DE60126516D1 - Verwendung von Polysulphiden zur Stabilisierung von vernetzen Silangruppen enthaltenden Polymeren - Google Patents
Verwendung von Polysulphiden zur Stabilisierung von vernetzen Silangruppen enthaltenden PolymerenInfo
- Publication number
- DE60126516D1 DE60126516D1 DE60126516T DE60126516T DE60126516D1 DE 60126516 D1 DE60126516 D1 DE 60126516D1 DE 60126516 T DE60126516 T DE 60126516T DE 60126516 T DE60126516 T DE 60126516T DE 60126516 D1 DE60126516 D1 DE 60126516D1
- Authority
- DE
- Germany
- Prior art keywords
- silane groups
- polysulphides
- polymers containing
- containing crosslinking
- stabilizing polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 title abstract 2
- 238000004132 cross linking Methods 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title abstract 2
- 229920001021 polysulfide Polymers 0.000 title 1
- 230000000087 stabilizing effect Effects 0.000 title 1
- 239000003381 stabilizer Substances 0.000 abstract 2
- 230000002378 acidificating effect Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 125000004185 ester group Chemical group 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 abstract 1
- 230000006641 stabilisation Effects 0.000 abstract 1
- 238000011105 stabilization Methods 0.000 abstract 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/372—Sulfides, e.g. R-(S)x-R'
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
- C08K5/375—Thiols containing six-membered aromatic rings
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Silicon Polymers (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01110688A EP1254923B1 (de) | 2001-05-02 | 2001-05-02 | Stabilisierung von vernetzen Silangruppen enthaltenden Polymeren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE60126516D1 true DE60126516D1 (de) | 2007-03-22 |
Family
ID=8177299
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60126516T Expired - Lifetime DE60126516D1 (de) | 2001-05-02 | 2001-05-02 | Verwendung von Polysulphiden zur Stabilisierung von vernetzen Silangruppen enthaltenden Polymeren |
| DE60122674T Expired - Lifetime DE60122674T2 (de) | 2001-05-02 | 2001-05-02 | Stabilisierung von vernetzen Silangruppen enthaltenden Polymeren |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE60122674T Expired - Lifetime DE60122674T2 (de) | 2001-05-02 | 2001-05-02 | Stabilisierung von vernetzen Silangruppen enthaltenden Polymeren |
Country Status (14)
| Country | Link |
|---|---|
| US (3) | US20040127641A1 (de) |
| EP (2) | EP1433811B1 (de) |
| JP (1) | JP3989848B2 (de) |
| KR (1) | KR100852906B1 (de) |
| CN (2) | CN100526377C (de) |
| AT (2) | ATE338092T1 (de) |
| BR (2) | BR0209373B1 (de) |
| CA (2) | CA2443824C (de) |
| DE (2) | DE60126516D1 (de) |
| ES (2) | ES2270917T3 (de) |
| PL (1) | PL210589B1 (de) |
| PT (2) | PT1433811E (de) |
| RU (1) | RU2292365C2 (de) |
| WO (1) | WO2002088239A1 (de) |
Families Citing this family (63)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2004253897A1 (en) * | 2003-06-25 | 2005-01-13 | Union Carbide Chemicals & Plastics Technology Llc | Moisture crosslinkable polymeric composition containing special antioxidants |
| US20070023735A1 (en) * | 2003-06-25 | 2007-02-01 | Biscoglio Michael B | Polymeric composition-corrosion inhibitors |
| PT1528574E (pt) * | 2003-10-24 | 2006-10-31 | Borealis Tech Oy | Cabo de alimentacao de baixa tensao com camada isoladora compreendendo poliolefina com grupos polares |
| ATE440906T1 (de) * | 2004-11-16 | 2009-09-15 | Borealis Tech Oy | Vernetzbare polyethylenzusammensetzung, diese enthaltendes elektrokabel und herstellungsverfahren dafür |
| CA2599793C (en) * | 2005-03-18 | 2013-08-13 | Dow Global Technologies Inc. | Moisture crosslinkable polymeric composition-improved heat aging performance |
| EP1760111A1 (de) | 2005-08-31 | 2007-03-07 | Borealis Technology Oy | Polyolefinzusammensetzung enthaltend entfärbefreien Silanolkondensationskatalysator |
| FR2892172B1 (fr) | 2005-10-13 | 2007-12-14 | Arkema Sa | Tube multicouche a base de polymere fluore modifie |
| FR2893696B1 (fr) | 2005-11-24 | 2009-03-06 | Arkema Sa | Tube multicouche pour le transport d'eau ou de gaz |
| ES2374415T3 (es) | 2006-05-30 | 2012-02-16 | Borealis Technology Oy | Un compuesto que contiene silicio como ayuda de procesamiento para composiciones de poliolefinas que comprenden poliolefinas entrecruzables con grupos silano hidrolizables. |
| DE602006002263D1 (de) * | 2006-05-30 | 2008-09-25 | Borealis Tech Oy | Silizium enthaltende Vebindung als pH Kontrollmittel in Polymerzusammensetzungen |
| TWI425041B (zh) * | 2006-07-25 | 2014-02-01 | Clariant Finance Bvi Ltd | 在以熔融加工製備聚乙烯物件過程中該物件之改良處理條件 |
| DE602006009828D1 (de) * | 2006-11-16 | 2009-11-26 | Borealis Tech Oy | Verfahren zur Herstellung eines Ethylen-Silan-Copolymeren |
| ES2328866T3 (es) | 2007-11-08 | 2009-11-18 | Borealis Technology Oy | Composicion de poliolefina reticulable que comprende dihidrocarbil estaño como catalizador de condensacion de silanol. |
| EP2075281A1 (de) * | 2007-12-03 | 2009-07-01 | Borealis Technology OY | Polyolefin-Zusammensetzung mit vernetzbarem Polyolefin mit Silangruppen, Silanolkondensierungskatalysator und siliziumhaltige Zusammensetzung |
| ATE536387T1 (de) * | 2007-12-20 | 2011-12-15 | Borealis Tech Oy | Uv-stabilisierung einer vernetzbaren polyolefinzusammensetzung mit einem sauren silanol-kondensationskatalysator |
| PL2072571T3 (pl) | 2007-12-21 | 2012-03-30 | Borealis Tech Oy | Zastosowanie kompozycji poliolefinowej zawierającej zdolną do sieciowania poliolefinę z grupami silanowymi, katalizator kondensacji silanolu i pigment do wytwarzania warstwy na przewodzie drutowym lub kablu |
| EP2083047A1 (de) | 2008-01-24 | 2009-07-29 | Borealis Technology OY | Teilweise vernetzte Polypropylenzusammensetzung mit einem sauren Silanol-Kondensationskatalysator |
| PL2251365T3 (pl) | 2009-05-14 | 2019-09-30 | Borealis Ag | Sieciowalna kompozycja poliolefinowa zawierająca grupy silanowe tworzące kwas lub zasadę w wyniku hydrolizy |
| EP2363267B1 (de) | 2010-03-03 | 2013-08-21 | Borealis AG | Vernetzbare Polyolefinzusammensetzung mit zwei Arten von Silangruppen |
| EP2582743B1 (de) | 2010-06-21 | 2014-04-02 | Borealis AG | Silanvernetzbare Polymerzusammensetzung |
| EP2691468A1 (de) * | 2011-03-31 | 2014-02-05 | Dow Corning Corporation | Zusammensetzungen mit sulfonsäurekatalysatoren und verfahren zur herstellung und verwendung dieser zusammensetzungen |
| EP2508558B1 (de) | 2011-04-07 | 2014-05-21 | Borealis AG | Silanvernetzbare Polymerzusammensetzung |
| PL2508566T3 (pl) | 2011-04-07 | 2014-08-29 | Borealis Ag | Sieciowalna poprzez grupy silanowe kompozycja polimerowa |
| CN104302694B (zh) | 2012-04-27 | 2016-06-29 | 博里利斯股份公司 | 阻燃聚合物组合物 |
| ES2570878T3 (es) | 2012-12-21 | 2016-05-20 | Borealis Ag | Procedimiento para la fabricación de un artículo de polietileno reticulado |
| WO2015091707A1 (en) | 2013-12-18 | 2015-06-25 | Borealis Ag | A polymer composition comprising a polyolefin composition and a at least one silanol condensation catalyst |
| US10233310B2 (en) | 2013-12-18 | 2019-03-19 | Borealis Ag | Polymer composition comprising a crosslinkable polyolefin with hydrolysable silane groups, catalyst and a surfactant interacting additive |
| JP6636469B2 (ja) | 2014-06-27 | 2020-01-29 | ダウ グローバル テクノロジーズ エルエルシー | 安定化された水分硬化性ポリマー組成物 |
| WO2015200016A1 (en) | 2014-06-27 | 2015-12-30 | Dow Global Technologies Llc | Stabilized moisture-curable polymeric compositions |
| TWI609908B (zh) | 2014-09-18 | 2018-01-01 | 柏列利斯股份公司 | 用於層元件之層的聚合物組成物 |
| TWI583706B (zh) | 2014-09-18 | 2017-05-21 | 柏列利斯股份公司 | 用於層元件之層的聚合物組成物 |
| NL2015495B1 (en) * | 2015-09-23 | 2017-04-20 | Strongbond B V | Silyl modified polymer sealant. |
| MX2018005732A (es) | 2015-11-30 | 2018-08-09 | Dow Global Technologies Llc | Composiciones polimericas curables por humedad estabilizadas. |
| RU2735228C2 (ru) | 2015-12-09 | 2020-10-29 | Дау Глоубл Текнолоджиз Ллк | Стабилизированные влагоотверждаемые полимерные композиции |
| ES3028507T3 (en) | 2015-12-18 | 2025-06-19 | Borealis Ag | A cable jacket composition, cable jacket and a cable, e.g. a power cable or a communication cable |
| ES2720524T3 (es) | 2015-12-18 | 2019-07-22 | Borealis Ag | Proceso para la fabricación de un cable de alimentación y cable de alimentación obtenible del mismo |
| BR112019007054B1 (pt) | 2016-11-02 | 2023-05-09 | Dow Global Technologies Llc | Composição de masterbatch de aditivo, composição de poliolefina curável por umidade, método de preparação de uma composição poliolefínica curável por umidade, artigo fabricado, condutor revestido e método de conduzir eletricidade |
| KR102569063B1 (ko) | 2016-11-02 | 2023-08-23 | 다우 글로벌 테크놀로지스 엘엘씨 | 반결정질 폴리올레핀계 첨가제 마스터배취 조성물 |
| MX2019015062A (es) | 2017-06-29 | 2020-02-13 | Dow Global Technologies Llc | Composicion de poliolefina. |
| WO2019007921A1 (en) * | 2017-07-05 | 2019-01-10 | Basf Se | CATALYSTS FOR THE SYNTHESIS OF POLYSTEROL |
| EP3688082B1 (de) | 2017-09-26 | 2023-11-08 | Dow Global Technologies LLC | Zusammensetzungen mit einem katalysator auf zinnbasis und titandioxid zur feuchtigkeitshärtung von silanfunktionalisierten ethylenpolymeren |
| EP3470442A1 (de) | 2017-10-11 | 2019-04-17 | Borealis AG | Dichtmaterial mit terpolymeren |
| EP3499515B1 (de) | 2017-12-12 | 2023-03-22 | Borealis AG | Flammenhemmende und feuerbeständige polyolefin-zusammensetzung |
| EP3499516A1 (de) | 2017-12-12 | 2019-06-19 | Borealis AG | Flammenhemmende und feuerbeständige polyolefin-zusammensetzung |
| EP3746503A4 (de) | 2018-02-01 | 2021-08-04 | Dow Global Technologies LLC | Masterbatch mit semikristallinem polyolefinträgerharz |
| MX2020007435A (es) | 2018-02-01 | 2020-09-14 | Dow Global Technologies Llc | Mezcla madre con resina portadora de poliolefina semicristalina. |
| FR3081602B1 (fr) | 2018-05-22 | 2020-05-01 | Arkema France | Cables multicouches pour environnement offshore |
