CN102067878A - Ultra-low-volume liquid preparation containing carbosulfan - Google Patents
Ultra-low-volume liquid preparation containing carbosulfan Download PDFInfo
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- CN102067878A CN102067878A CN2011100435230A CN201110043523A CN102067878A CN 102067878 A CN102067878 A CN 102067878A CN 2011100435230 A CN2011100435230 A CN 2011100435230A CN 201110043523 A CN201110043523 A CN 201110043523A CN 102067878 A CN102067878 A CN 102067878A
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- Prior art keywords
- carbosulfan
- low volume
- ultra low
- volume liquids
- ultra
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- JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 title claims abstract description 78
- 238000002360 preparation method Methods 0.000 title abstract description 10
- 239000004560 ultra-low volume (ULV) liquid Substances 0.000 title abstract 4
- 239000007788 liquid Substances 0.000 claims abstract description 70
- DIRFUJHNVNOBMY-UHFFFAOYSA-N fenobucarb Chemical compound CCC(C)C1=CC=CC=C1OC(=O)NC DIRFUJHNVNOBMY-UHFFFAOYSA-N 0.000 claims abstract description 27
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 14
- 235000009566 rice Nutrition 0.000 claims abstract description 14
- 238000005507 spraying Methods 0.000 claims abstract description 10
- 241001124076 Aphididae Species 0.000 claims abstract description 7
- 241001414720 Cicadellidae Species 0.000 claims abstract description 7
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 50
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims description 50
- 229930192474 thiophene Natural products 0.000 claims description 25
- 239000002131 composite material Substances 0.000 claims description 15
- 240000007594 Oryza sativa Species 0.000 claims description 13
- 241000607479 Yersinia pestis Species 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 7
- 239000003905 agrochemical Substances 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 4
- 239000000575 pesticide Substances 0.000 abstract description 11
- 241001498622 Cixius wagneri Species 0.000 abstract description 8
- 241000238631 Hexapoda Species 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
- 241000258937 Hemiptera Species 0.000 abstract description 3
- 239000005944 Chlorpyrifos Substances 0.000 abstract description 2
- 239000005941 Thiamethoxam Substances 0.000 abstract description 2
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 241000209094 Oryza Species 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 1
- QBSJMKIUCUGGNG-UHFFFAOYSA-N isoprocarb Chemical compound CNC(=O)OC1=CC=CC=C1C(C)C QBSJMKIUCUGGNG-UHFFFAOYSA-N 0.000 abstract 1
- VOEYXMAFNDNNED-UHFFFAOYSA-N metolcarb Chemical compound CNC(=O)OC1=CC=CC(C)=C1 VOEYXMAFNDNNED-UHFFFAOYSA-N 0.000 abstract 1
- NWWZPOKUUAIXIW-FLIBITNWSA-N thiamethoxam Chemical compound [O-][N+](=O)\N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-FLIBITNWSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 21
- 210000003298 dental enamel Anatomy 0.000 description 20
- 238000005538 encapsulation Methods 0.000 description 20
- 238000003756 stirring Methods 0.000 description 20
- 241000176086 Sogatella furcifera Species 0.000 description 13
- 239000003921 oil Substances 0.000 description 13
- 235000019198 oils Nutrition 0.000 description 13
- 239000002904 solvent Substances 0.000 description 13
- 239000003849 aromatic solvent Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 6
- 201000010099 disease Diseases 0.000 description 6
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 241001556089 Nilaparvata lugens Species 0.000 description 3
- 241000819999 Nymphes Species 0.000 description 3
- 241000700605 Viruses Species 0.000 description 3
- 235000021329 brown rice Nutrition 0.000 description 3
- 239000006184 cosolvent Substances 0.000 description 3
- 230000000749 insecticidal effect Effects 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 229920002101 Chitin Polymers 0.000 description 2
- 241000209140 Triticum Species 0.000 description 2
- 235000021307 Triticum Nutrition 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- -1 thiadiazine ketone Chemical class 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 244000144730 Amygdalus persica Species 0.000 description 1
- 240000007087 Apium graveolens Species 0.000 description 1
- 235000015849 Apium graveolens Dulce Group Nutrition 0.000 description 1
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- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 235000000832 Ayote Nutrition 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- 239000005885 Buprofezin Substances 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 240000008574 Capsicum frutescens Species 0.000 description 1
- 241001674939 Caulanthus Species 0.000 description 1
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 241001465828 Cecidomyiidae Species 0.000 description 1
- 244000241235 Citrullus lanatus Species 0.000 description 1
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 241001364569 Cofana spectra Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
