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EP2097501B1 - Nettoyant moussant pour surfaces dures - Google Patents

Nettoyant moussant pour surfaces dures Download PDF

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Publication number
EP2097501B1
EP2097501B1 EP06839936A EP06839936A EP2097501B1 EP 2097501 B1 EP2097501 B1 EP 2097501B1 EP 06839936 A EP06839936 A EP 06839936A EP 06839936 A EP06839936 A EP 06839936A EP 2097501 B1 EP2097501 B1 EP 2097501B1
Authority
EP
European Patent Office
Prior art keywords
composition
foamable composition
foregoing
weight
alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP06839936A
Other languages
German (de)
English (en)
Other versions
EP2097501A1 (fr
Inventor
Patrick Diet
Isabelle Leonard
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
Original Assignee
Colgate Palmolive Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Priority to PL06839936T priority Critical patent/PL2097501T3/pl
Publication of EP2097501A1 publication Critical patent/EP2097501A1/fr
Application granted granted Critical
Publication of EP2097501B1 publication Critical patent/EP2097501B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides

Definitions

  • Hard surface cleaners are usually mostly water that include cleaning materials, fragrance, and color. Hard Surface cleaners are usually sprayed onto a surface and then wiped to clean the surface. Because hard surface cleaners are mostly water, they will drip when applied to vertical surfaces because of gravity.
  • a foamable composition comprising:
  • ranges are used as a shorthand for describing each and every value that is within the range. Any value within the range can be selected as the terminus of the range.
  • the counter ion for the salt of a surfactant can be a metal ion, an ammonium ion, or an amine.
  • Metal cations that can be used include, but are not limited to, alkali metal ions and alkaline earth ions.
  • the metal cation ion can be lithium, sodium, potassium, magnesium, or calcium.
  • the amine is triethanolamine.
  • the foaming composition includes at least one anionic surfactant chosen from a salt of an alkyl sulfate surfactant and a salt of an alkyl ether sulfate surfactant, wherein the anionic surfactant comprises triethanolamine alkyl sulfate.
  • the surfactant is present in the composition in an amount of about 0.1 to about 1% by weight.
  • the alkyl is a C10 to C14 alkyl.
  • the surfactant comprises a triethanolamine lauryl sulfate.
  • the triethanolamine alkyl sulfate is present in an amount of about 0.1 to about 0.3% by weight, and in another embodiment in an amount of about 0.18 to about 0.22% by weight.
  • the surfactant comprises the salt of an alkyl ether sulfate.
  • the alkyl is a C10 to C14.
  • the surfactant is a sodium lauryl ether sulfate.
  • the sodium lauryl ether sulfate is present in an amount of about 0.05 to about 0.2% by weight, and in another embodiment at 0.06 to about 0.08 % by weight.
  • the foaming composition can include an amine oxide surfactant.
  • Amine oxide semi-polar nonionic surfactants can comprise compounds and mixtures of compounds having the formula: wherein R 1 is an alkyl, 2-hydroxyalkyl, 3-hydroxyalkyl, or 3-alkoxy-2-hydroxypropyl radical in which the alkyl and alkoxy, respectively, contain from 8 to 18 carbon atoms, R 2 and R 3 are each methyl, ethyl, propyl, isopropyl, 2-hydroxyethyl, 2-hydroxypropyl, or 3-hydroxypropyl, and n is from 0 to 10.
  • R 1 is a C 12-16 alkyl
  • R 2 and R 3 are methyl or ethyl.
  • the amine oxides comprise alkyl amine oxides and/or cocoamidopropyl amine oxide.
  • the ratio of anionic surfactant to amine oxide surfactant is about 3:1 to about 4:1.
  • the composition additionally includes at least one glycol ether.
  • the amount of glycol ether is about 0.1 to about 1.5% by weight.
  • glycol ethers include, but are not limited to, propylene glycol n-butyl ether, propylene glycol n-propyl ether, ethylene glycol n-hexal ether, ethylene glycol n-butyl ether, dipropylene glycol methyl ether, and combinations thereof.
  • the composition includes propylene glycol n-butyl ether in an amount up to about 1.5 % by weight, and in another embodiment at about 1.25 % by weight.
  • the foaming composition includes at least one alcohol. Any alcohol can be used in the composition.
  • the alcohol comprises a C 1 -C 6 alkyl alcohol.
  • the alcohol is chosen from methanol, ethanol, n-propanol, isopropanol, n-butyl alcohol, sec-butyl alcohol, isobutyl alcohol, tert-butyl alcohol, 1- 2-or 3- pentanol, neopentyl alcohol, and/or hexanol.
  • the alcohol is present in the composition in an amount of about 2 to about 6 % by weight, about 3 to about 5 % by weight, about 3 to about 4.5 % by weight, or in another embodiment, the amount is about 4% by weight.
  • the at least one alcohol comprises ethanol.
  • ethanol is present in the composition in an amount of about 2 to about 6% by weight, about 3 to about 5% by weight, about 3 to about 4.5% by weight, or in another embodiment, the amount is about 4% by weight.
