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EP3038711A1 - Produits en distributeur pour modifier la couleur de fibres de kératine par oxydation - Google Patents

Produits en distributeur pour modifier la couleur de fibres de kératine par oxydation

Info

Publication number
EP3038711A1
EP3038711A1 EP14793008.5A EP14793008A EP3038711A1 EP 3038711 A1 EP3038711 A1 EP 3038711A1 EP 14793008 A EP14793008 A EP 14793008A EP 3038711 A1 EP3038711 A1 EP 3038711A1
Authority
EP
European Patent Office
Prior art keywords
weight
preparation
total amount
acid
surfactants
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP14793008.5A
Other languages
German (de)
English (en)
Inventor
Burkhard Müller
Norbert Schettiger
Constanze Neuba
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Publication of EP3038711A1 publication Critical patent/EP3038711A1/fr
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/22—Peroxides; Oxygen; Ozone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60—Sugars; Derivatives thereof
    • A61K8/602—Glycosides, e.g. rutin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/08—Preparations for bleaching the hair
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D35/00—Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor
    • B65D35/22—Pliable tubular containers adapted to be permanently or temporarily deformed to expel contents, e.g. collapsible tubes for toothpaste or other plastic or semi-liquid material; Holders therefor with two or more compartments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/32—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents for packaging two or more different materials which must be maintained separate prior to use in admixture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D83/00—Containers or packages with special means for dispensing contents
    • B65D83/14—Containers for dispensing liquid or semi-liquid contents by internal gaseous pressure, i.e. aerosol containers comprising propellant
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/48—Thickener, Thickening system
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/87—Application Devices; Containers; Packaging
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88—Two- or multipart kits
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/88—Two- or multipart kits
    • A61K2800/882—Mixing prior to application

Definitions

  • the present invention relates to a product for coloring and / or lightening keratinic fibers, comprising a dispenser with two separate chambers, wherein the chambers have a common outlet opening.
  • a dispenser with two separate chambers, wherein the chambers have a common outlet opening.
  • Each of the two chambers each contain a preparation with a specific viscosity, and the viscosities of the two preparations are precisely matched.
  • the hair color can be changed temporarily.
  • already formed dyes diffuse from the colorant into the hair fiber.
  • the dyeing with substantive dyes is associated with little hair damage, but a disadvantage is the low durability and fast washability of the dyes obtained with substantive dyes.
  • Oxidative color-change agents are commonly used.
  • oxidation colorants are used for permanent, intensive colorations with corresponding fastness properties.
  • Such colorants usually contain oxidation dye precursors, so-called developer components and coupler components which, under the influence of oxidants, usually hydrogen peroxide, form the actual dyes with one another. Oxidation dyes are characterized by excellent, long-lasting staining results.
  • the mere whitening or bleaching of hair is often done by using one or more oxidizing agents without the addition of oxidation dye precursors.
  • the oxidizing agent used here is usually hydrogen peroxide.
  • Oxidative color-changing agents are usually marketed in the form of two-component compositions in which the two components are packaged separately in two separate containers and must be mixed together shortly before use.
  • the first component is usually an alkaline formulation which is often in the form of a cream or gel and which, if used concurrently with the Brightening also a color change is desired, in addition also contains the oxidation dye precursors.
  • This first component is provided in most cases in a tube, more rarely in a plastic or glass container.
  • the second component is a - usually acidified for reasons of stability - formulation containing hydrogen peroxide in concentrations of 3 to 12 wt .-% as the oxidizing agent.
  • the oxidizing agent formulation is usually in the form of an emulsion or dispersion and is usually provided in a plastic bottle with a reclosable outlet opening (developer bottle).
  • the consumer To prepare the ready-mix, the consumer must mix both components together shortly before use.
  • the alkaline cream or gel component from the tube or the glass or plastic container is usually transferred completely into the developer bottle, then both components are mixed as completely and homogeneously as possible by shaking and finally removed via an outlet opening in the head of the developer bottle.
  • multichamber containers having a common outlet opening have been developed in which the two components are mixed in the dispensing device of the dispenser during the exit.
  • the removal of the application mixture via the dispenser eliminates the need for mixing of the components by the consumer and has significantly increased the ease of use.
  • a first object of the invention is a product for oxidative coloring and / or lightening of keratinic fibers, comprising
  • the ratio of the viscosities V1 / V2 is at a value of 0.3 to 3.0.
  • Keratinic fibers, keratin-containing fibers or keratin fibers are understood to mean furs, wool, feathers and, in particular, human hair.
  • products according to the invention are primarily suitable for lightening and dyeing keratin fibers, in principle, there is nothing to prevent their use in other fields as well.
  • the preparations (a) and (b) in the chambers (A) and (B) are each based on an aqueous cosmetic carrier, for example in a suitable aqueous, alcoholic or aqueous-alcoholic carrier.
  • a suitable aqueous, alcoholic or aqueous-alcoholic carrier may be, for example, creams, emulsions, gels or surfactant-containing foaming solutions such as, for example, shampoos, foam aerosols, foam formulations or other preparations which are suitable for use on the hair.
  • preparations (a) and / or (b) are creams or emulsions.
  • the feature of the product essential to the invention is the precisely matched viscosity of the preparations (a) and (b).
  • the viscosity is a measure of the viscosity of a fluid.
  • the term fluids includes, for example, solutions, emulsions, gels or creams.
  • viscosity means the dynamic viscosity which is stated in the unit mPas.
  • the measurement of the viscosity is preferably carried out with a Brookfield viscometer (22 ° C / Brookfield viscometer / spindle 5/4 rpm).
  • the preparation (a), which is located in the chamber (A) of the dispenser, has a viscosity of 1000 to 100,000 mPas (22 ° C / Brookfield viscometer / spindle 5/4 rpm).
  • the preparation (b), which is located in the chamber (B) of the dispenser has a viscosity V2 of 1000 to 100 000 mPas (22 ° C / Brookfield viscometer / spindle 5/4 rpm).
  • an essential feature of the invention is that the ratio of the viscosities V1 / V2 is at a value of 0.3 to 3.0.
  • composition of the application mixture ((a) + (b)) remains particularly constant, especially when the viscosities V1 and V2 are set to very specific ranges.
  • a product for oxidative dyeing and / or lightening of keratinic fibers is characterized in that
  • the preparation (a) has a viscosity of from 2000 to 80,000 mPas, preferably from 4000 to 60,000 mPas, more preferably from 7,000 to 40,000 mPas, even more preferably from 8,000 to 35,000 mPas and particularly preferably from 10,000 to 30,000 mPas owns
  • the preparation (b) has a viscosity of from 2000 to 80,000 mPas, preferably from 4000 to 60,000 mPas, more preferably from 7000 to 40,000 mPas, even more preferably from 8000 to 35,000 mPas and particularly preferably from 10,000 to 30,000 mPas owns
  • Preferred is a product for oxidative staining and / or brightening of keratinic fibers, comprising
  • a product for oxidative staining and / or brightening of keratinic fibers comprising
  • the ratio of the viscosities V1 / V2 is at a value of 0.3 to 3.0.
  • Preferred is a product for oxidative staining and / or brightening of keratinic fibers, comprising
  • the ratio of the viscosities V1 / V2 is at a value of 0.3 to 3.0.
  • the ratio of the viscosities V1 / V2 is at a value of 0.3 to 3.0.
  • Very particular preference is given to a product for oxidative dyeing and / or brightening of keratinic fibers
  • the ratio of the viscosities V1 / V2 is at a value of 0.3 to 3.0.
  • a product for oxidative dyeing and / or lightening of keratinic fibers is characterized in that
  • the preparation (a) has a viscosity of from 1000 to 100,000 mPas, preferably from 2000 to 80,000 mPas, more preferably from 4,000 to 60,000 mPas, even more preferably from 7,000 to 50,000 mPas and particularly preferably from 10,000 to 45,000 mPas owns
  • the preparation (b) has a viscosity of from 2000 to 80,000 mPas, preferably from 4000 to 60,000 mPas, more preferably from 7000 to 40,000 mPas, even more preferably from 8000 to 35,000 mPas and particularly preferably from 10,000 to 30,000 mPas owns
  • a product for oxidative dyeing and / or brightening of keratinic fibers characterized in that the ratio of the viscosities V1 / V2 at a value of 0.5 to 2.0, preferably from 0.6 to 1.8, more preferably from 0.7 to 1.6, even more preferably from 0.8 to 1, 2 and more preferably from 0.9 to 1.1.
  • Preferred is a product for oxidative staining and / or brightening of keratinic fibers, comprising
  • the ratio of the viscosities V1 / V2 is at a value of 0.5 to 2.0.
  • Preferred is a product for oxidative staining and / or brightening of keratinic fibers, comprising
  • the ratio of the viscosities V1 / V2 is at a value of 0.5 to 2.0.
  • Preferred is a product for oxidative staining and / or brightening of keratinic fibers, comprising
  • the ratio of the viscosities V1 / V2 is at a value of 0.6 to 1.8.
  • Very particular preference is given to a product for oxidative dyeing and / or brightening of keratinic fibers
  • the ratio of the viscosities V1 / V2 is at a value of 0.7 to 1.6.
  • the ratio of the viscosities V1 / V2 is at a value of 0.8 to 1.2.
  • the ratio of the viscosities V1 / V2 is at a value of 0.9 to 1, 1.
  • Very particular preference is given to a product for oxidative dyeing and / or brightening of keratinic fibers
  • the ratio of the viscosities V1 / V2 is at a value of 0.7 to 1.6.
  • the flow behavior of cosmetic formulations can be influenced, for example, by the addition of bodying agents, thickeners and / or emulsifiers.
  • the application mixture is prepared from two components containing various reactive ingredients (preparation (a): oxidation dye precursors, preparation (b): hydrogen peroxide) and which differ widely both in their other ingredients and in their consistency.
  • preparation (a) is usually alkaline and has a higher viscosity
  • the preparation (b) contains the oxidizing agent, is acidic and in most cases has a lower viscosity.
  • a product for oxidative dyeing and / or brightening of keratinic fibers characterized in that at least 70 wt .-%, preferably at least 80 wt .-%, more preferably at least 85 wt .-% and most especially preferably at least 90% by weight of the ingredients contained in preparations (a) and (b) are the same.
