DE1297336B - Children's modeling clay - Google Patents
Children's modeling clayInfo
- Publication number
- DE1297336B DE1297336B DE1966H0058959 DEH0058959A DE1297336B DE 1297336 B DE1297336 B DE 1297336B DE 1966H0058959 DE1966H0058959 DE 1966H0058959 DE H0058959 A DEH0058959 A DE H0058959A DE 1297336 B DE1297336 B DE 1297336B
- Authority
- DE
- Germany
- Prior art keywords
- children
- dimethylpolysiloxane
- components
- crosslinking
- modeling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004927 clay Substances 0.000 title description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 8
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 8
- 239000003054 catalyst Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 7
- 238000004132 cross linking Methods 0.000 claims description 5
- 239000003431 cross linking reagent Substances 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 3
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 3
- 230000037213 diet Effects 0.000 claims 1
- 235000005911 diet Nutrition 0.000 claims 1
- 239000004033 plastic Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001734 carboxylic acid salts Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- -1 polysiloxanes Polymers 0.000 description 1
- 238000004382 potting Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Dental Preparations (AREA)
Description
Die Erfindung bezieht sich auf die Verwendung einer Dimethylpolysiloxane enthaltenden Zweikomponentenmasse als Kindermodelliermasse. The invention relates to the use of a dimethylpolysiloxane containing two-component material as a children's modeling material.
Plastische, knetbare Modelliermassen (Einkomponentenmodelliermassen) sind bekannt. Die Konsistenz derartiger Massen ist plastisch, kittartig und wird in verschiedenen Farben, vorzugsweise in Stangenform hergestellt und geliefert. Mit solchen Massen können Figuren und sonstige Formkörper durch einfaches Verformen hergestellt werden. Da die Masse dabei immer weich und plastisch bleibt, wird sie bei leichtestem Druck deformiert, d. h., die gefertigten Figuren oder Modelle werden zerstört. Plastic, kneadable modeling compounds (one-component modeling compounds) are known. The consistency of such masses is plastic, putty-like and will in different colors, preferably made and delivered in stick form. With such masses, figures and other shaped bodies can be simply deformed getting produced. Since the mass always remains soft and plastic, it becomes deformed at the slightest pressure, d. that is, the figures or models produced will be destroyed.
Ferner sind kalthärtbare Organopolysiloxanformmassen mit einem Gehalt an verschieden aufgebauten Polysiloxanen sowie an Füllmitteln und Katalysatoren bekannt. Hierbei handelt es sich nicht um Zweikomponentenmassen, und derartige Massen sind nicht zur Verwendung als Kindermodelliermassen geeignet. Furthermore, cold-curable organopolysiloxane molding compounds with a content of differently structured polysiloxanes as well as fillers and catalysts known. These are not two-component masses, and such masses are not suitable for use as children's modeling compounds.
Außerdem ist ein Verfahren zur Herstellung von Siloxanelastomeren bekannt, bei dem ein Gemisch aus einem Organopolysiloxan und einem Polykieselsäurealkylester in Gegenwart eines Carbonsäuresalzes eines Metalls der elektromotorischen Spannungsreihe von Blei bis Mangan umgesetzt wird. Die auf diese Weise gewonnenen Reaktionsprodukte sind zur Verwendung als Überzugs- oder Vergußmassen oder z. B. zur elektrischen Isolation vorgesehen, kommen aber als Kindermodelliermasse ebenfalls nicht in Frage. Also is a process for making siloxane elastomers known in which a mixture of an organopolysiloxane and a polysilicic acid alkyl ester in the presence of a carboxylic acid salt of a metal of the electromotive series from lead to manganese. The reaction products obtained in this way are for use as coating or potting compounds or z. B. to electrical Isolation provided, but are also out of the question as a children's modeling clay.
Aufgabe derErfining ist, die Verwendung solcher Massen als Kindermodelliermassen vorzusehen, die sich zwar gut verformen lassen, aber während -und insbesondere nach der Verarbeitung formbeständig bleiben. The task of Erfining is to use such materials as children's modeling materials to be provided that can be deformed well, but during and especially after remain dimensionally stable during processing.
Die erfindungsgemäße Lösung dieser Aufgabe besteht darin, daß man eine Dimethylpolysiloxane enthaltende Zweikomponentenmasse mit einem Gehalt an einer ersten Komponente aus Dimethylpolysiloxan, Füllstoff und Vernetzungskatalysatoren und einer damit zusammenzukneteiiea- - ZWiten Kompo;-nente aus Dimethylpolysiloxan, Füllstoff und Vernetzungsmittel zur Verwendung als Kindermodelliermasse vorsieht Namëntlich k40nnen lii aer verwendeten Masse -der -Vernetzungskatalysator DibutylzinndilaUrat und das Vernetzungsmittel H-Polysiloxane sein. The inventive solution to this problem is that one a two-component composition containing dimethylpolysiloxanes and containing one first component made of dimethylpolysiloxane, filler and crosslinking catalysts and a second component made of dimethylpolysiloxane to be kneaded together with it, Provides filler and crosslinking agent for use as children's modeling clay Namely, the compound used can contain the crosslinking catalyst dibutyltin dilaurate and the crosslinking agent can be H-polysiloxanes.
Zweckmäßigerweise sind die beiden Komponenten in der verwendeten Masse zur Keninlichmachüng verschiedenartig gefärbt. The two components are expediently used in the Mass to make it recognizable in various colors.
Weitere Einzelheiten der Erfindung sind nachstehend noch näher erläutert. Further details of the invention are explained in more detail below.
