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EP1328154A1 - Composition pesticide - Google Patents

Composition pesticide

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Publication number
EP1328154A1
EP1328154A1 EP01976797A EP01976797A EP1328154A1 EP 1328154 A1 EP1328154 A1 EP 1328154A1 EP 01976797 A EP01976797 A EP 01976797A EP 01976797 A EP01976797 A EP 01976797A EP 1328154 A1 EP1328154 A1 EP 1328154A1
Authority
EP
European Patent Office
Prior art keywords
group
substituted
unsubstituted
compound
atom
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP01976797A
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German (de)
English (en)
Other versions
EP1328154B1 (fr
Inventor
Masayuki c/o Ishihara Sangyo Kaisha Ltd. MORITA
Mitsugu c/o Ishihara Sangyo Kaisha Ltd. IWASA
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Ishihara Sangyo Kaisha Ltd
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Ishihara Sangyo Kaisha Ltd
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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings

Definitions

  • the present invention relates to an agriculturally useful pesticidal composition
  • an agriculturally useful pesticidal composition comprising a combination of a pyridic compound of the formula (I) described hereinafter or its salt with other insecticides, fungicides or the like.
  • a pyridic compound of the formula (I) or its salt is disclosed in Japanese Patent No. 2994182, JP-A-10-195072 , JP-A-11-180957 , WO 98/57969, WO 00/35285, WO 00/35912, WO 00/35913, WO 01/9104, WO 01/14373 and the like.
  • Conventional pesticides have respectively characteristic spectrums and effects, but have some problems that the effects are sometimes unsatisfactory to certain pests, that their residual activities are sometimes poor and the effects are not satisfactorily maintained for a certain period of time, and that satisfactory pesticidal effects can not be practically achieved depending on applications. Also, even if there are some pesticides excellent in their pesticidal effects, they are demanded to be improved in respect of safety to fishes, Crustacea and domestic animals and are also demanded to achieve a high pesticidal effect at a small dosage .
  • the present inventors have intensively studied to solve these problems, and as a result of the study, they have discovered that by combining a pyridic compound of the following formula (I) or its salt with other pesticide, unexpected effects of killing pests grown in some place by one time and reducing a dosage than in a case of using an effective component respectively alone, can be achieved.
  • the present invention has been accomplished on the basis of this discovery.
  • the present invention provides a pesticidal composition
  • a pesticidal composition comprising at least one of a pyridic compound of the formula (I) or its salt and at least one of other pesticides :
  • R 1 and R 2 are respectively independently a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted cycloalkyl group, a -C(W 1 )R 3 group, a -OR 4 group, a -S(0) n R 5 group, a -NHR 6 group,
  • R 3 is a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, an alkoxy group, an alkylthio group or a mono- or dialkylamino group
  • R 4 is a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alken
  • Y includes a haloalkyl group such as CF 3 , CHF 2 , CH 2 F, CF 2 C1, CFCl 2 , CC1 3 , CH 2 CF 3 , CF 2 CF 3 , CHBr 2 , CH 2 Br or the like.
  • a haloalkyl group having a carbon number of from 1 to 2 and a halogen atom of from 1 to 5 is preferable, and a trifluoromethyl group is particularly preferable.
  • Q 1 group include a halogen atom; an alkoxy group; an alkylthio group; a trialkylsilyl group; a phenyl group; a phenyl group substituted with a halogen, alkyl, alkoxy, nitro or haloalkyl group; a phenyl group substituted with a phenoxy group which may be substituted with an alkoxy or alkylthio group; a phenoxy group; a phenylthio group; an amino group; an amino group substituted with one or two alkyl group; a C 2 -6 cyclic amino group; a morpholino group; a morpholino group substituted with an alkyl group; a 1-piperazinyl group; a 1-piperazinyl group substituted with an alkyl, phenyl, pyridyl or trifluoromethylpyridyl group; a heterocyclic group which may be
  • substituents of a substituted or unsubstituted alkyl group defined as R 1 or R 2 included in the Q 1 group in the formula (I) include a 4-haloalkyl-3-pyridinecarboxyamide group, a N-methyl-4- haloalkyl-3-pyridinecarboxyamide group, a 4-haloalkyl-3- pyridinecarboxyamide-N-alkylenoxy group, and the like.