  • Preparations (a) and (b) contain the same substances or the same raw materials.
  • the ratio of the viscosities V1 / V2 is at a value of 0.3 to 3.0 and
  • ingredients which are identical in the preparations (a) and (b) may in particular be fatty constituents, thickening polymers, anionic surfactants, cationic surfactants, zwitterionic or amphoteric surfactants, nonionic surfactants, silicones, solvents and / or water act.
  • a product for oxidative dyeing and / or brightening of keratinic fibers wherein the preparation (a) - in each case based on their total weight -
  • one or more fat constituents in a total amount by weight (G1a) and / or
  • thickening polymers in a total amount by weight (G2a) and / or
  • one or more cationic surfactants in a total amount by weight (G3a) and / or
  • anionic surfactants in a total amount by weight (G4a) and / or
  • nonionic surfactants in a total amount by weight (G5a) and / or
  • one or more fat constituents in a total amount by weight (Gi b) and / or
  • one or more thickening polymers in a total amount by weight (G2b) and / or
  • one or more cationic surfactants in a total amount by weight (G3b) and / or
  • anionic surfactants in a total amount by weight (G4b) and / or
  • nonionic surfactants in a total amount by weight (G5b) and / or
  • the total weight amounts (G1a), (G2a), (G3a), (G4a), (G5a), (G6a), (Gib) are each given in weight percent, the reference base being the total weight of the preparation (a).
  • fatty constituents are organic compounds having a solubility in water at room temperature (22 ° C.) and atmospheric pressure (760 mmHg) of less than 1% by weight, preferably less than 0.1% by weight.
  • the definition of fat constituents explicitly includes only uncharged (ie nonionic) compounds
  • Fat constituents have at least one saturated or unsaturated alkyl group having at least 8 carbon atoms
  • the molecular weight of the fat constituents is at most 5000 g / mol, preferably at most 2500 g / mol and more preferably at a maximum of 1000 g / mol.
  • the fat constituents are neither polyoxyalkylated nor polyglycerylated compounds.
  • preferred constituents of the fat are understood as meaning the constituents from the group of C.sub.2-C.sub.33-fatty alcohols, C.sub.12-C.sub.3o-fatty acid triglycerides, C.sub.12-C.sub.3o-fatty acid monoglycerides, C.sub.12-C.sub.3o-fatty acid diglycerides and / or hydrocarbons.
  • nonionic substances are explicitly considered as fat constituents.
  • Charged compounds such as fatty acids and their salts are not understood as a fat ingredient.
  • the Ci2-C3o-fatty alcohols may be saturated, mono- or polyunsaturated, linear or branched fatty alcohols having 12 to 30 carbon atoms.
  • Examples of preferred linear saturated C 12 -C 30 -alcohols are dodecan-1-ol (dodecyl alcohol, lauryl alcohol), tetradecan-1-ol (tetradecyl alcohol, myristyl alcohol), hexadecan-1-ol (hexadecyl alcohol, cetyl alcohol, palmityl alcohol), octadecane 1-ol (octadecyl alcohol, stearyl alcohol), arachyl alcohol (eicosan-1-ol), heneicosyl alcohol (heneicosan-1-ol) and / or behenyl alcohol (docosan-1-ol).
  • dodecan-1-ol dodecyl alcohol, lauryl alcohol
  • tetradecan-1-ol tetradecyl alcohol, myristyl alcohol
  • hexadecan-1-ol hexadecyl alcohol, cetyl alcohol, palmityl alcohol
  • Preferred linear unsaturated fatty alcohols are (9Z) octadec-9-en-1-ol (oleyl alcohol), (9E) octadec-9-en-1-ol (elaidyl alcohol), (9Z, 12Z) octadeca-9, 12-diene-1-ol (linoleyl alcohol), (9Z, 12Z, 15Z) -octadeca-9,12,15-triene-1-ol (linolenoyl alcohol), gadoleyl alcohol ((9Z) -eicos-9-en-1 - ol), arachidonic alcohol ((5Z, 8Z, 11Z, 14Z) -eicosa-5,8,1 1, 14-tetraen-1-ol), erucyl alcohol ((13Z) -dozos-13-en-1-ol ) and / or brassidyl alcohol ((13E) -docosen-1-ol).
  • the preferred representatives of branched fatty alcohols are 2-octyl-dodecanol, 2-hexyl-dodecanol and / or 2-butyl-dodecanol.
  • Ci2-C3o-fatty acid triglyceride is understood as meaning the triester of the trihydric alcohol glycerol with three equivalents of fatty acid. Both structurally identical and different fatty acids within a triglyceride molecule can be involved in the ester formation.
  • fatty acids are to be understood as meaning saturated or unsaturated, unbranched or branched, unsubstituted or substituted C 12 -C 30 -carboxylic acids.
  • Unsaturated fatty acids may be monounsaturated or polyunsaturated.
  • For an unsaturated fatty acid its CC double bond (s) may have the cis or trans configuration.
  • the fatty acid triglycerides are characterized by particular suitability in which at least one of the ester groups is formed starting from glycerol with a fatty acid selected from dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (palmitic acid), tetracosanoic acid (lignoceric acid), octadecanoic acid (Stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), petroselinic acid [(Z) -6-octadecenoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [(9Z) -octadec-9-enoic acid] , Elaidic acid [(9E) - octadec-9-enoic acid], erucic acid [(13Z)
  • the fatty acid triglycerides may also be of natural origin.
  • the fatty acid triglycerides or mixtures thereof occurring in soybean oil, peanut oil, olive oil, sunflower oil, macadamia nut oil, moringa oil, apricot kernel oil, marula oil and / or optionally hydrogenated castor oil are particularly suitable for use in the product according to the invention.
  • a C 12 -C 30 -fatty acid monoglyceride is understood as meaning the monoester of the trivalent alcohol glycerol with one equivalent of fatty acid.
  • either the middle hydroxyl group of the glycerol or the terminal hydroxyl group of the glycerol may be esterified with the fatty acid.
  • the Ci2-C3o-fatty acid monoglycerides are characterized by particular suitability in which a hydroxy group of glycerol is esterified with a fatty acid, wherein the fatty acids are selected from dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (palmitic acid), tetracosanoic acid (lignoceric acid ), Octadecanoic acid (stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), petroselinic acid [(Z) -6-octadecenoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [(9Z) -octadec-9 -enoic acid], elaidic acid [(9E) -octadec-9-enoic acid], er
  • Ci2-C3o fatty acid diglyceride is understood as meaning the diester of the trivalent alcohol glycerol with two equivalents of fatty acid.
  • either the middle and one terminal hydroxy group of glycerol may be esterified with two equivalents of fatty acid, or both terminal hydroxy groups of glycerol are esterified with one fatty acid.
  • the glycerol may be esterified with two structurally identical as well as with two different fatty acids.
  • the fatty acid diglycerides are characterized by particular suitability in which at least one of the ester groups is formed starting from glycerol with a fatty acid selected from dodecanoic acid (lauric acid), tetradecanoic acid (myristic acid), hexadecanoic acid (palmitic acid), tetracosanoic acid (lignoceric acid), octadecanoic acid (Stearic acid), eicosanoic acid (arachidic acid), docosanoic acid (behenic acid), petroselinic acid [(Z) -6-octadecenoic acid], palmitoleic acid [(9Z) -hexadec-9-enoic acid], oleic acid [(9Z) -octadec-9-enoic acid] , Elaidineaure [(9E) - Octadec-9-enoic acid], erucic acid [(13Z) -doco
  • Hydrocarbons are exclusively compounds consisting of the atoms carbon and hydrogen with 8 to 80 carbon atoms.
  • aliphatic hydrocarbons such as mineral oils, liquid paraffin oils (e.g., Paraffinium Liquidum or Paraffinum Perliquidum), isoparaffin oils, semi-solid paraffin oils, paraffin waxes, Paraffin Solidum, Vaseline and Polydecene.
  • Suitable paraffin oils are, in particular, liquid paraffin oils (Paraffinum Liquidum and Paraffinium Perliquidum).
  • the hydrocarbon is very particularly preferably Paraffinum Liquidum, also known as white oil.
  • Paraffinum Liquidum is a mixture of purified, saturated, aliphatic hydrocarbons, consisting mostly of hydrocarbon chains with a C-chain distribution of 25 to 35 carbon atoms.
  • Preferred fat constituents are selected from the group of C 12 -C 30 -fatty alcohols, C 12 -C 30 -fatty acid triglycerides, C 12 -C 30 fatty acid monoglycerides, C 12 -C 30 -fatty acid diglycerides and / or hydrocarbons.
  • the Ci2-C3o-fatty alcohols and / or the hydrocarbons are preferred fat constituents.
  • Very particularly preferred fat constituents are the C 12 -C 30 -fatty alcohols.
  • the fat components are contained in a total amount by weight (G1a) in the preparation (a) (in% by weight).
  • the basis for calculating the total weight (G1 a) is the total weight of preparation (a).
  • the fat constituents are contained in a total amount by weight (Gi b) in preparation (b) (in% by weight).
  • the basis for calculating the total weight (G1a) is the total weight of preparation (b).
  • the fat constituents can be used in total weight amounts (G1a) or (G2a) of 0.1 to 40% by weight, based in each case on the total weight of the preparations (a) and (b).
  • thickening polymers are understood as meaning organic polymeric compounds which, when they are added in an amount of 0.1% by weight in water (at 22 ° C. and a pressure of 760 mmHg), The viscosity is measured at 22 ° C. (22 ° C. / Brookfield viscometer / spindle 1/10 rpm).
  • polymeric compounds are understood as meaning repeat-unit-based compounds having a molecular weight of more than 5000 g / mol, preferably more than 10,000 g / mol and more preferably more than 20,000 g / mol.
  • the maximum molecular weight of the polymers depends on the conditions of synthesis, the batch size and the degree of polymerization and preferably does not exceed 10 8 g / mol.
  • Repeat unit based compounds have at least 50 repeat units, preferably at least 100 repeat units, and most preferably at least 500 repeat units.
  • the thickening polymers are contained in a total amount by weight (G2a) in preparation (a) (in% by weight).
  • the basis for calculating the total amount by weight (G2a) is the total weight of preparation (a).