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- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 1
- 240000004244 Cucurbita moschata Species 0.000 description 1
- 235000009854 Cucurbita moschata Nutrition 0.000 description 1
- 235000009804 Cucurbita pepo subsp pepo Nutrition 0.000 description 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 1
- 206010015946 Eye irritation Diseases 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- 235000003228 Lactuca sativa Nutrition 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 241000409991 Mythimna separata Species 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 240000004713 Pisum sativum Species 0.000 description 1
- 235000010582 Pisum sativum Nutrition 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 240000001987 Pyrus communis Species 0.000 description 1
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 235000002597 Solanum melongena Nutrition 0.000 description 1
- 241001161749 Stenchaetothrips biformis Species 0.000 description 1
- 240000006677 Vicia faba Species 0.000 description 1
- 235000010749 Vicia faba Nutrition 0.000 description 1
- 235000002098 Vicia faba var. major Nutrition 0.000 description 1
- 235000010726 Vigna sinensis Nutrition 0.000 description 1
- 244000042314 Vigna unguiculata Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- PRLVTUNWOQKEAI-VKAVYKQESA-N buprofezin Chemical compound O=C1N(C(C)C)\C(=N\C(C)(C)C)SCN1C1=CC=CC=C1 PRLVTUNWOQKEAI-VKAVYKQESA-N 0.000 description 1
- 239000001390 capsicum minimum Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 231100000013 eye irritation Toxicity 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 230000017448 oviposition Effects 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 235000015136 pumpkin Nutrition 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004551 spreading oil Substances 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
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- 210000002845 virion Anatomy 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an ultra-low-volume liquid preparation containing carbosulfan, and application thereof to a paddy field. The pesticide preparation is an ultra-low-volume liquid preparation formed by compounding the carbosulfan with one of effective ingredients of chlorpyrifos, thiamethoxam, tsumacide, isoprocarb or fenobucarb; and the preparation is used for controlling piercing-sucking agricultural insects in paddy rice such as rice planthopper, aphid, leafhopper and whitefly. The pesticide provided by the invention is applicable to control of the insects by an ultra-low-volume spraying method. The ultra-low-volume liquid preparation has the advantages that the liquid preparation does not need to be diluted with water during the use process, the pesticide application efficiency is high, the control effect is obvious, and meanwhile a large amount of manpower and material resources can be saved compared with the traditional pesticide application method.
Description
Technical field
The present invention relates to a kind ofly contain the ultra low volume liquids of carbosulfan and prevent and treat the application of rice hoppers at paddy field.
Background technology
Rice fulgorid is one of the primary pest in harm China south and middle and lower reach of Yangtze River rice district, wherein brown planthopper and white-backed planthopper are intermittent big insect of taking place, with become, the nymph rice strain base portion of trooping inhales juice, cause that the rice plant Huang is withered, the deliquescing of stem stalk or the lodging of rotting, the harm of brown planthopper is the most serious, according to statistics, only 2005 and hazard area in 2006 are about about 2.5 hundred million mu, general paddy rice loss 5～10%, the outbreak year paddy rice underproduction 10～20%, it is about 40～50% that the heavy field piece of part loses, even total crop failure.Small brown rice planthopper harm mainly be with become, nymph by the juice of sucking (as the stripe disease) plant that suffers from virus disease after, become the band virion, it not only constantly passes to healthy plant with virus, also passes to its offspring, is continued to propagate by the offspring.From 2004～2007 years continuous 4 years in Jiangsu, Shanghai, Anhui and part rice district, Zhejiang small brown rice planthopper wildness cause disaster, cause the big generation of stripe disease, according to relevant plant protection department statistics, the incidence of disease of stripe disease in recent years, the rice seedling bed: 1～5%, heavy field piece 10～20%, the field piece 30～50% of especially severe, this class field piece is often ploughed and is replanted, and the household economy loss is serious; Transplant field: because the harm of small brown rice planthopper transmitted virus, the apparent disease of dancing leaf blight morbidity forms weak stubble, dead seedling causes the loss of the underproduction suitable with brown planthopper.As seen, the harm of rice fulgorid grain-production of serious threat China and safety.
