CN1788562A - Emamectin benzoate soluble liquor - Google Patents
Emamectin benzoate soluble liquor Download PDFInfo
- Publication number
- CN1788562A CN1788562A CN 200410098574 CN200410098574A CN1788562A CN 1788562 A CN1788562 A CN 1788562A CN 200410098574 CN200410098574 CN 200410098574 CN 200410098574 A CN200410098574 A CN 200410098574A CN 1788562 A CN1788562 A CN 1788562A
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- CN
- China
- Prior art keywords
- emamectin
- benzoate
- soluble liquid
- solvent
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- CXEGAUYXQAKHKJ-NSBHKLITSA-N emamectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](NC)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 CXEGAUYXQAKHKJ-NSBHKLITSA-N 0.000 title claims description 16
- 239000007788 liquid Substances 0.000 claims abstract description 12
- 239000002904 solvent Substances 0.000 claims abstract description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 7
- 239000006184 cosolvent Substances 0.000 claims abstract description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- 230000000740 bleeding effect Effects 0.000 claims description 4
- 238000009472 formulation Methods 0.000 claims description 4
- 230000000749 insecticidal effect Effects 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 2
- 239000012752 auxiliary agent Substances 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- 150000003738 xylenes Chemical class 0.000 claims description 2
- 239000000642 acaricide Substances 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 7
- 241000607479 Yersinia pestis Species 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 235000013311 vegetables Nutrition 0.000 abstract description 2
- GCKZANITAMOIAR-XWVCPFKXSA-N dsstox_cid_14566 Chemical compound [O-]C(=O)C1=CC=CC=C1.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H]([NH2+]C)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 GCKZANITAMOIAR-XWVCPFKXSA-N 0.000 abstract 2
- 235000013399 edible fruits Nutrition 0.000 abstract 1
- 230000002045 lasting effect Effects 0.000 abstract 1
- 239000005660 Abamectin Substances 0.000 description 8
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 3
- 239000002917 insecticide Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 241000500437 Plutella xylostella Species 0.000 description 2
- 241000256247 Spodoptera exigua Species 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 description 1
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 1
- 235000016068 Berberis vulgaris Nutrition 0.000 description 1
- 241000335053 Beta vulgaris Species 0.000 description 1
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000001169 Brassica oleracea var oleracea Nutrition 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- 241001674939 Caulanthus Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229950008167 abamectin Drugs 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 238000001212 derivatisation Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000004495 emulsifiable concentrate Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The soluble liquid preparation of methylamino abamectin benzoate for preventing and controlling pests in vegetable, fruit tree and other crops is compounded with methylamino abamectin benzoate, no-benzene co-solvent, solvent, emulsifier and synergist. It has the features of high efficiency, lasting efficiency, production and use safety, environment friendship, etc.
Description
Technical field
The present invention relates to agricultural chemicals, a kind of emamectin-benzoate soluble liquid of pest control specifically, efficient, the environmental protection novel form that process by the former powder of emamectin-benzoate, emulsifier, synergist, antioxidant, no benzene auxiliary agent and solvent etc.
Emamectin-benzoate be U.S. Merk company in 1984 to Avermectin 4 " hydroxyl of α-1-oleandrose carries out derivatization research and synthetic a kind of new and effective antibiotics Insecticidal and acaricidal agent.Have now found that it is the highest to the Lepidoptera insecticidal activity in present known insecticides.Its former medicine toxicity is about 1/6 of Avermectin for poisoning.Preparation mostly is low toxicity, and the existing many enterprises of China begin to produce at present.But present domestic preparation type is more single, mostly is the missible oil formulation, uses toluene, dimethylbenzene preparation, and formulation concentrations is also lower, and the use of a large amount of containing benezene solvents causes health harm to the producer, user in the missible oil production process.After simultaneously such missible oil sprays, a large amount of toxic solvents water that permeates the ground, polluted agricultural land, waters.Present many developing countries have banned use of the agricultural chemicals of dimethylbenzene preparation, thereby promote the formulations of pesticide to bring in constant renewal in and development.
The object of the present invention is to provide a kind of compound concentration higher, and dispersed, emulsifiability is good, to the producer, user's safety, with eco-friendly soluble liquid insecticides.
Implementation method of the present invention below is described in detail in detail:
In the soluble liquid insecticides of the present invention (by weight percentage): emamectin-benzoate 0.05～20%, cosolvent 0～30%, emulsifier 1～35%, bleeding agent 0～15%, synergist 0～5%, antioxidant 0.1～1%, all the other are solvent.
Emamectin-benzoate of the present invention is a kind of mixture that contains two kinds of Main Ingredients and Appearances, and a kind of is 4 " (table methylamino)-4 "-deoxidation Avermectin B greater than 90%
1A (MAB1a) and less than 4 " (table methylamino)-4 "-deoxidation Avermectin B of 10%
1B (MAB
1B).(Mrozik：4″-keto-and4″-amino-4″-deoxy avermectincompounds and substituted amino derivatives thereof[P].US4,427,6631984-01-24)
Emulsifier of the present invention be by two kinds of non-ionic surface active agents by 1: (1～3) is composite to form.Can select also that cationic surfactant, anion surfactant and non-ionic surface active agent are composite to form for use.
Bleeding agent of the present invention is CT-901, JFC, azone etc.
Cosolvent of the present invention, solvent are to remove toluene, dimethylbenzene, mixed xylenes, any or several mixture in the ketone outside the purified petroleum benzin, alcohols, pure ethers, the amide-type etc.
Synergist of the present invention is any or several mixture and the known material of those skilled in the art in synergy phosphorus, Butacide, the triphenyl phosphate.
The method for making of this soluble liquid is earlier emamectin-benzoate to be dissolved in the cosolvent, and after adding synergist, emulsifier, bleeding agent and solvent again and fully mixing, it is formulated to leave standstill, filter, weigh.