  • a chemical structure formula of the formula (I) including these substituents is illustrated below:
  • R 2 is as defined above, A is a -(CH 2 ) ⁇ - group or a - (CH 2 ) g-O- (CH 2 ) q - group, 1 is an integer of from 1 to 4 and q is 1 or 2) .
  • an effective component of the composition of the present invention includes a trimer .
  • Examples of a secondary substituent of a substituted or unsubstituted aryl group defined as R 1 , R 2 , R 3 , R 4 , R 8 , R 9 , R 12 or R 13 included in the Ql group in the formula (I) include a halogen atom; an alkyl group; a haloalkyl group; an alkoxy group; a haloalkoxy group; an alkylthio group; a cycloalkyl group; a cycloalkoxy group; an alkoxycarbonyl group; an alkylcarbonyl group; an alkylcarbonyloxy group; an aryl group; an aryloxy group; an arylthio group; an amino group; an amino group substituted with 1 or 2 alkyl group; a cyano group; a nitro group; a hydroxy group; and the like.
  • Examples of a secondary substituent of a substituted or unsubstituted heterocyclic group defined as R 4 , R 8 , R 9 , R 10 , R 11 , R 12 or R 13 included in the Q 1 group in the formula (I) include a halogen atom; an alkyl group; an alkoxy group; a haloalkoxy group; an alkylthio group; a phenyl group which may be substituted with a halogen, alkyl, alkoxy, nitro, haloalkyl or phenoxy group; a phenoxy group; a phenylthio group; a cycloalkyl group; a cycloalkoxy group; and the like.
  • Examples of an alkyl moiety or an alkyl group included in the Q 1 group in the formula (I) include a group having a carbon number of from 1 to 6 such as a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group and the like, and a group having a carbon number of at least 3 may include a linear or branched chain structure isomer.
  • Examples of an alkenyl group included in the Q 1 group in the formula (I) include a group having a carbon number of from 2 to 6 such as an ethenyl group, a propylenyl group, a butenyl group, a pentenyl group, a hexenyl group and the like, and a group having a carbon number of at least 3 may include a linear or branched chain structure isomer.
  • Examples of an alkynyl group included in the Q 1 group in the formula (I) include a group having a carbon number of from 2 to 6 such as an ethynyl group, a propynyl group, a butynyl group, a pentynyl group, a hexynyl group, and a group having a carbon number of at least 4 may include a linear of branched chain structure isomer.
  • Examples of a cycloalkyl group included in the Q 1 group in the formula (I) include a group having a carbon number of from 3 to 8 such as a cyclopropyl group, a cyclobutyl group, a cyclopentyl group or a cyclohexyl group.
  • Examples of a C 4 -C 5 5-membered or 6-membered heterocyclic group which may contain a nitrogen atom or an oxygen atom, formed from R 1 and R 2 together with an adjacent nitrogen atom, included in the Q 1 group in the formula (I), include a morpholino group, a pyrrolidino group, a piperidino group, a 1-imidazolidinyl group, a 2- cyanoimino-3-methyl-l-imidazolidinyl group, a 1- piperazinyl group or a 4-methyl-1-piperazinyl group.
  • Examples of an aryl group included in the Q 1 group in the formula (I) include a phenyl group, a thienyl group, a furanyl group, a pyridyl group, a naphthyl group, a benzothienyl group, a benzofuranyl group, a quinolinyl group and the like.
  • Examples of a heterocyclic moiety of a substituted or unsubstituted heterocyclic group included in the Q 1 group in the formula (I) include a 5 to 7-membered monocyclic or phenyl-condensed cyclic group containing 1 to 3 hetero atoms selected from a nitrogen atom, an oxygen atom and a sulfur atom, such as a pyridyl group, a thienyl group, a furyl group, a pirazinyl group, a pyrimidinyl group, a tetrahydrofuranyl group, a thiazolyl group, an isooxazolyl group, a quinolyl group, a pyrazolyl group, an oxazolyl group, an oxadiazolyl group, a thiadiazolyl group, a triazolyl group and the like.