Carbosulfan (Buprofezin) belongs to thiadiazine ketone chitin synthesis inhibitor.Low toxicity is extremely light to skin and eye irritation effect.Strong to the insect action of contace poison, stomach poison function is also arranged.It is synthetic to suppress insect chitin, disturbs metabolism, causes nymph cast off a skin deformity or wing deformity and slowly dead.Just can find out effect in 3～7 days after the general dispenser, adult not had direct killing power, but can shorten its life-span, reduce egg laying amount, and output be mostly addle-egg, even the also very fast death of larva hatching.Leafhopper, plant hopper and aleyrodid of control Semiptera and scale insect are active high.The drug effect phase reached more than 30 days.To pest natural enemy and insect pollinator safety.There is not mutual pesticide resistance problem with other insecticides.
But the agricultural chemicals of a kind of active ingredient of long-term single use will cause the generation of resistance very soon, thereby loses its using value.Itself and other pesticide active ingredient is combined into composite insecticide, is at present in exploitation with develop a kind of mode effectively and efficiently commonly used in the new insecticide pesticide.Main purpose with the composite back use of some single insecticidal constituents, except being its consumption of minimizing, improve insecticidal effect, reduce outside toxic action and the adverse effect the environment generation, another important purpose is exactly in order to solve the pesticide resistance that insect is produced the single component agricultural chemicals, make drug effect descend or be close to invalid agricultural chemicals and recover insecticidal effect again, even can also improve effect.Rule during agriculture chemical compounding is to guarantee that the composition of assembly should lack as far as possible under certain desinsection control efficiency prerequisite.
The existing preparation of carbosulfan mainly contains missible oil, granule, wetting powder, water dispersible granules, microemulsion, suspending agent and film-spreading oil solution etc.And the carbosulfan ultra low volume liquids is not appeared in the newspapers both at home and abroad.
The ultra low volume spraying technology abroad just begins one's study as far back as the forties, and up to the initial stage sixties, the U.S. has solved after the ultra low volume spraying agent, and this pesticide application technology just begins many countries in the world and grows up gradually.Because the benefit of this technology is very remarkable, used by dozens of country so far, carry out ultra low volume spraying as countries such as the U.S., Canada, Australia aircraft, the tractors of adopting, the ultra low volume spraying machine of main employing such as Thailand, Brazil and China, hand-held, backpack carries out small-scale spray pesticide more.
Summary of the invention
The objective of the invention is according to above-mentioned situation, provide a kind of by a kind of and composite ultra low volume liquids that forms of carbosulfan in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa.Not only can eliminate pierce-suck type pest such as aphid, plant hopper, leafhopper, aleyrodid to because a large amount of uses of carbosulfan may cause the resistance that produces, its control efficiency is obviously improved.
The present invention is a kind of with the composite ultra low volume liquids that forms of a kind of active ingredient in carbosulfan and chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa, is used to prevent and treat rice hoppers, aphid, leafhopper, aleyrodid and pierce-suck type pest.
Described weight ratio of constituents example is a kind of composition in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa: carbosulfan=1.0～80.0: 1.0～30.0.The preferred weight ratio is a kind of composition in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa: carbosulfan=2.0～35.0: 2.0～25.0.With it composite after, can not only delay the generation of pierce-suck type pest resistances such as aphid, plant hopper, leafhopper, aleyrodid, killing of sucking pest such as aphid, plant hopper, leafhopper, aleyrodid are all had certain synergistic effect.
