[go: up one dir, main page]

DE60012981D1 - Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit xanthaten - Google Patents

Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit xanthaten

Info

Publication number
DE60012981D1
DE60012981D1 DE60012981T DE60012981T DE60012981D1 DE 60012981 D1 DE60012981 D1 DE 60012981D1 DE 60012981 T DE60012981 T DE 60012981T DE 60012981 T DE60012981 T DE 60012981T DE 60012981 D1 DE60012981 D1 DE 60012981D1
Authority
DE
Germany
Prior art keywords
xanthates
radical polymerization
controlled radical
producing polymers
polymer composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE60012981T
Other languages
English (en)
Other versions
DE60012981T2 (de
Inventor
Mathias Destarac
Dominique Charmot
Samir Zard
Isabelle Gauthier-Gillaizeau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhodia Chimie SAS
Rhone Poulenc Chimie SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Chimie SAS, Rhone Poulenc Chimie SA filed Critical Rhodia Chimie SAS
Application granted granted Critical
Publication of DE60012981D1 publication Critical patent/DE60012981D1/de
Publication of DE60012981T2 publication Critical patent/DE60012981T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
DE60012981T 1999-12-09 2000-12-08 Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit xanthaten Expired - Fee Related DE60012981T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR9915555A FR2802208B1 (fr) 1999-12-09 1999-12-09 Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates
FR9915555 1999-12-09
PCT/FR2000/003458 WO2001042312A1 (fr) 1999-12-09 2000-12-08 Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates

Publications (2)

Publication Number Publication Date
DE60012981D1 true DE60012981D1 (de) 2004-09-16
DE60012981T2 DE60012981T2 (de) 2005-08-11

Family

ID=9553076

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60012981T Expired - Fee Related DE60012981T2 (de) 1999-12-09 2000-12-08 Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit xanthaten

Country Status (8)

Country Link
US (2) US6809164B2 (de)
EP (1) EP1242467B1 (de)
AT (1) ATE273326T1 (de)
AU (1) AU2685401A (de)
DE (1) DE60012981T2 (de)
ES (1) ES2225294T3 (de)
FR (1) FR2802208B1 (de)
WO (1) WO2001042312A1 (de)

Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7186419B2 (en) 2000-08-25 2007-03-06 Contura Sa Polyacrylamide hydrogel for arthritis
MY130475A (en) 2000-08-25 2007-06-29 Contura As Polyacrylamide hydrogel and its use as an endoprosthesis
FR2829140B1 (fr) * 2001-09-05 2003-12-19 Rhodia Chimie Sa Procede de synthese de polymeres a fonctions thiols
KR20030081462A (ko) * 2001-02-26 2003-10-17 로디아 쉬미 저에너지 표면의 친수성을 증가시키기 위한 양쪽성 블록코폴리머의 용도
DE60221008T2 (de) * 2001-05-04 2008-03-13 Rhodia Chimie Verfahren zur radikalen reduzierung von dithiocarbonyl- und dithiophosphorylfunktionen von polymeren
FR2829138B1 (fr) * 2001-09-05 2003-12-19 Rhodia Chimie Sa Procede de reduction radicalaire de fonctions dithiocarbonylees ou dithiophosphorylees portees par un polymere
FR2829494B1 (fr) * 2001-07-13 2005-10-28 Rhodia Chimie Sa Compositions aqueuses comprenant un microgel chimique associe a un polymere pontant, preparation et utilisation
FR2842190A1 (fr) 2002-07-10 2004-01-16 Rhodia Performance Fibres Materiaux composites renforces comprenant un liant hydraulique ou chimique,des fibres de polyamide ainsi qu'un ou plusieurs additifs pour comportement mecanique ameliore
FR2842814B1 (fr) 2002-07-26 2004-10-22 Coatex Sas Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres obtenus, et leurs applications.
DE10243666A1 (de) * 2002-09-20 2004-04-01 Bayer Ag Dithiocarbaminsäureester
FR2846973B1 (fr) 2002-11-07 2004-12-17 Rhodia Chimie Sa Composition d'antifroissage comprenant un copolymere a architecture controlee, pour articles en fibres textiles
FR2848556B1 (fr) 2002-12-13 2006-06-16 Bio Merieux Procede de polymerisation radicalaire controlee
ITMI20022703A1 (it) * 2002-12-20 2004-06-21 Enitecnologie Spa Procedimento per la polimerizzazione radicalica vivente di monomeri olefinicamente insaturi.
WO2004078793A1 (fr) * 2003-01-28 2004-09-16 Rhodia Chimie Procede de synthese de copolymeres ramifies par polymerisation radicalaire controlee
FR2872039B1 (fr) * 2004-06-23 2006-08-04 Rhodia Chimie Sa Composition cosmetique comprenant un polyorganosiloxane et ses utilisations
FR2872038A1 (fr) * 2004-06-23 2005-12-30 Rhodia Chimie Sa Composition cosmetique comprenant un polyorganosiloxane et ses utilisations
KR101322668B1 (ko) 2005-01-11 2013-10-30 시바 홀딩 인크 제어된 자유 라디칼 중합반응에 의해 제조된 단독중합체 및공중합체의 후개질방법
FR2883291B1 (fr) * 2005-03-17 2010-03-05 Rhodia Chimie Sa Copolymere a blocs pouvant etre utile comme tenseur
WO2007061954A2 (en) * 2005-11-18 2007-05-31 University Of Pittsburgh Biocidal surfaces, articles with biocidal surface agents and methods of synthesizing and evaluating biocidal surface agents
FR2923487B1 (fr) * 2007-11-09 2009-12-04 Rhodia Operations Copolymere ampholyte a architecture controlee
FI122734B (fi) 2007-05-21 2012-06-15 Kemira Oyj Prosessikemikaali käytettäväksi paperin tai kartongin valmistuksessa
JP2009001776A (ja) * 2007-06-11 2009-01-08 Rohm & Haas Co 水性エマルジョンポリマー会合性増粘剤
FR2917415B1 (fr) * 2007-06-14 2012-10-12 Rhodia Recherches Et Tech Microgel polymerique comprenant des unites cationiques
FR2921663A1 (fr) 2007-10-02 2009-04-03 Bluestar Silicones France Soc Polyorganosiloxanes a fonction piperidine depourvus de toxicite par contact cutane et utilisation de ces derniers dans des compositions cosmetiques
FR2934154B1 (fr) * 2008-07-23 2010-08-13 Rhodia Operations Emulsions thermosensibles
CA2732873A1 (en) * 2008-08-05 2010-02-11 Polymers Crc Limited Functionalized thin film polyamide membranes
EP2160946A1 (de) 2008-09-09 2010-03-10 Polymers CRC Limited Verfahren zur Herstellung eines antimikrobiellen Artikels
EP2160945A1 (de) 2008-09-09 2010-03-10 Polymers CRC Limited Antimikrobieller Artikel
KR20110118686A (ko) 2009-01-23 2011-10-31 커먼웰쓰 사이언티픽 앤드 인더스트리얼 리서치 오가니제이션 Ｒａｆｔ 중합
FR2941704B1 (fr) 2009-01-30 2011-12-23 Arkema France Copolymeres a blocs porteurs de groupes associatifs et adhesif les comprenant
FR2965264B1 (fr) 2010-09-27 2013-11-29 Rhodia Operations Polymerisation radicalaire controlee de n-vinyl lactames en milieu aqueux
FR2965564B1 (fr) 2010-09-30 2012-10-26 Rhodia Operations Preparation de polymeres hydrophiles de haute masse par polymerisation radicalaire controlee
EP2551338A1 (de) 2011-07-27 2013-01-30 Henkel AG & Co. KGaA Waschmittel mit Fleckenentfernungseigenschaften
RU2632886C2 (ru) 2011-10-24 2017-10-11 Родиа Операсьон Получение амфифильных блок-сополимеров путем контролируемой радикальной мицеллярной полимеризации
