CN1663380A - Matrine and capsaicin composite pesticide - Google Patents
Matrine and capsaicin composite pesticide Download PDFInfo
- Publication number
- CN1663380A CN1663380A CN 200510024661 CN200510024661A CN1663380A CN 1663380 A CN1663380 A CN 1663380A CN 200510024661 CN200510024661 CN 200510024661 CN 200510024661 A CN200510024661 A CN 200510024661A CN 1663380 A CN1663380 A CN 1663380A
- Authority
- CN
- China
- Prior art keywords
- matrine
- agent
- capsaicin
- composite pesticide
- capsaicin composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- YKPUWZUDDOIDPM-SOFGYWHQSA-N capsaicin Chemical compound COC1=CC(CNC(=O)CCCC\C=C\C(C)C)=CC=C1O YKPUWZUDDOIDPM-SOFGYWHQSA-N 0.000 title claims abstract description 51
- 239000000575 pesticide Substances 0.000 title claims abstract description 30
- ZSBXGIUJOOQZMP-UHFFFAOYSA-N Isomatrine Natural products C1CCC2CN3C(=O)CCCC3C3C2N1CCC3 ZSBXGIUJOOQZMP-UHFFFAOYSA-N 0.000 title claims description 34
- ZSBXGIUJOOQZMP-JLNYLFASSA-N Matrine Chemical compound C1CC[C@H]2CN3C(=O)CCC[C@@H]3[C@@H]3[C@H]2N1CCC3 ZSBXGIUJOOQZMP-JLNYLFASSA-N 0.000 title claims description 34
- 229930014456 matrine Natural products 0.000 title claims description 34
- 229960002504 capsaicin Drugs 0.000 title claims description 33
- 239000002131 composite material Substances 0.000 title claims description 18
- 235000017663 capsaicin Nutrition 0.000 title claims description 17
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- 230000000740 bleeding effect Effects 0.000 claims description 15
- 239000003995 emulsifying agent Substances 0.000 claims description 13
- 239000003755 preservative agent Substances 0.000 claims description 13
- 230000002335 preservative effect Effects 0.000 claims description 13
- 239000003381 stabilizer Substances 0.000 claims description 13
- 239000008367 deionised water Substances 0.000 claims description 11
- 229910021641 deionized water Inorganic materials 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 239000004480 active ingredient Substances 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 239000004359 castor oil Substances 0.000 claims description 4
- 235000019438 castor oil Nutrition 0.000 claims description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 4
- PEYUIKBAABKQKQ-AFHBHXEDSA-N (+)-sesamin Chemical compound C1=C2OCOC2=CC([C@H]2OC[C@H]3[C@@H]2CO[C@@H]3C2=CC=C3OCOC3=C2)=C1 PEYUIKBAABKQKQ-AFHBHXEDSA-N 0.000 claims description 2
- AXTGDCSMTYGJND-UHFFFAOYSA-N 1-dodecylazepan-2-one Chemical compound CCCCCCCCCCCCN1CCCCCC1=O AXTGDCSMTYGJND-UHFFFAOYSA-N 0.000 claims description 2
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 claims description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- 244000203593 Piper nigrum Species 0.000 claims description 2
- 235000008184 Piper nigrum Nutrition 0.000 claims description 2
- 235000013614 black pepper Nutrition 0.000 claims description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims description 2
- 229960001484 edetic acid Drugs 0.000 claims description 2
- PEYUIKBAABKQKQ-UHFFFAOYSA-N epiasarinin Natural products C1=C2OCOC2=CC(C2OCC3C2COC3C2=CC=C3OCOC3=C2)=C1 PEYUIKBAABKQKQ-UHFFFAOYSA-N 0.000 claims description 2
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims description 2
- 229960003639 laurocapram Drugs 0.000 claims description 2
- 229960005235 piperonyl butoxide Drugs 0.000 claims description 2
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 2
- VRMHCMWQHAXTOR-CMOCDZPBSA-N sesamin Natural products C1=C2OCOC2=CC([C@@H]2OC[C@@]3(C)[C@H](C=4C=C5OCOC5=CC=4)OC[C@]32C)=C1 VRMHCMWQHAXTOR-CMOCDZPBSA-N 0.000 claims description 2
- 239000004334 sorbic acid Substances 0.000 claims description 2
- 235000010199 sorbic acid Nutrition 0.000 claims description 2
- 229940075582 sorbic acid Drugs 0.000 claims description 2
- -1 sorbierite Chemical compound 0.000 claims description 2
- 150000003462 sulfoxides Chemical class 0.000 claims description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims 2
- 239000005711 Benzoic acid Substances 0.000 claims 1
- 235000010233 benzoic acid Nutrition 0.000 claims 1
- 235000011187 glycerol Nutrition 0.000 claims 1
- 231100000053 low toxicity Toxicity 0.000 abstract description 5
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000005660 Abamectin Substances 0.000 abstract 1
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 abstract 1
- 239000003094 microcapsule Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 8
- 239000003905 agrochemical Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 230000000749 insecticidal effect Effects 0.000 description 6
- 241000238631 Hexapoda Species 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000001228 spectrum Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000470 constituent Substances 0.000 description 3
- WITLAWYGGVAFLU-UHFFFAOYSA-N 3-(6-methoxy-1,3-benzodioxol-5-yl)-8,8-dimethylpyrano[2,3-f]chromen-4-one Chemical compound C1=CC(C)(C)OC2=CC=C(C(C(C3=CC=4OCOC=4C=C3OC)=CO3)=O)C3=C21 WITLAWYGGVAFLU-UHFFFAOYSA-N 0.000 description 2
- 241000208340 Araliaceae Species 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 2
- 235000003140 Panax quinquefolius Nutrition 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 235000019504 cigarettes Nutrition 0.000 description 2
- 235000008434 ginseng Nutrition 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- 235000002566 Capsicum Nutrition 0.000 description 1
- 240000008574 Capsicum frutescens Species 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000001390 capsicum minimum Substances 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a pesticide avermectin microcapsule belonging to the technological field of plant-source pesticides, whose hosts comprises sophocarpidine, capsicine and auxiliary agent, wherein these raw materials are available on the market. The advantages of the invention include scientific matching, highly performance, broad spectrum, low toxicity, less residual and resistance, and nuisance free during production and application.