It is carbosulfan 1.0%～30.0% that this ultra low volume liquids includes the effective constituent mass fraction, chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa are respectively 1.0%～40.0%, and chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa and carbosulfan component ratio are 40: 1～2.
In addition, this ultra low volume liquids also comprises cosolvent 1.0%～10.0%, and solvent complements to 100%.
The cosolvent that is fit to is selected from cyclohexanone, methyl-sulfoxide, or N-Methyl pyrrolidone.
The solvent that is fit to is many Fluhyzons, as line oil or two wires wet goods, heavy aromatics, vegetable oil such as turpentine oil or cottonseed oil, corn oil.Preferred two wires oil or the above aromatic hydrocarbons of C10.
Ultra low volume liquids of the present invention adopts the manner known in the art preparation, normally active ingredient and cosolvent, solvent is fully mixed and forms.
The target crop that is fit to is cereal crops such as paddy rice, wheat, economic crops such as soybean, peanut, cotton, tea tree, vegetable crops such as tomato, eggplant, capsicum, lettuce, celery, wild cabbage, Kidney bean, broad bean, cowpea, pea, ground family crops such as cucumber, pumpkin, watermelon, fruit tree crops such as grape, oranges and tangerines, apple, pear tree, peach.
Adopting agricultural chemicals of the present invention to use the ultra low volume spraying method prevents and treats.
Ultra low volume liquids of the present invention is fit to control rice thrips, rice gall midge, rice fulgorid, rice leafhopper, and wheat mythimna separata, aphid, aleyrodid, scale insect etc. are specially adapted to the ultra low volume spraying method and prevent and treat rice hoppers.
The present invention carries out the composite ultra low volume liquids that forms by carbosulfan and chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa, with the rice fulgorid is research object, the comparative study proof of imitating by composite synergistic effect, field not only can reduce or eliminate the pierce-suck type pest to because a large amount of uses of carbosulfan etc. cause the resistance that produces, and its control efficiency is obviously improved.Result of study sees attached list 1～5.
Utilization DPS software carries out statistical analysis, it is equivalent and adopt the abundant method of Sun Yun to obtain the co-toxicity coefficient of each mixed ratio with reference to NY/T 1154.7-2006 to obtain test toxicity regression line (Y=a+bx) of medicament and correlation coefficient (r) value, LC50, LC90, selects optimal proportion.Toxicity Determination result shows, chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa are mixed co-toxicity coefficient to rice fulgorid all greater than 100 with 5 kinds of different proportions of carbosulfan respectively, illustrate that it is to have certain synergistic effect that two composite reagents are used to prevent and treat rice fulgorid, can use in practice.
According to subordinate list 1-5, the field control effectiveness test data all show, carbosulfan and chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa carry out the composite ultra low volume liquids that forms to the quick-acting of rice fulgorid, lasting effect, anti-efficient significantly better than the contrast medicament.
Adopt this agricultural chemicals to use the ultra low volume spraying method, do not need the thin up soup in the use, dispenser work efficiency height, preventive effect is remarkable.Traditional application method of comparing can be saved a large amount of manpower and materials.
Embodiment
The present invention is a kind of by a kind of composition in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa and the composite Recompounded pesticide that forms of carbosulfan, and it is by a kind of composition in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa and carbosulfan and proper assistant and the composite ultra low volume liquids that forms of carrier.A kind of component content that contains in the complex preparation in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa is 1.0～40.0%, and carbosulfan content is 1.0～30.0%.
The present invention describes with the following example, but does not limit the scope of the invention.