EP2809697B1 (de) 2012-01-31 2017-07-19 Rhodia Operations Lebende poly-(n-vinyl lactam-)reaktive stabilisatoren für eine polymerisierung dispergierter phasen
CN104144956B (zh) 2012-01-31 2017-04-12 罗地亚运作公司 活性反应性稳定剂存在下卤化的乙烯基单体的分散相聚合反应
FR2987837B1 (fr) 2012-03-09 2014-03-14 Rhodia Operations Polymerisation radicalaire controlee en dispersion eau-dans-l'eau
FR3004458A1 (fr) 2013-04-11 2014-10-17 Rhodia Operations Fluides de fracturation a base de polymeres associatifs et de tensioactifs labiles
FR3011555A1 (fr) 2013-10-04 2015-04-10 Rhodia Operations Polymeres sequences pour le controle du filtrat
EP2896637A1 (de) 2014-01-21 2015-07-22 Rhodia Operations Copolymer mit Einheiten des Typs A, abgeleitet von Carbonsäuremonomeren und Einheiten von Typ B, abgeleitet von Sulfonsäuremonomeren
WO2015173193A1 (en) 2014-05-12 2015-11-19 Solvay Specialty Polymers Italy S.P.A. Method for the controlled polymerization of fluoromonomers
FR3027309B1 (fr) 2014-10-17 2018-08-10 Rhodia Operations Polymeres polyfonctionnels a base d'unites phosphonates et d'unites amines
FR3034776A1 (fr) 2015-04-07 2016-10-14 Rhodia Operations Polymeres sequences pour le controle du filtrat
FR3034777A1 (fr) 2015-04-07 2016-10-14 Rhodia Operations Polymeres sequences pour le controle du filtrat et de la rheologie
FR3034768B1 (fr) 2015-04-07 2017-05-05 Rhodia Operations Polymeres sequences pour le controle du filtrat
ES3007639T3 (en) 2015-05-04 2025-03-20 Specialty Operations France Use of copolymers comprising phosphorus groups for the protection of metals and for lubrication
FR3037074B1 (fr) 2015-06-03 2017-07-14 Rhodia Operations Agents de suspension obtenus par polymerisation micellaire
FR3043083B1 (fr) 2015-10-30 2019-04-19 Rhodia Operations Polymeres sequences amphiphiles solubles en milieu fortement salin
MX2019006158A (es) 2016-11-29 2019-09-09 Rhodia Operations Sistemas polimerícos para dispersión de partículas.
FR3064641A1 (fr) 2017-04-03 2018-10-05 Rhodia Operations Association pour le controle du filtrat et la migration de gaz
FR3070043B1 (fr) 2017-08-09 2019-08-16 Rhodia Operations Formulation contenant un polymere associatif
EP3682042B1 (de) 2017-09-14 2021-11-10 Chemetall GmbH Verfahren zur vorbehandlung von aluminiummaterialien, insbesondere von aluminiumrädern
CN111566184B (zh) 2017-12-19 2023-08-01 罗地亚经营管理公司 用于辅助开采石油的表面活性剂和缔合聚合物的水性配制品
MX2020006375A (es) 2017-12-20 2020-09-03 Rhodia Operations Sistemas polimericos para dispersion de particulas.
FR3079833B1 (fr) 2018-04-10 2020-10-09 Rhodia Operations Composition aqueuse gelifiee pour l'extraction petroliere
FR3083238A1 (fr) 2018-07-02 2020-01-03 Rhodia Operations Relargage progressif de chaines polymeres en milieu liquide
BR112020026261A2 (pt) 2018-07-05 2021-03-30 Chemetall Gmbh Método para tratar uma superfície metálica, kit de peças, uso do kit de peças, e, substrato
WO2020007925A1 (en) 2018-07-05 2020-01-09 Chemetall Gmbh Method for treating metallic surfaces with an acidic aqueous composition to improve corrosion resistance
JP7476173B2 (ja) 2018-09-07 2024-04-30 ケメタル ゲゼルシャフト ミット ベシュレンクテル ハフツング アルミニウム含有基材の表面を処理する方法
MX2021002643A (es) 2018-09-07 2021-05-12 Chemetall Gmbh Metodo para tratar superficies de sustratos que contienen aluminio.
MX2021004002A (es) 2018-10-08 2021-06-23 Rhodia Operations Metodo para la fosfatacion libre de ni de superficies metalicas y composicion para su uso en dicho metodo.
EP3864189A1 (de) 2018-10-08 2021-08-18 Chemetall GmbH Verfahren zur ni-freien phosphatierung von metalloberflächen und zusammensetzung zur verwendung in solch einem verfahren
FR3093514A1 (fr) 2019-03-05 2020-09-11 Rhodia Operations Suspension de polymères associatifs pour le traitement de formations souterraines
US11535739B2 (en) 2019-03-15 2022-12-27 Rhodia Operations Inc. Polymer compositions having fast hydration rate and use of the same for particle suspension
US12479968B2 (en) 2019-12-20 2025-11-25 Specialty Operations France Process for fragmenting a polymer
MX2023004398A (es) 2020-10-23 2023-07-11 Energy Solutions Us Llc Sistemas polimericos que tienen viscosidad mejorada y propiedades de transporte de apuntalantes.
FR3125296A1 (fr) 2021-07-13 2023-01-20 Rhodia Operations Préparation de polymères séquencés amphiphiles par polymérisation radicalaire micellaire inverse
EP4399248A1 (de) 2021-09-07 2024-07-17 Sika Technology AG Stabilisierung von pigmentierten zusammensetzungen auf (meth)acrylatbasis

