DE69600600T2 - Mischungen von Polyethylenterephthalat und Blockcopoly- meren aus Monovinylaromaten und konjugierten Dienen - Google Patents
Mischungen von Polyethylenterephthalat und Blockcopoly- meren aus Monovinylaromaten und konjugierten DienenInfo
- Publication number
- DE69600600T2 DE69600600T2 DE69600600T DE69600600T DE69600600T2 DE 69600600 T2 DE69600600 T2 DE 69600600T2 DE 69600600 T DE69600600 T DE 69600600T DE 69600600 T DE69600600 T DE 69600600T DE 69600600 T2 DE69600600 T2 DE 69600600T2
- Authority
- DE
- Germany
- Prior art keywords
- weight
- monovinylarene
- conjugated diene
- block copolymer
- diene block
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- -1 polyethylene terephthalate Polymers 0.000 title claims abstract description 76
- 150000001993 dienes Chemical class 0.000 title claims abstract description 44
- 229920000139 polyethylene terephthalate Polymers 0.000 title claims abstract description 44
- 239000005020 polyethylene terephthalate Substances 0.000 title claims abstract description 44
- 239000000203 mixture Substances 0.000 title claims abstract description 38
- 229920001400 block copolymer Polymers 0.000 title claims abstract description 37
- 229920002959 polymer blend Polymers 0.000 claims description 31
- 238000000034 method Methods 0.000 claims description 14
- KAKZBPTYRLMSJV-UHFFFAOYSA-N butadiene group Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 9
- 239000003607 modifier Substances 0.000 claims description 9
- 150000002009 diols Chemical class 0.000 claims description 7
- 150000001261 hydroxy acids Chemical class 0.000 claims description 5
- 238000010348 incorporation Methods 0.000 claims description 3
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 239000000178 monomer Substances 0.000 description 17
- 229920000642 polymer Polymers 0.000 description 17
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- 239000003999 initiator Substances 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 5
- 239000007822 coupling agent Substances 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 4
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 2
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 229920006158 high molecular weight polymer Polymers 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- VDNSZPNSUQRUMS-UHFFFAOYSA-N 1-cyclohexyl-4-ethenylbenzene Chemical compound C1=CC(C=C)=CC=C1C1CCCCC1 VDNSZPNSUQRUMS-UHFFFAOYSA-N 0.000 description 1
- DMADTXMQLFQQII-UHFFFAOYSA-N 1-decyl-4-ethenylbenzene Chemical compound CCCCCCCCCCC1=CC=C(C=C)C=C1 DMADTXMQLFQQII-UHFFFAOYSA-N 0.000 description 1
- OEVVKKAVYQFQNV-UHFFFAOYSA-N 1-ethenyl-2,4-dimethylbenzene Chemical compound CC1=CC=C(C=C)C(C)=C1 OEVVKKAVYQFQNV-UHFFFAOYSA-N 0.000 description 1
- VTPNYMSKBPZSTF-UHFFFAOYSA-N 1-ethenyl-2-ethylbenzene Chemical compound CCC1=CC=CC=C1C=C VTPNYMSKBPZSTF-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- XHUZSRRCICJJCN-UHFFFAOYSA-N 1-ethenyl-3-ethylbenzene Chemical compound CCC1=CC=CC(C=C)=C1 XHUZSRRCICJJCN-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- JHTICDZLXFNVKL-UHFFFAOYSA-N 1-ethenyl-4-(4-phenylbutyl)benzene Chemical compound C1=CC(C=C)=CC=C1CCCCC1=CC=CC=C1 JHTICDZLXFNVKL-UHFFFAOYSA-N 0.000 description 1
- WHFHDVDXYKOSKI-UHFFFAOYSA-N 1-ethenyl-4-ethylbenzene Chemical compound CCC1=CC=C(C=C)C=C1 WHFHDVDXYKOSKI-UHFFFAOYSA-N 0.000 description 1
- VVTGQMLRTKFKAM-UHFFFAOYSA-N 1-ethenyl-4-propylbenzene Chemical compound CCCC1=CC=C(C=C)C=C1 VVTGQMLRTKFKAM-UHFFFAOYSA-N 0.000 description 1
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- KXYAVSFOJVUIHT-UHFFFAOYSA-N 2-vinylnaphthalene Chemical compound C1=CC=CC2=CC(C=C)=CC=C21 KXYAVSFOJVUIHT-UHFFFAOYSA-N 0.000 description 1
- IGLWCQMNTGCUBB-UHFFFAOYSA-N 3-methylidenepent-1-ene Chemical compound CCC(=C)C=C IGLWCQMNTGCUBB-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- DXFURPHVJQITAC-UHFFFAOYSA-N 4-benzyl-1-ethenyl-2-ethylbenzene Chemical compound C1=C(C=C)C(CC)=CC(CC=2C=CC=CC=2)=C1 DXFURPHVJQITAC-UHFFFAOYSA-N 0.000 description 1
- 229940090248 4-hydroxybenzoic acid Drugs 0.000 description 1
- UGWOAPBVIGCNOV-UHFFFAOYSA-N 5-ethenyldec-5-ene Chemical compound CCCCC=C(C=C)CCCC UGWOAPBVIGCNOV-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010102 injection blow moulding Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US37132495A | 1995-01-11 | 1995-01-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69600600D1 DE69600600D1 (de) | 1998-10-15 |
| DE69600600T2 true DE69600600T2 (de) | 1999-02-04 |
Family
ID=23463494
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69600600T Expired - Fee Related DE69600600T2 (de) | 1995-01-11 | 1996-01-11 | Mischungen von Polyethylenterephthalat und Blockcopoly- meren aus Monovinylaromaten und konjugierten Dienen |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5756578A (ja) |
| EP (1) | EP0727461B1 (ja) |
| JP (1) | JP3464741B2 (ja) |
| KR (1) | KR960029405A (ja) |
| AT (1) | ATE170898T1 (ja) |
| CA (1) | CA2166637C (ja) |
| DE (1) | DE69600600T2 (ja) |
| DK (1) | DK0727461T3 (ja) |
| ES (1) | ES2120788T3 (ja) |
| MY (1) | MY115713A (ja) |
| TW (1) | TW364000B (ja) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6835778B2 (en) * | 1995-08-29 | 2004-12-28 | Chevron Phillips Chemical Company Lp | Conjugated diene/monovinylarene block copolymers blends |
| US6723428B1 (en) | 1999-05-27 | 2004-04-20 | Foss Manufacturing Co., Inc. | Anti-microbial fiber and fibrous products |
| US6855778B2 (en) * | 2001-12-10 | 2005-02-15 | Kama Of Illinois Corporation | Blended thermoformable RF sealable plastic |
| EP1510551B1 (en) * | 2003-08-14 | 2008-04-16 | Basf Se | Blend of polyester and block copolymers of monovinylaromatic monomer and conjugated diene |
| US20050166551A1 (en) * | 2004-02-02 | 2005-08-04 | Keane J. A. | Multilayer high clarity shrink film comprising monovinylarene-conjugated diene copolymer |
| US7686906B2 (en) * | 2005-06-30 | 2010-03-30 | Solutia Inc. | Methods of making polymer interlayers comprising poly(cyclohexanedimethylene terephthalate-co-ethylene terephthalate) copolyester |
| CA2607216C (en) * | 2006-10-20 | 2012-10-02 | Pepsico, Inc. | Extrudable polyethylene terephthalate blend |
| US8080191B2 (en) * | 2006-10-20 | 2011-12-20 | Pepsico, Inc. | Extrudable polyethylene terephthalate blend |
