ES484281A1 - Procedimiento para la produccion de una espuma de poliureta-no de celulas abiertas - Google Patents
Procedimiento para la produccion de una espuma de poliureta-no de celulas abiertasInfo
- Publication number
- ES484281A1 ES484281A1 ES484281A ES484281A ES484281A1 ES 484281 A1 ES484281 A1 ES 484281A1 ES 484281 A ES484281 A ES 484281A ES 484281 A ES484281 A ES 484281A ES 484281 A1 ES484281 A1 ES 484281A1
- Authority
- ES
- Spain
- Prior art keywords
- group
- polyurethane
- triol
- cooh
- substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920005830 Polyurethane Foam Polymers 0.000 title abstract 3
- 239000011496 polyurethane foam Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 abstract 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 3
- 125000001424 substituent group Chemical group 0.000 abstract 3
- 239000004604 Blowing Agent Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000006069 physical mixture Substances 0.000 abstract 2
- 239000005056 polyisocyanate Substances 0.000 abstract 2
- 229920001228 polyisocyanate Polymers 0.000 abstract 2
- 239000004814 polyurethane Substances 0.000 abstract 2
- 229920002635 polyurethane Polymers 0.000 abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Natural products C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 abstract 1
- JVVXZOOGOGPDRZ-SLFFLAALSA-N [(1R,4aS,10aR)-1,4a-dimethyl-7-propan-2-yl-2,3,4,9,10,10a-hexahydrophenanthren-1-yl]methanamine Chemical compound NC[C@]1(C)CCC[C@]2(C)C3=CC=C(C(C)C)C=C3CC[C@H]21 JVVXZOOGOGPDRZ-SLFFLAALSA-N 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Natural products C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 abstract 1
- 150000001454 anthracenes Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 238000009835 boiling Methods 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 abstract 1
- 125000001624 naphthyl group Chemical group 0.000 abstract 1
- 150000002987 phenanthrenes Chemical group 0.000 abstract 1
- 230000035939 shock Effects 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/2815—Monohydroxy compounds
- C08G18/282—Alkanols, cycloalkanols or arylalkanols including terpenealcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8003—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen
- C08G18/8006—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32
- C08G18/8009—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203
- C08G18/8012—Masked polyisocyanates masked with compounds having at least two groups containing active hydrogen with compounds of C08G18/32 with compounds of C08G18/3203 with diols
- C08G18/8019—Masked aromatic polyisocyanates
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
1. Procedimiento para la producción de una espuma de poliuretano de células abiertas, semiflexible, absorbedora de impactos y de energía, capaz de absorber repetidamente choques sin daños estructurales, caracterizado porque comprende las etapas de proporcionar una mezcla física de: (a) un polietertriol que tiene un índice de hidroxilo de 25 a 115, con (b) un compuesto modificador voluminoso que es soluble en dicho triol (a), sin reaccionar con dicho triol (a), que tiene un solo punto de hidrógeno reactivo, seleccionado del grupo consistente en: (i) naftaleno sustituido con un sustituyente del grupo consistente en -OH, -COOH, -NH2, Y -SH; (ii) antraceno sustituido con un sustituyente elegido del grupo consistente en -OH, -COOH, -NH2 y -SH; (iii) fenantreno sustituído con un sustituyente elegido del grupo consistente en -OH, -COOH, -NH2 y -SH; (iv) alcohol hidroabietílico; y (v) dehidroabietilamina; combinar entonces dicha mezcla física de (a) y (b) en estado sin reaccionar con: (c) un poliisocianato aromático; (d) al menos un agente expansionante elegido entre agua y agente expansionante