  • Examples of a heterocyclic moiety of a substituted or unsubstituted heterocyclic group represented by Q in the formula (I) include preferably a 5 to 7-membered monocyclic group containing 2 to 3 hetero atoms selected from a nitrogen atom, an oxygen atom and a sulfur atom, such as a 5-membered monocyclic group including a pyrazolyl group, an oxazolyl group, a thiazolyl group, an oxydiazolyl group, a thiadiazolyl group, a triazolyl group and the like; and a 6-membered monocyclic group such as :
  • Examples of a secondary substituent of a substituted or unsubstituted heterocyclic group expressed by Q in the formula (I) include a halogen atom, a nitro group, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, a substituted or unsubstituted cycloalkyl group, a hydroxyl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted alkenyloxy group, a substituted or unsubstituted alkynyloxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted heterocyclicoxy group, a substituted or unsubstituted
  • some substituents may further be substituted with a tertiary substituent such as a halogen atom; a cyano group; an alkyl group which may be substituted with halogen, haloalkyl, cyano, alkoxy or aryl; an alkoxy group which may be substituted with halogen or aryl; a hydroxyl group; an amino group which may be substituted with alkylsulfonyl, arylalkyl, heterocyclic alkyl, alkyl, aryl, alkylaryl, alkylhydroxy, cyanoalkyl , alkynyl, alkenyl or cycloalkyl; a carbonyl group which may be substituted with alkoxy, alkylamino or alkyl; an alkylthio group; an aryloxy group; an arylthio group; an aryl group which may be substituted with halogen, haloalkoxy, alkyl
  • Examples of an alkyl moiety or an alkyl group in a secondary substituent or a tertiary substituent of a substituted or unsubstituted heterocyclic group expressed by Q in the formula (I) include a group having a carbon number of from 1 to 6, such as a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group or a hexyl group, and a group having at least 3 carbon atoms may be a linear or branched chain structure isomer.
  • Examples of an alkenyl group include a group having a carbon number of from 2 to 6, such as an ethenyl group, a propenyl group, a butenyl group, a pentenyl group or a hexenyl group, and a group having at least 3 carbon atoms may be a linear or branched chain structure isomer.
  • Examples of an alkynyl group include a group having a carbon number of from 2 to 6, such as an ethynyl group, a propinyl group, a butynyl group, a pentynyl group or a hexynyl group, and a group having at least 3 carbon atoms may be a linear or branched chain structure isomer.
  • Examples of a cycloalkyl group include a group having a carbon number of from 3 to 8, such as a cyclopropyl group, a cyclobutyl group, a cyclopentyl group or a cyclohexyl group.
  • Examples of an aryl group include a phenyl group, a thienyl group, a furanyl group, a pyridyl group, a naphthyl group, a benzothienyl group, a benzofuranyl group or a quinolinyl group.
  • heterocyclic group examples include a 5-membered or 6-membered monocyclic or phenyl-condensed cyclic group having 1 to 3 hetero atoms selected from a nitrogen atom, an oxygen atom and a sulfur atom, such as a pyridyl group, a thienyl group, a furyl group, a pyrazinyl group, a thiazolyl group, an isooxazolyl group and a quinolyl group.
  • a compound of the formula (I) may form a salt with an acidic material or a basic material
  • examples of a salt with an acidic material include an inorganic acid salt such as a hydrochloride, a hydrobromide, a phosphate, a sulfate or a nitrate
  • examples of a salt with a basic material include an inorganic or organic base salt such as a sodium salt, a potassium salt, a calcium salt, an ammonium salt or a dimethylamine salt .
  • a compound of the formula (I) or its salt can be produced in accordance with a method disclosed in Japanese Patent No. 2994182, JP-A-10-195072 , JP-A-11- 180957, WO 98/57969, WO 00/35285, WO 00/35912, WO 00/35913, WO 01/9104, WO 01/14373 or the like.
  • Examples of a pyridic compound or its salt preferable as an effective component of a pesticidal composition of the present invention are illustrated below, but the present invention is not limited thereto.