  • the alcohol comprises ethanol and isopropanol.
  • isopropanol is present in an amount of 0 to about 1.5% by weight, and in another embodiment the isopropanol is present at about 1 % by weight.
  • the composition can optionally include at least one dispersant.
  • the dispersant can be present in any amount that provides a dispersant effect. In one embodiment, the dispersant is present in an amount of about 0.01 to about 1% by weight.
  • the dispersant is a maleic acid/ olefin copolymer. In one embodiment, a dispersant of this type is a maleic acid/diisobutylene copolymer available from Rohm and Haas under the trade name ACUSOLTM 460NK.
  • the composition can additionally include any fragrance or perfume.
  • the perfume is present in an amount of about 0.03 to about 0.08 % by weight.
  • the composition can additionally include any dye or coloring agent.
  • the composition can contain any pH agent, a biocide/antibacterial agent, or any other material for a desired effect.
  • ammonium hydroxide and/or vinegar can be included, and in one embodiment they can be included up to about 0.2% by weight.
  • citric acid can be used to adjust the pH of the composition.
  • Water can be included in the composition in any amount to make the sum of the amount of materials in the composition total 100 weight percent.
  • the composition when applied as a foam to a vertical glass surface will have a run down time of greater than about 15 seconds. In other embodiments, the run down time is greater than about 18 seconds, greater than about 20 seconds, greater than about 23 seconds, or about 15 to about 30 seconds. Run down time is measured by applying the foamed composition to a vertical glass surface, which is perpendicular to the earth's surface, at a first horizontal line marked on the surface from a distance of 20 cm perpendicular to the surface using a foaming dispenser. A second horizontal line is marked 10 cm below the first horizontal line on the glass surface. Run down time is the time that it takes the composition to run down from the first line to the second line. Both the first and second horizontal lines are parallel to the earth's surface.
  • the foam is generated by a foaming dispenser that mixes air with the composition when it is dispensed.
  • the composition does not contain any propellants that would eject the composition from the container or cause the composition to foam.
  • Any foaming dispenser can be used with the composition.
  • the dispenser is available from MeadWestvaco Calmar GmbH under the product name TS 800 Top Gun Trigger Sprayer.
  • the composition can be used as a cleaner on all surfaces.
  • the surface is a horizontal surface, which is parallel to the earth's surface.
  • the surface is a non-horizontal surfaces, such as those that arse angled at greater than 0 to 90Ā° to the earth's surface.
  • the composition can be used as a cleaner on a vertical surface, which is perpendicular to the earth's surface.
  • the composition is a glass cleaner.
  • the composition can be used in a method for removing soil from a surface comprising applying the composition to the surface and removing the composition.
  • Removing includes, but is not limited to, wiping, squeegeeing, rinsing, and mopping.
  • the surface can be, horizontal, non-horizontal, or vertical.
  • composition according to the invention was prepared by mixing the ingredients.
  • the composition was added to a container with a foaming dispenser.
  • Material % by weight Triethanolamine lauryl sulfate 0.2
  • composition was compared against AJAXTM Triple Action Glass Cleaner, which is commercially available in Europe in a conventional glass cleaner spray bottle, in the run down test described above.
  • a positioning device was used to position each container so that they sprayed at the same point on the vertical glass surface.
  • Several runs were conducted, and the results are shown in the table below. Time is in seconds.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne une composition moussante comprenant : a) au moins un tensioactif anionique choisi parmi un sel d'un sulfate d'alkyle et un sel d'un Ʃther sulfate d'alkyle en une quantitƩ d'environ 0,01 Ơ environ 1 % en poids de la composition ; b) au moins un Ʃther de glycol en une quantitƩ d'environ 0,1 Ơ environ 1,5 % en poids de la composition ; c) au moins un alcool en une quantitƩ d'environ 2 Ơ environ 6 % en poids de la composition ; et d) de l'eau. L'invention concerne Ʃgalement une composition moussante comprenant : a) au moins un tensioactif anionique choisi parmi un sel d'un sulfate d'alkyle et un sel d'un Ʃther sulfate d'alkyle ; b) au moins un Ʃther de glycol ; c) au moins un alcool ; et d) de l'eau, ladite composition ayant un temps d'Ʃcoulement supƩrieur Ơ environ 15 secondes sur une surface en verre verticale sur une distance de 10 cm.