  • the thickening polymers are contained in a total amount by weight (G2b) in preparation (b) (in% by weight).
  • the basis for calculating the total amount by weight (G2b) is the total weight of preparation (b).
  • the thickening polymers may be cationic, nonionic and / or anionic polymers.
  • the acrylic acid polymers, the acrylic acid copolymers, the methacrylic acid polymers and / or the methacrylic acid copolymers are used as thickening polymers, this is particularly preferred.
  • polysaccharides is the collective term for macromolecular carbohydrates whose molecules consist of a large number of glycosidically linked monosaccharide molecules (with a molecular weight of at least 5000 g / mol). These carbohydrates can also be chemically modified.
  • xanthan gums Within the group of polysaccharides the xanthan gums, alginates, carboxyalkylcelluloses and hyaluronic acids are very suitable.
  • Xanthan gum is a polysaccharide, which among other things is made up of the structural components D-glucose, D-mannose, D-glucuronic acid, acetate and pyruvate and which is also known under the INCI name Xanthan Gum. Xanthan bears carboxy groups and is anionic or anionizable. Also, the physiologically acceptable salts of xanthan are according to the invention.
  • Alginates are the salts of alginic acid. Alginates are acidic, carboxy group-containing polysaccharides consisting of D-mannuronic acid and D-guluronic acid in different ratios, which are linked to 1-4-glycosidic bonds.
  • the alkali metal salts and the alkaline earth metal salts of the alkenoic acids are according to the invention.
  • the use of alginic acid, sodium alginate, potassium alginate, ammonium alginate and / or calcium alginate has proven particularly advantageous in the preparations according to the invention.
  • Carboxyalkylcelluloses are cellulose ethers in which the hydrogen atoms of the hydroxy groups of the cellulose are partially or completely substituted by carboxyalkyl groups.
  • a preferred carboxyalkylcellulose is the carboxymethylcellulose, which may preferably be used as anionic polymer in the form of its sodium salt (sodium carboxymethylcellulose).
  • Basic building blocks of hyaluronic acid (INCI name Hyaluronic acid, sodium hyaluronate) is an aminodisaccharide composed of D-glucuronic acid and N-acetylglucosamine in 1-3-glycosidic bond, which is linked to the next unit ß-1-4-glycosidic.
  • Sodium and Potassium salts of hyaluronic acid have proven to be particularly suitable in the context of the work leading to this invention.
  • the thickening polymers may be contained in total weight amounts (G2a) or (G2b) of 0.1 to 20 wt .-% in the preparations (a) and / or (b).
  • the preparation (a) and / or the preparation (b) may also contain one or more cationic surfactants.
  • the cationic surfactants are contained in a total amount by weight (G3a) in preparation (a) (in% by weight).
  • the basis for calculating the total amount by weight (G3a) is the total weight of preparation (a).
  • the cationic surfactants are contained in a total amount by weight (G3b) in preparation (b) (in% by weight).
  • the basis for calculating the total weight (G3b) is the total weight of preparation (b).
  • Cationic surfactants are derived generally from ammonium ions and have a structure (NR1 R2R3R4) + with a correspondingly negatively charged counterion.
  • Further cationic surfactants are, for example, the esterquats or the imidazolium compounds.
  • Cationic surfactants (Tkat) of the quaternary ammonium compound type, the esterquats, the imidazolines and the amidoamines are particularly preferably used according to the invention.
  • Preferred quaternary ammonium compounds are ammonium halides, in particular chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, eg.
  • cetyltrimethylammonium chloride stearyltrimethylammonium chloride, distearyldimethyl ammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, as well as the imidazolium compounds known under the INCI names Quaternium-27 and Quaternium-83.
  • the long alkyl chains of the above-mentioned surfactants preferably have 8 to 30 carbon atoms.
  • Typical examples of cationic surfactants are quaternary ammonium compounds and esterquats, in particular quaternized fatty acid trialkanolamine ester salts.
  • cationic compounds containing behenyl radicals in particular the substances known as behentrimonium chloride or bromide (docosanyltrimethylammonium chloride or bromide), can be used with particular preference.
  • behentrimonium chloride or bromide docosanyltrimethylammonium chloride or bromide
  • Other preferred QAVs have at least two behenyl residues.
  • these substances are, for example, under the designations Genamin ® KDMP (Clariant).
  • Esterquats are substances which contain both at least one ester function and at least one quaternary ammonium group as structural element.
  • Preferred esterquats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines.
  • Such products are marketed under the trade names Stepantex® ®, ® and Dehyquart® Armocare® ®.
  • the radicals R independently of one another each represent a saturated or unsaturated, linear or branched hydrocarbon radical having a chain length of 8 to 30 carbon atoms.
  • the preferred compounds of formula (E5-V) for R each contain the same hydrocarbon radical.
  • the chain length of the radicals R is preferably 12 carbon atoms. Particular preference is given to compounds having a chain length of at least 16 carbon atoms and very particularly preferably having at least 20 carbon atoms.
  • a very particularly preferred compound of the formula I has a chain length of 21 carbon atoms. A commercial product of this chain length is known, for example, under the name Quaternium 91.
  • methosulfate is shown as a counterion.
  • the counterions also include the halides, such as chloride, fluoride, bromide, or else phosphates.
  • the imidazolines of the formula (Tkat-1) are present in the compositions according to the invention in amounts of from 0.01 to 20% by weight, preferably in amounts of from 0.05 to 10% by weight and very particularly preferably in amounts of 0.1 contain up to 7.5 wt .-%. The very best results are obtained with amounts of 0, 1 to 5 wt .-% each based on the total composition of the respective agent.
  • the alkylamidoamines are usually prepared by amidation of natural or synthetic fatty acids and fatty acid cuts with dialkylaminoamines.
  • a according to the invention particularly suitable compound from this group of substances under the name Tegoamid ® S 18 commercially available stearamidopropyl dimethylamine.
  • the alkylamidoamines can be present both as such and converted by protonation in accordance acid solution into a quaternary compound in the composition, they Of course, they can also be used as a permanent quaternary compound in the compositions according to the invention.
  • Examples of permanently quaternized amidoamines include the raw materials with the trade name Rewoquat ® UTM 50, Lanoquat ® DES-50 or Empigen CSC.
  • Glucquat ® 100 is, according to INCI nomenclature a "lauryl methyl Gluceth-10 Hydroxypropyl Dimonium Chloride”.
  • cationic surfactants of the present invention are also understood to mean cationic compounds of the following general structure: RCO-XN + RR 2 R 3 R 4 A (Tkat-2)
  • R here stands for a substituted or unsubstituted, branched or straight-chain alkyl or alkenyl radical having 1 to 35 carbon atoms in the chain
  • X is - O - or - NR 5 -
  • R is an alkylene group having 2 to 6 C atoms, which may be unsubstituted or substituted, in which case substitution with an -OH or -NH group is preferred in the case of a substitution,
  • R 2, R 3 and R 4 each independently represent an alkyl or hydroxyalkyl group having 1 to 6 C - atoms in the chain, which chain may be straight or branched.
  • radicals according to the invention are methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, pentyl, isopentyl, neopentyl, hexyl, iso-hexyl, hydroxyalkyl, dihydroxyalkyl, hydroxyethyl, hydroxypropyl, Dihydroxypropyl, hydroxybutyl, dihydroxybutyl, trihydroxybutyl, trihydroxypropyl, dihydroxyethyl,
  • R5 is hydrogen or a C1 to C6 straight-chain or branched, alkyl or alkenyl radical which may also be substituted by a hydroxy group, especially methyl, ethyl, propyl, isopropyl, Butyl,
  • a " represents a halide such as fluoride, chloride or bromide, an alkyl sulfate such as a methosulfate or ethosulfate, a phosphate, a citrate, tartrate, maleate or fumarate
  • the cationic surfactants may each be contained in total weight amounts (G3a) or (G3b) of 0.1 to 40% by weight in the preparations (a) and / or (b).
  • the preparation (a) and / or the preparation (b) may also contain one or more anionic surfactants.
  • the anionic surfactants are contained in a total amount by weight (G4a) in the preparation (a) (in% by weight).
  • the basis for calculating the total weight (G4a) is the total weight of preparation (a).
  • the anionic surfactants are contained in a total amount by weight (G4b) in the preparation (b) (in% by weight).
  • the basis for calculating the total weight (G4b) is the total weight of preparation (b).
  • Suitable anionic surfactants (tanion) in preparations according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. Example, a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group with about 8 to 30 C atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule.
  • anionic surfactants are alkylbenzenesulfonates, alkanesulfonates, olefinsulfonates, alkyl ether sulfonates, glycerol ether sulfonates, ⁇ -methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, fatty alcohol ether sulfates, glycerol ether sulfates, hydroxy mixed ether sulfates, monoglyceride (ether) sulfates, fatty acid amide (ether) sulfates, mono- and dialkyl sulfosuccinates , Mono- and dialkylsulfosuccinamates, sulfotriglycerides, amide soaps, ether carboxylic acids and their salts, fatty acid isethionates, fatty acid sarcosinates, fatty acid taurides, acyl lactylate
  • anionic surfactants contain polyglycol ether chains, these may have a conventional, but preferably a narrow homolog distribution.
  • particularly suitable anionic surfactants are, in each case in the form of the sodium, potassium and ammonium as well as the mono-, di- and trialkanolammonium salts having 2 to 4 C atoms in the alkanol group,
  • Acyl isethionates having 8 to 24 carbon atoms in the acyl group are long known, skin-friendly surfactants, which are accessible by esterification of fatty acids with the sodium salt of 2-hydroxyethane-sulfonic acid (isethionic acid). If you for this esterification fatty acids with 8 to 24 carbon atoms, ie z.
  • As lauric, myristic, palmititic or stearic or technical fatty acid fractions eg. If, for example, the C 12 -C 18 fatty acid fraction obtainable from coconut fatty acid is used, the C 12 -C 18 acyl isethionates which are preferably suitable according to the invention are obtained.
  • Sulfobernsteinklado- and dialkyl esters having 8 to 24 carbon atoms in the alkyl group and sulfosuccinic monoalkylpolyoxyethylester having 8 to 24 carbon atoms in the alkyl group and 1 to 6 oxyethyl groups.
