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DE29903417U1 - Desodorierendes und stark keimreduzierendes Mittel für Bearbeitungsflüssigkeiten - Google Patents

Desodorierendes und stark keimreduzierendes Mittel für Bearbeitungsflüssigkeiten

Info

Publication number
DE29903417U1
DE29903417U1 DE29903417U DE29903417U DE29903417U1 DE 29903417 U1 DE29903417 U1 DE 29903417U1 DE 29903417 U DE29903417 U DE 29903417U DE 29903417 U DE29903417 U DE 29903417U DE 29903417 U1 DE29903417 U1 DE 29903417U1
Authority
DE
Germany
Prior art keywords
acid
agent according
agent
weight
sodium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE29903417U
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Arconia Chur GmbH
Original Assignee
Arconia Chur GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arconia Chur GmbH filed Critical Arconia Chur GmbH
Priority to DE29903417U priority Critical patent/DE29903417U1/de
Publication of DE29903417U1 publication Critical patent/DE29903417U1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
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    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
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    • C10M129/26—Carboxylic acids; Salts thereof
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    • C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
    • C10M129/40—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
    • C—CHEMISTRY; METALLURGY
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    • C10M129/48—Carboxylic acids; Salts thereof having carboxyl groups bound to a carbon atom of a six-membered aromatic ring
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    • C10M129/26—Carboxylic acids; Salts thereof
    • C10M129/48—Carboxylic acids; Salts thereof having carboxyl groups bound to a carbon atom of a six-membered aromatic ring
    • C10M129/54—Carboxylic acids; Salts thereof having carboxyl groups bound to a carbon atom of a six-membered aromatic ring containing hydroxy groups
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    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
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    • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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Description

