CN1799360A - A group of soluble liquid pesticide making carbosulfan as raw material - Google Patents
A group of soluble liquid pesticide making carbosulfan as raw material Download PDFInfo
- Publication number
- CN1799360A CN1799360A CN 200410102929 CN200410102929A CN1799360A CN 1799360 A CN1799360 A CN 1799360A CN 200410102929 CN200410102929 CN 200410102929 CN 200410102929 A CN200410102929 A CN 200410102929A CN 1799360 A CN1799360 A CN 1799360A
- Authority
- CN
- China
- Prior art keywords
- carbosulfan
- soluble liquid
- chlopyrifos
- avermectin
- emamectin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 239000007788 liquid Substances 0.000 title claims description 13
- 239000000575 pesticide Substances 0.000 title abstract description 5
- 239000002994 raw material Substances 0.000 title abstract description 4
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 6
- 239000002904 solvent Substances 0.000 claims abstract description 6
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 27
- 239000005660 Abamectin Substances 0.000 claims description 13
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 12
- AZSNMRSAGSSBNP-UHFFFAOYSA-N 22,23-dihydroavermectin B1a Natural products C1CC(C)C(C(C)CC)OC21OC(CC=C(C)C(OC1OC(C)C(OC3OC(C)C(O)C(OC)C3)C(OC)C1)C(C)C=CC=C1C3(C(C(=O)O4)C=C(C)C(O)C3OC1)O)CC4C2 AZSNMRSAGSSBNP-UHFFFAOYSA-N 0.000 claims description 9
- SPBDXSGPUHCETR-JFUDTMANSA-N 8883yp2r6d Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O[C@@H]([C@@H](C)CC4)C(C)C)O3)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1C[C@H](C)[C@@H]([C@@H](C)CC)O[C@@]21O[C@H](C\C=C(C)\[C@@H](O[C@@H]1O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C1)[C@@H](C)\C=C\C=C/1[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\1)O)C[C@H]4C2 SPBDXSGPUHCETR-JFUDTMANSA-N 0.000 claims description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 229960002418 ivermectin Drugs 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000006184 cosolvent Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- 230000000740 bleeding effect Effects 0.000 claims description 3
- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 claims 3
- 238000009472 formulation Methods 0.000 claims 2
- 239000000642 acaricide Substances 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 150000002170 ethers Chemical class 0.000 claims 1
- 230000002349 favourable effect Effects 0.000 claims 1
- 230000000749 insecticidal effect Effects 0.000 claims 1
- 239000008096 xylene Substances 0.000 claims 1
- 150000003738 xylenes Chemical class 0.000 claims 1
- 241000607479 Yersinia pestis Species 0.000 abstract description 3
- 229920000742 Cotton Polymers 0.000 abstract description 2
- 235000013399 edible fruits Nutrition 0.000 abstract description 2
- 239000012747 synergistic agent Substances 0.000 abstract 1
- 235000013311 vegetables Nutrition 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 239000005864 Sulphur Substances 0.000 description 6
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 description 6
- 239000002917 insecticide Substances 0.000 description 5
- 230000003449 preventive effect Effects 0.000 description 5
- 241000238631 Hexapoda Species 0.000 description 4
- 241000497192 Phyllocoptruta oleivora Species 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 150000001555 benzenes Chemical class 0.000 description 3
- 231100000614 poison Toxicity 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000006071 cream Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 1
- 239000005944 Chlorpyrifos Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241001468227 Streptomyces avermitilis Species 0.000 description 1
- 229950008167 abamectin Drugs 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- -1 add synergist Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 1
- DUEPRVBVGDRKAG-UHFFFAOYSA-N carbofuran Chemical compound CNC(=O)OC1=CC=CC2=C1OC(C)(C)C2 DUEPRVBVGDRKAG-UHFFFAOYSA-N 0.000 description 1
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 230000001069 nematicidal effect Effects 0.000 description 1
- 239000005645 nematicide Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a group of novel soluble pesticides for controlling pests of cotton, vegetable and fruit trees, which is prepared from carbosulfan as the raw material as well as benzene-free auxiliary agent, benzene-free solvent, emulsifying agent and synergistic agent.
Description
The present invention relates to agricultural chemicals, be a kind of be one group of soluble liquid insecticides of raw material with carbosulfan (carbosulfan), product is one group of efficient, broad spectrum pesticide.Be applicable to crops controls such as control cotton, paddy rice, fruit tree, insect preventive effects such as citrus rust mite, apple skin worm be better than conventional 20% good year winter missible oil.