The present invention can measure by following example:
Experiment 1: take by weighing the former powder 2.23kg of 90% emamectin-benzoate, after adding 2.5kg cosolvent fully dissolves, add synergist 1.5kg again, compound emulsifying agent 12kg, penetrating agent JFC 1kg, antioxidant BHT 0.5kg, add non-toluene solvent behind the stirring and evenly mixing to 100kg, leave standstill, filter, promptly get 2% emamectin-benzoate soluble liquid.
Example 2: this example is that 2% emamectin-benzoate soluble liquid and Weiyuan, Hebei biochemical industry Co., Ltd use the 1.8% abamectin emulsifiable concentrate control diamond-back moth drug effect of Avermectin ointment preparation to compare, and the results are shown in Table 1.
Test adopts 2% emamectin-benzoate soluble liquid of the present invention's preparation to carry out control beet armyworm field trial in August, 2004 at academy of agricultural sciences, Jiangsu Province vegetable field, grows fine for the examination wild cabbage, and diamond-back moth is contained the phase of sending out for 1～2 age.5 processing are established in test, and every processing repeats for 4 times, totally 20 sub-districts, and the sub-district area is 23M
2, randomized arrangement.Every sub-district connects fixed 5 points of 5 point samplings, every 2 strain, and the mark of listing, respectively at handling back 3 days, 7 days, 10 days, 20 days residual borer populations alive of investigation calculated preventive effect.
Table 12% emamectin-benzoate soluble liquid (first dimension salt SL) control
Beet armyworm field control effectiveness test result
| Medicament | Dosage | The insect population radix | Preventive effect (%) | |||
| Ml/ mu | (head) | 3d | 7d | 10d | 20d | |
| 2% first dimension salt SL, 1.8% Avermectin EC | 15 17.5 20 | 213 209 242 | 81.33b 86.53ab 84.77ab | 91.26b 91.99a 87.31b | 89.87a 91.65a 91.08a | 91.88b 94.65ab 90.33ab |
By this example as seen, use 2% first dimension salt SL control beet moth that good preventive effect is arranged.Usage amount 15ml is suitable with 1.8% Avermectin EC mu consumption 20ml for mu.Therefore, use 2% first dimension salt soluble liquid, the agricultural chemicals usage amount reduces, and has alleviated the pollution of poisonous chemical solvent to environment.
Claims (3)
1, a kind of efficient, environment-friendly type emamectin-benzoate agricultural insecticidal, miticide.Its formulation is a soluble liquid.It is characterized in that adopting non-toluene solvent, auxiliary agent is formulated.
2, non-toluene solvent described in the claim 1 is the ester class to human body safety, alcohols, pure ethers equal solvent except that benzene, toluene, mixed xylenes.
3, the emamectin-benzoate soluble liquid described in the claim 1 is characterized in that forming content (by weight percentage), emamectin-benzoate 0.05～20%, cosolvent 0～30%, emulsifier 1～35%, bleeding agent 0～15%, synergist 0～5%, antioxidant 0.1-1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410098574 CN1788562A (en) | 2004-12-14 | 2004-12-14 | Emamectin benzoate soluble liquor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410098574 CN1788562A (en) | 2004-12-14 | 2004-12-14 | Emamectin benzoate soluble liquor |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1788562A true CN1788562A (en) | 2006-06-21 |
Family
ID=36786840
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410098574 Pending CN1788562A (en) | 2004-12-14 | 2004-12-14 | Emamectin benzoate soluble liquor |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1788562A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102302020A (en) * | 2011-09-28 | 2012-01-04 | 联保作物科技有限公司 | Pesticidal disease-prevention suspending seed coating agent |
| CN101601394B (en) * | 2009-07-14 | 2012-08-08 | 江苏龙灯化学有限公司 | Pesticide composition with synergistic effect |
| WO2016029859A1 (en) * | 2014-08-28 | 2016-03-03 | Rotam Agrochem International Company Limited | A pesticide formulation comprising a water soluble active ingredient and a penetration enhancer and use of the same |
| CN114342946A (en) * | 2021-12-27 | 2022-04-15 | 陕西新指南针化工科技服务有限责任公司 | Emamectin benzoate aqueous solution and preparation method thereof |
| CN116114694A (en) * | 2021-11-12 | 2023-05-16 | 赤峰绿水青山生物科技有限公司 | A kind of efficient environment-friendly insecticide and preparation method thereof |
-
2004
- 2004-12-14 CN CN 200410098574 patent/CN1788562A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101601394B (en) * | 2009-07-14 | 2012-08-08 | 江苏龙灯化学有限公司 | Pesticide composition with synergistic effect |
| CN102302020A (en) * | 2011-09-28 | 2012-01-04 | 联保作物科技有限公司 | Pesticidal disease-prevention suspending seed coating agent |
| WO2016029859A1 (en) * | 2014-08-28 | 2016-03-03 | Rotam Agrochem International Company Limited | A pesticide formulation comprising a water soluble active ingredient and a penetration enhancer and use of the same |
| CN116114694A (en) * | 2021-11-12 | 2023-05-16 | 赤峰绿水青山生物科技有限公司 | A kind of efficient environment-friendly insecticide and preparation method thereof |
| CN116114694B (en) * | 2021-11-12 | 2025-04-04 | 赤峰绿水青山生物科技有限公司 | A kind of high-efficiency environmentally friendly insecticide and preparation method |
| CN114342946A (en) * | 2021-12-27 | 2022-04-15 | 陕西新指南针化工科技服务有限责任公司 | Emamectin benzoate aqueous solution and preparation method thereof |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
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| C12 | Rejection of a patent application after its publication | ||
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Open date: 20060621 |