[go: up one dir, main page]

DE60128926D1 - Verfahren zur herstellung von flüssigem poly-alpha-olefin, metallocen dafür und diese enthaltende schmiermittel - Google Patents

Verfahren zur herstellung von flüssigem poly-alpha-olefin, metallocen dafür und diese enthaltende schmiermittel

Info

Publication number
DE60128926D1
DE60128926D1 DE60128926T DE60128926T DE60128926D1 DE 60128926 D1 DE60128926 D1 DE 60128926D1 DE 60128926 T DE60128926 T DE 60128926T DE 60128926 T DE60128926 T DE 60128926T DE 60128926 D1 DE60128926 D1 DE 60128926D1
Authority
DE
Germany
Prior art keywords
low
metallocos
homo
poly alpha
producing liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60128926T
Other languages
English (en)
Other versions
DE60128926T2 (de
Inventor
Anthony J Dimaio
John R Baranski
John G Bludworth
Daniel J Gillis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lanxess Solutions US Inc
Original Assignee
Uniroyal Chemical Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uniroyal Chemical Co Inc filed Critical Uniroyal Chemical Co Inc
Application granted granted Critical
Publication of DE60128926D1 publication Critical patent/DE60128926D1/de
Publication of DE60128926T2 publication Critical patent/DE60128926T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M143/00Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation
    • C10M143/08Lubricating compositions characterised by the additive being a macromolecular hydrocarbon or such hydrocarbon modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14Monomers containing five or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/026Butene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Lubricants (AREA)
DE60128926T 2000-08-11 2001-08-08 Verfahren zur herstellung von flüssigem poly-alpha-olefin, metallocen dafür und diese enthaltende schmiermittel Expired - Lifetime DE60128926T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US637791 2000-08-11
US09/637,791 US6858767B1 (en) 2000-08-11 2000-08-11 Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor, the resulting polymer and lubricant containing same
PCT/US2001/024815 WO2002014384A2 (en) 2000-08-11 2001-08-08 Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor and lubricants containing the same

Publications (2)

Publication Number Publication Date
DE60128926D1 true DE60128926D1 (de) 2007-07-26
DE60128926T2 DE60128926T2 (de) 2008-02-14

Family

ID=24557387

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60128926T Expired - Lifetime DE60128926T2 (de) 2000-08-11 2001-08-08 Verfahren zur herstellung von flüssigem poly-alpha-olefin, metallocen dafür und diese enthaltende schmiermittel

Country Status (10)

Country Link
US (1) US6858767B1 (de)
EP (1) EP1309633B1 (de)
JP (2) JP4074191B2 (de)
AT (1) ATE364640T1 (de)
AU (1) AU2001283177A1 (de)
BR (1) BR0113185B1 (de)
CA (1) CA2416894C (de)
DE (1) DE60128926T2 (de)
MX (1) MXPA03001289A (de)
WO (1) WO2002014384A2 (de)