For a long time, the main medicament of China's agricultural insect pests control use is organophosphorous pesticide and pyrethroid built cream preparation.Because long-term single use, pest resistance to insecticide is on the rise, and preventive effect reduces.And a large amount of poisonous uses that contain benzene solvent cause health harm to the producer, user in the cream preparation, simultaneously behind such pesticide application farmland, and a large amount of toxic solvents water that permeates the ground, polluted agricultural land, waters.At present, many developed countries to have banned use of dimethylbenzene be the agricultural chemicals of solvent preparation.Thereby, press for more efficient, low toxicities, novel form comes out.Carbosulfan be a kind of have higher in absorption, broad spectrum activity the carbamates desinsection, kill mite, nematocide.It is the low kind that poisons of carbofuran.We are through repetition test, succeed in developing efficient, the environmental protection novel form that are processed with chlopyrifos, Avermectin, ivermectin, emamectin-benzoate, no benzene cosolvent, non-toluene solvent, emulsifier, synergist etc. respectively by carbosulfan.
The object of the present invention is to provide a kind of preparation rationally, dispersed, emulsibility is good, to the producer and user's safety, with eco-friendly soluble liquid insecticides.
Implementation method of the present invention below is described in detail in detail:
In the soluble liquid insecticides of the present invention (by weight percentage), carbosulfan 1～20%, chlopyrifos 1～20%, (or Avermectin, ivermectin, emamectin-benzoate 0.1～5%), no benzene cosolvent 0～30%, emulsifier 1～35%, bleeding agent 0～15%, synergist 0～5%, antioxidant 0～1%, all the other are non-toluene solvent.
Chlopyrifos of the present invention (happy this benzene chlorpyrifos) chemical name is: 0, and 0-diethyl-O-(3,5, the 6-trichloro-2-pyridyl) thiophosphate.Molecular formula is C
9H
11CL
3NO
3PS.
Avermectin of the present invention is the tunning of A Foman streptomycete Streptomyces avermitilis, the mixture of being made up of eight quite similar homologues of structure.The general B that uses more
1a, B
1bMixture, B
1a＞80%, B
1b＜20%.Described ivermectin is the hydrogenating reduction product of Avermectin, (William C.Campbell, " Ivermectia and Abamectin ", Springer-Verlag, New York Inc, 1989, P1～23)
Emamectin-benzoate of the present invention is a kind of mixture that contains two kinds of Main Ingredients and Appearances, and a kind of is 4 " (table methylamino)-4 "-deoxidation Avermectin B greater than 90%
1a(MAB1a) with less than 4 " (table methylamino)-4 "-deoxidation Avermectin B of 10%
1B (MAB
1B).(Mrozik：4″-keto-and 4″-amino-4″-deoxyavermectin compounds and substituted amino derivatives thereof[P].US 4,427,6631984-01-24)。
The method for making of this soluble liquid is, earlier with the former medicine of carbosulfan and chlopyrifos (or Avermectin or ivermectin, or emamectin-benzoate) former medicine is dissolved in the no benzene cosolvent, add synergist, emulsifier, bleeding agent, antioxidant again, after fully mixing, it is formulated to leave standstill, filter, weigh.
The present invention can provide by following example:
Example one: take by weighing the former medicine 11.1kg of 90% carbosulfan, the former medicine 10.5kg of 95% chlopyrifos adds no benzene cosolvent 30kg, and it is fully dissolved, and adds synergist 2kg again, compound emulsifying agent 20kg, and penetrating agent JFC 2kg adds non-toluene solvent to 100kg.Fully leave standstill behind the stirring and evenly mixing, filter, promptly get 20% fourth sulphur chlopyrifos soluble liquid.
Example two: take by weighing the former medicine 11.1kg of 90% carbosulfan, the former medicine 0.21kg of 94% Avermectin, (or 92% ivermectin 0.22kg, or 90% emamectin-benzoate 0.22kg) adds no benzene auxiliary agent 10kg, penetrating agent JFC 2kg, antioxidant BHT 0.5kg adds non-toluene solvent to 100kg, leave standstill after stirring, filter, promptly get 10.2% carbosulfan Avermectin (or ivermectin or emamectin-benzoate soluble liquid).
Example three: this example is that Shi Shengbang agricultural chemicals Co., Ltd 20% carbosulfan missible oil is won in 20% carbosulfan chlopyrifos soluble liquid and Shandong, and LG-DOW company 40% happy this benzene missible oil is prevented and treated the citrus rust mite test in Guangxi.6 processing are established in test, and every processing repeats randomized arrangement 4 times.Every sub-district is by fixed 5 points of 5 point samplings, and investigation insect population radix before 2 blades of every some random searching, medicine was investigated residual borer population in 1 day, 3 days, 10 days, 15 days behind the medicine, calculated preventive effect, and the summary of results sees Table one.
Table one 20% fourth sulphur chlopyrifos soluble liquid control citrus rust mite
Field test results
| Handle | Dosage (g/hm 2) | Insect population radix (head) | Preventive effect (%) | |||
| 1d | 3d | 10d | 20d | |||
| 20% fourth sulphur chlopyrifos EC2000 doubly | 324 | 4721 | 98.7b | 99.5a | 93.5b | 81.4ab |
| 20% fourth sulphur chlopyrifos EC2500 doubly | 259.2 | 3799 | 97.7b | 98.8a | 90.5c | 73.2b |
| 1500 times of 2% fourth sulphur EC | 432 | 6813 | 99.9a | 99.2a | 95.8b | 86.2ab |
| 40% happy this benzene EC1000 doubly | 1296 | 6181 | 98.5b | 98.0a | 78.5d | 39.6c |
By this example as seen, use 20% fourth sulphur chlopyrifos soluble liquid control citrus rust mite to have good preventive effect.Mu makes dosage reduce 25%, can reach good quick-acting and lasting effect, has reduced drug cost, has alleviated the pollution of poisonous chemical solvent to environment.
Claims (3)
1. efficient, environment protection type butyronitrile Carbosulfan chlopyrifos (or Avermectin or ivermectin or emamectin-benzoate) agricultural insecticidal, miticide, its formulation is the soluble liquid novel form, it is characterized in that, this formulation emulsibility, favorable dispersibility use non-toluene solvent, auxiliary agent formulated.
2. non-toluene solvent auxiliary agent according to claim 1 is characterized in that, except that benzene, toluene, mixed xylenes to ester class, alcohols, the pure ethers equal solvent of human body safety.
3. carbosulfan chlopyrifos according to claim 1 (or Avermectin or ivermectin or emamectin-benzoate) soluble liquid, it is characterized in that, form content (by weight percentage), carbosulfan 1～20%, chlopyrifos 1～20% (or Avermectin or ivermectin or emamectin-benzoate 0.1～5%), cosolvent 0～50%, emulsifier 1～35%, bleeding agent 0～15%, synergist 0～5%, antioxidant 0.1～1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410102929 CN1799360A (en) | 2004-12-31 | 2004-12-31 | A group of soluble liquid pesticide making carbosulfan as raw material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410102929 CN1799360A (en) | 2004-12-31 | 2004-12-31 | A group of soluble liquid pesticide making carbosulfan as raw material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1799360A true CN1799360A (en) | 2006-07-12 |
Family
ID=36809742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410102929 Pending CN1799360A (en) | 2004-12-31 | 2004-12-31 | A group of soluble liquid pesticide making carbosulfan as raw material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1799360A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102060612A (en) * | 2010-11-30 | 2011-05-18 | 福州康诺生态农业技术服务有限公司 | Special insecticide fertilizer for radish and preparation method thereof |
| CN102067878A (en) * | 2011-02-23 | 2011-05-25 | 广西田园生化股份有限公司 | Ultra-low-volume liquid preparation containing carbosulfan |
| CN103300029A (en) * | 2012-03-12 | 2013-09-18 | 刘勤学 | Emamectin benzoate-carbosulfan emulsion in water and application of same in prevention and treatment of Meloidogyne incognita |
| CN103828826A (en) * | 2014-02-26 | 2014-06-04 | 陕西安德瑞普生物化学有限公司 | Insecticidal composition containing abamectin and carbosulfan |
| CN105935058A (en) * | 2016-05-07 | 2016-09-14 | 广东中迅农科股份有限公司 | Insecticidal sustained release granule containing carbosulfan and chlopyrifos, and preparation method thereof |
| CN106614673A (en) * | 2016-12-14 | 2017-05-10 | 中国农业科学院棉花研究所 | Insecticide composition containing emamectin benzoate and carbosulfan and application thereof |
-
2004
- 2004-12-31 CN CN 200410102929 patent/CN1799360A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102060612A (en) * | 2010-11-30 | 2011-05-18 | 福州康诺生态农业技术服务有限公司 | Special insecticide fertilizer for radish and preparation method thereof |
| CN102060612B (en) * | 2010-11-30 | 2013-01-16 | 福建美地有机农业有限公司 | Special insecticide fertilizer for radish and preparation method thereof |
| CN102067878A (en) * | 2011-02-23 | 2011-05-25 | 广西田园生化股份有限公司 | Ultra-low-volume liquid preparation containing carbosulfan |
| CN102067878B (en) * | 2011-02-23 | 2014-09-03 | 广西田园生化股份有限公司 | Ultra-low-volume liquid preparation containing carbosulfan |
| CN103300029A (en) * | 2012-03-12 | 2013-09-18 | 刘勤学 | Emamectin benzoate-carbosulfan emulsion in water and application of same in prevention and treatment of Meloidogyne incognita |
| CN103828826A (en) * | 2014-02-26 | 2014-06-04 | 陕西安德瑞普生物化学有限公司 | Insecticidal composition containing abamectin and carbosulfan |
| CN105935058A (en) * | 2016-05-07 | 2016-09-14 | 广东中迅农科股份有限公司 | Insecticidal sustained release granule containing carbosulfan and chlopyrifos, and preparation method thereof |
| CN106614673A (en) * | 2016-12-14 | 2017-05-10 | 中国农业科学院棉花研究所 | Insecticide composition containing emamectin benzoate and carbosulfan and application thereof |
| CN106614673B (en) * | 2016-12-14 | 2019-11-19 | 中国农业科学院棉花研究所 | A kind of insecticidal composition containing emamectin benzoate and carbosulfan and its application |
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Open date: 20060712 |