Embodiment 1, carbosulfan, chlopyrifos ultra low volume liquids
A, 2.0% carbosulfan chlopyrifos ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, with carbosulfan 1.0kg, chlopyrifos 1.0kg, N-Methyl pyrrolidone 3.0kg, neopelex 2.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
B, 12.0% carbosulfan chlopyrifos ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 2.0kg, chlopyrifos 10.0kg, N-Methyl pyrrolidone 5.0kg, neopelex 4.5kg, residue complements to 100kg with the C10 aromatic solvent, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
C, 30.0% carbosulfan chlopyrifos ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 6.0kg, chlopyrifos 24.0kg, N-Methyl pyrrolidone 7.5kg, neopelex 5.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
D, 41.0% carbosulfan chlopyrifos ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 1.0kg, chlopyrifos 40.0kg, N-Methyl pyrrolidone 10.0kg, neopelex 7.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
Embodiment 2, carbosulfan, thiophene worm piperazine ultra low volume liquids
A, 2.0% carbosulfan thiophene worm piperazine ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 1.0kg, thiophene worm piperazine 1.0kg, N-Methyl pyrrolidone 3.0kg, neopelex 2.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
B, 12.0% carbosulfan thiophene worm piperazine ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 2.0kg, thiophene worm piperazine 10.0kg, N-Methyl pyrrolidone 5.0kg, neopelex 4.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
C, 30.0% carbosulfan thiophene worm piperazine ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 6.0kg, thiophene worm piperazine 24.0kg, N-Methyl pyrrolidone 7.5kg, neopelex 5.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
D, 41.0% carbosulfan thiophene worm piperazine ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 1.0kg, thiophene worm piperazine 40.0kg, N-Methyl pyrrolidone 10.0kg, neopelex 7.5kg, residue complements to 100kg with the two wires oil solvent, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
Embodiment 3, carbosulfan, meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids
A, 2.0% carbosulfan meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 1.0kg, meta-tolyl-N-methylcarbamate (MTMC) 1.0kg, N-Methyl pyrrolidone 3.0kg, neopelex 2.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
B, 12.0% carbosulfan meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 2.0kg, meta-tolyl-N-methylcarbamate (MTMC) 10.0kg, N-Methyl pyrrolidone 5.0kg, neopelex 4.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
C, 30.0% carbosulfan meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 6.0kg, meta-tolyl-N-methylcarbamate (MTMC) 24.0kg, N-Methyl pyrrolidone 7.5kg, neopelex 5.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
D, 41.0% carbosulfan meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 1.0kg, meta-tolyl-N-methylcarbamate (MTMC) 40.0kg, N-Methyl pyrrolidone 10.0kg, neopelex 7.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
Embodiment 4, carbosulfan, Mobucin ultra low volume liquids
A, 2.0% carbosulfan Mobucin ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 1.0kg, Mobucin 1.0kg, N-Methyl pyrrolidone 3.0kg, neopelex 2.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
B, 12.0% carbosulfan Mobucin ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 2.0kg, Mobucin 10.0kg, N-Methyl pyrrolidone 5.0kg, neopelex 4.5kg, the two wires oil solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
C, 30.0% carbosulfan/Mobucin ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 6.0kg, Mobucin 24.0kg, N-Methyl pyrrolidone 7.5kg, neopelex 5.5kg, residue complements to 100kg with the C10 aromatic solvent, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
D, 41.0% carbosulfan/Mobucin ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 1.0kg, Mobucin 40.0kg, N-Methyl pyrrolidone 10.0kg, neopelex 7.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
Embodiment 5, carbosulfan, Bassa ultra low volume liquids
A, 2.0% carbosulfan Bassa ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 1.0kg, Bassa 1.0kg, N-Methyl pyrrolidone 3.0kg, neopelex 2.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
B, 12.0% carbosulfan Bassa ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 2.0kg, Bassa 10.0kg, N-Methyl pyrrolidone 5.0kg, neopelex 4.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
C, 30.0% carbosulfan Bassa ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 6.0kg, Bassa 24.0kg, N-Methyl pyrrolidone 7.5kg, neopelex 5.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
D, 41.0% carbosulfan Bassa ultra low volume liquids 100kg
With the finished product ultra low volume liquids is that weight 100% is calculated, carbosulfan 1.0kg, Bassa 40.0kg, N-Methyl pyrrolidone 10.0kg, neopelex 7.5kg, the C10 aromatic solvent complements to 100kg, pour in the enamel stirred tank, stir about 30 minutes is to transparent fully, detect up-to-standard after, metering encapsulation is finished product.
