DE10103625A1 - Reductant-free aqueous hair-dyeing composition based on oxidation dye precursor system, contains an aminopyrimidine developer and a resorcinol, naphthol, aminophenol or aminobenzene coupler - Google Patents
Reductant-free aqueous hair-dyeing composition based on oxidation dye precursor system, contains an aminopyrimidine developer and a resorcinol, naphthol, aminophenol or aminobenzene couplerInfo
- Publication number
- DE10103625A1 DE10103625A1 DE10103625A DE10103625A DE10103625A1 DE 10103625 A1 DE10103625 A1 DE 10103625A1 DE 10103625 A DE10103625 A DE 10103625A DE 10103625 A DE10103625 A DE 10103625A DE 10103625 A1 DE10103625 A1 DE 10103625A1
- Authority
- DE
- Germany
- Prior art keywords
- hair
- coupler
- resorcinol
- reductant
- amino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 27
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 13
- 230000003647 oxidation Effects 0.000 title claims abstract description 12
- 239000002243 precursor Substances 0.000 title claims abstract description 12
- 238000004043 dyeing Methods 0.000 title claims abstract description 7
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 title abstract description 8
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 title abstract description 6
- CDAWCLOXVUBKRW-UHFFFAOYSA-N 2-aminophenol Chemical compound NC1=CC=CC=C1O CDAWCLOXVUBKRW-UHFFFAOYSA-N 0.000 title abstract description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 title abstract 4
- 150000005005 aminopyrimidines Chemical class 0.000 title 1
- 150000003839 salts Chemical class 0.000 claims abstract description 12
- 150000002978 peroxides Chemical class 0.000 claims abstract description 9
- PZRKPUQWIFJRKZ-UHFFFAOYSA-N pyrimidine-2,4,5,6-tetramine Chemical compound NC1=NC(N)=C(N)C(N)=N1 PZRKPUQWIFJRKZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 claims abstract description 4
- OQWWMUWGSBRNMA-UHFFFAOYSA-N 1-(2,4-diaminophenoxy)ethanol Chemical compound CC(O)OC1=CC=C(N)C=C1N OQWWMUWGSBRNMA-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229940113489 2,4-diaminophenoxyethanol Drugs 0.000 claims abstract description 4
- SBUMIGFDXJIPLE-UHFFFAOYSA-N 2-(3-amino-4-methoxyanilino)ethanol Chemical compound COC1=CC=C(NCCO)C=C1N SBUMIGFDXJIPLE-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000000126 substance Substances 0.000 claims description 12
- 239000000975 dye Substances 0.000 claims description 10
- 239000000118 hair dye Substances 0.000 claims description 10
- 239000003638 chemical reducing agent Substances 0.000 claims description 6
- SYEYEGBZVSWYPK-UHFFFAOYSA-N 2,5,6-triamino-4-hydroxypyrimidine Chemical compound NC1=NC(N)=C(N)C(O)=N1 SYEYEGBZVSWYPK-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 3
- CWLKGDAVCFYWJK-UHFFFAOYSA-N 3-aminophenol Chemical compound NC1=CC=CC(O)=C1 CWLKGDAVCFYWJK-UHFFFAOYSA-N 0.000 abstract description 2
- 229940018563 3-aminophenol Drugs 0.000 abstract description 2
- JQVAPEJNIZULEK-UHFFFAOYSA-N 4-chlorobenzene-1,3-diol Chemical compound OC1=CC=C(Cl)C(O)=C1 JQVAPEJNIZULEK-UHFFFAOYSA-N 0.000 abstract description 2
- 125000002091 cationic group Chemical group 0.000 abstract 2
- VBEGHXKAFSLLGE-UHFFFAOYSA-N n-phenylnitramide Chemical compound [O-][N+](=O)NC1=CC=CC=C1 VBEGHXKAFSLLGE-UHFFFAOYSA-N 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 5
- 239000007800 oxidant agent Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 2
- DBFYESDCPWWCHN-UHFFFAOYSA-N 5-amino-2-methylphenol Chemical compound CC1=CC=C(N)C=C1O DBFYESDCPWWCHN-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000002537 cosmetic Substances 0.000 description 2