  • the Sulfobernsteinklamonoalkyl (C8-C24) ester dinatrium salts are prepared by known methods z. B. prepared by reacting maleic anhydride with a fatty alcohol having 8 - 24 carbon atoms to maleic acid monoester of the fatty alcohol and sulfites this with sodium sulfite to Sulfobernsteinklaester.
  • Particularly suitable sulfosuccinic acid esters are derived from fatty alcohol fractions having 12- 18 C atoms, as z. B. from coconut oil or Kokosfettkladester are accessible by hydrogenation, linear alkanesulfonates having 8 to 24 carbon atoms, linear alpha-olefin sulfonates having 8 to 24 C atoms,
  • Alpha-sulfofatty acid methyl esters of fatty acids having 8 to 30 carbon atoms are alpha-sulfofatty acids having 8 to 30 carbon atoms.
  • Alkyl sulfates and alkyl polyglycol ether sulfates of the formula R-O (CH 2 -CH 2 O) x -OSO 3 H, in which R is a preferably linear alkyl group having 8 to 30 C atoms and x 0 or 1 to 12,
  • Hydroxysulfonates essentially corresponding to at least one of the following two formulas or mixtures thereof and salts thereof,
  • R 1 is a linear alkyl radical having 1 to 24 C atoms
  • R 2 is a linear one or branched, saturated alkyl radical having 1 to 24 C atoms
  • R 3 is hydrogen or a linear alkyl radical having 1 to 24 C atoms
  • R 4 is hydrogen or a methyl radical
  • M is hydrogen, ammonium, alkylammonium, alkanolammonium, wherein the alkyl and alkanol radicals each have 1 to 4 C atoms, or a metal atom selected from lithium, sodium, potassium, calcium or magnesium
  • n is a number in the range from 0 to 12 and furthermore the total number of C contained in R and R 3 Atoms 2 to 44, sulfonates of unsaturated fatty acids having 8 to 24 carbon
  • R is preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms
  • R 2 is hydrogen, a radical (CH2CH20) n R 2 or X
  • n is a number of 1 to 10
  • X is hydrogen, an alkali metal or alkaline earth metal or NR 3 R 4 R 5 R 6 , where R 3 to R 6 independently of one another represent hydrogen or a C 1 to C 4 hydrocarbon radical, is a sulfated fatty acid alkylene glycol ester of the formula RCO (AlkO) n SO 3 M
  • RCO-- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical having 6 to 22 C atoms, Alk for CH 2 CH 2, CHCH 3 CH 2 and / or CH 2 CHCH 3, n for numbers from 0.5 to 5 and M for a metal such as alkali metal, in particular sodium, potassium, lithium, alkaline earth metal, in particular magnesium, calcium, zinc, or ammonium ion, such as + NR 3 R 4 R 5 R 6 , where R 3 to R 6 are independently hydrogen or a C1 to C4 - hydrocarbon radical, Monoglyceride sulfates and monoglyceride ether sulfates of the formula
  • R 8 CO is a linear or branched acyl radical having 6 to 22 carbon atoms
  • x, y and z are in total 0 or numbers of 1 to 30, preferably 2 to 10
  • X is an alkali or alkaline earth metal.
  • monoglyceride ether sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride and their ethylene oxide adducts with sulfur trioxide or chlorosulfonic acid in the form of their sodium salts.
  • monoglyceride sulfates are used, in which R 8 CO is a linear acyl radical having 8 to 18 carbon atoms,
  • Amide ether carboxylic acids R-CO-NR 2 -CH 2 CH 2 -O- (CH 2 CH 2 O) 2 COOM, with R as a straight-chain or branched alkyl or alkenyl radical having a number of carbon atoms in the chain of 2 to 30, n is an integer Number from 1 to 20 and R 2 is hydrogen, a methyl, ethyl, propyl, isopropyl, n-butyl, t-butyl or iso-butyl radical and M is hydrogen or a metal such as alkali metal, in particular Sodium, potassium, lithium, alkaline earth metal, in particular magnesium, calcium, zinc, or an ammonium ion, such as + NR 3 R 4 R 5 R 6 , with R 3 to R 6 independently of one another represent hydrogen or a C 1 to C 4 hydrocarbon radical.
  • Such products are obtainable, for example, by the company Chem Y under the product name Akypo ®.
  • Condensation products of a water-soluble salt of a water-soluble protein hydrolyzate-fatty acid condensation product are prepared by condensation of C8 - C30 fatty acids, preferably of fatty acids having 12 - 18 C atoms with amino acids, mono-, di- and water-soluble oligopeptides and mixtures of such products, as obtained in the hydrolysis of proteins.
  • These protein hydrolyzate-fatty acid condensation products are neutralized with a base and are then preferably present as alkali metal, ammonium, mono-, di- or Trialkanolammoniumsalz.
  • Such products are available under the trademark Lamepon® ®, Maypon ®, Gluadin® ®, Hostapon® ® KCG or Amisoft ® has long been in the trade,
  • Preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acids having from 10 to 18 carbon atoms in the alkyl group and up to 12 glycol ether groups in the molecule, sulfosuccinic acid mono- and dialkyl esters having from 8 to 18 carbon atoms in the alkyl group and sulfosuccinic acid monoalkylpolyoxyethyl esters with 8 to 18 C atoms in the alkyl group and 1 to 6 Oxyethyl phenomenon, Monoglycerdisulfate, alkyl and Alkenyletherphosphate and protein fatty acid condensates.
  • the anionic surfactants may each be contained in total weight amounts (G4a) or (G4b) of 0.1 to 40% by weight in the preparations (a) and / or (b).
  • the preparation (a) and / or the preparation (b) may also contain one or more nonionic surfactants.
  • the nonionic surfactants are contained in a total amount by weight (G5a) in the preparation (a) (in% by weight).
  • the basis for calculating the total weight (G5a) is the total weight of preparation (a).
  • the anionic surfactants are contained in a total amount by weight (G5b) in the preparation (b) (in% by weight).
  • the basis for calculating the total weight (G5b) is the total weight of preparation (b).
  • Nonionic surfactants contain as hydrophilic group e.g. a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether group.
  • hydrophilic group e.g. a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether group.
  • Such compounds are, for example
  • Ci2-C3o fatty acid mono- and diesters of addition products of 1 to 30 moles of ethylene oxide with glycerol,
  • Hydroxy mixed ethers as described, for example, in DE-OS 19738866, sorbitan fatty acid esters and addition products of ethylene oxide onto sorbitan fatty acid esters, for example the polysorbates,
  • R 4 is an alkyl or alkenyl radical having 4 to 22 carbon atoms
  • G is a sugar radical having 5 or 6 carbon atoms
  • p is a number from 1 to 10.
  • the alkyl and alkenyl oligoglycosides can be derived from aldoses or ketoses with 5 or 6 carbon atoms, preferably glucose.
  • the preferred alkyl and / or alkenyl oligoglycosides are thus alkyl and / or alkenyl oligoglucosides.
  • the index number p in the general formula (Tnio-2) indicates the degree of oligomerization (DP), ie the distribution of mono- and oligoglycosides and stands for a number between 1 and 10.
  • the value p for a given alkyloligoglycoside is an analytically determined arithmetic quantity, which usually represents a fractional number. Preference is given to using alkyl and / or alkenyl oligoglycosides having an average degree of oligomerization p of from 1.1 to 3.0. From an application point of view, those alkyl and / or alkenyl oligoglycosides whose degree of oligomerization is less than 1.7 and in particular between 1.2 and 1.4 are preferred.
  • the alkyl or alkenyl radical R 4 can be derived from primary alcohols having 4 to 1 1, preferably 8 to 10 carbon atoms. Typical examples are butanol, caproic alcohol, caprylic alcohol, capric alcohol and undecyl alcohol and technical mixtures thereof, as obtained, for example, in the hydrogenation of technical fatty acid methyl esters or in the hydrogenation of aldehydes from Roelen's oxo synthesis.
  • the alkyl or alkenyl radical R 5 can also be derived from primary alcohols having 12 to 22, preferably 12 to 14 carbon atoms.
  • Typical examples are lauryl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol, brassidyl alcohol, and technical mixtures thereof as described above can be obtained.
  • Preference is given to alkyl oligoglucosides based on hydrogenated C 12/14 coconut alcohol having a DP of 1 to 3.
  • R 5 CO is an aliphatic acyl radical having 6 to 22 carbon atoms
  • R 6 is hydrogen, an alkyl or hydroxyalkyl having 1 to 4 carbon atoms
  • [Z] is a linear or branched polyhydroxyalkyl radical having 3 to 12 carbon atoms and 3 to 10 hydroxyl groups, stands.
  • the fatty acid N-alkyl polyhydroxyalkylamides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
  • the fatty acid N-alkylpolyhydroxyalkylamides are derived from reducing sugars having 5 or 6 carbon atoms, especially glucose.
  • the preferred fatty acid N-alkylpolyhydroxyalkylamides are therefore fatty acid N-alkylglucamides as represented by the formula (Tnio-4):
  • the fatty acid N-alkylpolyhydroxyalkylamides used are preferably glucamides of the formula (Tnio 4) in which R 8 is hydrogen or an alkyl group and R 7 CO is the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitic acid, Stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, arachidic acid, gadoleic acid, behenic acid or erucic acid or those technical mixtures.
  • R 8 is hydrogen or an alkyl group
  • R 7 CO is the acyl radical of caproic acid, caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, palmitic acid, Stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic
  • fatty acid N-alkylglucamides of the formula (Tnio-4) which are obtained by reductive amination of glucose with methylamine and subsequent acylation with lauric acid or C12 / 14 coconut fatty acid or a corresponding derivative.
  • the polyhydroxyalkylamides can also be derived from maltose and palatinose.
  • nonionic surfactants are fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, mixed ethers or mixed formalin, protein hydrolysates (especially wheat-based vegetable products) and polysorbates.
  • the alkylene oxide adducts to saturated linear fatty alcohols and fatty acids having in each case 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid and the sugar surfactants have proven.
  • the nonionic surfactants may each be contained in total weight amounts (G5a) or (G5b) of 0.1 to 40% by weight in the preparations (a) and / or (b).
  • the preparation (a) and / or the preparation (b) may also contain one or more zwitterionic surfactants.
  • the zwitterionic surfactants are in a total amount by weight (G6a) in the Preparation (a) included (in wt .-%).