Claims (14)

  1. Composition moussante comprenant :
    a) au moins un tensioactif anionique choisi parmi un sel d'un sulfate d'alkyle et un sel d'un sulfate d'Ć©ther d'alkyle dans une quantitĆ© de 0,01 % Ć  1 % en poids de la composition, oĆ¹ le tensioactif anionique comprend un sulfate d'alkyle triĆ©thanolamine ;
    b) au moins un Ʃther de glycol dans une quantitƩ de 0,1 % Ơ 1,5 % en poids de la composition ;
    c) au moins un alcool dans une quantitƩ de 2 % Ơ 6 % en poids de la composition ; et
    d) de l'eau.
  2. Composition moussante selon la revendication 1, dans laquelle le tensioactif anionique comprend du sulfate de lauryle triƩthanolamine.
  3. Composition moussante selon la revendication 1 ou 2, dans laquelle l'Ć©ther de glycol est le propylĆØne glycol n-butyl Ć©ther.
  4. Composition moussante selon l'une quelconque des revendications prƩcƩdentes, dans laquelle l'alcool comprend un alcool alkylique en C1 Ơ C6,
  5. Composition moussante selon l'une quelconque des revendications prƩcƩdentes, dans laquelle l'alcool alkylique en C1 Ơ C6 est l'Ʃthanol, ou un mƩlange d'Ʃthanol et d'isopropanol.
  6. Composition moussante selon l'une quelconque des revendications prĆ©cĆ©dentes, comprenant en outre un tensioactif d'oxyde d'amine, oĆ¹ l'oxyde d'amine est Ć©ventuellement prĆ©sent dans la composition moussante dans un rapport du tensioactif anionique par rapport au tensioactif d'oxyde d'amine de 3 : 1 Ć  4 : 1.
  7. Composition moussante selon l'une quelconque des revendications prĆ©cĆ©dentes, comprenant en outre un dispersant, oĆ¹ le dispersant comprend Ć©ventuellement un copolymĆØre d'acide malĆ©ique et une olĆ©fine.
  8. Composition moussante selon l'une quelconque des revendications prĆ©cĆ©dentes, dans laquelle le tensioactif anionique comprend du sulfate de lauryle triĆ©thanolamine, l'Ć©ther de glycol comprend du propylĆØne glycol n-butyl Ć©ther, et l'alcool comprend de l'Ć©thanol.
  9. Composition moussante selon l'une quelconque des revendications prƩcƩdentes, comprenant en outre un matƩriau choisi parmi un agent pH, une fragrance, un parfum, un agent colorant, un colorant, un agent biocide/antibactƩrien, de l'hydroxyde d'ammonium et du vinaigre.
  10. Composition moussante selon l'une quelconque des revendications prĆ©cĆ©dentes, dans laquelle la composition prĆ©sente un temps d'Ć©coulement supĆ©rieur Ć  environ 15 secondes, oĆ¹ le temps d'Ć©coulement est mesurĆ© en fournissant une surface verticale en verre avec une premiĆØre ligne horizontale qui est Ć  10 cm au-dessus d'une deuxiĆØme ligne horizontale, en appliquant la composition Ć  la surface verticale en verre Ć  la premiĆØre ligne horizontale Ć  partir d'une distance de 20 cm perpendiculairement Ć  la surface, et en mesurant le temps pour que la composition descende de la premiĆØre ligne horizontale Ć  la deuxiĆØme ligne horizontale.
  11. Composition moussante selon la revendication 10, dans laquelle le temps d'Ʃcoulement est supƩrieur Ơ environ 20 secondes.
  12. Article comprenant un rƩcipient dotƩ d'un distributeur qui fait mousser une composition distribuƩe Ơ travers le distributeur et la composition moussante selon l'une quelconque des revendications prƩcƩdentes disposƩe dans le rƩcipient.
  13. ProcƩdƩ destinƩ Ơ Ʃliminer une salissure d'une surface, consistant Ơ appliquer la composition selon l'une quelconque des revendications prƩcƩdentes Ơ la surface, et Ơ Ʃliminer la composition.
  14. ProcƩdƩ selon la revendication 13, dans lequel la surface est une surface verticale.
EP06839936A 2006-11-17 2006-11-17 Nettoyant moussant pour surfaces dures Not-in-force EP2097501B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL06839936T PL2097501T3 (pl) 2006-11-17 2006-11-17 Pieniący środek do czyszczenia stałych powierzchni

