GB1066114A - Method of photonitrosation of cycloalkane - Google Patents
Method of photonitrosation of cycloalkaneInfo
- Publication number
- GB1066114A GB1066114A GB1706865A GB1706865A GB1066114A GB 1066114 A GB1066114 A GB 1066114A GB 1706865 A GB1706865 A GB 1706865A GB 1706865 A GB1706865 A GB 1706865A GB 1066114 A GB1066114 A GB 1066114A
- Authority
- GB
- United Kingdom
- Prior art keywords
- photonitrosation
- cycloalkane
- thalium
- cyclododecane
- cyclooctane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000001924 cycloalkanes Chemical class 0.000 title abstract 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 abstract 1
- 239000004157 Nitrosyl chloride Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- DDTBPAQBQHZRDW-UHFFFAOYSA-N cyclododecane Chemical compound C1CCCCCCCCCCC1 DDTBPAQBQHZRDW-UHFFFAOYSA-N 0.000 abstract 1
- WJTCGQSWYFHTAC-UHFFFAOYSA-N cyclooctane Chemical compound C1CCCCCCC1 WJTCGQSWYFHTAC-UHFFFAOYSA-N 0.000 abstract 1
- 239000004914 cyclooctane Substances 0.000 abstract 1
- VPCDQGACGWYTMC-UHFFFAOYSA-N nitrosyl chloride Chemical compound ClN=O VPCDQGACGWYTMC-UHFFFAOYSA-N 0.000 abstract 1
- 235000019392 nitrosyl chloride Nutrition 0.000 abstract 1
- 150000002923 oximes Chemical class 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J61/00—Gas-discharge or vapour-discharge lamps
- H01J61/02—Details
- H01J61/12—Selection of substances for gas fillings; Specified operating pressure or temperature
- H01J61/125—Selection of substances for gas fillings; Specified operating pressure or temperature having an halogenide as principal component
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/08—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
- B01J19/12—Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electromagnetic waves
- B01J19/122—Incoherent waves
- B01J19/123—Ultraviolet light
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Electromagnetism (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Cycloalkanone oximes are obtained by the photonitrosation of cycloalkanes, under irradiation of light from a thalium lamp, while maintaining the concentration of nitrosating agent in the reaction system at the equivalent of 0.15-0.8 weight per cent nitrosyl chloride. Specified starting materials are cyclohexane, cyclooctane and cyclododecane.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2456064 | 1964-05-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1066114A true GB1066114A (en) | 1967-04-19 |
Family
ID=12141527
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1706865A Expired GB1066114A (en) | 1964-05-01 | 1965-04-22 | Method of photonitrosation of cycloalkane |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE1493257A1 (en) |
| GB (1) | GB1066114A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140158522A1 (en) * | 2012-06-26 | 2014-06-12 | Toray Industries, Inc. | Method of producing cycloalkanone oxime |
-
1965
- 1965-04-22 GB GB1706865A patent/GB1066114A/en not_active Expired
- 1965-04-27 DE DE19651493257 patent/DE1493257A1/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20140158522A1 (en) * | 2012-06-26 | 2014-06-12 | Toray Industries, Inc. | Method of producing cycloalkanone oxime |
| US9181177B2 (en) * | 2012-06-26 | 2015-11-10 | Toray Industries, Inc. | Method of producing cycloalkanone oxime |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1493257A1 (en) | 1969-04-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR6354668D0 (en) | AN IMPROVEMENT IN THE PROCESS FOR CATALYTIC PREPARATION OF OLEFINICALLY Unsaturated NITRILLES FROM A MIXTURE CONTAINING OLEPHINE AMMONIUM AND OXYGEN CONTAINING OLEFINE AMMONIUM AND OXYGEN | |
| DK134515B (en) | Process for the preparation of 3-cyano-3,5,5-trimethylcyclohexanone from isophorone and hydrogen cyanide. | |
| GB1066114A (en) | Method of photonitrosation of cycloalkane | |
| GB1112837A (en) | Process for the preparation of cycloalkanols and mixtures of cycloalkanols and cycloalkanones | |
| GB1345481A (en) | Process and apparatus for the oximation of cycloalkanes simultaneous area measurement thereof | |
| GB1017242A (en) | Method of photonitrosation of cycloalkane | |
| AT318540B (en) | Circulation process for the production of cyclohexanone oxime and device for carrying out the process | |
| GB1022797A (en) | Process for the oxidation of cyclohexane | |
| GB964869A (en) | Improvements in the oxidation of cyclohexane | |
| CH430686A (en) | Process for the production of urea by synthesis from carbon dioxide and ammonia | |
| GB1073248A (en) | Oxime preparation | |
| GB1183109A (en) | Method of Photonitrosation of Cycloalkanes | |
| GB1015572A (en) | Cycloaliphatic oximes | |
| FR2094612A5 (en) | Photo-oximation of higher cycloalkanes - without using a solvent | |
| GB1122776A (en) | Preparation of ªÏ-laurolactam | |
| GB922364A (en) | Method of producing cycloalkanoneoxime hydrochlorides | |
| GB1189723A (en) | A Method of Preparing Cycloalkanoneoxime Hydrochlorides. | |
| GB1040122A (en) | Process for preparing monochloro-ªŠ-caprolactams | |
| CH444134A (en) | Process for the preparation of 2-hydroxy-2 ', 4,5-trimethylbenzophenone | |
| GB1323372A (en) | Method for removing esters from mixtures containing cyclohexanone and cyclohexanol | |
| GB939828A (en) | Photochemical method of producing cycloalkanoneoxime hydrochlorides | |
| GB1013709A (en) | Process for the production of rubber articles resistant to ozone, ozone-resistant rubber and an anti-ozonant agent | |
| DK114768B (en) | Process for the preparation of cyclohexanol and cyclohexanone by oxidation of cyclohexane. | |
| FR2100991A6 (en) | N-(1-ethyl-2-piperidylmethyl) propion anilide and prepn - with analge activity | |
| GB1085892A (en) | Oxidation of organic compounds with gases containing molecular oxygen |