  • the basis for calculating the total weight (G6a) is the total weight of preparation (a).
  • the zwitterionic surfactants are contained in a total amount by weight (G6b) in preparation (b) (in% by weight).
  • the basis for calculating the total weight (G6b) is the total weight of preparation (b).
  • Zwitterionic surfactants are surface-active compounds which carry at least one quaternary ammonium group and at least one -COO ( - ) or -SO 3 ( - ) group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycineate, N-acylaminopropyl-N, N-dimethylammonium glycinates, for example cocoacylaminopropyl-dimethylammonium glycinate, and 2-alkyl-3-carboxymethyl-3-hydroxyethyl imidazolines having in each case 8 to 18 C atoms in the alkyl or acyl group, and the cocoacylamino-ethylhydroxyethylcarboxymethylglycinate.
  • a preferred zwitterionic surfactant is the fatty acid
  • preparations (a) and / or (b) contain in a further very particularly preferred embodiment
  • one or more total weight amounts from the group (G1a), (G2a), (G3a), (G4a), (G5a), (G6a) can also be 0.
  • one or more total weight amounts from the group (Gib), (G2b), (G3b), (G4b), (G5b), (G6b) may also be 0.
  • the proviso must be fulfilled that at least one (preferably at least two, particularly preferably at least three) weight ratio (s) from the group (G1a) / (G1b), (G2a) / (G2b), (G3a) / ( G3b), (G4a) / (G4b) (G5a) / (G5b) and (G6a) / (G6b) are at a value of 0.8 to 1.2.
  • At least one (preferably at least two, more preferably at least three) of the amounts of (G1a), (G2a), (G3a), (G4a), (G5a), (G6a) must be different from 0 and furthermore at least one (Preferably, at least two, more preferably at least three) of the amounts of (Gi b), (G2b), (G3b), (G4b), (G5b), (G6b) must be unequal.
  • a product for oxidative dyeing and / or brightening of keratinic fibers wherein the preparation (a) - in each case based on their total weight -
  • one or more cationic surfactants in a total amount by weight (G3a) and / or
  • anionic surfactants in a total amount by weight (G4a) and / or
  • nonionic surfactants in a total amount by weight (G5a) and / or
  • one or more fat constituents in a total amount by weight (Gi b) and / or
  • one or more thickening polymers in a total amount by weight (G2b) and / or
  • one or more cationic surfactants in a total amount by weight (G3b) and / or
  • anionic surfactants in a total amount by weight (G4b) and / or
  • nonionic surfactants in a total amount by weight (G5b) and / or
  • the weight ratio (G1a) / (G1 b) is at a value of 0.8 to 1.2
  • the fatty alcohols are mandatory ingredients in the preparations (a) and (b), the other ingredients are optional.
  • a product for oxidative dyeing and / or brightening of keratinic fibers wherein the preparation (a) - in each case based on their total weight -
  • thickening polymers in a total amount by weight (G2a) and / or
  • one or more cationic surfactants in a total amount by weight (G3a) and / or
  • anionic surfactants in a total amount by weight (G4a) and / or
  • nonionic surfactants in a total amount by weight (G5a) and / or
  • one or more fat constituents in a total amount by weight (Gi b) and / or
  • one or more thickening polymers in a total amount by weight (G2b) and / or
  • one or more cationic surfactants in a total amount by weight (G3b) and / or
  • anionic surfactants in a total amount by weight (G4b) and / or
  • nonionic surfactants in a total amount by weight (G5b) and / or
  • the weight ratio (G1a) / (G1 b) is at a value of 0.8 to 1.2
  • the weight ratio (G2a) / (G2b) is at a value of 0.8 to 1.2.
  • the fatty alcohols and the thickening polymers are compulsory ingredients in the preparations (a) and (b), the other ingredients are optional.
  • a product for oxidative dyeing and / or lightening of keratinic fibers wherein the preparation (a) - in each case based on their total weight -
  • one or more cationic surfactants in a total amount by weight (G3a) and / or
  • anionic surfactants in a total amount by weight (G4a) and / or
  • nonionic surfactants in a total amount by weight (G5a) and / or
  • one or more fat constituents in a total amount by weight (Gi b) and / or
  • one or more thickening polymers in a total amount by weight (G2b) and / or
  • one or more cationic surfactants in a total amount by weight (G3b) and / or
  • anionic surfactants in a total amount by weight (G4b) and / or
  • nonionic surfactants in a total amount by weight (G5b) and / or
  • the weight ratio (G1a) / (G1 b) is at a value of 0.8 to 1.2
  • the weight ratio (G3a) / (G3b) is at a value of 0.8 to 1.2.
  • the fatty alcohols and the cationic surfactants are compulsory ingredients in the preparations (a) and (b), the other ingredients are optional.
  • a product for oxidative dyeing and / or lightening of keratinic fibers wherein the preparation (a) - in each case based on their total weight -
  • one or more fat constituents in a total amount by weight (G1a) and / or
  • thickening polymers in a total amount by weight (G2a) and / or
  • one or more cationic surfactants in a total amount by weight (G3a) and / or
  • anionic surfactants in a total amount by weight (G4a) and / or
  • nonionic surfactants in a total amount by weight (G5a) and / or
  • one or more fat constituents in a total amount by weight (Gi b) and / or
  • one or more thickening polymers in a total amount by weight (G2b) and / or
  • one or more cationic surfactants in a total amount by weight (G3b) and / or
  • anionic surfactants in a total amount by weight (G4b) and / or
  • nonionic surfactants in a total amount by weight (G5b) and / or
  • the weight ratio (G1a) / (G1 b) is at a value of 0.8 to 1.2
  • the weight ratio (G4a) / (G4b) is at a value of 0.8 to 1.2.
  • the fatty alcohols and the anionic surfactants are mandatory ingredients in the preparations (a) and (b), the other ingredients are optional.
  • a product for oxidative dyeing and / or lightening of keratinic fibers wherein the preparation (a) - in each case based on their total weight - one or more fat constituents in a total amount by weight (G1a) and / or
  • thickening polymers in a total amount by weight (G2a) and / or
  • one or more cationic surfactants in a total amount by weight (G3a) and / or
  • anionic surfactants in a total amount by weight (G4a) and / or
  • nonionic surfactants in a total amount by weight (G5a) and / or
  • one or more fat constituents in a total amount by weight (Gi b) and / or
  • one or more thickening polymers in a total amount by weight (G2b) and / or
  • one or more cationic surfactants in a total amount by weight (G3b) and / or
  • anionic surfactants in a total amount by weight (G4b) and / or
  • nonionic surfactants in a total amount by weight (G5b) and / or
  • the weight ratio (G1a) / (G1 b) is at a value of 0.8 to 1.2
  • the weight ratio (G5a) / (G5b) is at a value of 0.8 to 1.2.
  • the fatty alcohols and the nonionic surfactants are compulsory ingredients in preparations (a) and (b), the other ingredients are optional.
  • a product for oxidative dyeing and / or lightening of keratinic fibers wherein the preparation (a) - in each case based on their total weight -
  • one or more fat constituents in a total amount by weight (G1a) and / or
  • thickening polymers in a total amount by weight (G2a) and / or
  • one or more cationic surfactants in a total amount by weight (G3a) and / or
  • anionic surfactants in a total amount by weight (G4a) and / or
  • nonionic surfactants in a total amount by weight (G5a) and / or
  • one or more fat constituents in a total amount by weight (Gi b) and / or
  • one or more thickening polymers in a total amount by weight (G2b) and / or
  • one or more cationic surfactants in a total amount by weight (G3b) and / or
  • anionic surfactants in a total amount by weight (G4b) and / or
  • nonionic surfactants in a total amount by weight (G5b) and / or
  • the weight ratio (G1a) / (G1 b) is at a value of 0.8 to 1.2
  • the weight ratio (G6a) / (G6b) is at a value of 0.8 to 1.2.
  • the fatty alcohols and the zwitterionic surfactants are compulsory ingredients in the preparations (a) and (b), the other ingredients are optional.
  • a product for oxidative dyeing and / or lightening of keratinic fibers wherein the preparation (a) - in each case based on their total weight -
  • one or more fat constituents in a total amount by weight (G1a) and / or
  • thickening polymers in a total amount by weight (G2a) and / or
  • one or more cationic surfactants in a total amount by weight (G3a) and / or
  • anionic surfactants in a total amount by weight (G4a) and / or
  • nonionic surfactants in a total amount by weight (G5a) and / or
  • one or more fat constituents in a total amount by weight (Gi b) and / or
  • one or more thickening polymers in a total amount by weight (G2b) and / or
  • one or more cationic surfactants in a total amount by weight (G3b) and / or
  • anionic surfactants in a total amount by weight (G4b) and / or
  • nonionic surfactants in a total amount by weight (G5b) and / or
  • the weight ratio (G1a) / (G1 b) is at a value of 0.8 to 1.2
  • the weight ratio (G2a) / (G2b) is at a value of 0.8 to 1.2
  • the weight ratio (G3a) / (G3b) is at a value of 0.8 to 1.2
  • the fatty alcohols, the thickening polymers and the cationic surfactants are compulsory ingredients in the preparations (a) and (b), the other ingredients are optional.
  • a product for oxidative dyeing and / or lightening of keratinic fibers wherein the preparation (a) - in each case based on their total weight -
  • one or more fat constituents in a total amount by weight (G1a) and / or
  • thickening polymers in a total amount by weight (G2a) and / or
  • one or more cationic surfactants in a total amount by weight (G3a) and / or
  • anionic surfactants in a total amount by weight (G4a) and / or
  • nonionic surfactants in a total amount by weight (G5a) and / or
  • one or more fat constituents in a total amount by weight (Gi b) and / or
  • one or more thickening polymers in a total amount by weight (G2b) and / or
  • one or more cationic surfactants in a total amount by weight (G3b) and / or
  • anionic surfactants in a total amount by weight (G4b) and / or
  • nonionic surfactants in a total amount by weight (G5b) and / or
  • the weight ratio (G1a) / (G1 b) is at a value of 0.8 to 1.2
  • the weight ratio (G2a) / (G2b) is at a value of 0.8 to 1.2
  • - The weight ratio (G4a) / (G4b) is at a value of 0.8 to 1.2
  • the fatty alcohols, the thickening polymers and the anionic surfactants are compulsory ingredients in the preparations (a) and (b), the other ingredients are optional.