  • R 1 and R 2 are respectively independently a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted cycloalkyl group, a -C(W 1 )R 3 group, a -S(0) n R 5 group, a -NHR 6 group,
  • R 1 and R 2 are respectively independently a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted cycloalkyl group, a -C(W 1 )R 3 group, a
  • R 1 is a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted alkynyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group or a -C(W 1 )R 3 group, and R 3 , R 4 and W 1 are as defined above .
  • R 1 is a hydrogen atom
  • R 8 and R 9 are as defined above.
  • R 10 is a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group or a substituted or unsubstituted heterocyclic group
  • R 12 and-R 13 are as defined above.
  • a compound or its salt of the above (1) wherein the compound of the formula (I) is at least one member selected from the group consisting of N-cyanomethyl-4- trifluoromethyl-3-pyridinecarboxyamide (Compound No. 1), N-ethyl-4-trifluoromethyl-3-pyridinecarboxyamide (Compound No. 2), 4-trifluoromethyl-3- pyridinecarboxyamide 1-oxide (Compound No. 3), 4- trifluoromethyl-3-pyridinecarboxyamide (Compound No.
  • heterocyclic group moiety is a 5 to 7-membered monocyclic group having 2 to 3 hetero atoms selected from the group consisting of a nitrogen atom, an oxygen atom and a sulfur atom.
  • heterocyclic group moiety is a 5-membered monocyclic group containing 2 to 3 hetero atoms selected from the group consisting of a nitrogen atom, an oxygen atom and a sulfur atom.
  • a compound or its salt of the above (18) wherein the 5-membered monocyclic group is a pyrazolyl group, an oxazolyl group, a thiazolyl group, an oxydiazolyl group, a thiadiazolyl group or a triazolyl group.
  • the heterocyclic group moiety is a 6-membered monocyclic group containing 2 to 3 hetero atoms selected from the group consisting of a nitrogen atom, an oxygen atom and a sulfur atom.
  • R 16 is an alkyl group
  • R 16 is a methyl group or an isopropyl group.
  • a compound of the formula 10. (I) or its salt is used in combination with other pesticides, examples of which include insecticides, fungicides, microbial agricultural chemicals such as B.T. and insect viruses, but it is preferable to use insecticides and/or fungicides, and it is more preferable 15 to use insecticides.
  • insecticides usable as an effective component for a pesticidal composition of the present invention are illustrated below.
  • IGR agent insect growth regulating agent
  • IGR agent insect growth regulating agent
  • IGR agent insect growth regulating agent
  • insecticides usable as a pesticide include a dinitro type compound, an organic sulfur compound, a urea type compound, a triazine type compound, a hydrazone type compound; an IGR agent (insect growth regulating agent) such as Cyromazine; an IGR agent for mites such as Hexythiazox or Etoxazole; Pyridaben, Amitraz, Chlordimeform, Triazamate, Pymetrozine,
  • IGR agent Pyrimidifen, Indoxacarb, Acequinocyl, 1, 3-dichloropropene, Fluacrypyrim, Spirodiclofen, Bifenazate or the like, or Bacillus thuringienses or a crystalline protein toxin produced thereby, and the like.
  • IGR agent it is preferable to use an IGR agent.
  • an IGR agent it is preferable to use at least one member selected from the group consisting of (E) a benzoylurea type compound, (G) a hydrazine type compound, (H) a juvenile hormone-like compound, (K) a thiadiazine type compound, Hexythiazox, Etoxazole and Cyromazine.
  • E a benzoylurea type compound
  • G a hydrazine type compound
  • H a juvenile hormone-like compound
  • K a thiadiazine type compound
  • Hexythiazox Etoxazole and Cyromazine.
  • a pesticidal composition comprising a compound of the formula (I) or its salt and a benzoylurea type compound as effective components achieves a particularly excellent pesticidal effect.
  • benzoylurea type compound it is preferable to use at least one member selected from the group consisting of the compounds illustrated in the above (E-1) to (E-8), but it is more preferable to use at least one compound selected from the group consisting of Diflubenzuron, Chlorfluazuron, Teflubenzuron and Flufenoxuron, and it is most preferable to use Chlorfluazuron and/or Flufenoxuron.