- 239000012458 free base Substances 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 235000013772 propylene glycol Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- XUNNOCZTJBRTEX-UHFFFAOYSA-N 2-(diethylaminomethyl)aniline Chemical compound CCN(CC)CC1=CC=CC=C1N XUNNOCZTJBRTEX-UHFFFAOYSA-N 0.000 description 1
- VLZVIIYRNMWPSN-UHFFFAOYSA-N 2-Amino-4-nitrophenol Chemical compound NC1=CC([N+]([O-])=O)=CC=C1O VLZVIIYRNMWPSN-UHFFFAOYSA-N 0.000 description 1
- SWFNPENEBHAHEB-UHFFFAOYSA-N 2-amino-4-chlorophenol Chemical compound NC1=CC(Cl)=CC=C1O SWFNPENEBHAHEB-UHFFFAOYSA-N 0.000 description 1
- BMTSZVZQNMNPCT-UHFFFAOYSA-N 2-aminopyridin-3-ol Chemical compound NC1=NC=CC=C1O BMTSZVZQNMNPCT-UHFFFAOYSA-N 0.000 description 1
- ZTMADXFOCUXMJE-UHFFFAOYSA-N 2-methylbenzene-1,3-diol Chemical compound CC1=C(O)C=CC=C1O ZTMADXFOCUXMJE-UHFFFAOYSA-N 0.000 description 1
- OBOSXEWFRARQPU-UHFFFAOYSA-N 2-n,2-n-dimethylpyridine-2,5-diamine Chemical compound CN(C)C1=CC=C(N)C=N1 OBOSXEWFRARQPU-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QGNGOGOOPUYKMC-UHFFFAOYSA-N 4-hydroxy-6-methylaniline Chemical compound CC1=CC(O)=CC=C1N QGNGOGOOPUYKMC-UHFFFAOYSA-N 0.000 description 1
- YGRFRBUGAPOJDU-UHFFFAOYSA-N 5-(2-hydroxyethylamino)-2-methylphenol Chemical compound CC1=CC=C(NCCO)C=C1O YGRFRBUGAPOJDU-UHFFFAOYSA-N 0.000 description 1
- BLQFHJKRTDIZLX-UHFFFAOYSA-N 5-amino-2-methoxyphenol Chemical compound COC1=CC=C(N)C=C1O BLQFHJKRTDIZLX-UHFFFAOYSA-N 0.000 description 1
- TWLMSPNQBKSXOP-UHFFFAOYSA-N 6358-09-4 Chemical compound NC1=CC([N+]([O-])=O)=CC(Cl)=C1O TWLMSPNQBKSXOP-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- SNPLKNRPJHDVJA-ZETCQYMHSA-N D-panthenol Chemical compound OCC(C)(C)[C@@H](O)C(=O)NCCCO SNPLKNRPJHDVJA-ZETCQYMHSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 150000003840 hydrochlorides Chemical class 0.000 description 1
- KDNFLUWYIMPBSA-UHFFFAOYSA-N hydrogen peroxide;1,3,5-triazine-2,4,6-triamine Chemical compound OO.NC1=NC(N)=NC(N)=N1 KDNFLUWYIMPBSA-UHFFFAOYSA-N 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- FZZQNEVOYIYFPF-UHFFFAOYSA-N naphthalene-1,6-diol Chemical compound OC1=CC=CC2=CC(O)=CC=C21 FZZQNEVOYIYFPF-UHFFFAOYSA-N 0.000 description 1
- ZUVBIBLYOCVYJU-UHFFFAOYSA-N naphthalene-1,7-diol Chemical compound C1=CC=C(O)C2=CC(O)=CC=C21 ZUVBIBLYOCVYJU-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000001005 nitro dye Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229940101267 panthenol Drugs 0.000 description 1
- 235000020957 pantothenol Nutrition 0.000 description 1
- 239000011619 pantothenol Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- QXYMVUZOGFVPGH-UHFFFAOYSA-N picramic acid Chemical compound NC1=CC([N+]([O-])=O)=CC([N+]([O-])=O)=C1O QXYMVUZOGFVPGH-UHFFFAOYSA-N 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- MIROPXUFDXCYLG-UHFFFAOYSA-N pyridine-2,5-diamine Chemical compound NC1=CC=C(N)N=C1 MIROPXUFDXCYLG-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/347—Phenols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/411—Aromatic amines, i.e. where the amino group is directly linked to the aromatic nucleus
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/415—Aminophenols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
- A61K8/4953—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom containing pyrimidine ring derivatives, e.g. minoxidil
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
Description
Die Erfindung betrifft ein Haarfärbemittel auf Basis von Oxidationsfarbstoff- Vorprodukten, das nach dem Vermischen mit einer Peroxid-Zusammensetzung auf das menschliche Haar aufgebracht wird, und ein Verfahren zur Haarfärbung unter Verwendung dieses Mittels.The invention relates to a hair dye based on oxidation dye Precursors that after mixing with a peroxide composition human hair is applied, and a process for coloring hair Use of this agent.