  • a product for oxidative dyeing and / or lightening of keratinic fibers wherein the preparation (a) - in each case based on their total weight -
  • one or more fat constituents in a total amount by weight (G1a) and / or
  • thickening polymers in a total amount by weight (G2a) and / or
  • one or more cationic surfactants in a total amount by weight (G3a) and / or
  • anionic surfactants in a total amount by weight (G4a) and / or
  • nonionic surfactants in a total amount by weight (G5a) and / or
  • one or more fat constituents in a total amount by weight (Gi b) and / or
  • one or more thickening polymers in a total amount by weight (G2b) and / or
  • one or more cationic surfactants in a total amount by weight (G3b) and / or
  • anionic surfactants in a total amount by weight (G4b) and / or
  • nonionic surfactants in a total amount by weight (G5b) and / or
  • the weight ratio (G1a) / (G1 b) is at a value of 0.8 to 1.2
  • the weight ratio (G2a) / (G2b) is at a value of 0.8 to 1.2
  • the weight ratio (G5a) / (G5b) is at a value of 0.8 to 1.2
  • the fatty alcohols, the thickening polymers and the nonionic surfactants are compulsory ingredients in the preparations (a) and (b), the other ingredients are optional.
  • a product for oxidative dyeing and / or lightening of keratinic fibers wherein the preparation (a) - in each case based on their total weight -
  • one or more fat constituents in a total amount by weight (G1a) and / or
  • thickening polymers in a total amount by weight (G2a) and / or
  • one or more cationic surfactants in a total amount by weight (G3a) and / or
  • anionic surfactants in a total amount by weight (G4a) and / or
  • nonionic surfactants in a total amount by weight (G5a) and / or
  • one or more fat constituents in a total amount by weight (Gi b) and / or
  • one or more thickening polymers in a total amount by weight (G2b) and / or
  • one or more cationic surfactants in a total amount by weight (G3b) and / or
  • anionic surfactants in a total amount by weight (G4b) and / or
  • nonionic surfactants in a total amount by weight (G5b) and / or
  • one or more zwitterionic surfactants in a total amount by weight (G6b) contains, characterized in that
  • the weight ratio (G1a) / (G1 b) is at a value of 0.8 to 1.2
  • the weight ratio (G2a) / (G2b) is at a value of 0.8 to 1.2
  • the weight ratio (G6a) / (G6b) is at a value of 0.8 to 1.2
  • the fatty alcohols, the thickening polymers and the zwitterionic surfactants are mandatory ingredients in the preparations (a) and (b), the other ingredients are optional.
  • the aforementioned ingredients (G1) to (G6) were used in the preparations (a) and (b) in such total amounts that the sums of the total weight of Ingredients (G1) to (G6) in both formulations were also the same, ie if the weight ratio
  • a product for oxidative dyeing and / or brightening of keratinic fibers is therefore characterized in that
  • [(G1a) + (G2a) + (G3a) + (G4a) + (G5a) + (G6a)] / [(G1b) + (G2b) + (G3b) + (G4b) + (G5b) + ( G6b)] is at a value of from 0.6 to 1.4, preferably from 0.7 to 1.3, more preferably from 0.8 to 1.2, and particularly preferably from 0.9 to 1.1.
  • a product for oxidative dyeing and / or lightening of keratinic fibers wherein the preparation (a) - based on its total weight -
  • the weight ratio (G4a) / (G4b) at a value of 0.8 to 1, 2, preferably from 0.9 to 1, 1, is located. Also preferred is a product for oxidative dyeing and / or whitening of keratinic fibers, wherein the preparation (a) - based on its total weight -
  • G3b containing one or more cationic surfactants in a total amount by weight
  • the weight ratio (G3a) / (G3b) is at a value of 0.8 to 1, 2, preferably from 0.9 to 1, 1. Also preferred is a product for oxidative dyeing and / or whitening of keratinic fibers, wherein the preparation (a) - based on its total weight -
  • the weight ratio (G5a) / (G5b) is at a value of 0.8 to 1, 2, preferably from 0.9 to 1, 1. In the work leading to this invention, it has turned out, in particular, that it is essential to match the respective content of C 12 -C 30 fatty alcohols in preparations (a) and (b).
  • the Ci2-C3o-fatty alcohols are the most preferred fat constituents. Also preferred is a product for oxidative dyeing and / or whitening keratinischer fibers
  • the preparation (a) contains one or more fatty constituents selected from the group consisting of C 12 -C 30 fatty alcohols;
  • the preparation (b) contains one or more fatty constituents from the group of C 12-C 30 fatty alcohols,
  • the preparations (a) and (b) contain the same fatty alcohols.
  • the "same fatty alcohols” are understood to mean that the preparations (a) and (b) both contain the same or the same fatty alcohols or the same fatty alcohol raw materials, for example, the preparations (a) and (b) contain the same Fatty alcohols, if they contain both cetearyl alcohols, or both contain hydrazol D (cetearyl alcohol) or both contain Lorol C12-C18 techn. (Mixture of C12-C18 fatty alcohols)
  • the two preparations (a) and (b) contain mixtures of fatty alcohols of different chain lengths , so the distribution of the Fatty alcohol chain lengths should be the same in both preparations. When using the same raw materials in the two preparations (a) and (b) this is the case.
  • Preferred is a product for oxidative staining and / or brightening of keratinic fibers, comprising
  • the preparation (a) has a viscosity V1 of from 2000 to 80,000 mPas (22 ° C./ Brookfield viscometer / spindle 5/4 rpm),
  • the preparation (a) contains one or more fatty components from the group of C 12-C 30 -alcohols,
  • the preparation (b) has a viscosity V2 of 2000 to 80 000 mPas (22 ° C / Brookfield viscometer / spindle 5/4 rpm),
  • the preparation (b) contains one or more fatty constituents from the group of C 12-C 30 fatty alcohols,
  • the preparations (a) and (b) contain the same fatty alcohols.
  • the preparation (a) one or more anionic surfactants from the group of
  • the preparations (a) and (b) contain the same anionic surfactants.
  • a further particularly preferred product for oxidative dyeing and / or whitening of keratinic fibers is characterized in that -
  • the preparation (a) one or more nonionic surfactants from the group
  • preparations (a) and (b) contain the same nonionic surfactants.
  • preparation (a) is preferably an alkaline formulation, which optionally - if in addition to the lightening and a color change is desired, the oxidation dye precursors.
  • Preparation (b) is a formulation of oxidizing agent which, for reasons of stability, is acidified.
  • a product according to the invention is therefore characterized in that
  • the preparation (a) at least one alkalizing agent, preferably ammonia and / or monoethanolamine, and
  • the preparation (b) at least one oxidizing agent, preferably hydrogen peroxide.
  • the preparation (a) preferably contains at least one alkalizing agent, preferably ammonia and / or monoethanolamine.
  • Alkaliating agents useful in the invention may be selected from the group consisting of ammonia, alkanolamines, basic amino acids, and inorganic alkalizing agents such as (earth) alkali metal hydroxides, (earth) alkali metal metasilicates, (alkaline) alkaline metal phosphates, and (earth) alkali metal hydrogen phosphates.
  • Suitable inorganic alkalizing agents are sodium hydroxide, potassium hydroxide, sodium silicate and sodium metasilicate.
  • Organic alkalizing agents which can be used according to the invention can be selected from monoethanolamine, 2-amino-2-methylpropanol and triethanolamine.
  • the basic amino acids which can be used as alkalizing agents according to the invention are preferably selected from the group formed from arginine, lysine, ornithine and histidine, more preferably arginine.
  • ammonia is used in the form of its aqueous solution.
  • Aqueous ammonia solutions often contain ammonia (Nh) in concentrations between 10% and 32% by weight. Preference is given to the use of an aqueous ammonia solution containing 25 wt .-% ammonia (Nh).
  • ammonia and / or monoethanolamine in the preparation (a) in amounts of 0.01 to 10 wt .-%, preferably from 0.1 to 7.5 wt .-%, more preferably from 0.2 to 5.5 Wt .-% and particularly preferably from 0.4 to 4.5 wt .-% - each based on the total weight of the preparation (a) - included.
  • the pH of the ready-to-use By means of (ie the mixture of the preparations (a) and (b)) between 7 and 1 1, in particular between 8 and 10.5, is.
  • the pH values are pH values which were measured at a temperature of 22 ° C.
  • the preparation (a) is preferably adjusted to an alkaline pH, and the preparation (b) advantageously has an acidic pH.
  • a product according to the invention is characterized in that
  • the preparation (a) has a pH of 8 to 12.5, preferably from 8.5 to 12, more preferably from 9 to 1 1, 5 and particularly preferably from 9.5 to 1 1
  • the preparation (b) has a pH of 1 to 7, preferably from 1, 5 to 6, more preferably from 2.5 to 5.5 and particularly preferably from 3.0 to 5.0.
  • compositions (a) and / or (b) may contain further additional ingredients.
  • the preparation (a) additionally also contain one or more oxidation dye precursors, preferably at least one oxidation dye precursor of the developer type and at least one oxidation dye precursor of the coupler type.
  • developer-type oxidation dye precursors are selected from at least one compound from the group formed from p-phenylenediamine, p-toluenediamine, 2- (2-hydroxyethyl) -p-phenylenediamine, 2- (1,2-dihydroxyethyl ) -p-phenylenediamine, N, N-bis (2-hydroxyethyl) -p-phenylenediamine, 2-methoxymethyl-p-phenylenediamine, N- (4-amino-3-methylphenyl) -N- [3- ( 1 H -imidazol-1-yl) -propyl] amine, N, N'-bis (2-hydroxyethyl) -N, N'-bis (4-aminophenyl) -1, 3-diamino-propane-2 ol, bis (2-hydroxy-5-aminophenyl) methane, 1, 3-bis (2,5-diaminophenoxy) propan-2
  • coupler-type oxidation dye precursors are selected from the group formed from 3-aminophenol, 5-amino-2-methylphenol, 3-amino-2-chloro-6-methylphenol, 2-hydroxy-4-aminophenoxyethanol, 5-Amino-4-chloro-2-methylphenol, 5- (2-hydroxyethyl) amino-2-methylphenol, 2,4-dichloro-3-aminophenol, 2-aminophenol, 3-phenylenediamine, 2- (2,4 - diaminophenoxy) ethanol, 1, 3-bis (2,4-diaminophenoxy) propane, 1-methoxy-2-amino-4- (2-hydroxyethylamino) benzene, 1, 3-bis (2,4-diaminophenyl) propane, 2,6-bis (2'-hydroxyethylamino) -1-methylbenzene, 2 - ( ⁇ 3 - [(2-hydroxyethyl) amino] -4-methoxy-5-methylphenyl ⁇ amino) ethanol, 2
  • the preparation (a) may also contain at least one substantive dye from the group of anionic, nonionic and / or cationic dyes.
  • nonionic substantive direct dyes from the group HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Yellow 6, HC Yellow 12, HC Orange 1, Disperse Orange 3, HC Red 1, HC HC Red 7, HC Red 10, HC Red 1, HC Red 1, HC Red BN, HC Blue 2, HC Blue 1 1, HC Blue 12, Disperse Blue 3, HC Violet 1, Disperse Violet 1, Disperse Violet 4, Disperse Black 9, 1, 4-diamino-2-nitrobenzene, 2-amino-4-nitrophenol, 1, 4-bis (2-hydroxyethyl) amino-2-nitrobenzene, 3-nitro-4- ( 2-hydroxyethyl) aminophenol, 2- (2-hydroxyethyl) amino-4,6-dinitrophenol, 4 - [(2-hydroxyethyl) amino] -3-nitro-1-methylbenzene, 1-amino-4- (2 - hydroxyethyl) amino-5-chloro-2-nitrobenzene, 4-amino-3-nitrophenol, 1- (2'-
  • an agent according to the invention is characterized in that it additionally contains one or more nonionic substantive dyes from the group HC Yellow 2, HC Yellow 4, HC Yellow 5, HC Yellow 6, HC Yellow 12, HC Orange 1, Disperse HC Red 1, HC Red 1, HC Red 1, HC Red 1, HC Red 1, HC Red 1, HC Red 1, HC Red 1, HC Red BN, HC Blue 2, HC Blue 1 1, HC Blue 12, Disperse Blue 3, HC Violet 1, Disperse Violet 1, Disperse Violet 4, Disperse Black 9, 1, 4-diamino-2-nitrobenzene, 2-amino-4-nitrophenol, 1, 4-bis (2-hydroxyethyl) amino-2-nitrobenzene , 3-nitro-4- (2-hydroxyethyl) aminophenol, 2- (2-hydroxyethyl) amino-4,6-dinitrophenol, 4 - [(2-hydroxyethyl) amino] -3-nitro-1-methylbenzene, 1-Amino-4- (2-hydroxyethyl) amino-5-chloro-2-nitrobenz
  • anionic direct dyes may also be present, which are available under the international names or trade names Acid Yellow 1, Yellow 10, Acid Yellow 23, Acid Yellow 36, Acid Orange 7, Acid Red 33, Acid Red 52, Pigment Red 57: 1, Acid Blue 7, Acid Green 50, Acid Violet 43, Acid Black 1, Acid Black 52, Bromophenol Blue and Tetrabromophenol Blue are known.
  • Suitable cationic substantive dyes are cationic triphenylmethane dyes such as Basic Blue 7, Basic Blue 26, Basic Violet 2 and Basic Violet 14, aromatic systems, substituted with a quaternary nitrogen group, such as Basic Yellow 57, Basic Red 76, Basic Blue 99, Basic Brown 16 and Basic Brown 17, cationic anthraquinone dyes, such as HC Blue 16 (Bluequat B) and direct dyes that are a heterocycle containing at least one quaternary nitrogen atom, in particular Basic Yellow 87, Basic Orange 31 and Basic Red 51.
  • the cationic substantive dyes sold under the trademark Arianor are according to the invention also suitable cationic substantive dyes.
  • the oxidation dye precursors i. Developer components and coupler components, as well as the optionally additionally contained substantive dyes, for example, in an amount of 0.0001 to 5.0 wt .-%, preferably 0.001 to 3.5 wt .-%, each based on the total weight of the preparation (a) be used.
  • the preparations (a) and (b) may further comprise additional active ingredients, auxiliaries and additives in order to improve the coloring or brightening performance and to adjust further desired properties of the agents.
  • the colorants i.e., formulations (a) and especially (b)
  • they additionally contain hydrogen peroxide contain at least one stabilizer or complexing agent.
  • Particularly preferred stabilizers are phenacetin, alkali benzoates (sodium benzoate), salicylic acid and dipicolinic acid.
  • all complexing agents of the prior art can be used.
  • Preferred complexing agents according to the invention are nitrogen-containing polycarboxylic acids, in particular EDTA and EDDS, and phosphonates, in particular 1-hydroxyethane-1, 1-diphosphonate (HEDP) and / or ethylenediaminetetramethylenephosphonate (EDTMP) and / or diethylenetriaminepentamethylenephosphonate (DTPMP) or their sodium salts.
  • EDTA 1-hydroxyethane-1, 1-diphosphonate
  • EDTMP ethylenediaminetetramethylenephosphonate
  • DTPMP diethylenetriaminepentamethylenephosphonate
  • the preparations according to the invention may contain further active ingredients, auxiliaries and additives, for example nonionic polymers such as, for example, vinylpyrrolidinone / vinylacrylate copolymers, polyvinylpyrrolidinone, vinylpyrrolidinone / vinyl acetate copolymers, polyethylene glycols and polysiloxanes; additional silicones, such as volatile or nonvolatile, straight-chain, branched or cyclic, crosslinked or uncrosslinked polyalkylsiloxanes (such as dimethicones or cyclomethicones), polyarylsiloxanes and / or polyalkylarylsiloxanes, especially polysiloxanes with organofunctional groups, such as substituted or unsubstituted amines (amodimethicones), carboxyl Alkoxy and / or hydroxyl groups (dimethicone copolyols), linear polysiloxane (A) polyoxyalkylene (B) block copolymers
  • the dispenser is understood to mean a container comprising at least two chambers ((A) and (B)), which can be made of plastic, metal and / or plastic-metal composites, for example.
  • the donor can u. a.
  • all embodiments of the dispenser are suitable which ensure that the product compositions (a) and (b) present in the two chambers of the dispenser are reliably kept isolated from each other until removal.
  • the dispenser expediently comprises, in addition to the chambers (A), (B), a dispensing head within which the product compositions (a), (b) are conveyed from the chambers to the outlet opening (C).
  • a suitable mixing device is formed in the dispensing head, which provides the desired mixing of the product compositions (a), (b) upstream of the outlet opening (C) before the mixed overall formulation, ie (a) + (b) via the outlet opening (C). is delivered.
  • a mixing device is structurally integrated directly into the dispensing head or alternatively arranged as a separate component within the dispensing head.
  • Suitable mixing devices in the sense of the invention are, for example, static mixers or comparably acting mixing sections which are flowed through by the flowable product compositions (a), (b) and are sufficiently mixed in the course of this throughflow.
  • such a mixing section usually has suitable flow installations or flow baffles, which cause a mixing of individual fluid components in the case of flow around due to generated turbulences.
  • the mixing section of the mixing device according to the invention is preferably designed such that, although a defined minimum length of the mixing section is guaranteed, without giving up a compact overall construction of the mixing device and thus of the dispensing head. This ensures sufficient mixing results and at the same time ensures desired compact external dimensions of the mixing device and the dispensing head.
  • the mixing section is formed, for example, spirally or comparably compact within the dispensing head.
  • the chamber (B) of the dispenser may be located adjacent to, above or below the chamber (A). Furthermore, the chamber (B) within the chamber (A) or the chamber (A) inside the chamber (B), wherein each one of the chamber partially or completely envelops the other.
  • the capacity of the chambers (A) and (B) may be 10 cm 3 to 1000 cm 3, respectively, and the capacities of the chambers (A) and (B) may be the same or different.
  • the capacity of the chambers (A) and (B) is the same.
  • the chambers A and B are arranged side by side.
  • the dispenser has an outlet opening (C) which is in fluid communication with the two chambers (A) and (B) or can be fluidly connected thereto via valves.
  • the two formulations (a) and (b) are taken out simultaneously via the common outlet opening and preferably mixed together already upstream by means of the mixing device described above.
  • the usually reactive individual formulations (a) and (b) come into contact with each other only during product application and in this case form the ready-to-use mixture.
  • the outlet port (C) may be, for example, a pressure vessel dispenser, a pumping element, a valve, or a pasty mass dispenser.
  • the removal of the preparations (a) and (b) via the common outlet opening (C) can be effected by pressing the valve or by pumping the pumping element.
  • the dispenser can also be a squeeze container, in which case the removal of the preparations (a) and (b) preferably takes place by pressing the squeeze container, the pressure on the squeeze container for exiting the preparations (a) and (b) from the common outlet opening (C) leads.
  • a particularly preferred product is characterized in that the dispenser is a pressure vessel, wherein the outlet opening (C) is a pressure vessel dispenser, which also has a corresponding mixing device, and that the dispenser additionally comprises at least one propellant gas from the Propane, propene, n-butane, iso-butane, iso-butene, n-pentane, pentene, iso-pentane, iso-pentene, air, nitrogen, argon, N2O and / or CO2 contains.
  • the product according to the invention comprises a pressure vessel.
  • pressure gas container come vessels made of metal (aluminum, tinplate, tin), protected or non-splitterndem plastic or glass, which is coated with plastic outside, in question, in their selection pressure and fracture resistance, corrosion resistance, easy fillability as well as aesthetic Aspects, handiness, printability etc. play a role.
  • Special internal protective lacquers can, if necessary, guarantee the corrosion resistance to the preparation contained in the pressure vessel.
  • the two separate chambers (A) and (B) are two deformable bags, preferably of laminated aluminum, which each communicate with the outlet opening (C).
  • the outlet port (C) is a pressure vessel dispenser.
  • Both bags are located in a can-shaped pressure vessel, wherein the pressure vessel, together with the pressure vessel dispensing device, seals off the dispenser to the outside in a pressure-tight manner.
  • the space between the outer wall of the bag and the inner wall of the pressure vessel is filled with at least one propellant gas.