  • examples of a more preferable form of an insecticide usable as an effective component of a pesticidal composition of the present invention include the following cases.
  • the insecticide is at least one compound selected from the group consisting of (A) organophosphorus compounds, (B) carbamate compounds, (C) pyrethroid compounds, (D) neonicotinoid compounds, (E) benzoylurea compounds, (F) nelicetoxin derivatives, (G) hydrazine compounds, (H) juvenile hormone-like compounds, (I) antibiotics, (J) pyrrole compounds, (K) thiadiazine compounds, (L) silane compounds, (M) organochlorine compounds, (N) pyrazole compounds, and (0) organotin compounds .
  • A organophosphorus compounds
  • B carbamate compounds
  • C pyrethroid compounds
  • D neonicotinoid compounds
  • E benzoylurea compounds
  • F nelicetoxin derivatives
  • G hydrazine compounds
  • H juvenile hormone-like compounds
  • I antibiotics
  • J pyrrole compounds
  • K thiadiazine compounds
  • the insecticide is at least one compound of (1) selected from the group consisting of (A) organophosphorus compounds, (B) carbamate compounds, (C) pyrethroid compounds, (D) neonicotinoid compounds, (E) benzoylurea compounds, (F) nelicetoxin derivatives, (G) hydrazine compounds, (H) juvenile hormone-like compounds, (I) antibiotics, (J) pyrrole compounds, (K) thiadiazine compounds, (L) silane compounds and (M) organochlorine compounds .
  • the insecticide is at least one compound of (2) selected from the group consisting of Dichlorvos, Diazinon, Chlorpyrifos, Acephate, Fosthiazate, Isoxathion, Methidathion, ESP, Methomyl, Ethiofencarb, Pirimicarb, Fenoxycarb, Fenvalerate, Cypermethrin, Deltamethrin, Cyhalothrin, Ethofenprox, Fluvalinate, Acetamiprid, Diflubenzuron, Chlorfluazuron, Teflubenzuron, Flufenoxuron, Cartap, Tebufenozide, Pyriproxyfen, Spinosad, Emamectin-benzoate, Chlorfenapyr, Buprofezin, and Silafluofen.
  • a fungicide usable as an effective component of a pesticidal composition of the present invention are illustrated below.
  • examples of an effective component of a fungicide usable as other pesticide include pyrimidinamine compounds such as Mepanipyrim, Pyrimethanil and Cyprodinil;
  • Azole compounds such as Triadimefon, Bitertanol, Triflumizole, Etaconazole, Propiconazole, Penconazole, Flusilazole, Myclobutanil, Cyproconazole, Terbuconazole, Hexaconazole, Furconazole-cis, Prochloraz, Metconazole, Epoxiconazole, Tetraconazole, Oxpoconazole and Sipconazole; Quinoxaline compounds such as Quinomethionate; Dithiocarbamate compounds such as Maneb, Zineb, Mancozeb, polycarbamate and Propineb;
  • Imidazole compounds such as Benomyl, Thiophanate- Methyl, Carbendazim and Cyazofamid; Pyridinamine compounds such as Fluazinam;
  • Cyanoacetamide compounds such as Cymoxanil
  • Phenylamide compounds such as Metalaxyl, Oxadixyl, Ofurace, Benalaxyl, Furalaxyl and Cyprofuram;
  • Sulfenic acid compounds such as Dichlofluanid
  • Copper compounds such as Cupric hydroxide and Oxine Copper
  • Isoxazole compounds such as Hydroxyisoxazole; N-halogenothioalkyl compounds such as Captan, Captafol and Folpet; Dicarboxyimide compounds such as Procymidone, Iprodion and Vinclozolin;
  • Piperazine compounds such as Triforine; Pyridine compounds such as Pyrifenox; Carbinol compounds such as Fenarimol and Flutriafol; Piperidine compounds such as Fenpropidine; Morpholine compounds such as Fenpropimorph; Urea compounds such as Pencycuron;
  • Cinnamic acid compounds such as Dimethomorph
  • Phenylcarbamate compounds such as Diethofencarb
  • Cyanopyrrole compounds such as Fludioxonil and Fenpiclonil
  • Strobilurin compounds such as Azoxystrobin
  • oxazolidinone compounds such as Famoxadone, thiazolecarboxyamide compounds such as Ethaboxam;
  • Silylamide compounds such as Silthiopham; amino acid amide carbamate compounds such as Iprovalicarb; imidazolidine compounds such as Fenamidone; Hydroxyanilide compounds such as Fenhexamide; Benzenesulfonamide compounds such as Flusulfamid;
  • fungicide is at least one compound selected from the group consisting of (P) organophosphorus compounds, (Q) antibiotics, (R) organochlorine compounds, (S) benzanilide compounds, (T) condensed heterocyclic compounds containing a nitrogen atom or a sulfur atom, and (U) organotin compounds .
