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EP0115299A1 - Procédé pour la récupération simultanée de 4-hydroxydiphényle et de 4,4'-dihydroxydiphényle - Google Patents

Procédé pour la récupération simultanée de 4-hydroxydiphényle et de 4,4'-dihydroxydiphényle Download PDF

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Publication number
EP0115299A1
EP0115299A1 EP84100524A EP84100524A EP0115299A1 EP 0115299 A1 EP0115299 A1 EP 0115299A1 EP 84100524 A EP84100524 A EP 84100524A EP 84100524 A EP84100524 A EP 84100524A EP 0115299 A1 EP0115299 A1 EP 0115299A1
Authority
EP
European Patent Office
Prior art keywords
mono
dod
alkali
diphenyl
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP84100524A
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German (de)
English (en)
Other versions
EP0115299B1 (fr
Inventor
Eike Dr. Gabel
Heinz Ulrich Dr. Blank
Horst Dr. Behre
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
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Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/68—Purification; separation; Use of additives, e.g. for stabilisation
    • C07C37/86—Purification; separation; Use of additives, e.g. for stabilisation by treatment giving rise to a chemical modification

Definitions

  • the present invention relates to a process for the simultaneous production of 4-hydroxydiphenyl (mono- O D) and 4,4'-dihydroxydiphenyl (DOD) from a mixture containing the two substances by treating such a mixture with aqueous alkali metal hydroxide solution.
  • Dihydroxy-diphenyls are used, for example, as a starting material for high-quality condensation polymers, such as polycarbonates, polyesters and powder coatings, the property of high-temperature resistance being particularly remarkable (DE-OS 30 31 094). Because of the structural similarity, monohydroxydiphenyls can be used as chain terminators for adjusting the molecular weights. Dihydroxy-diphenyls are also used as intermediates for pharmaceutical products and as stabilizers and antioxidants for rubbers, oils and polymers.
  • 4-Hydroxy-diphenyls (p-phenylphenols) are used as intermediates for the production of coating resins, non-ionic emulsifiers and pesticides are used (Ullmann's Encyclopedia of Industrial Chemistry, 4th edition, volume 18, page 219).
  • An important production route for mono-OD and DOD is based on diphenyl-4-sulfonic acid or diphenyl-4,4'-disulfonic acid, which is converted into mono-OD or DOD with the help of an alkali melt by exchanging the sulfo group for the hydroxyl group be (DE-OS 30 31 094).
  • the sodium salts of the sulfonic acids mentioned are often used for this alkali melt, which are obtained after sulfonation of diphenyl with excess sulfuric acid, dilution of the sulfonation batch with water, partial neutralization with sodium hydroxide solution or salting out with sodium chloride, subsequent filtration and drying.
  • DOD can be produced in such a way that no or only small amounts of mono-OD have to be separated off
  • the sulfonation of diphenyl can only be carried out economically in such a way that a considerable amount of diphenyl- disulfonic acid arises in addition to the desired diphenyl monosulfonic acid.
  • JP patent application 56-92236 (1981) proposes to separate mono-OD and DOD by extracting an aqueous solution of these phenols in alkali metal hydroxide solution with a water-immiscible alcohol or ketone at elevated pressure, mono- OD passes into the organic phase as free phenol. Even small amounts of mono-OD require a considerable amount of organic solvent for this, so that this process is uneconomical and cannot be used for mixtures with a large proportion of mono-OD.
  • DE-OS 31 07 473 (equivalent to GB 2 071 090) proposes mono-OD from an alkaline solution of the phenolates mentioned in water by adsorption on active to remove coal. Here too, only small amounts of mono-OD can be removed; No information is given at all for a preparative extraction of this separated mono-OD.
  • a process for the simultaneous recovery of 4-hydroxydiphenyl (mono-OD) and 4,4'-dihydroxydiphenyl (DOD) from a mixture containing the two substances in free form or in the form of the alkali phenolates was found, which is characterized in that such a mixture treated with such an amount of aqueous alkali lye that 1-15 moles of alkali hydroxide per mole of diphenyl compounds are present after the formation of the alkali phenolates, and a concentration of 4-25 wt Water, is given, at a temperature of -28 ° C to + 40 ° C, the resulting solution, which essentially contains the DOD, from the resulting Soil body, which essentially contains the mono-DOD, separates and acidifies solution and soil body separately to form the free mono-OD and the free DOD.
  • the aqueous solution of the hydroxide of an alkali metal may be mentioned as the aqueous alkali hydroxide solution.
  • Mixtures of alkali metal hydroxides can of course also be used.
  • mixtures of mono-OD and DOD are mixed with so much excess alkali hydroxide that 1-15 mol, preferably 3-10 mol, of the alkali hydroxide are present per mol of diphenyl compound used in the form of the mono-OD or DOD.
  • the alkali metal hydroxide required for the formation of the phenolates must also be used.