  • Corresponding dispensers are known, for example, from US 2009/0108021 A1.
  • a particularly preferred product for the treatment of keratinic fibers is therefore characterized by such a dispenser with a corresponding pressure vessel, which also has the mixing device described above.
  • the product further comprises a dispenser (corresponding to the outlet port C) which may have a valve for dispensing the application mixture.
  • the aerosol dispenser comprises a valve having a poppet and / or a flexible element having a return characteristic which is / are coated with a lacquer or a polymeric plastic are also preferred according to the invention.
  • the valve has a flexible element with a return characteristic and / or a valve disk of at least one plastic, preferably an elastomeric plastic.
  • cosmetic products according to the invention in which the valve has a flexible element with a return characteristic and / or a valve cone made of at least one plastic are preferred, with preferred plastics being elastomeric plastics.
  • Particularly preferred elastomeric plastics are selected from Buna, in particular Buna N, Buna 421, Buna 1602 and Buna KA 6712, neoprene, butyl and chlorobutyl.
  • the flexible element with return characteristic can be formed as a spiral spring or helical compression spring.
  • the flexible element of the valve with return characteristic can be formed integrally with the valve cone and have flexible legs. Such a spring may be made of metal or plastic.
  • All the valves used in the invention preferably have an internally painted valve disk, wherein paint and valve material are compatible with each other.
  • their valve disks can be internally z. B. be coated with Micoflex paint.
  • tinplate valves are used according to the invention, their valve disks can be internally z. B. be coated with PET (polyethylene terephthalate).
  • PET polyethylene terephthalate
  • the used containers, the z. B. tinplate or aluminum may be, aluminum containers are preferred according to the invention, in view of the corrosivity of the present invention used in water emulsions must also be painted or coated inside.
  • the dispensers additionally contain at least one propellant from the group of propane, propene, n-butane, isobutane, isobutene, n-pentane, pentene, isopentane, isopentene, Air, nitrogen, argon, N2O and / or CO2.
  • propellant from the group of propane, propene, n-butane, isobutane, isobutene, n-pentane, pentene, isopentane, isopentene, Air, nitrogen, argon, N2O and / or CO2.
  • the permanent gases air, nitrogen, argon, N2O and / or CO2 are preferred, most preferably nitrogen, argon and / or CO2.
  • the propellant gases are contained in certain pressures in the dispenser.
  • the inventive propellant gases are contained in certain pressures in the dispenser.
  • Dispenser one or more other propellant gases therefore with a pressure of 3 - 12 bar, preferably from
  • the dispenser is a dispenser for pasty masses, a multi-chamber tube or a squeeze container.
  • a product according to the invention is characterized in that - It is the dispenser to a dispenser for pasty masses, a tube or a squeeze container and
  • the product according to the invention comprises a multi-chamber tube which has an inner and an outer chamber, both of which terminate in a common outlet opening (C).
  • the head area is designed so that the two preparations emerge together from the tube as soon as pressure is exerted on the tube.
  • the design of this head area determines in which pattern the preparations emerge from the tube.
  • the present invention may include any distribution of the chambers within the tube.
  • the two individual chambers may be arranged side by side in an outer shell.
  • the multi-chamber tube consists of an inner tube which is completely surrounded by an outer tube.
  • the multi-chamber tube is preferably made of a material that is suitable for the packaging of oxdial- tive color change agents of this type.
  • laminated aluminum has proved itself both for the outer walls and for the inner walls.
  • tubes made of plastic laminate (PE, PET, PP) or plastic coextrudates (PE, PET, PP) are also conceivable.
  • the material of the inner tube can be selected independently of the material of the outer tube.
  • the invention has very particularly preferred a tube has been found in which the inner tube made of aluminum laminate, which is optionally still protected with a paint, and the outer tube is made either of aluminum laminate or plastic laminate. Under aluminum laminate is understood according to the invention a coated with plastic aluminum layer.
  • the shoulder region of the outer tube is reinforced with blanks which have particularly good barrier properties. It is advantageous to incorporate aluminum in the material of the blanks. In order to prevent leakage of the mixture during storage and to assure the consumer of the integrity of the tube, it is advantageous to seal the dispensing opening with a tamper-evident closure made of aluminum or plastic, which is removed by the consumer.
  • the choice of the volumes of the individual chambers (A) and (B) depends on the desired ratio of the volumes of preparation (a) and preparation (b). Preferably, the volumes of the chambers (A) and (B) are the same.
  • the amount ratio of preparation (a) to the amount of preparation (b) according to the invention is preferably in a range of 1: 3 to 3: 1, a range of 1: 1, 5 to 1, 5: 1 is preferred according to the invention, particularly preferred a ratio of 1: 1.
  • a product for oxidative dyeing and / or lightening of keratinic fibers comprising
  • the ratio of the viscosities V1 / V2 is at a value of 0.3 to 3.0 and
  • the weight ratio of the total weight of the preparation (a) to the total weight of the preparation (b) at a value of 0.5 to 2.0, preferably from 0.6 to 1, 8, more preferably from 0.7 to 1, 4 and more preferably from 0.8 to 1.2.
  • the indicated viscosities are viscosities measured at 22 ° C (22 ° C / Brookfield viscometer / spindle 5/4 rpm).
  • the products according to the invention can be used in processes for the oxidative change of the hair color. These processes are characterized by particular ease of use for the consumer, since the consuming and error-prone production of the application mixtures by the consumer is eliminated. In addition, application of the products enables a particularly uniform color result, since it is possible by the special rheological approximation of the formulations (a) and (b) to remove the two formulations during the entire application process in precisely defined, mutually always equal proportions.
  • the removal of the application mixture is usually carried out in portions, so that the chambers (A) and (B) of the product are gradually emptied in a defined ratio to each other.
  • the consumer will remove the amount of application mixture necessary for the coloring or lightening of one or more strands or hairpieces from the dispenser, and then apply these to the hair. This process will be repeated by the consumer until either the product is completely emptied or until the consumer has treated all the hair.
  • Another object of the present invention is a method for dyeing and / or lightening keratinischen fibers using a product of the first subject of the invention, wherein
  • the dispenser is continuously emptied in one step or in portions in individual steps and - At each step, respectively defined, constant amounts of the preparations (a) and (b) from the chambers (A) and (B) via the common outlet opening (C) of the dispenser until the complete emptying of the two chambers (A) and (B ).
  • Preferred is a method in which the chambers (A) and (B) are emptied in portions in several steps.
  • Particularly preferred is a method for dyeing and / or lightening keratinic fibers using a product of the first subject of the invention, wherein
  • the dispenser is depleted in portions in several steps and
  • (b) is the same, i. if the same quantities (a) and (b) are taken from the donor at each withdrawal step.
  • Glyceryl oleate fat component 0.6 0.6
  • Emulsifier 0.6 Coco-glucoside nonion.
  • Vitamin C Reducing Agent 0.10 -
  • Product W 37194 1 -propanaminium, N, N, N-trimethyl-3 - [(1-oxo-2-propenyl) amino] -, chlorides, polymer with sodium 2-propenoate (INCI: ACRYLAMIDOPROPYLTRIMONIUM CHLORIDE / ACRYLATES COPOLYMER) (20% aqueous solution)
  • Glyceryl oleate fat component 0.6 0.6
  • Emulsifier 0.6 Coco-glucoside nonion.
  • Vitamin C Reducing Agent 0.10 -
  • Vitamin C Reducing Agent 0.10 -
  • Vitamin C Reducing Agent 0.10 -

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Abstract

L'invention concerne un produit de coloration par oxydation et/ou d'éclaircissement de fibres de kératine, comprenant (1) un distributeur qui comporte deux chambres séparées (A) et (B), un orifice de sortie (C) qui est en communication avec la chambre (A) et la chambre (B), (2) une préparation cosmétique aqueuse (a) placée dans la chambre (A) et ayant une viscosité V1 de 1000 à 100 000 mPas (22°C/viscosimètre Brookfield/broche 5/4 tours par minute), (3) une préparation cosmétique aqueuse (b) placée dans la chambre (B) et ayant une viscosité V2 de 1000 à 100 000 mPas (22° C/viscosimètre Brookfield/broche 5/4 tours par minute). L'invention est caractérisée en ce que le rapport entre les viscosités V1/V2 a une valeur de 0,3 à 3,0.
EP14793008.5A 2013-08-27 2014-08-22 Produits en distributeur pour modifier la couleur de fibres de kératine par oxydation Ceased EP3038711A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102013217024.6A DE102013217024A1 (de) 2013-08-27 2013-08-27 Produkte im Spender zur oxidativen Farbveränderung von keratinischen Fasern
PCT/DE2014/200419 WO2015028015A1 (fr) 2013-08-27 2014-08-22 Produits en distributeur pour modifier la couleur de fibres de kératine par oxydation

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EP3038711A1 true EP3038711A1 (fr) 2016-07-06

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EP14793008.5A Ceased EP3038711A1 (fr) 2013-08-27 2014-08-22 Produits en distributeur pour modifier la couleur de fibres de kératine par oxydation

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US (1) US20160158582A1 (fr)
EP (1) EP3038711A1 (fr)
DE (1) DE102013217024A1 (fr)
WO (1) WO2015028015A1 (fr)

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DE102014017032A1 (de) 2014-11-19 2016-05-19 Henkel Ag & Co. Kgaa Abgabevorrichtung sowie zugehöriger Spender für fließfähige Produktzusammensetzungen
DE102015226171A1 (de) 2015-12-21 2017-06-22 Henkel Ag & Co. Kgaa Verfahren zur multitonalen Farbveränderung keratinischer Fasern
US10918183B2 (en) * 2017-12-21 2021-02-16 L'oreal Hair color cartridge and compositions for use in the hair color cartridge
DE102020207461A1 (de) * 2020-06-17 2021-12-23 Henkel Ag & Co. Kgaa Verdickte Alkalisierungskomponente für oxidatives Haaraufhellungsmittel
DE102020207463A1 (de) * 2020-06-17 2021-12-23 Henkel Ag & Co. Kgaa Verdickte Alkalisierungskomponente für oxidatives Haarfärbemittel

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WO2015028015A1 (fr) 2015-03-05
DE102013217024A1 (de) 2015-03-05

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