Der die Oxidationsfarbstoffvorprodukte enthaltenden Zusammensetzung wird grund sätzlich ein Reduktionsmittel, vorzugsweise Ascorbinsäure oder ein Alkalisulfit, zuge setzt, um diese Vorprodukte gegen eine unerwünschte vorzeitige Oxidation zu stabi lisieren (vgl. hierzu beispielsweise die Monographie von K. Schrader, Grundlagen und Rezepturen der Kosmetika, 2. Aufl. (1989), S. 786).The composition containing the oxidation dye precursors becomes basic additionally a reducing agent, preferably ascorbic acid or an alkali sulfite, added sets to stabilize these precursors against unwanted premature oxidation (see, for example, the monograph by K. Schrader, Fundamentals and formulations of cosmetics, 2nd ed. (1989), p. 786).
Diese seit Jahrzehnten geübte Praxis weist jedoch den Nachteil auf, daß mit weite ren Rezepturbestandteilen Unverträglichkeiten auftreten können. Darüberhinaus ist bei der Applikation der anwendungsfertigen Färbemischung, d. h. bei der Mischung der Oxidationsfarbstoffvorprodukt-Zusammensetzung, die in der Regel eine wäßrige Lösung, Emulsion, Dispersion oder Gel darstellt, mit der Peroxid-Zusammensetzung ein erheblicher Peroxid-Überschuß erforderlich, um die antioxidierende Wirkung die ser Reduktionsmittel aufzuheben. Gleichwohl kann die Färbereaktion verzögert sein, was sich auf die Qualität der erhaltenden Färbung, insbesondere deren Intensität, auswirken kann.However, this practice, which has been practiced for decades, has the disadvantage that with far incompatibilities may occur. Beyond that when applying the ready-to-use dye mixture, d. H. when mixing the oxidation dye precursor composition, which is usually an aqueous Represents solution, emulsion, dispersion or gel with the peroxide composition a significant excess of peroxide is required to achieve the antioxidant effects cancel this reducing agent. Nevertheless, the coloring reaction can be delayed, which affects the quality of the dyeing obtained, especially its intensity, can impact.
Außerdem dauert der Färbevorgang verhältnismäßig lange.In addition, the dyeing process takes a relatively long time.
Es wurde nunmehr überraschenderweise gefunden, daß sich dieses Problem da durch lösen läßt und auf die Anwesenheit eines Reduktionsmittels verzichtet werden kann, wenn man als Oxidationsfarbstoffvorprodukte eine Kombination aus minde stens einem Tetraaminopyrimidin, insbesondere 2,4,5,6-Tetraaminopyrimidin, und/oder einem Hydroxytriaminopyrimidin, insbesondere 4-Hydroxy-2,5,6- triaminopyrimidin bzw. deren Salzen, und mindestens einer Kupplersubstanz, aus gewählt aus 1,3-Diaminobenzol, 2-Amino-4-hydroxyethylaminoanisol und/oder 2,4-Diaminophenoxyethanol bzw. deren Salzen, einsetzt. It has now surprisingly been found that this problem is there can be solved and the presence of a reducing agent can be dispensed with can, if a combination of minde as oxidation dye precursors at least one tetraaminopyrimidine, in particular 2,4,5,6-tetraaminopyrimidine, and / or a hydroxytriaminopyrimidine, in particular 4-hydroxy-2,5,6- triaminopyrimidine or its salts, and at least one coupler substance selected from 1,3-diaminobenzene, 2-amino-4-hydroxyethylaminoanisole and / or 2,4-diaminophenoxyethanol or its salts.