RALF M.
J^1T-. ^College«
Heimo Wessollek 25.02.1999
Arconia GmbH
Desodorierendes und stark keimreduzierendes Mittel für Bearbeitungsflüssigkeiten
Die Erfindung liegt in einem desodorierenden und stark keimreduzierenden Mittel ohne Chlor für Bearbeitungsflüssigkeiten wie z.B. bohr- und schneidölhaltige Flüssigkeiten.
Derartige Flüssigkeiten sind übelriechend und äußerst stark verkeimt, so daß sie z.B. als Bearbeitungsflüssigkeiten äußerst ungünstige, auch gesundheitsschädliche, beispielsweise stark giftige und ätzende Eigenschaften aufweisen bzw. entwickeln und bei ihrer Ensorgung umweitschädlich und damit aufwendig zu entsorgen sind.
Überraschenderweise hat sich die Zugabe eines Mittels mit im wesentlichen folgenden Zusammensetzungskomponenten als kurzfristig intensiv desodorierend und keimreduzierend und damit als vorteilhafte Lösung bei der Behandlung mit einer Mittelkombination gemäß Schutzanspruch 1 erwiesen.
Besonders überraschend für die Wirksamkeit des Mittels ist, daß die zu behandelnden Bearbeitungsflüssigkeiten im hochkontaminierten Zustand pH-Werte von 6,0 bis z.T. 7 oder 9,2 bis 9,4 und noch darüber aufweisen und das Mittel selbst bei rein biologischer Zusammensetzung gemäß Schutzanspruch 1 mit z.T. alkalischen Komponenten eine
gründliche Entkeimung und vollständige Geruchseliminierung bewirkt.
Die mit dem Mittel insbesondere nach den Ansprüchen 1 und
2 erzielte synergistische Wirkung des Mittels wird durch
die Zumischung von sauerstoffabgebenden Stoffen gemäß Anspruch 3 verstärkt.
Die Erfindung erfasst die in den Ansprüchen 4 bis 7 enthaltenen speziellen Ausführungsformen, wobei die in Wasser gelöste Mischungskombination bei einem pH-Wert zwischen etwa 2 bis 7 liegt.
Zwecks wirkungsverstärkender Benetzung können der Mischung gemäß den Ansprüchen l bis 10
1,0 bis 5 % eines oder mehrerer Tenside ausgewählt aus der Gruppe bestehend aus in der verwendeten Menge untoxischen anionischen und nichtionischen Tensiden, Seifen, Fettsäure-Amxnocarbonsäurekondensate, Alkylbenzolsulfonate, Ligninsulfonate, Alkylsulfonate, Fettsäureestern, sulfatierten Fettsäureglyceriden, Betaine, Sulfobetaine, Saponine, Fettsäureester von Polyalkoholen, Oxyäthylierte Fettsäuren, etc., von denen Natriumdodecylsulfonat und Natriumlaurylsulfat besonders bevorzugt sind, beigefügt sein.
Das Lebensmittelkonservierungsmittel kann gemäß Anspruch 2 vorteilhafterweise ausgewählt sein aus der Gruppe bestehend aus Citronensäure, Natriumbenzoat, Weinsäure, Milchsäure, Apfelsäure, Essigsäure, Bernsteinsäure, Acetylsalicylsäure und L-Ascorbinsäure, Sorbinsäure, Benzoesäure, p-Hydroxybenzoesäure, Ameisensäure und
Propionsäure sowie deren Abkömmlingen, eingeschlossen Salze und Estern derselben.
Es kann sinnvoll sein, daß das Behandlungs-Mittel zusätzlich ein oder mehrere von Materialien ausgewählt aus der Gruppe bestehend aus lebensmittelrechtlich unbedenklichen Stabilisatoren, Trocknungsmittel, Säuerungsmittel, Korrosionsinhibitoren, Emulgatoren, Sprengmittel und/oder Tenside enthält.
Insbesondere zur Vermeidung einer Nachverkeimung hat es sich als vorteilhaft herausgestellt, wenn eine zu behandelnde Bearbeitungsflüssigkeit mindestens ein wasserlösliches Silbersalz aufweist, das eine Nachverkeimung verhindert bzw. die Wirkungsdauer erheblich verlängert. Der Gehalt an Silbersalzen beträgt vorteilhafterweise zwischen weniger als 0,2 bis 0,5 Gew.% des Mittels als Trockenmasse.
Um das Lösungsverhalten weiter günstig zu beeinflussen, kann es sinnvoll sein, MgCl2 einzusetzen, das durch Ionenaustausch mit anderen zweiwertigen Salzen die Lösung der Ablagerungen zweiwertiger Ionen fördert.
Dadurch, daß nun Citronensäure mit ihren günstigen Lösungseigenschaften gemeinsam mit Silberverbindungen, wie -salzen, die gegen ein Wachstum von Keimen eingesetzt werden, kann bei einer überraschend guten unabhängigen Entkeimungswirkung auch die Nachverkeimung herabgesetzt werden.
Die Wirkung des erfindungsgemäßen Mittels ist vor allem deshalb überraschend, weil es den vorstehend definierten, äußerst verunreinigten Flüssigkeiten nur in wenigen
Prozent oder auch nur in Bruchteilen von Prozenten der zu desodorierenden und zu entkeimenden Flüssigkeit zugesetzt zu werden braucht, obwohl es aus nachweislich völlig untoxischen, biologisch verträglichen und biologisch völlig abbaubaren Bestandteilen ohne jegliche Chlor- und Halogenbestandteile und auch ohne jegliche Antibiotika, Pestizide, Fungizide und Insektizide zusammengesetzt ist und in vergleichsweise kurzer Zeit und zeitlich lang anhaltend wirksam ist.
Bei der erfindungsgemäßen Behandlung der Bearbeitungsflüssigkeiten kann zudem eine Trennung in ihre Fest- und Flüssigbestandteile, d.h. unter Freisetzen der Flüssigbestandteile sowie auch unter Abtrennung ihrer eventuellen Ölbestandteile erfolgen, welche auch gereinigt und wiederverwertbar gemacht werden können.
Das Mittel ist sowohl völlig untoxisch als auch vollständig biologisch abbaubar und hautschonend. Es baut sogar aufgrund seiner fungiziden Wirkung Antibiotika ab und löst keinerlei Resistenzerscheinungen aus.
Die vorbeschriebene Verwendung des Mittels schließt auch einen entsprechenden Verfahrensschutz ein.
Das für das erfindungsgemäße Verfahren mit den genannten überraschenden Vorteilen - biologisch untoxisch (mit Trinkwasserklassifizierungs-Klasse 0) - und doch wirksam entkeimende Mittel macht grundsätzlich Gebrauch von der Anwendung einer synergistisch wirksamen Kombination eines oder mehrerer Lebensmittel-Konservierungsstoffe mit mindestens einer nicht-toxischen, insbesondere organischen Säure, wobei in vergleichsweise geringer
Konzentration in Wasser eine überraschend starke entkeimende bzw. keimreduzierende Wirkung eintritt.
Mit der erfindungsgemäßen Verwendung des Mittels nach den Ansprüchen 1 bis 12 wird die erfindungsgemäße, unerwartet wirksame Lösung der vorgenannten Aufgabe mit den eingangs genannten Vorteilen bzw. Wirkungen erreicht.
Das Mittel wirkt gegen Keime wie Bakterien (bakterizid), Pilze wie Schimmelpilze (fungizid), Pilzsporen und Blütenstaub, Hefen, Protozoen, Eukaryoten, Eiweißmoleküle, Enzyme, Makrophagen und auch molekularbiologische Schädlinge oder dergleichen, aber auch gegen Kleinlebewesen, Insekten, Milben, Parasiten durch Zerstörung deren Nachwuchs und Eier, sowie Biofouling und Epelithionbildung.
Konkret ist das erfindungsgemäße Mittel auch gegen sämtliche Arten von Aspergillus, Legionellen und Salmonellen, sowie
Escherichia coli,
Klebsielle pneumoniae,
Staphylococcus aureus,
Pseudomonas aeruginosa,
Streptococcus faecalis,
Proteus mirabilis,
Mycobacterium tuberculosis,
Clostridium sporogenes,
Candida albicans
mit bis zu völliger Entkeimung erprobt.