| CN113614120B (zh) * | 2018-10-02 | 2024-03-22 | 博里利斯股份公司 | 接枝塑性体的高速交联 |
| WO2020180495A1 (en) | 2019-03-07 | 2020-09-10 | Dow Global Technologies Llc | Catalyst system |
| EP3990525A1 (de) | 2019-06-27 | 2022-05-04 | Dow Global Technologies LLC | Verfahren zur herstellung einer homogenen mischung aus polyolefin und flüssiger organischer säure |
| EP3778747A1 (de) | 2019-08-14 | 2021-02-17 | Borealis AG | Uv-stabilisierung einer vernetzbaren polyolefinzusammensetzung mit einem sauren silanolkondensationskatalysator |
| EP3778746A1 (de) | 2019-08-14 | 2021-02-17 | Borealis AG | Uv-stabilisierung einer vernetzbaren polyolefinzusammensetzung mit einem sauren silanolkondensationskatalysator |
| EP3831875A1 (de) | 2019-12-05 | 2021-06-09 | Borealis AG | Flammhemmende polymerzusammensetzung |
| CN117222520A (zh) | 2021-05-18 | 2023-12-12 | 美国圣戈班性能塑料公司 | 复合管及其制造方法 |
| ES2971885T3 (es) | 2021-10-14 | 2024-06-10 | Borealis Ag | Composición de polímero retardante de la llama |
| CN118076687A (zh) | 2021-10-15 | 2024-05-24 | 博里利斯股份公司 | 无卤阻燃聚合物组合物 |
| EP4169976A1 (de) | 2021-10-19 | 2023-04-26 | Borealis AG | Polyethylenzusammensetzung für kabelisolierungen mit verbesserter uv-stabilität |
| ES2966148T3 (es) * | 2021-12-08 | 2024-04-18 | Nexam Chemical Ab | Nuevo procedimiento de reciclaje de polietileno |
| EP4201985A1 (de) | 2021-12-21 | 2023-06-28 | Borealis AG | Polymerzusammensetzung zur kabelisolierung |
| WO2023180367A1 (en) * | 2022-03-24 | 2023-09-28 | Borealis Ag | Polymer composition and use thereof as silanol condensation catalyst masterbatch |
| EP4474421A1 (de) * | 2023-06-07 | 2024-12-11 | Nexam Chemical AB | Verfahren zur bereitstellung einer zusammensetzung mit recyceltem polyethylen |
| EP4570854A1 (de) | 2023-12-15 | 2025-06-18 | Borealis AG | Flammwidrige polymerzusammensetzung |
| EP4668292A1 (de) | 2024-06-20 | 2025-12-24 | Borealis GmbH | Zirkoniumphosphat als flammhemmungsverstärker für mdh-gefüllte silanvernetzte systeme |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL133211C (de) * | 1959-06-10 | |||
| BE635979A (de) * | 1962-08-10 | |||
| BE794718Q (fr) * | 1968-12-20 | 1973-05-16 | Dow Corning Ltd | Procede de reticulation d'olefines |
| NL7104234A (de) * | 1970-05-11 | 1971-11-15 | ||
| GB1526398A (en) * | 1974-12-06 | 1978-09-27 | Maillefer Sa | Manufacture of extruded products |
| JPS5813655A (ja) * | 1981-07-15 | 1983-01-26 | Kanegafuchi Chem Ind Co Ltd | 室温硬化性組成物 |
| JP2512468B2 (ja) * | 1987-04-13 | 1996-07-03 | 鐘淵化学工業株式会社 | 硬化性樹脂組成物 |
| JP2612193B2 (ja) * | 1988-10-07 | 1997-05-21 | チッソ株式会社 | プラスチックマグネット組成物 |
| SE462752B (sv) * | 1988-12-23 | 1990-08-27 | Neste Oy | Silanfoernaetningsbar polymerkomposition innehaallande en silanfoerening som motverkar foer tidig haerdning |
| JP2738037B2 (ja) * | 1989-07-05 | 1998-04-08 | 三井化学株式会社 | ポリオレフィン樹脂繊維 |
| IT1243985B (it) * | 1990-10-12 | 1994-06-28 | Enichem Sintesi | Stabilizzanti u.v. siliconici contenenti gruppi reattivi. |
| US5216061A (en) * | 1991-01-11 | 1993-06-01 | Phillips Petroleum Company | Process to graft stereoregular polymers of branched, higher alpha-olefins and compositions thereof |
| DE69229852T2 (de) * | 1991-05-31 | 2000-02-24 | Borealis A/S, Lyngby | Vernetzbare Polymerzusammensetzung |