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS516128B2 (de) * 1973-04-11 1976-02-25
JPS50111106A (de) * 1974-06-28 1975-09-01
FR2665450B1 (fr) * 1990-08-01 1994-04-08 Rhone Poulenc Chimie Procede de preparation de dispersions aqueuses de copolymeres.
FR2738573B1 (fr) * 1995-09-08 1997-10-17 Rhone Poulenc Chimie Utilisation en tant qu'agents thermoepaississants de copolymeres multiblocs
BR9710219A (pt) * 1996-07-10 1999-08-10 Du Pont Processo para a sintese de polímeros agente de transferéncia de cadeia e polímero
FR2764892B1 (fr) * 1997-06-23 2000-03-03 Rhodia Chimie Sa Procede de synthese de polymeres a blocs
FR2794463B1 (fr) 1999-06-04 2005-02-25 Rhodia Chimie Sa Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes
US6569969B2 (en) * 2000-09-28 2003-05-27 Symyx Technologies, Inc. Control agents for living-type free radical polymerization, methods of polymerizing and polymers with same

Also Published As

Publication number Publication date
AU2685401A (en) 2001-06-18
US20050054794A1 (en) 2005-03-10
FR2802208B1 (fr) 2003-02-14
ES2225294T3 (es) 2005-03-16
US6809164B2 (en) 2004-10-26
US7285610B2 (en) 2007-10-23
DE60012981T2 (de) 2005-08-11
FR2802208A1 (fr) 2001-06-15
ATE273326T1 (de) 2004-08-15
EP1242467B1 (de) 2004-08-11
EP1242467A1 (de) 2002-09-25
US20030045661A1 (en) 2003-03-06
WO2001042312A1 (fr) 2001-06-14

Similar Documents

Publication Publication Date Title
DE60012981D1 (de) Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit xanthaten
ATE293133T1 (de) Verfahren zur herstellung von polymeren durch eine kontrollierte radikalischpolymerisation mit halogenierten xanthaten
ATE444313T1 (de) Sprüpolymerisationsverfahren
DE60001829T2 (de) Verfahren zur herstellung von polypropylenharzen mit kontrollierter rheologie
DE60118007D1 (de) Verfahren zur herstellung von blockcopolymeren durch eine kontrollierte radikalpolymerisation in gegenwart von einer disulfidverbindung
ATE219881T1 (de) Verfahren zur herstellung antimikrobieller kunststoffe
DE60125186D1 (de) Verfahren zur herstellung von blockcopolymeren durch kontrollierte radikalische polymerisation
ATE158311T1 (de) Verfahren zur (co)polymerisation von fluorenthaltenden olefinischen monomeren in wässriger emulsion
DE69808622D1 (de) Verfahren zur herstellung von blockcopolymeren durch kontrollierte radikalische polymerisation
DE59704400D1 (de) Verfahren zur herstellung einer polymerdispersion durch radikalische wässrige emulsionspolymerisation mit einer kontinuierlich hergestellten wässrigen monomerenemulsion
ATE281475T1 (de) Polymere mit thermoverdickungs-eigenschaften und verfahren zu deren herstellung
ATE276292T1 (de) Herstellungsverfahren von siliciumorganischen hybridcopolymeren durch kontrollierte radikalische polymerisation
ATE122360T1 (de) Verfahren zur herstellung einer stryrolpolymerzusammensetzung.
ATE289703T1 (de) Verfahren zur herstellung von pi-konjugierten polymeren
DE69921194D1 (de) Verfahren zur herstellung von polymeren enthaltend endständige n-0 gruppen
DE60316947D1 (de) Verfahren zur polymerisation ethylenisch ungesättigter monomere
ATE376562T1 (de) Verfahren zur herstellung von blockcopolymeren
DE50112718D1 (de) Verfahren zur herstellung von übergangsmetallverbindungen und deren verwendung zur polymerisation von olefinen
ATE542835T1 (de) Polymerisationsverfahren zur herstellung von (co)polymeren
ATE122267T1 (de) Verfahren zur herstellung von vernetzten copolymerperlen mit poröser oberfläche.
DE502004003695D1 (de) Verfahren zur herstellung einer wässrigen polymerisatdispersion
ATE455798T1 (de) Verfahren zur herstellung von methacrylat- einheiten enthaltenden polymeren mit niedriger polydispersität
ATE19092T1 (de) Verfahren zur herstellung von styrenpfropfpolymeren.
ATE357463T1 (de) Verfahren zur herstellung eines katalysators für ethylenpolymerisierung und eines ethylenpolymers
DE69121321D1 (de) Polymerperoxid, Polymerisationsinitiator und Verfahren zur Herstellung von Blockcopolymeren

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee