DD156970A5 - Waessrige peroxidemulsion und ihre verwendung bei suspensions (ko)-polymerisations-reaktionen - Google Patents
Waessrige peroxidemulsion und ihre verwendung bei suspensions (ko)-polymerisations-reaktionen Download PDFInfo
- Publication number
- DD156970A5 DD156970A5 DD81226989A DD22698981A DD156970A5 DD 156970 A5 DD156970 A5 DD 156970A5 DD 81226989 A DD81226989 A DD 81226989A DD 22698981 A DD22698981 A DD 22698981A DD 156970 A5 DD156970 A5 DD 156970A5
- Authority
- DD
- German Democratic Republic
- Prior art keywords
- emulsion
- peroxide
- emulsions
- carbon atoms
- suspension
- Prior art date
Links
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 13
- 239000000725 suspension Substances 0.000 title claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 71
- 150000002978 peroxides Chemical class 0.000 claims abstract description 32
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 30
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 18
- 239000007788 liquid Substances 0.000 claims abstract description 14
- 150000001451 organic peroxides Chemical class 0.000 claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- BEQKKZICTDFVMG-UHFFFAOYSA-N 1,2,3,4,6-pentaoxepane-5,7-dione Chemical compound O=C1OOOOC(=O)O1 BEQKKZICTDFVMG-UHFFFAOYSA-N 0.000 claims abstract description 8
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000084 colloidal system Substances 0.000 claims abstract description 8
- 230000001681 protective effect Effects 0.000 claims abstract description 8
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 10
- 238000000034 method Methods 0.000 abstract description 4
- 238000002360 preparation method Methods 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 101000588924 Anthopleura elegantissima Delta-actitoxin-Ael1a Proteins 0.000 description 7
- -1 ethylhexyl Chemical group 0.000 description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 150000003440 styrenes Chemical class 0.000 description 3
- 229920001567 vinyl ester resin Polymers 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical compound C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- NSGQRLUGQNBHLD-UHFFFAOYSA-N butan-2-yl butan-2-yloxycarbonyloxy carbonate Chemical compound CCC(C)OC(=O)OOC(=O)OC(C)CC NSGQRLUGQNBHLD-UHFFFAOYSA-N 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 231100000989 no adverse effect Toxicity 0.000 description 2
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 2
- 125000005634 peroxydicarbonate group Chemical group 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000230 xanthan gum Substances 0.000 description 2
- 229920001285 xanthan gum Polymers 0.000 description 2
- 229940082509 xanthan gum Drugs 0.000 description 2
- 235000010493 xanthan gum Nutrition 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 1
- ZWKNLRXFUTWSOY-QPJJXVBHSA-N (e)-3-phenylprop-2-enenitrile Chemical compound N#C\C=C\C1=CC=CC=C1 ZWKNLRXFUTWSOY-QPJJXVBHSA-N 0.000 description 1
- IZMZREOTRMMCCB-UHFFFAOYSA-N 1,4-dichloro-2-ethenylbenzene Chemical compound ClC1=CC=C(Cl)C(C=C)=C1 IZMZREOTRMMCCB-UHFFFAOYSA-N 0.000 description 1
- ZXFHYTWKGJWGFM-UHFFFAOYSA-N 1-chloroethenyl acetate Chemical compound CC(=O)OC(Cl)=C ZXFHYTWKGJWGFM-UHFFFAOYSA-N 0.000 description 1
- OEVVKKAVYQFQNV-UHFFFAOYSA-N 1-ethenyl-2,4-dimethylbenzene Chemical compound CC1=CC=C(C=C)C(C)=C1 OEVVKKAVYQFQNV-UHFFFAOYSA-N 0.000 description 1
- SXZSFWHOSHAKMN-UHFFFAOYSA-N 2,3,4,4',5-Pentachlorobiphenyl Chemical compound C1=CC(Cl)=CC=C1C1=CC(Cl)=C(Cl)C(Cl)=C1Cl SXZSFWHOSHAKMN-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- MENUHMSZHZBYMK-UHFFFAOYSA-N 2-cyclohexylethenylbenzene Chemical compound C1CCCCC1C=CC1=CC=CC=C1 MENUHMSZHZBYMK-UHFFFAOYSA-N 0.000 description 1
- KBKNKFIRGXQLDB-UHFFFAOYSA-N 2-fluoroethenylbenzene Chemical compound FC=CC1=CC=CC=C1 KBKNKFIRGXQLDB-UHFFFAOYSA-N 0.000 description 1
- PIAOLBVUVDXHHL-UHFFFAOYSA-N 2-nitroethenylbenzene Chemical compound [O-][N+](=O)C=CC1=CC=CC=C1 PIAOLBVUVDXHHL-UHFFFAOYSA-N 0.000 description 1
- SAFZQLDSMLNONX-UHFFFAOYSA-N 2-phenoxyethenylbenzene Chemical compound C=1C=CC=CC=1OC=CC1=CC=CC=C1 SAFZQLDSMLNONX-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- HKADMMFLLPJEAG-UHFFFAOYSA-N 3,3,3-trifluoroprop-1-enylbenzene Chemical compound FC(F)(F)C=CC1=CC=CC=C1 HKADMMFLLPJEAG-UHFFFAOYSA-N 0.000 description 1
- CEBRPXLXYCFYGU-UHFFFAOYSA-N 3-methylbut-1-enylbenzene Chemical compound CC(C)C=CC1=CC=CC=C1 CEBRPXLXYCFYGU-UHFFFAOYSA-N 0.000 description 1
- AIMDYNJRXHEXEL-UHFFFAOYSA-N 3-phenylprop-1-enylbenzene Chemical compound C=1C=CC=CC=1CC=CC1=CC=CC=C1 AIMDYNJRXHEXEL-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 208000002874 Acne Vulgaris Diseases 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical class NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- HETCEOQFVDFGSY-UHFFFAOYSA-N Isopropenyl acetate Chemical compound CC(=C)OC(C)=O HETCEOQFVDFGSY-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- YMOONIIMQBGTDU-VOTSOKGWSA-N [(e)-2-bromoethenyl]benzene Chemical compound Br\C=C\C1=CC=CC=C1 YMOONIIMQBGTDU-VOTSOKGWSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 206010000496 acne Diseases 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- AKUHVUBQELUSIY-UHFFFAOYSA-N butan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CCC(C)OC(=O)OOC(=O)OC(C)C AKUHVUBQELUSIY-UHFFFAOYSA-N 0.000 description 1
- ZGPBOPXFOJBLIV-UHFFFAOYSA-N butoxycarbonyloxy butyl carbonate Chemical compound CCCCOC(=O)OOC(=O)OCCCC ZGPBOPXFOJBLIV-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000007942 carboxylates Chemical class 0.000 description 1
- 150000001733 carboxylic acid esters Chemical class 0.000 description 1
- JLSIEHRMXULWOA-UHFFFAOYSA-N carboxyoxy 3-ethyloctan-3-yl carbonate Chemical compound CCCCCC(CC)(CC)OC(=O)OOC(O)=O JLSIEHRMXULWOA-UHFFFAOYSA-N 0.000 description 1
- IRVTWLLMYUSKJS-UHFFFAOYSA-N carboxyoxy propyl carbonate Chemical compound CCCOC(=O)OOC(O)=O IRVTWLLMYUSKJS-UHFFFAOYSA-N 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- NHOGGUYTANYCGQ-UHFFFAOYSA-N ethenoxybenzene Chemical compound C=COC1=CC=CC=C1 NHOGGUYTANYCGQ-UHFFFAOYSA-N 0.000 description 1
- AFIQVBFAKUPHOA-UHFFFAOYSA-N ethenyl 2-methoxyacetate Chemical compound COCC(=O)OC=C AFIQVBFAKUPHOA-UHFFFAOYSA-N 0.000 description 1
- FFYWKOUKJFCBAM-UHFFFAOYSA-N ethenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC=C FFYWKOUKJFCBAM-UHFFFAOYSA-N 0.000 description 1
- MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
- GFJVXXWOPWLRNU-UHFFFAOYSA-N ethenyl formate Chemical compound C=COC=O GFJVXXWOPWLRNU-UHFFFAOYSA-N 0.000 description 1
- BLCTWBJQROOONQ-UHFFFAOYSA-N ethenyl prop-2-enoate Chemical compound C=COC(=O)C=C BLCTWBJQROOONQ-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NUMHUJZXKZKUBN-UHFFFAOYSA-N methyl 4-ethenylbenzoate Chemical compound COC(=O)C1=CC=C(C=C)C=C1 NUMHUJZXKZKUBN-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical class C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 description 1
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
- 150000002976 peresters Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- KGKNBDYZZIBZQL-UHFFFAOYSA-N tert-butyl carboxyoxy carbonate Chemical compound CC(C)(C)OC(=O)OOC(O)=O KGKNBDYZZIBZQL-UHFFFAOYSA-N 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
- Adhesives Or Adhesive Processes (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL8000260A NL8000260A (nl) | 1980-01-16 | 1980-01-16 | Waterige peroxyde emulsie en de toepassing ervan in suspensie(co-)polymerisatiereacties. |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DD156970A5 true DD156970A5 (de) | 1982-10-06 |
Family
ID=19834682
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DD81226989A DD156970A5 (de) | 1980-01-16 | 1981-01-14 | Waessrige peroxidemulsion und ihre verwendung bei suspensions (ko)-polymerisations-reaktionen |
Country Status (16)
| Country | Link |
|---|---|
| EP (1) | EP0032757B2 (no) |
| JP (1) | JPS56139509A (no) |
| AR (1) | AR226090A1 (no) |
| AU (1) | AU541743B2 (no) |
| BR (1) | BR8100220A (no) |
| CA (1) | CA1171847A (no) |
| CS (2) | CS239913B2 (no) |
| DD (1) | DD156970A5 (no) |
| DE (1) | DE3160119D1 (no) |
| ES (1) | ES8203838A1 (no) |
| HU (1) | HU190362B (no) |
| NL (1) | NL8000260A (no) |
| NO (1) | NO156166C (no) |
| PL (1) | PL229210A1 (no) |
| PT (1) | PT72334B (no) |
| YU (1) | YU41372B (no) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58134103A (ja) * | 1982-02-02 | 1983-08-10 | Nippon Oil & Fats Co Ltd | 塩化ビニル系不飽和単量体の懸濁重合方法 |
| US4515928A (en) * | 1982-07-20 | 1985-05-07 | Ppg Industries, Inc. | Organic peroxide composition containing trihydric alcohol, alkali or alkaline earth metal chloride, or monosaccharide |
| US4552682A (en) * | 1982-09-30 | 1985-11-12 | Ppg Industries, Inc. | Peroxide composition containing phenolic antioxidant |
| US4515929A (en) * | 1983-07-28 | 1985-05-07 | Ppg Industries, Inc. | Peroxide composition |
| JPS60258212A (ja) * | 1984-06-05 | 1985-12-20 | Nippon Oil & Fats Co Ltd | 塩化ビニル系不飽和単量体の懸濁重合方法 |
| JPS61130372A (ja) * | 1984-11-30 | 1986-06-18 | Nippon Oil & Fats Co Ltd | 有機過酸化物含有水性懸濁液 |
| JPS61130315A (ja) * | 1984-11-30 | 1986-06-18 | Nippon Oil & Fats Co Ltd | 塩化ビニル系不飽和単量体の懸濁重合方法 |
| JPH0717690B2 (ja) * | 1986-10-07 | 1995-03-01 | 日本油脂株式会社 | 有機過酸化物水性分散液 |
| TW341579B (en) * | 1996-06-24 | 1998-10-01 | Akzo Nobel Nv | Process for enhancing the melt strength of polypropylene (co)polymers |
| TW426707B (en) | 1997-07-24 | 2001-03-21 | Akzo Nobel Nv | Emulsions of peroxyesters |
| JPH11171914A (ja) * | 1997-12-16 | 1999-06-29 | Kayaku Akzo Corp | 有機過酸化物のエマルション配合物 |
| CA2441583A1 (en) | 2001-03-23 | 2002-10-03 | Akzo Nobel Nv | Storage stable aqueous organic peroxide emulsions |
| KR100984714B1 (ko) † | 2002-05-08 | 2010-10-01 | 아크조 노벨 엔.브이. | 낮은 화학적 산소 요구량 값을 가지며 안정하고 안전한 고농도의 디아실 퍼옥시드와 퍼옥시디카르보네이트 유탁액 |
| FR2851245B1 (fr) * | 2003-02-14 | 2007-03-23 | Emulsion non gelee d'hydroxyperoxyester | |
| PT1564225E (pt) * | 2004-02-10 | 2015-02-06 | Arkema France | Emulsão de hidroxiperoxiéster não gelificada |
| CN105367688B (zh) | 2009-08-06 | 2018-07-06 | 阿克佐诺贝尔化学国际公司 | 具有高活性氧含量的储存稳定且安全的过氧化物乳液 |
| JP6198670B2 (ja) * | 2013-05-27 | 2017-09-20 | ダイキン工業株式会社 | フルオロポリマーの製造方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB931629A (en) * | 1959-07-11 | 1963-07-17 | Distillers Co Yeast Ltd | Vinyl chloride polymerisation process |
| GB1095914A (en) * | 1965-03-12 | 1967-12-20 | U S Peroxygen Corp | Pigmented peroxide compositions |
| US3507800A (en) * | 1966-10-05 | 1970-04-21 | U S Peroxygen Corp | Flame resistant peroxides |
| US3988261A (en) * | 1975-07-28 | 1976-10-26 | Ppg Industries, Inc. | Frozen organic peroxide emulsion |
| SE389811B (sv) * | 1975-07-29 | 1976-11-22 | Kema Nord Ab | Sett att framstella stabila, vattenhaltiga dispersioner av fasta dialkyl-peroxidikarbonat med bibehallet aktivt peroxidinnehall, varvid en uppslamning av vatten, dispergeringsmedel och peroxidkarbonat dispergeras... |
| DE2629467A1 (de) * | 1976-06-30 | 1978-01-05 | Wacker Chemie Gmbh | Waessrige katalysatorkonfektion |
-
1980
- 1980-01-16 NL NL8000260A patent/NL8000260A/nl not_active Application Discontinuation
-
1981
- 1981-01-06 DE DE8181200005T patent/DE3160119D1/de not_active Expired
- 1981-01-06 EP EP81200005A patent/EP0032757B2/en not_active Expired - Lifetime
- 1981-01-09 PT PT72334A patent/PT72334B/pt unknown
- 1981-01-09 CS CS81206A patent/CS239913B2/cs unknown
- 1981-01-09 CS CS81939A patent/CS239920B2/cs unknown
- 1981-01-14 DD DD81226989A patent/DD156970A5/de unknown
- 1981-01-14 PL PL22921081A patent/PL229210A1/xx unknown
- 1981-01-14 JP JP328181A patent/JPS56139509A/ja active Granted
- 1981-01-15 CA CA000368615A patent/CA1171847A/en not_active Expired
- 1981-01-15 ES ES498542A patent/ES8203838A1/es not_active Expired
- 1981-01-15 BR BR8100220A patent/BR8100220A/pt not_active IP Right Cessation
- 1981-01-15 AU AU66222/81A patent/AU541743B2/en not_active Expired
- 1981-01-15 AR AR283957A patent/AR226090A1/es active
- 1981-01-15 HU HU8186A patent/HU190362B/hu unknown
- 1981-01-15 NO NO810128A patent/NO156166C/no not_active IP Right Cessation
- 1981-01-16 YU YU100/81A patent/YU41372B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| PT72334A (en) | 1981-02-01 |
| PL229210A1 (no) | 1981-10-02 |
| NO156166B (no) | 1987-04-27 |
| YU10081A (en) | 1983-10-31 |
| ES498542A0 (es) | 1982-04-16 |
| NO810128L (no) | 1981-07-17 |
| YU41372B (en) | 1987-02-28 |
| NL8000260A (nl) | 1981-08-17 |
| CA1171847A (en) | 1984-07-31 |
| EP0032757A2 (en) | 1981-07-29 |
| BR8100220A (pt) | 1981-08-04 |
| EP0032757A3 (en) | 1981-08-05 |
| JPS6345405B2 (no) | 1988-09-09 |
| PT72334B (en) | 1981-12-18 |
| AU6622281A (en) | 1981-07-23 |
| CS239913B2 (en) | 1986-01-16 |
| HU190362B (en) | 1986-08-28 |
| DE3160119D1 (en) | 1983-04-28 |
| NO156166C (no) | 1987-08-05 |
| JPS56139509A (en) | 1981-10-31 |
| EP0032757B2 (en) | 1990-03-07 |
| AR226090A1 (es) | 1982-05-31 |
| EP0032757B1 (en) | 1983-03-23 |
| CS239920B2 (en) | 1986-01-16 |
| AU541743B2 (en) | 1985-01-17 |
| ES8203838A1 (es) | 1982-04-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DD156970A5 (de) | Waessrige peroxidemulsion und ihre verwendung bei suspensions (ko)-polymerisations-reaktionen | |
| DE3883251T2 (de) | Latex enthaltende agrochemische zusammensetzungen. | |
| DE2633363B2 (de) | Wäßrige, beim Gefrier-Auftaucyclus beständige Emulsion eines organischen Peroxids | |
| KR940010530B1 (ko) | 유기과산화물 수성분산액 | |
| DE60301625T3 (de) | Hochkonzentrierte stabile und sichere diacylperoxid und peroxydicarbonat emulsionen | |
| EP2506708A1 (de) | Pestizid-haltige mikrokapseln mit polyvinylmonomeren als vernetzer | |
| DE1595846C3 (de) | Verfahren zur Herstellung von Vinylchloridpolymerisaten | |
| JPS59186902A (ja) | 微細に分散された液体の植物保護剤およびその製造方法 | |
| DE2834939A1 (de) | Dispersionsstabilisator fuer die suspensionspolymerisation von vinylverbindungen | |
| DE69812363T2 (de) | Emulsionen von peroxyestern | |
| US5260390A (en) | Peroxide emulsions containing an antifreezing compound | |
| DE102004047118A1 (de) | Polymerdispersionen mit fungizider Aktivität und deren Verwendung | |
| DE69702923T2 (de) | Verfahren zur Herstellung einer Initiatorzusammensetzung auf Basis von Polyvinylalkohol und Emulgator | |
| DE1005272B (de) | Verbessertes Verfahren zur Polymerisation in waessriger Suspension | |
| WO2013092466A1 (de) | Hochtemperaturperoxid-haltige styrolpolymerisatperlen für die saatpolymerisation | |
| Vandegaer | Latex growth | |
| US4950422A (en) | Peroxide emulsions containing an anti-freezing compound | |
| EP1569965B1 (de) | Verfahren zur radikalischen polymerisation in gegenwart eines reglers | |
| DE2400217A1 (de) | Pestizide zusammensetzungen | |
| DE1301065B (de) | Verfahren zur Herstellung von Mischpolymerisatlatizes durch Emulsionspolymerisation | |
| DE1770521A1 (de) | Polymerisate aus praktisch wasserunloeslichen,ungesaettigten,fluessigen Monomeren und Verfahren zu ihrer Herstellung | |
| DD240550A1 (de) | Verfahren zur polymerisation von vinylchlorid | |
| DE2710278A1 (de) | Verfahren zur herstellung von transparenten, schlagfesten mischpolymerisaten von styrol | |
| DE2414357A1 (de) | Initiatoremulsion fuer olefinische polymerisationsreaktionen | |
| DD112276B1 (de) | VERFAhiREN ZUR HERSTELLUNG VON WAERfi/lEEf/iPRNDLICHHiS! POLYMERISATDiSPERSlONEN |