Families Citing this family (92)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6713582B2 (en) * 2001-12-14 2004-03-30 Uniroyal Chemical Company, Inc. Process for the oligomerization of α-olefins having low unsaturation, the resulting polymers, and lubricants containing same
US6887305B2 (en) 2002-05-29 2005-05-03 Exxonmobil Chemical Patents Inc. Release agent and uses for same
US6706828B2 (en) * 2002-06-04 2004-03-16 Crompton Corporation Process for the oligomerization of α-olefins having low unsaturation
US7531594B2 (en) * 2002-08-12 2009-05-12 Exxonmobil Chemical Patents Inc. Articles from plasticized polyolefin compositions
US8003725B2 (en) 2002-08-12 2011-08-23 Exxonmobil Chemical Patents Inc. Plasticized hetero-phase polyolefin blends
US7998579B2 (en) 2002-08-12 2011-08-16 Exxonmobil Chemical Patents Inc. Polypropylene based fibers and nonwovens
US7662885B2 (en) 2002-08-12 2010-02-16 Exxonmobil Chemical Patents Inc. Method to make an article comprising polymer concentrate
US7271209B2 (en) 2002-08-12 2007-09-18 Exxonmobil Chemical Patents Inc. Fibers and nonwovens from plasticized polyolefin compositions
KR101008786B1 (ko) 2002-08-12 2011-01-14 엑손모빌 케미칼 패턴츠 인코포레이티드 가소화된 폴리올레핀 조성물
AU2003299143A1 (en) 2002-10-02 2004-04-23 Dow Global Technologies Inc. Liquid and gel-like low molecular weight ethylene polymers
US8192813B2 (en) 2003-08-12 2012-06-05 Exxonmobil Chemical Patents, Inc. Crosslinked polyethylene articles and processes to produce same
JP2005200448A (ja) * 2004-01-13 2005-07-28 Mitsui Chemicals Inc 潤滑油添加剤および潤滑油組成物
JP2005200453A (ja) * 2004-01-13 2005-07-28 Mitsui Chemicals Inc α−オレフィン(共)重合体の製造方法
JP2005200447A (ja) * 2004-01-13 2005-07-28 Mitsui Chemicals Inc 潤滑油添加剤および潤滑油組成物
US7589145B2 (en) * 2004-04-15 2009-09-15 Exxonmobil Chemical Patents Inc. Syndiotactic rich polyolefins
US7285608B2 (en) 2004-04-21 2007-10-23 Novolen Technology Holdings C.V. Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins
CN101039967B (zh) 2004-10-18 2010-06-09 巴塞尔聚烯烃意大利有限责任公司 低全同立构规整度丁烯-1均聚物或共聚物
EP1802669B1 (de) * 2004-10-21 2011-03-09 Basell Polyolefine GmbH 1-buten-polymer und herstellungsverfahren dafür
JP5027665B2 (ja) * 2004-10-21 2012-09-19 バーゼル・ポリオレフィン・ゲーエムベーハー 1−ブテンポリマー及びこの調製方法
GB2420348B (en) * 2004-10-28 2009-11-18 Exxonmobil Chem Patents Inc Syndiotactic rich polyolefins
US8389615B2 (en) 2004-12-17 2013-03-05 Exxonmobil Chemical Patents Inc. Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin
US8399390B2 (en) * 2005-06-29 2013-03-19 Exxonmobil Chemical Patents Inc. HVI-PAO in industrial lubricant and grease compositions
ATE555166T1 (de) 2005-07-15 2012-05-15 Exxonmobil Chem Patents Inc Elastomere zusammensetzungen
WO2007011462A1 (en) * 2005-07-19 2007-01-25 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
US7989670B2 (en) * 2005-07-19 2011-08-02 Exxonmobil Chemical Patents Inc. Process to produce high viscosity fluids