de poliuretano líquido, orgánico, volátil, de bajo punto de ebullición; (e) al menos una sustancia que es un agente extendedor de cadena o reticulante de poliuretano que tiene al menos dos hidrógenos reactivos; y (f) un catalizador para la reacción de formación de poliuretano entre dicho triol (a) y dicho poliisocianato (c); con lo cual se forma una espuma de poliuretano capaz de distribuir cargas y que tiene unas características realzadas de absorción de impactos y energía en comparación con una espuma por otra parte similar pero de la cual se ha omitido el citado compuesto modificador (b).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA311,684A CA1111996A (en) | 1978-09-20 | 1978-09-20 | Semi-flexible shock-absorbing polyurethane foam |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES484281A1 true ES484281A1 (es) | 1980-05-16 |
Family
ID=4112394
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES484281A Expired ES484281A1 (es) | 1978-09-20 | 1979-09-19 | Procedimiento para la produccion de una espuma de poliureta-no de celulas abiertas |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US4209593A (es) |
| EP (1) | EP0010842B1 (es) |
| JP (1) | JPS5543197A (es) |
| AU (1) | AU528720B2 (es) |
| BR (1) | BR7905958A (es) |
| CA (1) | CA1111996A (es) |
| DE (1) | DE2966189D1 (es) |
| ES (1) | ES484281A1 (es) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62143642U (es) * | 1986-03-03 | 1987-09-10 | ||
| JPS62143644U (es) * | 1986-03-03 | 1987-09-10 | ||
| JPS62143643U (es) * | 1986-03-03 | 1987-09-10 | ||
| GB2191208A (en) * | 1986-06-05 | 1987-12-09 | Basf Corp | High resiliency molded polyurethane foams |
| US4722946A (en) * | 1986-07-03 | 1988-02-02 | Polymer Dynamics (Delaware), Ltd. | Energy-attenuating polyurethanes |
| US4788269A (en) * | 1987-12-04 | 1988-11-29 | W. R. Grace & Co.-Conn. | Polyurethane coatings for bridge deckings and the like |
| DE3901189A1 (de) * | 1989-01-17 | 1990-09-20 | Bayer Ag | Verfahren zur herstellung von polyurethan-weichformschaumstoffen niedriger rohdichte |
| US4950695A (en) * | 1989-03-06 | 1990-08-21 | Pmc, Inc. | Reduction of firmness in flexible polyurethane foam by addition of monofunctional alcohols, polyesters, and polyethers |
| US4950694A (en) * | 1989-06-29 | 1990-08-21 | Union Carbide Chemicals And Plastics Company Inc. | Preparation of polyurethane foams without using inert blowing agents |
| US5496911A (en) * | 1993-10-04 | 1996-03-05 | Ecp Enichem Polimeri Netherlands, B.V. | Process for the production of polyurea based articles |
| US5527833A (en) * | 1995-06-07 | 1996-06-18 | Woodbridge Foam Corp. | Process for producing a polyurethane foam |
| US6391935B1 (en) | 2000-01-31 | 2002-05-21 | Bayer Antwerp, N.V. | Viscoelastic polyurethane foams |
| US20040266900A1 (en) * | 2003-06-26 | 2004-12-30 | Raymond Neff | Viscoelastic polyurethane foam |
| US7208531B2 (en) * | 2003-06-26 | 2007-04-24 | Basf Corporation | Viscoelastic polyurethane foam |
| US7238730B2 (en) * | 2003-06-26 | 2007-07-03 | Basf Corporation | Viscoelastic polyurethane foam |
| US7078443B2 (en) * | 2003-10-22 | 2006-07-18 | Intellectual Property Holdings, Llc | Viscoelastic foam layer and composition |
| US20070105969A1 (en) * | 2005-11-10 | 2007-05-10 | Kenneth Warnshuis | Multi-density flexible foam |
| US20070105970A1 (en) * | 2005-11-10 | 2007-05-10 | Kenneth Warnshuis | Energy absorbing flexible foam |
| JP5398122B2 (ja) * | 2006-03-31 | 2014-01-29 | エスケー化研株式会社 | 高分子化合物からなる、乳濁液の安定剤 |
| JP5136750B2 (ja) * | 2007-06-11 | 2013-02-06 | 株式会社ブリヂストン | 断熱材組成物、ポリウレタン発泡断熱材及び断熱施工方法 |
| EP2543689B1 (en) | 2011-07-04 | 2016-08-10 | Repsol, S.A. | Continuous method for the synthesis of polyols |
| US8975335B2 (en) | 2011-09-23 | 2015-03-10 | Bayer Materialscience Llc | Process for the production of high air flow polyether foams and the foams produced by this process |