Directly the above-mentioned finished product that is mixed with is added in the ultra low volume spraying device during use, opening sprayer unit just can the effective pest control of large tracts of land.
Subordinate list 1 carbosulfan and chlorpyrifos mixture ultra low volume liquids and single agent control rice fulgorid field efficacy result
Subordinate list 2 carbosulfans and Thiamethoxam compound ultra low volume liquids and single agent control rice fulgorid field efficacy result
Subordinate list 3 carbosulfans and the composite ultra low volume liquids of meta-tolyl-N-methylcarbamate (MTMC) and single agent control rice fulgorid field efficacy result
Subordinate list 4 carbosulfans and the composite ultra low volume liquids of Mobucin and single agent control rice fulgorid field efficacy result
Subordinate list 5 carbosulfans and fenobucarb composite ultra low volume liquids and single agent control rice fulgorid field efficacy result
Claims (6)
1. ultra low volume liquids that contains carbosulfan, it is characterized in that: this liquor is a kind of with the composite ultra low volume liquids that forms of a kind of active ingredient in carbosulfan and chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa.
2. the ultra low volume liquids that contains carbosulfan according to claim 1 is characterized in that described weight ratio of constituents example is: a kind of in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa: carbosulfan=1.0～80.0: 1.0～30.0.
3. the ultra low volume liquids that contains carbosulfan according to claim 1 and 2 is characterized in that described composition preferred weight ratio is: a kind of in chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or the Bassa: carbosulfan=2.0～35.0: 2.0～25.0.
4. the ultra low volume liquids that contains carbosulfan according to claim 1 is characterized in that: chlopyrifos, thiophene worm piperazine, meta-tolyl-N-methylcarbamate (MTMC), Mobucin or Bassa and carbosulfan component ratio are 40: 1～2.
5. the ultra low volume liquids that contains carbosulfan according to claim 1 is characterized in that: adopt agricultural chemicals of the present invention to use the ultra low volume spraying method and prevent and treat.
6. the ultra low volume liquids that contains carbosulfan according to claim 1 is characterized in that: be used to prevent and treat rice hoppers, aphid, leafhopper, aleyrodid and pierce-suck type pest.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102273442A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing epoxiconazole |
| CN102273444A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing thiamethoxam |
| CN102273441A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing azoxystronbin |
| CN102349506A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Ultralow-volume solvent containing Flusilazole |
| CN102379292A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Super low volume liquid formulation containing trifloxystrobin |
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| CN1799360A (en) * | 2004-12-31 | 2006-07-12 | 潘贞德 | A group of soluble liquid pesticide making carbosulfan as raw material |
| CN101084747A (en) * | 2006-06-06 | 2007-12-12 | 中国农业科学院植物保护研究所 | Microemulsion liquid agent for pesticide novel preparation |
| CN101703066A (en) * | 2009-09-27 | 2010-05-12 | 广西田园生化股份有限公司 | Ultralow-volume compound medicament for preventing and controlling cotton aphids |
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| CN1274530A (en) * | 2000-04-21 | 2000-11-29 | 常州农药厂 | Insecticides effective in controlling rice gall midges |
| CN1799360A (en) * | 2004-12-31 | 2006-07-12 | 潘贞德 | A group of soluble liquid pesticide making carbosulfan as raw material |
| CN101084747A (en) * | 2006-06-06 | 2007-12-12 | 中国农业科学院植物保护研究所 | Microemulsion liquid agent for pesticide novel preparation |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102273442A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing epoxiconazole |
| CN102273444A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing thiamethoxam |
| CN102273441A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Ultralow volume liquid containing azoxystronbin |
| CN102349506A (en) * | 2011-09-13 | 2012-02-15 | 广西田园生化股份有限公司 | Ultralow-volume solvent containing Flusilazole |
| CN102379292A (en) * | 2011-09-13 | 2012-03-21 | 广西田园生化股份有限公司 | Super low volume liquid formulation containing trifloxystrobin |
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| CN102067878B (en) | 2014-09-03 |
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