ES378736A1 - Polymerization process - Google Patents
Polymerization processInfo
- Publication number
- ES378736A1 ES378736A1 ES378736A ES378736A ES378736A1 ES 378736 A1 ES378736 A1 ES 378736A1 ES 378736 A ES378736 A ES 378736A ES 378736 A ES378736 A ES 378736A ES 378736 A1 ES378736 A1 ES 378736A1
- Authority
- ES
- Spain
- Prior art keywords
- acrylate
- methacrylate
- methyl
- monomer
- stearyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006116 polymerization reaction Methods 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 5
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 3
- JTHZUSWLNCPZLX-UHFFFAOYSA-N 6-fluoro-3-methyl-2h-indazole Chemical compound FC1=CC=C2C(C)=NNC2=C1 JTHZUSWLNCPZLX-UHFFFAOYSA-N 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract 2
- 229920001577 copolymer Polymers 0.000 abstract 2
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 abstract 2
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 abstract 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 abstract 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 abstract 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 abstract 1
- 125000005250 alkyl acrylate group Chemical group 0.000 abstract 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 abstract 1
- 229920001038 ethylene copolymer Polymers 0.000 abstract 1
- 239000011953 free-radical catalyst Substances 0.000 abstract 1
- MCVVUJPXSBQTRZ-ONEGZZNKSA-N methyl (e)-but-2-enoate Chemical compound COC(=O)\C=C\C MCVVUJPXSBQTRZ-ONEGZZNKSA-N 0.000 abstract 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07K—PEPTIDES
- C07K1/00—General methods for the preparation of peptides, i.e. processes for the organic chemical preparation of peptides or proteins of any length
- C07K1/06—General methods for the preparation of peptides, i.e. processes for the organic chemical preparation of peptides or proteins of any length using protecting groups or activating agents
- C07K1/061—General methods for the preparation of peptides, i.e. processes for the organic chemical preparation of peptides or proteins of any length using protecting groups or activating agents using protecting groups
- C07K1/063—General methods for the preparation of peptides, i.e. processes for the organic chemical preparation of peptides or proteins of any length using protecting groups or activating agents using protecting groups for alpha-amino functions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Biochemistry (AREA)
- Biophysics (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Proteomics, Peptides & Aminoacids (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A monomer comprising (a) at least 50% by weight of methyl methacrylate, (b) up to 50% of an alkyl acrylate or vinyl acetate and (c) up to 20% of another comonomer is polymerized in the presence of a copolymer of (1) 50 to 95% by weight of ethylene, (2) 50 to 5% of vinyl acetate, aC 1 to C 18 -alkyl acrylate or methacrylate, acrylic acid or methacrylic acid and (3) up to 20% of another comonomer and a free radical catalyst and in the absence of water, the polymerizatiori being carried out in two stages, in the second of which additional catalyst and monomer are added. In one embodiment, the ethylene copolymer is cross-linked prior to the interpolymerization and in another embodiment the interpolymer produced is cross-linked. In examples, monomer (b) is ,selected from ethyl acrylate, vinyl acetate, stearyl acrylate, n-butyl acrylate, t-butyl acrylate and methyl acrylate, optional monomer (c) is selected from acrylic acid, stearyl methacrylate and acrylonitrile and the copolymer is of (1) ethylene, (2) vinyl acetate, stearyl methacrylate, acrylic acid, methacrylic acid, lauryl methacrylate, butyl acrylate, stearyl acrylate, methyl methacrylate, ethyl acrylate, . methyl acrylate, stearyl acrylate and (3) optional monomer acrylonitrile, vinyl chloride, alpha-methyl styrene, acrylamide, vinylidene chloride or methyl crotonate.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US81715669A | 1969-04-17 | 1969-04-17 | |
| US81715769A | 1969-04-17 | 1969-04-17 | |
| US81715869A | 1969-04-17 | 1969-04-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES378736A1 true ES378736A1 (en) | 1973-02-01 |
Family
ID=27420116
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES378736A Expired ES378736A1 (en) | 1969-04-17 | 1970-04-17 | Polymerization process |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS4919712B1 (en) |
| DE (1) | DE2018607C3 (en) |
| ES (1) | ES378736A1 (en) |
| FR (1) | FR2045365A5 (en) |
| GB (1) | GB1254267A (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5182415U (en) * | 1974-12-24 | 1976-07-01 | ||
| JPS51141524U (en) * | 1975-05-07 | 1976-11-15 | ||
| JPS52147415U (en) * | 1976-05-06 | 1977-11-08 | ||
| JPS5357918U (en) * | 1976-10-20 | 1978-05-17 | ||
| DE3834637A1 (en) * | 1988-10-11 | 1990-04-12 | Alkor Gmbh | METHOD AND DEVICE FOR PRODUCING MOLDED PARTS OR ITEMS USING AN EXTRUSION MOLDING METHOD |
| JP6007789B2 (en) | 2011-05-10 | 2016-10-12 | 三菱レイヨン株式会社 | Acrylic resin composition, acrylic resin sheet, acrylic resin laminate, and production method thereof |
| WO2014073385A1 (en) * | 2012-11-06 | 2014-05-15 | 三菱レイヨン株式会社 | Method for producing (meth)acrylic resin composition, method for producing (meth)acrylic resin molded body, (meth)acrylic resin molded body, front surface plate for liquid crystal display device, and touch panel |
| JP6470983B2 (en) * | 2014-01-24 | 2019-02-13 | 三井・デュポンポリケミカル株式会社 | Methacrylic resin composition and molded body |
-
1970
- 1970-03-09 GB GB1122770A patent/GB1254267A/en not_active Expired
- 1970-04-16 FR FR7013848A patent/FR2045365A5/fr not_active Expired
- 1970-04-17 ES ES378736A patent/ES378736A1/en not_active Expired
- 1970-04-17 JP JP3239570A patent/JPS4919712B1/ja active Pending
- 1970-04-17 DE DE19702018607 patent/DE2018607C3/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2018607C3 (en) | 1980-10-30 |
| DE2018607B2 (en) | 1980-02-28 |
| GB1254267A (en) | 1971-11-17 |
| FR2045365A5 (en) | 1971-02-26 |
| DE2018607A1 (en) | 1970-10-29 |
| JPS4919712B1 (en) | 1974-05-20 |
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