| EP2867281A1 (de) * | 2012-06-27 | 2015-05-06 | Bayer Materialscience AG | Dielektrischer polyurethan film |
| US9951174B2 (en) | 2015-05-20 | 2018-04-24 | Covestro Llc | Polyol compositions, a process for the production of these polyol compositions, and their use in the production of open celled polyurethane foams having high airflow |
| JP7162609B2 (ja) | 2017-03-15 | 2022-10-28 | コベストロ・エルエルシー | 温度感度が低減した改良粘弾性フォーム用ポリオール |
| US10766998B2 (en) | 2017-11-21 | 2020-09-08 | Covestro Llc | Flexible polyurethane foams |
| US10793692B2 (en) | 2018-10-24 | 2020-10-06 | Covestro Llc | Viscoelastic flexible foams comprising hydroxyl-terminated prepolymers |
| US11572433B2 (en) | 2021-03-12 | 2023-02-07 | Covestro Llc | In-situ formed polyols, a process for their preparation, foams prepared from these in-situ formed polyols and a process for their preparation |
| US11718705B2 (en) | 2021-07-28 | 2023-08-08 | Covestro Llc | In-situ formed polyether polyols, a process for their preparation, and a process for the preparation of polyurethane foams |
| WO2024153757A1 (en) | 2023-01-19 | 2024-07-25 | Repsol, S.A. | Controlled addition of ligand in polyol synthesis |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1143019B (de) * | 1961-04-29 | 1963-01-31 | Bayer Ag | Verfahren zur Herstellung von Urethangruppen aufweisenden Schaumstoffen |
| US3703482A (en) * | 1962-03-15 | 1972-11-21 | Johns Manville | Polyurethane foam |
| US3298857A (en) * | 1964-11-30 | 1967-01-17 | Hoover Ball & Bearing Co | Method of stiffening polyurethane foams |
| NL6600253A (es) * | 1966-01-10 | 1967-07-11 | ||
| CH547328A (de) * | 1967-07-20 | 1974-03-29 | Cincinnati Milling Machine Co | Verfahren zur herstellung eines zelligen, starren polyurethan-formkoerpers. |
| US3630819A (en) * | 1968-09-23 | 1971-12-28 | Goodyear Tire & Rubber | Foamed polyurethane laminates |
| US3836487A (en) * | 1968-09-23 | 1974-09-17 | Goodyear Tire & Rubber | High impact rigid self-skinned polyurethane foam and method |
| US3664976A (en) * | 1969-08-21 | 1972-05-23 | Uniroyal Ltd | Polyurethane foam with integral skin |
| US3677869A (en) * | 1970-11-27 | 1972-07-18 | Goodyear Tire & Rubber | Polyureaurethane shock absorbing compositions |
| US3833526A (en) * | 1971-05-27 | 1974-09-03 | Ici America Inc | Semi-rigid polyurethane foams from a mixture of oxypropylated polyols |
| CH554387A (de) * | 1971-12-18 | 1974-09-30 | Weber Wilhelm G | Verfahren zur herstellung von poroesen stoffen. |
| US3823833A (en) * | 1973-08-08 | 1974-07-16 | Goodyear Tire & Rubber | Polyureaurethane shock absorbing unit |
| US3847859A (en) * | 1973-08-29 | 1974-11-12 | Dow Chemical Co | Rapid-setting polyurethanes containing substituted hydroxyl-containing aromatic compounds as modifiers |
-
1978
- 1978-09-20 CA CA311,684A patent/CA1111996A/en not_active Expired
- 1978-11-15 US US05/960,994 patent/US4209593A/en not_active Expired - Lifetime
-
1979
- 1979-09-03 EP EP79301810A patent/EP0010842B1/en not_active Expired
- 1979-09-03 DE DE7979301810T patent/DE2966189D1/de not_active Expired
- 1979-09-11 AU AU50721/79A patent/AU528720B2/en not_active Ceased
- 1979-09-18 BR BR7905958A patent/BR7905958A/pt unknown
- 1979-09-19 JP JP12060379A patent/JPS5543197A/ja active Granted
- 1979-09-19 ES ES484281A patent/ES484281A1/es not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2966189D1 (en) | 1983-10-27 |
| BR7905958A (pt) | 1980-06-03 |
| JPS579734B2 (es) | 1982-02-23 |
| CA1111996A (en) | 1981-11-03 |
| AU5072179A (en) | 1980-03-27 |
| AU528720B2 (en) | 1983-05-12 |
| EP0010842A1 (en) | 1980-05-14 |
| JPS5543197A (en) | 1980-03-26 |
| US4209593A (en) | 1980-06-24 |
| EP0010842B1 (en) | 1983-09-21 |
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