  • the fungicide is at least one compound of (1) selected from the group consisting of Validamycin, Kasugamycin, Fthalide, Dichlomezine, Flutolanil, Tricyclazole and Pro. benazole.
  • a mixing ratio of at least one of compounds of the formula (I) or their salts and at least one active ingredient of other pesticides is from 1:100 to 100:1, preferably from 1:50 to 50:1.
  • the pesticidal composition of the present invention may be formulated together with agricultural adjuvants into various forms such as emulsifiable concentrates, dusts, granules, wettable powders, water dispersible granules, suspension concentrates, soluble concentrates, aerosols or pastes, and the like, in the same manner as in a case of conventional agricultural chemicals.
  • Such formulations are usually composed of 0.001 to 99 parts by weight, preferably 0.01 to 95 parts by weight, more preferably 0.01 to 80 parts by weight of an active ingredient and 1 to 99.999 parts by weight, preferably 5 to 99.99 parts by weight, more preferably 20 to 99.99 parts by weight of agricultural adjuvants.
  • Such formulations When such formulations are to be actually used, they may be used as they are or after being diluted with suitable diluents such as water to a predetermined concentration.
  • suitable diluents such as water to a predetermined concentration.
  • suitable diluents such as water to a predetermined concentration.
  • suitable diluents such as water to a predetermined concentration.
  • suitable diluents such as water to a predetermined concentration.
  • suitable diluents such as water to a predetermined concentration.
  • suitable diluents such as water to a predetermined concentration.
  • suitable diluents such as water to a predetermined concentration.
  • carriers emulsifiers, suspending agents, dispersants, extenders, penetrating agents, wetting agents, thickeners, defoaming agents, stabilizers or antifreezing agents. They may be added as the case requires.
  • the carriers may be classified into solid carriers and liquid carriers.
  • powders of animal and plant origin such as starch, activated carbon, soybean flour, wheat flour, wood powder, fish powder or powdered milk; or mineral powders such as talc, kaolin, bentonite, calcium carbonate, zeolite, diatomaceous earth, white carbon, clay or alumina, sulfur powder, anhydrous sodium .sulfate, and the like.
  • liquid carriers there may be mentioned water; alcohols such as methyl alcohol or ethylene glycol; ketones such as acetone, methyl ethyl ketone or N-methyl-2-pyrrolidone; ethers such as dioxane or tetrahydrofuran; aliphatic hydrocarbons such as kerosine, gas oil or the like; aromatic hydrocarbons such as xylene, trimethylbenzene, tetramethylbenzene, cyclohexane or solvent naphtha; halogenated hydrocarbons such as chloroform or chlorobenzene; acid amides such as dimethyIformamide; esters such as ethyl acetate or glycerine ester of a fatty acid; nitriles such as acetonitrile; sulfur-containing compounds such as dimethyl sulfoxide; vegetable oils such as soybean oil or corn oil; and the like.
  • alcohols such as methyl alcohol or ethylene glycol
  • ketones such as
  • the pesticidal composition of the present invention may be prepared by mixing respective effective components and then formulating the resultant mixture, or may be prepared by formulating respective effective components and then mixing the resultant formulations.