WO2007011459A1 (en) 2005-07-19 2007-01-25 Exxonmobil Chemical Patents Inc. Polyalpha-olefin compositions and processes to produce the same
AU2006270083B2 (en) * 2005-07-19 2011-01-20 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
US8299007B2 (en) 2006-06-06 2012-10-30 Exxonmobil Research And Engineering Company Base stock lubricant blends
US8535514B2 (en) * 2006-06-06 2013-09-17 Exxonmobil Research And Engineering Company High viscosity metallocene catalyst PAO novel base stock lubricant blends
US8834705B2 (en) 2006-06-06 2014-09-16 Exxonmobil Research And Engineering Company Gear oil compositions
US8921290B2 (en) 2006-06-06 2014-12-30 Exxonmobil Research And Engineering Company Gear oil compositions
US8501675B2 (en) 2006-06-06 2013-08-06 Exxonmobil Research And Engineering Company High viscosity novel base stock lubricant viscosity blends
US8188170B2 (en) 2006-06-20 2012-05-29 Chemtura Corporation Polymers with low gel content and enhanced gas-fading
JP5613416B2 (ja) * 2006-07-19 2014-10-22 エクソンモービル・ケミカル・パテンツ・インク 高粘度流体の生成プロセス
CN101490105B (zh) 2006-07-19 2013-10-02 埃克森美孚化学专利公司 采用茂金属催化剂制备聚烯烃的方法
US8080699B2 (en) * 2009-08-28 2011-12-20 Chemtura Corporation Two-stage process and system for forming high viscosity polyalphaolefins
US7601255B2 (en) 2006-09-06 2009-10-13 Chemtura Corporation Process for removal of residual catalyst components
US8513478B2 (en) * 2007-08-01 2013-08-20 Exxonmobil Chemical Patents Inc. Process to produce polyalphaolefins
WO2009020706A1 (en) * 2007-08-07 2009-02-12 Exxonmobil Chemical Patents Inc. Plasticized polyolefin compositions
US8227392B2 (en) 2008-01-25 2012-07-24 Exxonmobil Research And Engineering Company Base stocks and lubricant blends containing poly-alpha olefins
ATE524500T1 (de) * 2008-01-31 2011-09-15 Exxonmobil Chem Patents Inc Verbesserte verwendung linearer alpha-olefine bei der herstellung von metallocen-katalysierten poly-alpha-olefinen
US7943807B2 (en) * 2008-02-06 2011-05-17 Chemtura Corporation Controlling branch level and viscosity of polyalphaolefins with propene addition
US8865959B2 (en) * 2008-03-18 2014-10-21 Exxonmobil Chemical Patents Inc. Process for synthetic lubricant production
WO2009123800A1 (en) * 2008-03-31 2009-10-08 Exxonmobil Chemical Patents Inc. Production of shear-stable high viscosity pao
US7880047B2 (en) 2008-05-06 2011-02-01 Chemtura Corporation Polyalphaolefins and processes for forming polyalphaolefins
US8394746B2 (en) * 2008-08-22 2013-03-12 Exxonmobil Research And Engineering Company Low sulfur and low metal additive formulations for high performance industrial oils
JP5319992B2 (ja) * 2008-09-08 2013-10-16 三井化学株式会社 ギヤ油用潤滑油組成物
JP2010077336A (ja) * 2008-09-29 2010-04-08 Mitsui Chemicals Inc α−オレフィン(共)重合体の製造方法
US8476205B2 (en) 2008-10-03 2013-07-02 Exxonmobil Research And Engineering Company Chromium HVI-PAO bi-modal lubricant compositions