  • the concentration of the alkali metal hydroxide, if necessary after the alkali metal phenates have been formed, is 4-25, preferably 8-20, particularly preferably between 8 and 15% by weight of alkali metal hydroxide, based on the amount of water present in the reaction mixture.
  • the treatment according to the invention of the mixture containing mono-OD and DOD is carried out at normal to elevated temperature, for example at 15-100 ° C. Temperatures outside this range can also be used.
  • the reaction mixture is then particularly at a temperature of -28 ° C to + 40 ° C, preferably -15 ° C to + 35 ° C preferably -10 ° C to + 30 ° C, separately.
  • the separation is carried out in a known manner, for example by filtration or by centrifugation.
  • the filtration residue contains up to 99% of the mono-OD used, which, based on 100 parts by weight, for example 5, in many cases contains less than 1 part by weight of DOD. If a mixture is assumed which already contained only close to 1 part by weight of DOD before use in the process according to the invention, the content of DOD in the filtration residue obtained according to the invention can be less than 0.5 part by weight per 100 parts by weight. Parts are mono OD.
  • the purity of the filtration residue can be further increased, for example, by washing with an alkali metal hydroxide solution, the concentration of which is preferably the same as the concentration of the alkali metal hydroxide solution used for the treatment.
  • the mono-OD obtained in this way can then be contaminated to a greater extent with DOD.
  • the filtrate contains 70 to 95% by weight of the free alkali solution used. It also contains the rest of the one set DOD and small amounts of mono-OD, which for example do not exceed 25% of the sum of DOD and mono-OD in the solution. If you want to separate a mono-OD that is almost DOD-free, for example by diluting the batch more or washing the residue with an alkali solution, the mono-OD part of the sum of mono-OD and DOD in the solution can also be 25 % exceed. With the product obtained from the filtrate, a further separation can easily be carried out. In many cases, however, the proportion of mono-OD is less than 10%, based on the total amount of DOD and mono-OD in the solution.
  • mixtures of mono-OD and DOD in free form or in the form of their alkali metal salts in a ratio of 1: 100 to 100: 1, preferably 5: 100 to 100: 5, particularly preferably 10: 100 to 100: 10 can be used .
  • the mixtures which can be used according to the invention and are separated for the simultaneous recovery of mono-OD and DOD can furthermore contain alkali metal sulfate, for example 0 to 5 mol Alkali sulfate per 1 mole of diphenyl compounds present, and optionally further alkali sulfite, for example 0 to 1 mole of alkali sulfite per mole of phenolate group present.
  • alkali metal sulfate for example 0 to 5 mol Alkali sulfate per 1 mole of diphenyl compounds present
  • alkali sulfite for example 0 to 1 mole of alkali sulfite per mole of phenolate group present.
  • a content of more than 1 mole of alkali sulfite per mole of phenolate group is also harmless for the successful implementation of the process according to the invention.
  • the amount of alkali sulfite which may be present is about 1 mole per mole of phenolate
  • the filtration residue is acidified after dissolving in water or the filtrate.
  • a pH value of at most 8, for example 7 to 1 . set.
  • Acidification can in principle be carried out with any acid whose acid strength is greater than that of the phenolic groups of the mono-OD or the DOD.
  • simple and inexpensive mineral acids such as hydrochloric acid, sulfuric acid, nitric acid or phosphoric acid, preferably hydrochloric acid or sulfuric acid, will generally be chosen.
  • Such mixtures of diphenylsulfonic acid can be converted directly into the corresponding mixtures of the alkali salts of the hydroxydiphenyl compounds by alkali melt and separated in the manner according to the invention for the simultaneous production of mono-OD and DOD.
  • a mixture of 85.1 g of 4-hydroxydiphenyl and 93.1 g of 4,4'-dihydroxydiphenyl was dissolved in 1633 g of 13.5% strength by weight sodium hydroxide solution with heating. After cooling to 20 ° C, a crystalline precipitate formed, which is filtered off.
  • the sodium hydroxide-moist residue was dissolved in 3000 ml of H 2 O and neutralized to pH 7 with HCl. After cooling to room temperature, the product was filtered off with suction and washed free of salt with water. The filtrate was neutralized analogously. The extracted products were dried at 70 ° C in a vacuum drying cabinet.
  • Example 5 The experiment from Example 5 was repeated with the difference that the mixture was diluted with a total of 3475 ml or 1095 ml of H 2 O.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP84100524A 1983-02-01 1984-01-19 Procédé pour la récupération simultanée de 4-hydroxydiphényle et de 4,4'-dihydroxydiphényle Expired EP0115299B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3303220 1983-02-01
DE19833303220 DE3303220A1 (de) 1983-02-01 1983-02-01 Verfahren zur gleichzeitigen gewinnung von 4-hydroxydiphenyl und 4,4'-dihydroxydiphenyl

