
- acetone
- cymene
- cymene hydroperoxide
- hydroperoxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
1284326 Acetone and cresol MITSUI PETROCHEMICAL INDUSTRIES Ltd 12 June 1970 [18 June 1969] 28662/70 Heading C2C Cresol and acetone are prepared from cymene hydroperoxide by subjecting a liquid oxidation product of cymene containing at least 50 weight per cent of cymene hydroperoxide to an acidcatalysed cleavage at a temperature of 60-90‹ C. until the concentration of cymene hydroperoxide in the liquid is 0À5-5 weight per cent neutralizing the incompletely cleaved product with a base to stop the acid catalysed cleavage, thermally decomposing the cymene hydroperoxide remaining in the oil phase of the neutralized product and recovering cresol and acetone from the products of the thermal decomposition.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4757769A JPS4945854B1 (en) | 1969-06-18 | 1969-06-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1284326A true GB1284326A (en) | 1972-08-09 |
Family
ID=12779085
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB2866270A Expired GB1284326A (en) | 1969-06-18 | 1970-06-12 | Process for preparation of cresol and acetone from cymene hydroperoxide |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS4945854B1 (en) |
| BE (1) | BE752189A (en) |
| DE (1) | DE2029706C3 (en) |
| FR (1) | FR2052765A5 (en) |
| GB (1) | GB1284326A (en) |
| NL (1) | NL144918B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0077749A1 (en) * | 1981-10-21 | 1983-04-27 | The Goodyear Tire & Rubber Company | Process for preparing a methyl phenol |
| EP0796833A3 (en) * | 1996-03-20 | 1998-04-01 | Rütgers Kureha Solvents GmbH | Process for the preparation of hydroxyaromatics |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5257130A (en) * | 1975-11-04 | 1977-05-11 | Mitsubishi Gas Chem Co Inc | Process for preparation of methylphenols |
| CA2127375A1 (en) * | 1992-11-05 | 1994-05-11 | Shintaro Araki | Process for producing aromatic hydroxylic compound |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB673576A (en) * | 1949-08-23 | 1952-06-11 | Allied Chem & Dye Corp | Decomposition of aralkyl alpha hydroperoxides |
| GB684039A (en) * | 1949-12-30 | 1952-12-10 | Distillers Co Yeast Ltd | Phenol production |
| GB754053A (en) * | 1953-07-30 | 1956-08-01 | Stamicarbon | Splitting up of hydroperoxides of aromatic hydrocarbons by means of an acid catalyst |
-
1969
- 1969-06-18 JP JP4757769A patent/JPS4945854B1/ja active Pending
-
1970
- 1970-06-12 GB GB2866270A patent/GB1284326A/en not_active Expired
- 1970-06-16 DE DE19702029706 patent/DE2029706C3/en not_active Expired
- 1970-06-18 NL NL7008931A patent/NL144918B/en not_active IP Right Cessation
- 1970-06-18 BE BE752189D patent/BE752189A/en unknown
- 1970-06-18 FR FR7022442A patent/FR2052765A5/fr not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0077749A1 (en) * | 1981-10-21 | 1983-04-27 | The Goodyear Tire & Rubber Company | Process for preparing a methyl phenol |
| EP0796833A3 (en) * | 1996-03-20 | 1998-04-01 | Rütgers Kureha Solvents GmbH | Process for the preparation of hydroxyaromatics |
| US6107527A (en) * | 1996-03-20 | 2000-08-22 | Rutgers Kureha Solvents Gmbh | Process for the production of hydroxy-aromatic substances |
Also Published As
| Publication number | Publication date |
|---|---|
| DE2029706A1 (en) | 1971-02-11 |
| DE2029706C3 (en) | 1978-06-22 |
| BE752189A (en) | 1970-12-01 |
| NL7008931A (en) | 1970-12-22 |
| DE2029706B2 (en) | 1977-11-03 |
| JPS4945854B1 (en) | 1974-12-06 |
| NL144918B (en) | 1975-02-17 |
| FR2052765A5 (en) | 1971-04-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed | ||
| PCNP | Patent ceased through non-payment of renewal fee |