  • the pesticidal composition of the present invention achieves pesticidal effects against various noxious animals including anthropods such as agriculturally noxious insects, mites and the like; ne atodes; and soil insects; or various diseases.
  • the pesticidal composition of the present invention is useful as pesticides, for example, insecticides, miticides, nematicides, soil pesticides and fungicides.
  • plant parasitic mites such as two-spotted spider mite (Tetranychus urticae) , carmine spider mite (Tetranychus cinnabarinus) , citrus red mite (Panonychus citri) or bulb mite (Rhizoglyphus echinopus) ; aphids such as green peach aphid (Myzus persicae) or cotton aphid (Aphis gossypii) ; agricultural insect pests such as diamondback moth (Plutella xylostella) , cabbage armyworm (Mamestra brassicae) , common cutworm (Spodoptera litura) , Colorado potato beetle (Leptinotarsa decemlineata) , codling moth
  • the soil pests include gastropods such as slugs or snails, or isopods such as pillbugs or sowbugs .
  • the composition of the present invention has excellent systemic properties, and by the application of the composition of the present invention to soil treatment, not only soil noxious insects, plant parasitic noxious mites, noxious nematodes, noxious gastropods and noxious isopods in soil but also foliage pests can be controlled.
  • the pesticidal composition of the present invention is applied in an active ingredient concentration of a compound of the formula (I) or its salt of from 1 to 100,000 ppm, preferably from 1 to 50,000 ppm, more preferably from 10 to 20,000 ppm, and in an active ingredient concentration of other pesticide of from 1 to 100,000 ppm, preferably from 1 to 50,000 ppm, more preferably from 10 to 20,000 ppm.
  • the active ingredient concentration may optionally be changed depending upon the formulation, the manner, purpose, timing or place of the application and the condition of the insect pests . For instance, aquatic noxious insects can be controlled by applying a formulation having the above-mentioned concentration to the site of the outbreak, and thus, the concentration of the active ingredient in water is less than the above-mentioned range.
  • the amount of the application of the active ingredient per unit surface area is usually from about 1 to 50,000 g, preferably from 10 to 10,000 g, per hectare as an active ingredient of a compound of the formula (I) or its salt, and from about 1 to 50,000, preferably from 10 to 10,000 g, per hectare as an active ingredient of other pesticide. However, in a certain special case, the amount of the application may be outside the above range.
  • Various formulations containing the compounds of the present invention or their diluted compositions may be applied by conventional methods for application which are commonly employed, such as spraying (e.g. spraying, jetting, misting, atomizing, powder or grain scattering or dispersing in water), soil application (e.g. mixing or drenching), surface application (e.g.
  • An agroche ical liquid diluted to a predetermined concentration was applied by a spray gun to a 10 to 12- foliate eggplant having Thrips palmi parasitic thereon in a pot so as to make the eggplant fully wet with the agrochemical liquid, and the pot was placed in a greenhouse.
  • the numbers of the parasitic insects were counted before treatment and three days after the treatment, and a Percent Control was calculated in accordance with the following formula, and the results are shown in the following Table 1.
  • Tb Number of insects per treated plants before treatment
  • Cb Number of insects per untreated plants before treatment
  • An agrochemical liquid diluted to a predetermined concentration was applied by a spray gun to a 10 to 12 foliate eggplant having Thrips palmi parasitic thereon in a pot so as to make the eggplant fully wet with the agrochemical liquid, and the pot was placed in a greenhouse .
  • An agrochemical liquid diluted to a predetermined concentration was applied by a spray gun to a 10 to 12 foliate eggplant having Western Flower Thrips
  • TEST EXAMPLE 4 Insecticidal test of Thrips palmi (test in a vinyl house) An agrochemical liquid diluted to a predetermined concentration was applied by a shoulder sprayer on a 6 to 8 foliate eggplant having Thrips palmi parasitic thereon in an amount of 100 ⁇ per 10 are. The numbers of the parasitic insects were counted before treatment and 12 days' after the treatment, and a Percent Control was calculated in the same manner as in Test Example 1, and the results are shown in the following Table 4.