Publications (2)

Publication Number Publication Date
EP0115299A1 true EP0115299A1 (fr) 1984-08-08
EP0115299B1 EP0115299B1 (fr) 1985-08-21

Family

ID=6189695

Family Applications (1)

Application Number Title Priority Date Filing Date
EP84100524A Expired EP0115299B1 (fr) 1983-02-01 1984-01-19 Procédé pour la récupération simultanée de 4-hydroxydiphényle et de 4,4'-dihydroxydiphényle

Country Status (4)

Country Link
US (1) US4538007A (fr)
EP (1) EP0115299B1 (fr)
JP (1) JPS59141531A (fr)
DE (2) DE3303220A1 (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04273257A (ja) * 1991-02-28 1992-09-29 Canon Inc 電力供給制御装置及び画像処理装置
DE10040165A1 (de) * 2000-08-17 2002-02-28 Bayer Ag ortho-Phenylphenolat-Konzentrate
JP6416008B2 (ja) * 2015-02-12 2018-10-31 三井化学株式会社 ｐ−クミルフェノールの精製方法および製造方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1885176A (en) * 1929-12-05 1932-11-01 Dow Chemical Co Method for separating phenylphenols
US3993700A (en) * 1973-02-20 1976-11-23 The Dow Chemical Company Purification of p-phenylphenol
US4366329A (en) * 1981-06-22 1982-12-28 Eastman Kodak Company Process for the separation of meta and para isomers of the sodium salt of bromophenol

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1887227A (en) * 1929-12-05 1932-11-08 Dow Chemical Co Method of separating phenylphenols
JPS599533B2 (ja) * 1978-02-21 1984-03-03 三光化学株式会社 ジオキシジフエニルの製造法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1885176A (en) * 1929-12-05 1932-11-01 Dow Chemical Co Method for separating phenylphenols
US3993700A (en) * 1973-02-20 1976-11-23 The Dow Chemical Company Purification of p-phenylphenol
US4366329A (en) * 1981-06-22 1982-12-28 Eastman Kodak Company Process for the separation of meta and para isomers of the sodium salt of bromophenol

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS, Band 92, Nr. 5, 4. Februar 1980, Seite 747, Nr. 41563d, Columbus, Ohio, USA *

Also Published As

Publication number Publication date
DE3460002D1 (en) 1985-09-26
JPH0210131B2 (fr) 1990-03-06
US4538007A (en) 1985-08-27
DE3303220A1 (de) 1984-08-02
JPS59141531A (ja) 1984-08-14
EP0115299B1 (fr) 1985-08-21

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