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2006/061047 WO2008060303A1 (fr) 2006-11-17 2006-11-17 Nettoyant moussant pour surfaces dures

Publications (2)

Publication Number Publication Date
EP2097501A1 EP2097501A1 (fr) 2009-09-09
EP2097501B1 true EP2097501B1 (fr) 2012-06-06

Family

ID=38255536

Family Applications (1)

Application Number Title Priority Date Filing Date
EP06839936A Not-in-force EP2097501B1 (fr) 2006-11-17 2006-11-17 Nettoyant moussant pour surfaces dures

Country Status (14)

Country Link
EP (1) EP2097501B1 (fr)
CN (1) CN101563442B (fr)
AU (1) AU2006350750B2 (fr)
CA (1) CA2669329C (fr)
CR (1) CR10800A (fr)
DK (1) DK2097501T3 (fr)
EC (1) ECSP099329A (fr)
ES (1) ES2388617T3 (fr)
MX (1) MX2009005155A (fr)
NO (1) NO20092326L (fr)
NZ (1) NZ576960A (fr)
PL (1) PL2097501T3 (fr)
PT (1) PT2097501E (fr)
WO (1) WO2008060303A1 (fr)

Families Citing this family (4)

* Cited by examiner, ā€  Cited by third party
Publication number Priority date Publication date Assignee Title
MX338888B (es) * 2011-03-08 2016-05-04 Sca Hygiene Prod Ab Composicion limpiadora antimicrobiana baja en alcohol.
CN111479911A (zh) * 2017-12-12 2020-07-31 č·å…°č”åˆåˆ©åŽęœ‰é™å…¬åø åÆå‘ę³”ęø…꓁ē»„合ē‰©
CN111718804A (zh) * 2020-07-24 2020-09-29 äøŠęµ·ē»æē‘žē”Ÿē‰©ē§‘ęŠ€ęœ‰é™å…¬åø äø€ē§ę³”ę²«åž‹ęø…ę“—å‰‚ē»„合ē‰©åŠå…¶åŗ”ē”Ø
CN117651757A (zh) * 2021-02-24 2024-03-05 胜ē‰Œå…Øēƒäŗ§å“ēŸ„čƆäŗ§ęƒęœ‰é™å…¬åø å‘ę³”č’ø发å™Øē›˜ē®”ęø…ę“å‰‚

Citations (1)

* Cited by examiner, ā€  Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007033761A1 (fr) * 2005-09-16 2007-03-29 Henkel Kommanditgesellschaft Auf Aktien Produit de nettoyage pour surfaces dures

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Publication number Priority date Publication date Assignee Title
US3463735A (en) * 1967-10-18 1969-08-26 Drackett Co Glass cleaning composition
US4606842A (en) * 1982-03-05 1986-08-19 Drackett Company Cleaning composition for glass and similar hard surfaces
ZA925727B (en) * 1991-08-09 1993-03-10 Bristol Myers Squibb Co Glass cleaning composition.
CA2299292C (fr) * 1997-08-13 2003-07-15 The Procter & Gamble Company Composition de nettoyage de vitres, a bon pouvoir lubrifiant de surfaces et a tampon alcalin
GB2339789A (en) * 1998-07-16 2000-02-09 Reckitt & Colman Inc Aqueous cleaning and surface treatment compositions
US7666826B2 (en) * 2002-11-27 2010-02-23 Ecolab Inc. Foam dispenser for use in foaming cleaning composition
US20050026796A1 (en) * 2003-07-30 2005-02-03 Colgate-Palmolive Company Foam glass cleaning composition

Patent Citations (1)

* Cited by examiner, ā€  Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007033761A1 (fr) * 2005-09-16 2007-03-29 Henkel Kommanditgesellschaft Auf Aktien Produit de nettoyage pour surfaces dures

Also Published As

Publication number Publication date
AU2006350750A1 (en) 2008-05-22
CA2669329C (fr) 2013-10-01
WO2008060303A1 (fr) 2008-05-22
CA2669329A1 (fr) 2008-05-22
ES2388617T3 (es) 2012-10-17
AU2006350750B2 (en) 2011-05-12
DK2097501T3 (da) 2012-09-17
PT2097501E (pt) 2012-09-10
CR10800A (es) 2009-09-03
NZ576960A (en) 2011-11-25
CN101563442A (zh) 2009-10-21
NO20092326L (no) 2009-08-04
ECSP099329A (es) 2009-06-30
EP2097501A1 (fr) 2009-09-09
PL2097501T3 (pl) 2012-10-31
MX2009005155A (es) 2009-05-25
CN101563442B (zh) 2013-06-19

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