Claims (12)

1. Desodorierendes und keimreduzierendes Mittel zur Behandlung von stark kontaminierten und ölemulsionshaltigen Bearbeitungsflüssigkeiten und dergleichen aufwendig zu handhabende und zu entsorgende Stoffe mit einem oder mehreren Lebensmittel-Konservierungsstoffen sowie mindestens einer nicht-toxischen, insbesondere organischen Säure.
2. Mittel nach Anspruch 1, welches mindestens eine Kombination einer oder mehrerer Verbindungen aus der Gruppe der Verbindungen Citronensäure, Sorbinsäure, L-Ascorbinsäure und/oder Acetylsalicylsäure oder deren Derivate aufweist
mit mindestens einem Lebensmittelkonservierungsstoff wie beispielsweise Benzoesäure und deren Derivate wie
Sorbinsäure, Citronensäure, Weinsäure, Milchsäure, Apfelsäure, Essigsäure, Bernsteinsäure, Acetysalicyl- und L-Ascorbinsäure sowie
Natriumbenzoat, p-Hydroxybenzoesäure, Ameisensäure, Propionsäure und Abkömmlinge sowie Salze, Ester und/oder Mischungen derselben.
3. Mittel nach Anspruch 1, dadurch gekennzeichnet, daß es einen Anteil eines Oxidationsmittels wie eine Perverbindung aus z. B. einem Peroxid, wie Natrium-, Kalium-, Calcium- oder Wasserstoffperoxid oder einen Abkömmling einer Persäure wie Perborat, Perphosphat, Percarbonat oder eine stark oxidierende Verbindung wie ein Permanganat aufweist.
4. Mittel nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß die Kombination von 50 bis 80 Gew.-%, bevorzugt 55 bis 70 Gew.-%, insbesondere 60 bis 65 Gew.-% Citronensäure, 20 bis 50 Gew.-%, bevorzugt 30 bis 45 Gew.-%, insbesondere 35 bis 40 Gew.-% einer festen Peroxoverbindung, sowie 0,3 bis 1 Gew.-% eines Lebensmittelkonservierungsstoffes aufweist, wobei die Summe aller Prozentsätze jeweils 100 ist.
5. Mittel nach Anspruch 4, dadurch gekennzeichnet, daß die Citronensäure bis zu 1 bis 25 Gew.-% der Gesamtmenge durch L-Ascorbinsäure und/oder Acetylsalicylsäure ersetzt ist.
6. Mittel nach einem der Ansprüche 1 bis 5 in wässriger Lösung von 15-0,03 g Mittel, bevorzugt 10-0,1 g, insbesondere 8-0,1 g Mittel pro Liter Wasser.
7. Mittel nach einem der Ansprüche 1 bis 5, gekennzeichnet durch 0,05-10 g, bevorzugt 0,2-6 g und besonders bevorzugt 0,3-4 g Natriumbenzoat und 0,1-10 g, bevorzugt 0,2-5 g und besonders bevorzugt 0,3-3 g Sorbinsäure.
8. Mittel nach einem der Ansprüche 1 bis 6 mit zusätzlich 0,001-16, vorzugsweise 12, insbesondere 10 Vol.-% H2O2 pro Liter Wasser sowie gegebenenfalls Stabilisatoren für die Peroxidverbindung.
9. Mittel nach einem der vorhergehenden Ansprüche 1 bis 6, dadurch gekennzeichnet, daß die Lösung einen sauren PH-Wert zwischen etwa 2 und 7 aufweist.
10. Mittel, insbesondere nach einem der vorhergehenden Ansprüche, gekennzeichnet durch 0,1 bis 5% eines oder mehrerer Tenside ausgewählt aus der Gruppe bestehend aus in der verwendeten Menge untoxischen anionischen und nichtionischen Tensiden, Seifen, Fettsäure-Aminocarbonsäurekondensate, Alkylbenzolsulfonate, Ligninsulfonate, Alkylsulfonate, Fettsäureestern, sulfatierten Fettsäureglyceriden, Betaine, Sulfobetaine, Saponine, Fettsäureester von Polyalkoholen, Oxyäthylierte Fettsäuren, etc., und insbesondere Natriumdodecylsulfonat und Natriumlaurylsulfat.
11. Mittel nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß die organischen Säuren gesättigte oder ungesättigte Carbonsäuren mit 1-14 C- Atomen, bevorzugt 1-12 C-Atomen sind.
12. Mittel nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß ihm ein Korrosionsschutzmittel vorzugsweise in 0,1 bis 1 Gew.-% in der bei der Behandlung verwendeten Konzentration der Lösung zugesetzt ist.
DE29903417U 1999-02-25 1999-02-25 Desodorierendes und stark keimreduzierendes Mittel für Bearbeitungsflüssigkeiten Expired - Lifetime DE29903417U1 (de)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010078883A3 (de) * 2008-12-18 2010-12-29 Bode Chemie Gmbh Kombinierte desinfektions- und dekontaminationsmittel mit erhöhter wirksamkeit
DE202020105154U1 (de) 2020-09-07 2021-09-08 Steffen Berger Vollständig biologisch abbaubares Biozid

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010078883A3 (de) * 2008-12-18 2010-12-29 Bode Chemie Gmbh Kombinierte desinfektions- und dekontaminationsmittel mit erhöhter wirksamkeit
US8999399B2 (en) 2008-12-18 2015-04-07 Bose Chemie GmbH Combined disinfection and decontamination agent having increased effectiveness
DE202020105154U1 (de) 2020-09-07 2021-09-08 Steffen Berger Vollständig biologisch abbaubares Biozid

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