US8114946B2 (en) * 2008-12-18 2012-02-14 Chevron Phillips Chemical Company Lp Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
US8389625B2 (en) 2008-12-23 2013-03-05 Exxonmobil Research And Engineering Company Production of synthetic hydrocarbon fluids, plasticizers and synthetic lubricant base stocks from renewable feedstocks
WO2010084966A1 (ja) * 2009-01-23 2010-07-29 出光興産株式会社 歯車用潤滑油
SG175149A1 (en) * 2009-04-10 2011-11-28 Idemitsu Kosan Co A-olefin ologimer and method for producing same
RU2510404C2 (ru) 2009-06-16 2014-03-27 Шеврон Филлипс Кемикал Компани Лп Олигомеризация альфа-олефинов с применением каталитических систем металлоцен-тск и применение полученных полиальфаолефинов для получения смазывающих смесей
US8969636B2 (en) * 2009-07-29 2015-03-03 The United States Of America As Represented By The Secretary Of The Navy Homogeneous metallocene ziegler-natta catalysts for the oligomerization of olefins in aliphatic-hydrocarbon solvents
US8067652B2 (en) * 2009-08-13 2011-11-29 Chemtura Corporation Processes for controlling the viscosity of polyalphaolefins
US8716201B2 (en) * 2009-10-02 2014-05-06 Exxonmobil Research And Engineering Company Alkylated naphtylene base stock lubricant formulations
EP2485839A1 (de) * 2009-10-06 2012-08-15 Chevron Phillips Chemical Company LP Oligomerisierung von olefinwachsen mittels katalysatorsystemen auf metallocenbasis
CA2782873C (en) * 2009-12-24 2016-06-28 Exxonmobil Chemical Patents Inc. Process for producing novel synthetic basestocks
US8728999B2 (en) * 2010-02-01 2014-05-20 Exxonmobil Research And Engineering Company Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient
US8748362B2 (en) * 2010-02-01 2014-06-10 Exxonmobile Research And Engineering Company Method for improving the fuel efficiency of engine oil compositions for large low and medium speed gas engines by reducing the traction coefficient
US8642523B2 (en) * 2010-02-01 2014-02-04 Exxonmobil Research And Engineering Company Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient
US8598103B2 (en) * 2010-02-01 2013-12-03 Exxonmobil Research And Engineering Company Method for improving the fuel efficiency of engine oil compositions for large low, medium and high speed engines by reducing the traction coefficient
US8759267B2 (en) * 2010-02-01 2014-06-24 Exxonmobil Research And Engineering Company Method for improving the fuel efficiency of engine oil compositions for large low and medium speed engines by reducing the traction coefficient
WO2012027139A2 (en) 2010-08-25 2012-03-01 Exxonmobil Chemical Patents Inc. Functionalizable synthetic hydrocarbon fluids and integrated method of for production thereof
US20120165580A1 (en) * 2010-09-03 2012-06-28 Bahler Kenneth A Process For Production of Polyolefins
US9815915B2 (en) * 2010-09-03 2017-11-14 Exxonmobil Chemical Patents Inc. Production of liquid polyolefins
EP2623914B1 (de) 2010-09-28 2018-12-26 Panasonic Corporation Wärmespeichervorrichtung und klimaanlage damit
WO2012134688A1 (en) 2011-03-30 2012-10-04 Exxonmobil Chemical Patents Inc. Polyalphaolefins by oligomerization and isomerization
US20140256997A1 (en) * 2011-05-19 2014-09-11 Idemitsu Kosan Co., Ltd. 1-octene, 1-decene, 1-dodecene ternary copolymer and lubricant composition containing same
US9399746B2 (en) 2011-10-10 2016-07-26 Exxonmobil Chemical Patents Inc. Poly alpha olefin compositions
EP2738151B8 (de) * 2012-11-28 2014-12-17 Saudi Basic Industries Corporation Verfahren zur Oligomerisierung von Ethylen
US20140274849A1 (en) * 2013-03-14 2014-09-18 Exxonmobil Research And Engineering Company Lubricating composition providing high wear resistance
EP3124505B1 (de) 2014-03-28 2025-03-19 Mitsui Chemicals, Inc. Ethylen/alpha-olefin-copolymer und schmieröl
CA2949322A1 (en) * 2014-05-30 2015-12-03 Total Research & Technology Feluy Use of a metallocene catalyst to produce a polyalpha-olefin
FR3021664B1 (fr) 2014-05-30 2020-12-04 Total Marketing Services Polyolefines lubrifiantes de basse viscosite
WO2016039295A1 (ja) 2014-09-10 2016-03-17 三井化学株式会社 潤滑油組成物
US9732300B2 (en) 2015-07-23 2017-08-15 Chevron Phillipa Chemical Company LP Liquid propylene oligomers and methods of making same
US10059898B2 (en) 2015-08-21 2018-08-28 Exxonmobil Chemical Patents Inc. High-viscosity metallocene polyalpha-olefins with high electrohydrodynamic performance
JP2018523746A (ja) 2015-08-21 2018-08-23 エクソンモービル・ケミカル・パテンツ・インク 潤滑油基油ブレンド
US10611980B2 (en) 2015-10-15 2020-04-07 Exxonmobil Chemical Patents Inc. Lubricant containing high-viscosity metallocene polyalpha-olefins
US10351488B2 (en) 2016-08-02 2019-07-16 Exxonmobil Chemical Patents Inc. Unsaturated polyalpha-olefin materials
HUE048946T2 (hu) 2016-09-06 2020-09-28 Total Res & Technology Feluy Javított monovinil-aromás polimer készítmények, amelyek magas viszkozitású, metallocénnel katalizált poli-alfa-olefin adalékanyagokat tartalmaznak
DE102016220263A1 (de) 2016-10-17 2018-04-19 Clariant Plastics & Coatings Ltd Haftklebstoffe
US10584297B2 (en) 2016-12-13 2020-03-10 Afton Chemical Corporation Polyolefin-derived dispersants
US10221267B2 (en) 2016-12-13 2019-03-05 Afton Chemical Corporation Microstructure-controlled copolymers of ethylene and C3-C10 alpha-olefins
JP6741790B2 (ja) 2017-01-16 2020-08-19 三井化学株式会社 自動車ギア用潤滑油組成物
KR102462295B1 (ko) 2018-03-06 2022-11-03 발보린 라이센싱 앤드 인텔렉츄얼 프러퍼티 엘엘씨 견인 유체 조성물
KR102111865B1 (ko) * 2018-11-27 2020-05-18 대림산업 주식회사 균일한 구조를 가지는 폴리알파올레핀 및 이의 제조방법
WO2020112547A1 (en) * 2018-11-29 2020-06-04 Exxonmobil Chemical Patents Inc. Poly(alpha-olefin)s and methods thereof
CA3130106C (en) 2019-03-13 2023-05-02 Valvoline Licensing And Intellectual Property Llc Novel traction fluid with improved low temperature properties
CN112745415B (zh) 2019-10-30 2022-09-09 中国石油化工股份有限公司 一种制备高粘度指数聚α-烯烃的方法

Family Cites Families (88)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1208196A (en) * 1982-03-10 1986-07-22 Raymond F. Watts Lubricating composition
US5227478A (en) 1982-09-13 1993-07-13 Sandoz Ltd. 2-chloro-4-[4'-(4",8"-disulfonaphth-2"-ylazo)-2'-methoxy-5'-methylanilino]-6
US5324800A (en) 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US4594469A (en) * 1983-09-08 1986-06-10 Uniroyal Chemical Company, Inc. Method for the oligomerization of alpha-olefins
DE3508887A1 (de) 1985-03-13 1986-09-25 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von optisch aktiven polyolefinen
US4752597A (en) 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
US5384299A (en) 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
US5391629A (en) 1987-01-30 1995-02-21 Exxon Chemical Patents Inc. Block copolymers from ionic catalysts
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5241025A (en) 1987-01-30 1993-08-31 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5064797A (en) * 1987-04-03 1991-11-12 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
JP2538595B2 (ja) 1987-05-13 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒
DE3726067A1 (de) 1987-08-06 1989-02-16 Hoechst Ag Verfahren zur herstellung von 1-olefinpolymeren
JP2573613B2 (ja) 1987-08-14 1997-01-22 三菱化学株式会社 エチレンの重合法
US4931417A (en) 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
US5017714A (en) 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US4871705A (en) 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
US5229478A (en) 1988-06-16 1993-07-20 Exxon Chemical Patents Inc. Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system
CA1327673C (en) 1988-06-16 1994-03-08 Sigmund Floyd Process for production of high molecular weight epdm elastomers using a metallocene-alumoxane catalyst system
US5001205A (en) 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
US5155080A (en) 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US4892851A (en) 1988-07-15 1990-01-09 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
US5223468A (en) 1988-07-15 1993-06-29 Fina Technology, Inc. Process and catalyst for producing syndiotactic polymers
US5243002A (en) 1988-07-15 1993-09-07 Fina Technology, Inc. Process and catalyst for producing syndiotactic polymers
DE3836059A1 (de) 1988-10-22 1990-05-03 Hoechst Ag Verfahren zur herstellung eines ethylen-propylen-copolymers
JPH02140295A (ja) * 1988-11-19 1990-05-29 Kao Corp フロン雰囲気下で用いる潤滑油
IT1237398B (it) 1989-01-31 1993-06-01 Ausimont Srl Catalizzatori per la polimerizzazione di olefine.
DE3907964A1 (de) 1989-03-11 1990-09-13 Hoechst Ag Verfahren zur herstellung eines syndiotaktischen polyolefins
US5441920A (en) 1989-03-21 1995-08-15 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
DE3916553A1 (de) 1989-05-20 1990-11-22 Hoechst Ag Syndio- isoblockpolymer und verfahren zu seiner herstellung
DE3922546A1 (de) 1989-07-08 1991-01-17 Hoechst Ag Verfahren zur herstellung von cycloolefinpolymeren
US5034549A (en) 1989-07-28 1991-07-23 Akzo N.V. Olefin polymerization catalyst
US5026798A (en) 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5227440A (en) 1989-09-13 1993-07-13 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
US5036034A (en) 1989-10-10 1991-07-30 Fina Technology, Inc. Catalyst for producing hemiisotactic polypropylene
EP0427697B1 (de) 1989-10-10 1996-05-08 Fina Technology, Inc. Metallocenkatalysator mit Lewissäure und Alkylaluminium
EP0426638B2 (de) 1989-10-30 2005-03-02 Fina Technology, Inc. Addition von Alkylaluminium zum Verbessern eines Metallocenkatalysators
DE4005947A1 (de) 1990-02-26 1991-08-29 Basf Ag Loesliche katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen
ATE134658T1 (de) 1990-09-14 1996-03-15 Exxon Chemical Patents Inc Ionischer katalysator zur herstellung von polyalphaolefinen mit kontrollierter takticität
DE59104869D1 (de) 1990-11-12 1995-04-13 Hoechst Ag 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation.
DE69127811T3 (de) 1990-11-30 2012-04-26 Idemitsu Kosan Co., Ltd. Verfahren zur herstellung von olefinpolymeren
JP3048653B2 (ja) 1991-02-07 2000-06-05 三菱化学株式会社 α‐オレフィン重合体の製造
JP3117231B2 (ja) 1991-03-11 2000-12-11 三井化学株式会社 幅広い分子量分布を有するシンジオタクチックポリ−α−オレフィンの製造方法
JP3193066B2 (ja) 1991-05-02 2001-07-30 三菱化学株式会社 プロピレンランダム共重合体の製造法
US5401817A (en) 1991-05-09 1995-03-28 Phillips Petroleum Company Olefin polymerization using silyl-bridged metallocenes
US5191132A (en) 1991-05-09 1993-03-02 Phillips Petroleum Company Cyclopentadiene type compounds and method for making
US5436305A (en) 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
US5399636A (en) 1993-06-11 1995-03-21 Phillips Petroleum Company Metallocenes and processes therefor and therewith
EP0516019B1 (de) * 1991-05-27 1995-12-27 Hoechst Aktiengesellschaft Verfahren zur Herstellung von syndiotaktischen Polyolefinen mit breiter Molmassenverteilung
DE4120009A1 (de) 1991-06-18 1992-12-24 Basf Ag Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen
US5391789A (en) 1991-08-08 1995-02-21 Hoechst Aktiengesellschaft Bridged, chiral metallocenes, processes for their preparation and their use as catalysts
US5416228A (en) 1991-10-07 1995-05-16 Fina Technology, Inc. Process and catalyst for producing isotactic polyolefins
DE59210001D1 (de) 1991-10-15 2005-02-17 Basell Polyolefine Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
US5281679A (en) 1991-11-07 1994-01-25 Exxon Chemical Patents Inc. Catalyst and method of broadening polymer molecular weight distribution and increasing polymer tensile impact strength and products made thereof
CA2124187C (en) 1991-11-25 2001-08-07 Howard William Turner Polyonic transition metal catalyst composition
DE69224463T2 (de) 1991-11-28 1998-07-09 Showa Denko Kk Neues Metallocen und Verfahren zur Herstellung von Polyolefinen unter Verwendung desselben
TW318184B (de) 1991-11-30 1997-10-21 Hoechst Ag
DE59206948D1 (de) 1991-11-30 1996-09-26 Hoechst Ag Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
WO1993014132A1 (en) 1992-01-06 1993-07-22 The Dow Chemical Company Improved catalyst composition
US5331057A (en) 1992-02-22 1994-07-19 Hoechst Aktiengesellschaft Cycloolefin block copolymers and a process for their preparation
US5807949A (en) 1992-03-19 1998-09-15 Exxon Chemical Patents Inc. Polymers and additive compositions
US5330948A (en) 1992-03-31 1994-07-19 Northwestern University Homogeneous catalysts for stereoregular olefin polymerization
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5308817A (en) 1992-05-18 1994-05-03 Fina Technology, Inc. Metallocene catalyst component with good catalyst efficiency after aging
US5434115A (en) 1992-05-22 1995-07-18 Tosoh Corporation Process for producing olefin polymer
WO1993024539A1 (en) 1992-05-26 1993-12-09 Amoco Corporation Reactive, low molecular weight, viscous poly(1-olefins) and copoly(1-olefins) and their method of manufacture
DK0575875T3 (da) 1992-06-18 2000-09-18 Montell Technology Company Bv Katalysator til polymerisation af olefiner
US5264642A (en) 1992-06-19 1993-11-23 Mobil Oil Corp. Molecular weight control of olefin oligomers
ATE165832T1 (de) 1992-08-03 1998-05-15 Targor Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung von metallocenen mit speziell substituierten indenylliganden
EP0586777B1 (de) 1992-08-31 1999-04-28 Fina Research S.A. Verfahren zur Herstellung von flüssigen statistischen Copolymerisaten des Typs Ethylen
JP2936189B2 (ja) 1992-09-09 1999-08-23 東ソー株式会社 有機遷移金属錯体
US5317036A (en) 1992-10-16 1994-05-31 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization reactions utilizing soluble unsupported catalysts
KR100311244B1 (ko) 1993-02-22 2001-12-15 가지와라 야스시 에틸렌/α-올레핀공중합체의제조방법
US5372980A (en) 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
IT1264482B1 (it) 1993-06-30 1996-09-23 Spherilene Srl Copolimeri amorfi dell'etilene con propilene e procedimento per la loro preparazione
ES2141833T3 (es) 1993-08-06 2000-04-01 Exxon Chemical Patents Inc Catalizadores de polimerizacion, su produccion y uso.
US5459117A (en) 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
IT1271407B (it) 1993-09-13 1997-05-28 Spherilene Srl Procedimento per la preparazione di copolimeri elastomerici dell'etilene e prodotti ottenuti
US5466649A (en) 1993-10-15 1995-11-14 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
DE4337233A1 (de) 1993-10-30 1995-05-04 Basf Ag Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶0¶-Alk-1-enen unter Verwendung von racemischen Metallocenkomplexen als Katalysatoren
JP3379172B2 (ja) 1993-11-11 2003-02-17 東ソー株式会社 エチレン・α−オレフィン共重合体
US5491207A (en) 1993-12-14 1996-02-13 Exxon Chemical Patents Inc. Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system
DE69502744T2 (de) * 1994-02-17 1998-10-01 Union Carbide Chem Plastic Sprühgetrocknete Füllstoffe enthaltende Metallocenkatalysatorzusammensetzung zur Herstellung von Polyolefinen
JPH07267883A (ja) * 1994-03-31 1995-10-17 Idemitsu Petrochem Co Ltd オレフィンオリゴマーの製造方法
US6225426B1 (en) * 1996-04-10 2001-05-01 Uniroyal Chemical Company, Inc. Process for producing polyolefin elastomer employing a metallocene catalyst