Description
Technical field
The invention belongs to agricultural chemicals manufacturing technology field, relate to matrine specifically. capsaicine is the preparing process of active ingredient.
Technical background
For a long time, people utilize the chemical pesticide control damage by disease and insect to obtain remarkable result, but the long-term public hazards that caused of using of chemical pesticide: contaminated environment, soil compaction, residual exceeding standard; Influenced people, animal health, chemical pesticide uses the back insect to produce tangible resistance for a long time simultaneously, and preventive effect is descended, and the consumption of agricultural chemicals constantly increases, and has improved the control cost, has increased the weight of user's burden.
Along with the enhancing of people's environmental consciousness, hypertoxic chemical pesticide is progressively being forbidden producing and use, the just worldwide further in-depth of development low toxicity, few noresidue, few nonresistant pesticide species; Wherein botanical pesticide is one of important kind of low toxicity, few noresidue, few nonreactive domestic animal.More agriculture chemical registration and application have been obtained as matrine as botanical pesticide, its registration number that is mixed has LS97479,1.8% chlorine kuh-seng missible oil, LS97483,3.2% chlorine kuh-seng missible oil, LS97318,0.6% cigarette ginseng alkali missible oil, LS95475,1.2% cigarette ginseng alkali missible oil; And patent 96109680 is arranged, and matrine-cybermethrin mixed preparation and manufacture method thereof, also disclosing the patent No. is 01130605, the application of jamaicin matrine sterilization and disinsection aqua.The patent No. that has that capsicum and nicotine are mixed is 00105208, a kind of agricultural chemical insecticide that contains capsaicine, and agriculture chemical registration is arranged.
Though above-mentioned technology has been made good contribution for development low toxicity, few noresidue, few free of contamination pesticide species, but owing to above-mentioned kind or because insecticidal spectrum is narrower, or because times liquid is little, quick-acting is not enough, or, aspect promoting the use of, also exist bigger limitation owing to the more high reason of price.
Botanical pesticide join mutual technology, its essence is a kind of selection invention, capsaicine and matrine known to the public can have insecticidal action, but both are that people grasp as yet with the composite synergistic function that can play of different ratios, skill wood just of the present invention place; Up to the present, through consulting related data, do not find that also the two joins mutual technology and answer generation.
Summary of the invention
The objective of the invention is a kind of matrine. capsaicin composite pesticide, after utilizing matrine and capsaicine preferably to join mutually, overcome matrine and capsaicine folk prescription or above-mentioned compound insecticidal spectrum is narrow, times liquid is little, quick-acting is not enough and price is more high is not enough to and pollution problem that chemical pesticide production and use are caused, the present invention has following advantage:
1. insecticidal spectrum is wide: above-mentioned two kinds of folk prescriptions and mixed insecticide, insecticidal spectrum only are 2 to 3 kinds of insects, and the present invention is through the various crop field trial, and insecticidal spectrum reaches 16 kinds, has tangible broad spectrum activity.
2. doubly liquid is big: times liquid of above-mentioned agricultural chemicals when the different target of control is at 200 times to 1000 times, and times liquid that the present invention prevents and treats different targets reaches 1500 to 2000 times.
3. quick-acting is good: when above-mentioned agricultural chemicals used, the dead peak period of general insect was all more than 3 days, and the dead peak period of insect was at 4 to 6 hours when the present invention used.
4. price is low: the average price of above-mentioned agricultural chemicals is at 90,000 yuan/ton, and this product price is 60,000 yuan/ton, compares price low 1/3.
5. produce and use pollution-free, few noresidue, few non-resistant, low toxicity, overcome the defective of chemical pesticide.