  • the pesticidal composition of the present invention achieves a stable high pesticidal effect, and noxious insects and other organisms can be killed by this composition.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pyridine Compounds (AREA)

Abstract

L'invention concerne une composition pesticide comprenant une dose nécessaire sur le plan antiparasitaire d'au moins un composé pyridique représenté par la formule générale (I), dans laquelle Y représente un groupe halogénure d'alkyle, m est égal à 0 ou 1, et Q représente le groupe (II) ou un groupe hétérocyclique substitué ou non (dans lequel X représente un atome d'oxygène ou un atome de soufre, R1 et R2 représentent respectivement un atome d'hydrogène, un groupe alkyle substitué ou non, un groupe alcényle substitué ou non, un groupe alcynyle substitué ou non, un groupe cycloalkyle substitué ou non et analogue), ou son sel et au moins un autre pesticide.
EP01976797A 2000-10-23 2001-10-22 Composition pesticide Expired - Lifetime EP1328154B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP2000322558 2000-10-23
JP2000322558 2000-10-23
PCT/JP2001/009253 WO2002034050A1 (fr) 2000-10-23 2001-10-22 Composition pesticide

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EP1328154A1 true EP1328154A1 (fr) 2003-07-23
EP1328154B1 EP1328154B1 (fr) 2005-07-27

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AR (2) AR031031A1 (fr)
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AU (2) AU2001295990B2 (fr)
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EG (1) EG22823A (fr)
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HR (1) HRP20030281B1 (fr)
HU (1) HU228905B1 (fr)
IL (2) IL155507A0 (fr)
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MX (1) MXPA03003582A (fr)
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PT (1) PT1328154E (fr)
RU (1) RU2264099C2 (fr)
SK (1) SK287548B6 (fr)
TW (1) TWI242006B (fr)
WO (1) WO2002034050A1 (fr)
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CN103053604A (zh) * 2011-10-20 2013-04-24 南京华洲药业有限公司 一种含氟啶虫酰胺和氟硅菊酯的增效杀虫组合物及其用途
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HUP0302406A3 (en) 2004-06-28
AR082565A2 (es) 2012-12-19
CN1568143A (zh) 2005-01-19
DK1328154T3 (da) 2005-11-28
ECSP034564A (es) 2003-06-25
HU228905B1 (en) 2013-06-28
CN101185441A (zh) 2008-05-28
PT1328154E (pt) 2005-09-30
EG22823A (en) 2003-09-30
BR0114832A (pt) 2004-07-06
RU2264099C2 (ru) 2005-11-20
ATE300177T1 (de) 2005-08-15
US20040024026A1 (en) 2004-02-05
US7514094B2 (en) 2009-04-07
PL202740B1 (pl) 2009-07-31
TWI242006B (en) 2005-10-21
WO2002034050A1 (fr) 2002-05-02
KR100819325B1 (ko) 2008-04-02
US20070142439A1 (en) 2007-06-21
MA25919A1 (fr) 2003-10-01
IL155507A (en) 2009-12-24
DE60112317D1 (de) 2005-09-01
MXPA03003582A (es) 2003-07-14
AR031031A1 (es) 2003-09-03
CZ20031034A3 (cs) 2003-09-17
SK4932003A3 (en) 2003-12-02
SK287548B6 (sk) 2011-01-04
ZA200302869B (en) 2004-04-13
HUP0302406A2 (hu) 2003-10-28
US7195773B2 (en) 2007-03-27
ES2244665T3 (es) 2005-12-16
AU2001295990B2 (en) 2006-03-30
DE60112317T2 (de) 2005-12-29
CA2424864A1 (fr) 2002-05-02
CZ302285B6 (cs) 2011-02-02
CN100496248C (zh) 2009-06-10
EP1328154B1 (fr) 2005-07-27
BR0114832B1 (pt) 2014-07-01
CA2424864C (fr) 2009-05-19
PL362483A1 (en) 2004-11-02
AU9599001A (en) 2002-05-06
JP2004512285A (ja) 2004-04-22
HRP20030281B1 (en) 2006-03-31
IL155507A0 (en) 2003-11-23
HRP20030281A2 (en) 2005-02-28
KR20030042022A (ko) 2003-05-27

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