Also Published As

Publication number Publication date
DE60128926T2 (de) 2008-02-14
US6858767B1 (en) 2005-02-22
JP2004506758A (ja) 2004-03-04
BR0113185B1 (pt) 2011-05-03
EP1309633B1 (de) 2007-06-13
ATE364640T1 (de) 2007-07-15
JP2006206925A (ja) 2006-08-10
AU2001283177A1 (en) 2002-02-25
CA2416894C (en) 2010-05-25
EP1309633A2 (de) 2003-05-14
BR0113185A (pt) 2003-09-16
WO2002014384A2 (en) 2002-02-21
CA2416894A1 (en) 2002-02-21
WO2002014384A3 (en) 2002-05-23
JP4074191B2 (ja) 2008-04-09
MXPA03001289A (es) 2003-06-30
JP5420816B2 (ja) 2014-02-19

Similar Documents

Publication Publication Date Title
DE60128926D1 (de) Verfahren zur herstellung von flüssigem poly-alpha-olefin, metallocen dafür und diese enthaltende schmiermittel
Yang et al. Terpolymerization of Ethylene and Two Different Methoxyaryl‐Substituted Propylenes by Scandium Catalyst Makes Tough and Fast Self‐Healing Elastomers
AU2002352486A1 (en) PROCESS FOR THE OLIGOMERIZATION OF AlphaOLEFINS HAVING LOW UNSATURATION, THE RESULTING POLYMERS, AND LUBRICANTS CONTAINING SAME
ATE557077T1 (de) Copolymere aus 1-decen und 1-dodecen als schmierstoffe
EP0893455A4 (de) Olefin-polymerisationskatalysator, olefin-polymerisations verfahren, olefin-polymerzusammensetzungen und in der wärme geformte gegenstände
MY150532A (en) Polyethylene compositions, method of producing the same, fibers made therefrom, and method of making the same
DE69828049D1 (de) Copolymere aus ethylen und alpha-olefinen,verfahren und verwendung davon
BR9710969A (pt) Processo para preparar um copolìmero de etileno, copolìmero de etileno, composição de mistura polimérica, processo para formar uma composição de mistura polìmerica, pó de sintetização e artigo fabricado
PT743324E (pt) Producao de polietileno usando metalocenos estereoisomericos
BR0212176A (pt) Composição de poli-alfa olefina, lubrificante, e, métodos de fabricação de uma poli-alfa olefina, e de um lubrificante
JPH05279481A (ja) フルオロシリコ−ンブロック共重合体およびその製造方法
JPS626600B2 (de)
KR970006403A (ko) 폴리아미드 수지 조성물
WO2003038017A1 (fr) Additif pour huile lubrifiante et composition d'huile lubrifiante
JP2004527617A5 (de)
RU1788957C (ru) Способ получени привитого сополимера
KR20010049193A (ko) 비닐리덴 함유 폴리머 및 이의 용도
ES2584163T3 (es) Composiciones mejoradoras de la viscosidad que proporcionan al aceite lubricante características mejoradas a baja temperatura
USH1799H (en) Star polymer viscosity index improver for oil compositions
JP2023546724A (ja) 化粧料組成物及びその製造方法
JPS58152038A (ja) 射出成形用ポリプロピレン組成物
Ninago et al. Effects of Branches on the Isothermal Crystallization of Copolymers Based on Poly (ϵ‐caprolactone)
Liou et al. Synthesis of a star‐shaped poly (ethylene‐co‐propylene) copolymer as a viscosity index improver for lubricants
JP3812855B2 (ja) 潤滑油基油組成物
Lomège et al. Epoxidized oleic acid‐based Polymethacrylates as viscosity index improvers

Legal Events

Date Code Title Description
8327 Change in the person/name/address of the patent owner

Owner name: CHEMTURA CORPORATION, MIDDLEBURY, CONN., US

8364 No opposition during term of opposition
8328 Change in the person/name/address of the agent

Representative=s name: KROHER, STROBEL RECHTS- UND PATENTANWAELTE, 80336

8328 Change in the person/name/address of the agent

Representative=s name: DR. SCHOEN & PARTNER, 80336 MUENCHEN