| EP0547277A1 (de) * | 1991-12-16 | 1993-06-23 | BP Chemicals Limited | Verfahren zur Herstellung von stabilisierten Silancopolymere |
| NO175597C (no) * | 1992-09-14 | 1994-11-02 | Norsk Hydro As | Kryssbundet silanholdig PVC-kopolymer og en fremgangsmåte for fremstilling av denne |
| US5661219A (en) * | 1993-09-06 | 1997-08-26 | Nof Corporation | Curable composition, thermal latent acid catalyst, method of coating, coated article, method of molding and molded article |
| SE9304201L (sv) * | 1993-12-20 | 1994-11-21 | Neste Oy | Tennorganisk katalysator med ökad förnätningshastighet för silanförnätningsreaktioner |
| SE502171C2 (sv) | 1993-12-20 | 1995-09-04 | Borealis Holding As | Polyetenkompatibla sulfonsyror som silanförnätningskatalysatorer |
| US5814695A (en) * | 1995-09-08 | 1998-09-29 | General Electric Company | Silicone molding compositions having extended useful life |
| US5922403A (en) * | 1996-03-12 | 1999-07-13 | Tecle; Berhan | Method for isolating ultrafine and fine particles |
| CA2223380A1 (en) * | 1996-12-17 | 1998-06-17 | Fiberstars Incorporated | Acrylic flexible light pipe of improved photo-thermal stability |
| JP2000309677A (ja) * | 1999-04-26 | 2000-11-07 | Teijin Ltd | 帯電防止abs系樹脂組成物及びその製造方法 |
| JP2000309691A (ja) * | 1999-04-26 | 2000-11-07 | Teijin Ltd | 帯電防止pbt系樹脂組成物及びその製造方法 |
| JP2000310360A (ja) * | 1999-04-27 | 2000-11-07 | Sumitomo Bakelite Co Ltd | シラン架橋ポリオレフィン管用樹脂組成物 |
-
2001
- 2001-05-02 PT PT04003302T patent/PT1433811E/pt unknown
- 2001-05-02 ES ES01110688T patent/ES2270917T3/es not_active Expired - Lifetime
- 2001-05-02 ES ES04003302T patent/ES2281700T3/es not_active Expired - Lifetime
- 2001-05-02 EP EP04003302A patent/EP1433811B1/de not_active Expired - Lifetime
- 2001-05-02 EP EP01110688A patent/EP1254923B1/de not_active Expired - Lifetime
- 2001-05-02 DE DE60126516T patent/DE60126516D1/de not_active Expired - Lifetime
- 2001-05-02 AT AT01110688T patent/ATE338092T1/de not_active IP Right Cessation
- 2001-05-02 DE DE60122674T patent/DE60122674T2/de not_active Expired - Lifetime
- 2001-05-02 PT PT01110688T patent/PT1254923E/pt unknown
- 2001-05-02 AT AT04003302T patent/ATE353352T1/de active
-
2002
- 2002-04-30 WO PCT/EP2002/004773 patent/WO2002088239A1/en not_active Ceased
- 2002-04-30 CN CNB028092198A patent/CN100526377C/zh not_active Expired - Fee Related
- 2002-04-30 BR BRPI0209373-1A patent/BR0209373B1/pt not_active IP Right Cessation
- 2002-04-30 RU RU2003134702/04A patent/RU2292365C2/ru active
- 2002-04-30 CA CA002443824A patent/CA2443824C/en not_active Expired - Lifetime
- 2002-04-30 CA CA002652848A patent/CA2652848A1/en not_active Abandoned
- 2002-04-30 CN CNB2005100836739A patent/CN100408619C/zh not_active Expired - Fee Related
- 2002-04-30 KR KR1020037013313A patent/KR100852906B1/ko not_active Expired - Lifetime
- 2002-04-30 JP JP2002585533A patent/JP3989848B2/ja not_active Expired - Lifetime
- 2002-04-30 PL PL366999A patent/PL210589B1/pl unknown
- 2002-04-30 BR BRPI0216095-1A patent/BR0216095B1/pt not_active IP Right Cessation
-
2003
- 2003-10-17 US US10/688,252 patent/US20040127641A1/en not_active Abandoned
-
2007
- 2007-06-26 US US11/823,022 patent/US7842772B2/en not_active Expired - Fee Related
- 2007-06-26 US US11/823,039 patent/US7781557B2/en not_active Expired - Lifetime
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