Die beiden Massen, die im folgenden kurz mit A bzw. B bezeichnet sind, können beispielsweise wie folgt zusammengesetzt sein: A: Dimethylpolysiloxan ohne Lösungsmittel und Stabilsatoren, Füllstoffe, z. B. Quarzmehl, Kieselgur, Bentonit, Diatomeen-Erde, Calciumcarbonat und Vernetzungskatalysator, z. B. Metallsalzkatalysatoren (Zinnorganische Salze), Dibutylzinndilaurat. The two masses, referred to below as A and B for short can be composed, for example, as follows: A: dimethylpolysiloxane without solvents and stabilizers, fillers, e.g. B. quartz powder, kieselguhr, bentonite, Diatomaceous earth, calcium carbonate and crosslinking catalyst, e.g. B. metal salt catalysts (Organotin salts), dibutyltin dilaurate.
B: Dimethylpolysiloxan ohne Lösungsmittel und Stabilisatoren, Füllstoffe, z. B. Quarzmehl, Kieselgur, Bentonit, Diatomeen-Erde, Aluminiumsilikat und Vernetzungsmittel, z. B. H-Siloxane. B: Dimethylpolysiloxane without solvents and stabilizers, fillers, z. B. quartz powder, kieselguhr, bentonite, diatomaceous earth, aluminum silicate and crosslinking agents, z. B. H-siloxanes.
Die beiden Komponenten A und B werden in knetfähige bzw. mischfähige Konsistenz gebracht. Sie können in Stangen, getrennten Näpfen, Platten oder sonstigen Verpackungsformen auf den Markt gebracht werden. Durch verschiedenartige Einfärbung der Komponenten, z. B. rot und weiß, wird leicht erkennbar gemacht, wann die Massen richtig, d. h. innig miteinander vermischt sind, da dann eine einheitliche gemischte Farbmasse entsteht. Außerdem dient diese Einfärbung zur Kenntlichmachung der Komponenten A und B. The two components A and B are kneadable or mixable Brought consistency. They can be in rods, separate bowls, plates or otherwise Packaging forms are brought onto the market. By different coloring the components, e.g. B. red and white, it is easy to see when the crowds correct, d. H. are intimately mixed with one another, since then a uniform mixed Color mass is created. This coloring also serves to identify the components A and B.
Durch einfaches Zusammenkneten von jeweils gleichen Volumen- oder Gewichtsmengen der beiden Komponenten erhärten diese nach einiger Zeit, z. B. nach etwa 10 Minuten, zu einem gummielastischen Körper, verlieren also ihre weichplastischen Eigenschaften und bleiben dauernd gummielastisch, so daß sie durch Druck, Stoß- oder Schlag nicht mehr zerstört oder verformt werden können. Das Material bleibt vor, während und nach der Verarbeitung absolut volumenbeständig. Vor allem Kindern bietet diese Modelliermasse eine phantasieanregende, schulende Beschäftigung, bei der-Figuren und andere Formkörper hergestellt werden können, die formbeständig bleiben. By simply kneading together the same volume or Amounts by weight of the two components harden them after some time, e.g. B. after about 10 minutes, to a rubber elastic body, so lose their soft plastic Properties and remain permanently rubber-elastic, so that they or impact can no longer be destroyed or deformed. The material remains Absolutely volume-stable before, during and after processing. Especially children this modeling clay offers an imaginative, educational activity der-figures and other shaped bodies can be produced that retain their shape.
Bevor man die beiden Komponenten miteinander mischt und zusammenknetet, was z. B. mit der Hand erfolgen kann, werden zwei gleiche Mengen von jeder Komponente bereitgestelIt. Dies erfolgt entweder durch Abwägen oder durch Verwendung gleicher Volumenanteile, die mittels Dosierschalen oder durch Abschätzen bestimmt werden. Die noch plastische Knetmasse wird dann verformt;-was vorzugsweise von Hand erfolgt. Es ist selbstverständlich auch möglich, die Formkörper mittels Metall--oder Kunststofformen herzustellen. Before you mix and knead the two components together, what z. B. Can be done by hand, two equal amounts of each component provided. This is done either by weighing or by using the same Volume fractions that are determined by means of dosing bowls or by estimating. The plasticine, which is still plastic, is then deformed, which is preferably done by hand. It is of course also possible to mold the moldings using metal or plastic molds to manufacture.
Claims (4)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH1318465A CH467301A (en) | 1965-09-23 | 1965-09-23 | Rubber-elastic hardening children's modeling clay |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE1297336B true DE1297336B (en) | 1969-06-12 |
Family
ID=4390100
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE1966H0058959 Pending DE1297336B (en) | 1965-09-23 | 1966-03-30 | Children's modeling clay |
Country Status (2)
| Country | Link |
|---|---|
| CH (1) | CH467301A (en) |
| DE (1) | DE1297336B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1019462B (en) * | 1954-02-18 | 1957-11-14 | Dow Corning | Process for the production of siloxane elastomers |
| GB921046A (en) * | 1958-09-10 | 1963-03-13 | Wacker Chemie Gmbh | Organosiloxane resin compositions |
-
1965
- 1965-09-23 CH CH1318465A patent/CH467301A/en unknown
-
1966
- 1966-03-30 DE DE1966H0058959 patent/DE1297336B/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1019462B (en) * | 1954-02-18 | 1957-11-14 | Dow Corning | Process for the production of siloxane elastomers |
| GB921046A (en) * | 1958-09-10 | 1963-03-13 | Wacker Chemie Gmbh | Organosiloxane resin compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| CH467301A (en) | 1969-01-15 |
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