| WO2009129469A1 (en) | 2008-04-18 | 2009-10-22 | Pepsico, Inc. | Polyester compositions and method for preparing articles by extrusion blow molding |
| US20100272975A1 (en) * | 2009-04-23 | 2010-10-28 | Chevron Phillips Chemical Company Lp | System and method for the production and use of lamination films |
| CN112724615B (zh) * | 2020-12-16 | 2022-10-21 | 金发科技股份有限公司 | 一种pbt树脂组合物及其制备方法和应用 |
| CN118715281A (zh) * | 2022-02-16 | 2024-09-27 | 电化株式会社 | 含有嵌段共聚物的嵌段共聚物组合物、嵌段共聚物树脂组合物、成型体、片材和膜 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4483949A (en) * | 1983-08-22 | 1984-11-20 | Ethyl Corporation | Polyethylene terephthalate blends |
| US4745148A (en) * | 1984-04-13 | 1988-05-17 | Mobay Corporation | Thermoplastic polyester molding composition having an improved impact performance |
| US4675970A (en) * | 1985-11-14 | 1987-06-30 | Neal Galen | Sorter for automotive glove compartments |
| US4952629A (en) * | 1988-12-07 | 1990-08-28 | Plastics Engineering Company | Thermoplastic polyester blends |
| US5162416A (en) * | 1989-03-17 | 1992-11-10 | Monsanto Company | Impact resistant polyester blends |
| EP0402279A1 (en) * | 1989-06-05 | 1990-12-12 | Eastman Chemical Company | Impact resistant polymer blends |
| US5149734A (en) * | 1989-10-20 | 1992-09-22 | General Electric Company | Highly filled thermoplastic polyester molding compositions |
| EP0554369A1 (en) * | 1991-08-27 | 1993-08-11 | General Electric Company | Poly(alkylene cyclohexanedicarboxylate) binary blends |
| US5391619A (en) * | 1993-10-19 | 1995-02-21 | Phillips Petroleum Company | Poly(ethylene terephthalate) and monovinylarene/conjugated diene block copolymer blends |
-
1996
- 1996-01-05 CA CA002166637A patent/CA2166637C/en not_active Expired - Fee Related
- 1996-01-10 KR KR1019960000362A patent/KR960029405A/ko not_active Abandoned
- 1996-01-11 DK DK96100356T patent/DK0727461T3/da active
- 1996-01-11 AT AT96100356T patent/ATE170898T1/de not_active IP Right Cessation
- 1996-01-11 DE DE69600600T patent/DE69600600T2/de not_active Expired - Fee Related
- 1996-01-11 EP EP96100356A patent/EP0727461B1/en not_active Expired - Lifetime
- 1996-01-11 ES ES96100356T patent/ES2120788T3/es not_active Expired - Lifetime
- 1996-01-11 MY MYPI96000106A patent/MY115713A/en unknown
- 1996-01-11 JP JP00341296A patent/JP3464741B2/ja not_active Expired - Fee Related
- 1996-01-29 TW TW085101089A patent/TW364000B/zh active
- 1996-05-29 US US08/655,062 patent/US5756578A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ATE170898T1 (de) | 1998-09-15 |
| JPH08253656A (ja) | 1996-10-01 |
| EP0727461B1 (en) | 1998-09-09 |
| TW364000B (en) | 1999-07-11 |
| KR960029405A (ko) | 1996-08-17 |
| DK0727461T3 (da) | 1999-02-08 |
| JP3464741B2 (ja) | 2003-11-10 |
| CA2166637A1 (en) | 1996-07-12 |
| EP0727461A1 (en) | 1996-08-21 |
| MY115713A (en) | 2003-08-30 |
| ES2120788T3 (es) | 1998-11-01 |
| CA2166637C (en) | 2000-11-07 |
| DE69600600D1 (de) | 1998-10-15 |
| US5756578A (en) | 1998-05-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition | ||
| 8339 | Ceased/non-payment of the annual fee |