Bei Anwendung dieser Gemische mit Peroxiden, insbesondere Wasserstoffperoxid, werden nach kurzer Einwirkungszeit ausdrucksvolle, intensive Färbungen erhalten, die durch Zusatz weiterer Entwickler- und Kupplersubstanzen zu den verschieden sten Nuancen variierbar sind.When using these mixtures with peroxides, in particular hydrogen peroxide, expressive, intensive colorations are obtained after a short exposure time, which by adding further developer and coupler substances to the different most nuances are variable.
Die eingesetzten Tetraaminopyrimidine sind ebenso wie die Hydroxytriaminopyrimi dine als Entwicklersubstanzen in Haarfärbemitteln an sich bekannt, letztere z. B. aus der EP-B 467 026, und bedürfen keiner näheren Erläuterung.The tetraaminopyrimidines used are just like the hydroxytriaminopyrimi dine known as developer substances in hair dyes, the latter z. B. from EP-B 467 026, and require no further explanation.
Sie können als freie Basen oder, sofern aus Löslichkeitsgründen erforderlich, auch als wasserlösliche Salze, insbesondere als Hydrochloride oder Sulfate, eingesetzt werden.They can also be used as free bases or, if required for reasons of solubility used as water-soluble salts, in particular as hydrochlorides or sulfates will.
Die erfindungsgemäßen Haarfärbemittel können, neben den obengenannten essen tiellen Bestandteilen, weitere Oxidationsfarbstoffvorprodukte enthalten.The hair dyes according to the invention can eat in addition to the above tial components, contain further oxidation dye precursors.
Beispiele hierfür sind 2-Amino-3-hydroxypyridin, 2,5-Diaminopyridin, 3-Amino-2-me thylamino-6-methoxypyridin, 2-(Dimethylamino)-5-aminopyridin, 2-Amino-N,N-diethyl aminotoluol, Resorcin, 2-Methylresorcin, 4-Chlorresorcin, 2-Amino-4-chlorphenol, 1,6-Dihydroxynaphthalin, 1,7-Dihydroxynaphthalin, 2-Aminophenol, 3-Aminophenol, 1-Methyl-2-hydroxy-4-aminobenzol, 5-Amino-2-methoxyphenol, 2-Methyl-5-hydroxy ethylaminophenol, 4-Amino-3-methylphenol, 5-Amino-2-methylphenol und/oder 1-Naphthol bzw. deren wasserlösliche Salze.Examples include 2-amino-3-hydroxypyridine, 2,5-diaminopyridine, 3-amino-2-me thylamino-6-methoxypyridine, 2- (dimethylamino) -5-aminopyridine, 2-amino-N, N-diethyl aminotoluene, resorcinol, 2-methylresorcinol, 4-chlororesorcinol, 2-amino-4-chlorophenol, 1,6-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, 2-aminophenol, 3-aminophenol, 1-methyl-2-hydroxy-4-aminobenzene, 5-amino-2-methoxyphenol, 2-methyl-5-hydroxy ethylaminophenol, 4-amino-3-methylphenol, 5-amino-2-methylphenol and / or 1-naphthol or its water-soluble salts.
Damit soll jedoch der Zusatz weiterer Entwickler- und Kupplersubstanzen keines wegs ausgeschlossen sein.However, the addition of further developer and coupler substances is not intended to mean this be excluded.
Bei Anwendung dieser Zusammensetzungen auf Basis einer üblichen Grundlage werden, wie bereits erwähnt, nach der Oxidation mit Peroxid auch schon nach relativ kurzer Einwirkungszeit sehr ausdrucksvolle, intensive, dauerhafte Haarfärbungen vor allem im Rotbereich erhalten, die durch Zusatz entsprechender weiterer Kupplersub stanzen noch zu anderen Farbnuancen variiert werden können. Using these compositions on a common basis , as already mentioned, after oxidation with peroxide also after relative short exposure time very expressive, intensive, permanent hair coloring all in the red area obtained by adding appropriate further coupler sub punching can be varied to other color shades.
Die Gesamtkonzentration der Entwicklersubstanzen liegt üblicherweise zwischen etwa 0,05 und 5%, vorzugsweise 0,1 und 4%, insbesondere 0,25 bis 0,5% und 2,5 bis 3 Gew.-% der Gesamtzusammensetzung des Haarfärbemittels (ohne Oxidati onsmittel), wobei sich die Angaben jeweils auf den Anteil an freier Base beziehen. Das bevorzugte Gewichtsverhältnis von Entwickler- zu Kupplersubstanzen liegt dabei zwischen etwa 1 : 8 bis 8 : 1, vorzugsweise etwa 1 : 5 bis 5 : 1, insbesondere 1 : 2 bis 2 : 1.The total concentration of developer substances is usually between about 0.05 and 5%, preferably 0.1 and 4%, in particular 0.25 to 0.5% and 2.5 up to 3% by weight of the total composition of the hair dye (without oxidati onsmittel), where the information relates to the proportion of free base. The preferred weight ratio of developer to coupler substances is between about 1: 8 to 8: 1, preferably about 1: 5 to 5: 1, in particular 1: 2 up to 2: 1.
Die Kupplersubstanz(en) als Reaktionspartner der Entwicklersubstanz(en) liegen in den erfindungsgemäßen Haarfärbemitteln etwa im gleichen molaren Anteil wie die Entwicklersubstanzen vor, d. h., also in Mengen von 0,05 bis 5,0%, vorzugsweise 0,1 bis 4%, insbesondere 0,5 bis 3 Gew.-% der Gesamtzusammensetzung (ohne Oxidationsmittel), wobei sich die Angaben jeweils auf den Anteil an freier Base be ziehen.The coupler substance (s) as reaction partner of the developer substance (s) are in the hair dye according to the invention in about the same molar proportion as that Developer substances before, d. that is, in amounts of 0.05 to 5.0%, preferably 0.1 to 4%, in particular 0.5 to 3% by weight of the total composition (without Oxidizing agent), the information being based on the proportion of free base pull.
Die erfindungsgemäßen Zusammensetzungen können erwünschtenfalls auch soge nannte Nuanceure zur Feineinstellung des gewünschten Farbtones, insbesondere auch direktziehende Farbstoffe, enthalten.If desired, the compositions according to the invention can also be so-called called nuances for fine adjustment of the desired color, in particular also contain direct dyes.
Solche Nuanceure sind beispielsweise Nitrofarbstoffe wie 2-Amino-4,6-dinitrophenol, 2-Amino-4-nitrophenol, 2-Amino-6-chlor-4-nitrophenol, etc., vorzugsweise in Mengen von etwa 0,05 bis 2,5%, insbesondere 0,1 bis 1% Gew.-% der Farbzusammenset zung (ohne Oxidationsmittel).Such nuances are, for example, nitro dyes such as 2-amino-4,6-dinitrophenol, 2-amino-4-nitrophenol, 2-amino-6-chloro-4-nitrophenol, etc., preferably in amounts from about 0.05 to 2.5%, in particular 0.1 to 1% by weight of the color composition tongue (without oxidizing agent).
Die erfindungsgemäßen Haarfärbemittel können die in solchen Mitteln üblichen Grund- und Zusatzstoffe, ausgenommen Reduktionsmittel, wie Konditioniermittel, etc. enthalten, die dem Fachmann aus dem Stand der Technik bekannt und bei spielsweise in der Monographie von K. Schrader, "Grundlagen und Rezepturen der Kosmetika", 2. Aufl. (Hüthig Buch Verlag, Heidelberg, 1989), S. 782 bis 815, be schrieben sind. The hair colorants according to the invention can be those customary in such compositions Raw materials and additives, with the exception of reducing agents, such as conditioning agents, etc. contain, which are known to the expert from the prior art and at for example in the monograph by K. Schrader, "Basics and Recipes of Cosmetics ", 2nd edition (Hüthig Buch Verlag, Heidelberg, 1989), pp. 782 to 815, be are written.
Sie können als Lösungen, Cremes, Gele oder auch in Form von Aerosol-Präparaten vorliegen; geeignete Trägermaterial-Zusammensetzungen sind aus dem Stand der Technik hinreichend bekannt.They can be used as solutions, creams, gels or in the form of aerosol preparations present; suitable carrier material compositions are known from the prior art Technology well known.
Zur Applikation wird das erfindungsgemäße Oxidationsfarbstoff-Vorprodukt mit ei nem Oxidationsmittel vermischt. Bevorzugtes Oxidationsmittel ist Wasserstoff peroxid, beispielsweise in 2- bis 6-prozentiger Konzentration.For application, the oxidation dye precursor according to the invention with egg mixed with an oxidizing agent. The preferred oxidizing agent is hydrogen peroxide, for example in a 2 to 6 percent concentration.
Es können jedoch auch andere Peroxide wie Harnstoffperoxid und Melaminperoxid eingesetzt werden.However, other peroxides such as urea and melamine peroxide can also be used be used.
Der pH-Wert des applikationsfertigen Haarfärbemittels, d. h. nach Vermischung mit Peroxid, kann sowohl im schwach sauren, d. h. einem Bereich von 5,5 bis 6,9, im neutralen als auch im alkalischen Bereich, d. h. zwischen pH 7,1 und 10 liegen. The pH of the ready-to-use hair dye, d. H. after mixing with Peroxide, both in weakly acidic, i.e. H. a range from 5.5 to 6.9, in neutral as well as in the alkaline range, d. H. are between pH 7.1 and 10.
Die folgenden Beispiele dienen der Illustration der Erfindung.The following examples serve to illustrate the invention.
Die erfindungsgemäße Entwickler-Kuppler-Kombination wurde, jeweils unter ent sprechender Verringerung des Wassergehalts, in diese Grundlage eingearbeitet.The developer-coupler combination according to the invention was, in each case under ent speaking reduction in water content, incorporated into this basis.
Die Ausfärbungen erfolgen jeweils an Strähnen aus gebleichtem Menschenhaar durch Aufbringung einer einen alkalischen pH-Wert aufweisenden Mischung aus Farbstoff-Vorprodukt und 6%-iger Wasserstoffperoxid-Lösung und zwanzigminütiger Einwirkung bei Zimmertemperatur, Auswaschen und Trocknen. The coloring takes place on strands of bleached human hair by applying a mixture which has an alkaline pH Dye intermediate and 6% hydrogen peroxide solution and twenty minutes Exposure to room temperature, washing and drying.
Überraschenderweise wiesen die erfindungsgemäßen Zusammensetzungen Nr. 1, 4, 8, 11, 14 und 18 durchgängig eine stärkere Farbintensität sowie einen ausge prägteren Glanz auf als die Zusammensetzungen 2, 3, 5, 6, 7, 9, 10, 12, 13, 15, 16, 17, 19 und 20.Surprisingly, compositions no. 1, 4, 8, 11, 14 and 18 consistently have a stronger color intensity as well as an out more pronounced gloss than compositions 2, 3, 5, 6, 7, 9, 10, 12, 13, 15, 16, 17, 19 and 20.
Auch erfolgte der Farbaufzug schneller (bereits nach etwa 15 Minuten) als mit den Zusammensetzungen, die ein Reduktionsmittel enthielten.The color was also applied faster (after about 15 minutes) than with the Compositions containing a reducing agent.
Claims (4)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10103625A DE10103625A1 (en) | 2001-01-27 | 2001-01-27 | Reductant-free aqueous hair-dyeing composition based on oxidation dye precursor system, contains an aminopyrimidine developer and a resorcinol, naphthol, aminophenol or aminobenzene coupler |
| JP2001382774A JP2002220328A (en) | 2001-01-27 | 2001-12-17 | Hair dye composition |
| DE50111314T DE50111314D1 (en) | 2001-01-04 | 2001-12-27 | Hair dye and method of dyeing human hair |
| AT01130827T ATE343368T1 (en) | 2001-01-04 | 2001-12-27 | HAIR DYE PRODUCTS AND METHOD FOR DYEING HUMAN HAIR |
| EP01130827A EP1222911B1 (en) | 2001-01-04 | 2001-12-27 | Hair dye composition and process for dyeing human hair |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10103625A DE10103625A1 (en) | 2001-01-27 | 2001-01-27 | Reductant-free aqueous hair-dyeing composition based on oxidation dye precursor system, contains an aminopyrimidine developer and a resorcinol, naphthol, aminophenol or aminobenzene coupler |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE10103625A1 true DE10103625A1 (en) | 2002-08-14 |
Family
ID=7671901
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE10103625A Withdrawn DE10103625A1 (en) | 2001-01-04 | 2001-01-27 | Reductant-free aqueous hair-dyeing composition based on oxidation dye precursor system, contains an aminopyrimidine developer and a resorcinol, naphthol, aminophenol or aminobenzene coupler |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE10103625A1 (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2516118A1 (en) * | 1975-04-12 | 1976-10-21 | Henkel & Cie Gmbh | HAIR DYE PRODUCTS |
| US4003699A (en) * | 1974-11-22 | 1977-01-18 | Henkel & Cie G.M.B.H. | Oxidation hair dyes based upon tetraaminopyrimidine developers |
| EP0376078A2 (en) * | 1988-12-26 | 1990-07-04 | Kao Corporation | Dye composition for keratinous fiber |
-
2001
- 2001-01-27 DE DE10103625A patent/DE10103625A1/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4003699A (en) * | 1974-11-22 | 1977-01-18 | Henkel & Cie G.M.B.H. | Oxidation hair dyes based upon tetraaminopyrimidine developers |
| DE2516118A1 (en) * | 1975-04-12 | 1976-10-21 | Henkel & Cie Gmbh | HAIR DYE PRODUCTS |
| EP0376078A2 (en) * | 1988-12-26 | 1990-07-04 | Kao Corporation | Dye composition for keratinous fiber |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE20017640U1 (en) | Hair Dye | |
| EP1222911B1 (en) | Hair dye composition and process for dyeing human hair | |
| EP1293192A2 (en) | Hair dye and process for dyeing human hair | |
| EP1222912B1 (en) | Hair dye and process for dyeing human hair | |
| EP0943319B1 (en) | Hair-dye | |
| DE10103625A1 (en) | Reductant-free aqueous hair-dyeing composition based on oxidation dye precursor system, contains an aminopyrimidine developer and a resorcinol, naphthol, aminophenol or aminobenzene coupler | |
| DE19821535C1 (en) | Oxidation hair dye composition containing specific developer | |
| DE10229742C1 (en) | Hair colorant based on oxidation dye precursor reacting with peroxide contains specified developer and/or coupler, e.g. 3- and/or 2-chloro-p-aminophenol, 3-(N-hydroxyalkylamino)- and/or 3-morpholino-phenol or o-aminophenol | |
| DE20100140U1 (en) | Hair Dye | |
| DE10100269A1 (en) | Reductant-free aqueous hair-dyeing composition based on oxidation dye precursor system, contains an aminopyrimidine developer and a resorcinol, naphthol, aminophenol or aminobenzene coupler | |
| DE10100272A1 (en) | Reductant-free aqueous hair-dyeing composition based on oxidation dye precursor system, contains an aminopyrimidine developer and a resorcinol, naphthol, aminophenol or aminobenzene coupler | |
| DE10103626A1 (en) | Reductant-free aqueous hair-dyeing composition based on oxidation dye precursor system, contains an aminopyrimidine developer and a resorcinol, naphthol, aminophenol or aminobenzene coupler | |
| DE10100863A1 (en) | Reductant-free aqueous hair-dyeing composition based on oxidation dye precursor system, contains an aminopyrimidine developer and an aminopyridine coupler | |
| DE10100268A1 (en) | Reductant-free aqueous hair-dyeing composition based on oxidation dye precursor system, contains an aminopyrimidine developer and a resorcinol, naphthol, aminophenol or aminobenzene coupler | |
| DE20101437U1 (en) | Hair Dye | |
| DE10020730C1 (en) | Oxidation hair dye composition containing 6-amino-2,4-dichloro-3-methylphenol and developer(s), giving strong, lasting dyeings without damaging the hair | |
| DE10100271A1 (en) | Reductant-free aqueous hair-dyeing composition based on oxidation dye precursor system, contains an aminopyrimidine developer and a resorcinol, naphthol, aminophenol or aminobenzene coupler | |
| DE20100133U1 (en) | Hair Dye | |
| DE20100131U1 (en) | Hair Dye | |
| DE20100414U1 (en) | Hair Dye | |
| DE20100132U1 (en) | Hair Dye | |
| DE10020731C2 (en) | Hair Dye | |
| DE20101420U1 (en) | Hair Dye | |
| EP1310231B1 (en) | Process for dyeing human hair | |
| DE10100907A1 (en) | Reductant-free aqueous hair-dyeing composition based on oxidation dye precursor system, contains an aminopyrimidine developer and an aminopyridine coupler |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| OP8 | Request for examination as to paragraph 44 patent law | ||
| 8139 | Disposal/non-payment of the annual fee |