The present invention is achieved through the following technical solutions:
By active ingredient, auxiliary agent by weight percentage by following percentage configuration host for raw material.
Host: matrine 0.05%～30%
Capsaicine 0.1%～30%
Auxiliary agent: synergist 0.5%～10%
Bleeding agent 0.3%～20%
Stabilizing agent 0.1%～15%
Emulsifier 1%～20%
Preservative 0.2%～8%
Antifreezing agent 0.1%～8%
Deionized water 5%～60%
Synergist is any of black pepper alkali, sesamin, Butacide, sulfoxide.
Bleeding agent is any of high bleeding agent 961, Laurocapram, JFC-2, JFC-S.
Stabilizing agent is any of modified castor oil, sulfurized castor oil, ethylenediamine tetra-acetic acid, benzenediol.
Emulsifier be agricultural newborn 100#, 600 any.
Preservative is any of sorbic acid, sorbierite, Sodium Benzoate, ethyl acetate.
Antifreezing agent be ethylene glycol, interior triol, propane diols, any.
Preparation process:
In proportion the host that contains matrine and capsaicine is mixed, add synergist, bleeding agent, stabilizing agent, emulsifier, preservative, antifreezing agent and deionized water more in proportion successively, in 50 ℃～60 ℃ scopes, stir while adding and mix by the refinement mixing apparatus, through the active constituent content of sample analysis host, can pack warehouse-in after meeting the requirements.
For the technology of the present invention is described better, with embodiment technology contents of the present invention is described below.
The active constituent content of host of the present invention join mutual ratio, be not limited to following embodiment.
Embodiment 1 11.5% matrine capsaicin composite pesticide
Host matrine 11%
Capsaicine 0.5%
Auxiliary agent synergist 3%
Bleeding agent 3%
Stabilizing agent 1.5%
Emulsifier 6%
Preservative 1.5%
Antifreezing agent 1%
Add deionized water to 100%
Host is by active ingredient, auxiliary agent by weight percentage, following examples with.
Preparation process:
In proportion the host that contains matrine and capsaicine is mixed, add synergist, bleeding agent, stabilizing agent, emulsifier, preservative, antifreezing agent and deionized water more in proportion successively, in 50 ℃～60 ℃ scopes, stir while adding and mix by the refinement mixing apparatus, through the active constituent content of sample analysis host, can pack warehouse-in after meeting the requirements.
Following examples preparation process is similar.
Embodiment 2 8.6% matrine capsaicin composite pesticides
Host matrine 8%
Capsaicine 0.6%
Auxiliary agent synergist 3%
Bleeding agent 3%
Stabilizing agent 1.5%
Emulsifier 6%
Preservative 1.5%
Antifreezing agent 1%
Add deionized water to 100%
Embodiment 3 4.8% matrine capsaicin composite pesticides
Host matrine 4%
Capsaicine 0.8%
Auxiliary agent synergist 3%
Bleeding agent 3%
Stabilizing agent 1.5%
Emulsifier 6%
Preservative 1.5%
Antifreezing agent 1%
Add deionized water to 100%
Embodiment 4 1.8% matrine capsaicin composite pesticides
Host matrine 0.8%
Capsaicine 1%
Auxiliary agent synergist 3%
Bleeding agent 3%
Stabilizing agent 1.5%
Emulsifier 6%
Preservative 1.5%
Antifreezing agent 1%
Add deionized water to 100%
Embodiment 5 15% matrine capsaicin composite pesticides
Host matrine 0.5%
Capsaicine 1%
Auxiliary agent synergist 3%
Bleeding agent 3%
Stabilizing agent 1.5%
Emulsifier 6%
Preservative 1.5%
Antifreezing agent 1%
Add deionized water to 100%
Embodiment 6 2% matrine capsaicin composite pesticides
Host matrine 0.25%
Capsaicine 1.75%
Auxiliary agent synergist 3%
Bleeding agent 3%
Stabilizing agent 1.5%
Emulsifier 6%
Preservative 1.5%
Antifreezing agent 1%
Add deionized water to 100%
Embodiment 7 2.2% matrine capsaicin composite pesticides
Host matrine 0.2%
Capsaicine 2%
Auxiliary agent synergist 3%
Bleeding agent 3%
Stabilizing agent 1.5%
Emulsifier 6%
Preservative 1.5%
Antifreezing agent 1%
Add deionized water to 100%
Claims (7)
1. a matrine capsaicin composite pesticide is characterized in that being made up of the active ingredient degree of following host and the percentage by weight of auxiliary agent.
Host matrine 0.05%～30%
Capsaicine 0.1%～30%
Auxiliary agent synergist 0.5%～10%
Bleeding agent 0.3%～20%
Stabilizing agent 0.1%～15%
Emulsifier 1%～20%
Preservative 0.2%～8%
Antifreezing agent 0.1%～8%
Deionized water 5%～60%
2. a kind of matrine capsaicin composite pesticide according to claim 1 is characterized in that synergist is selected from any of black pepper alkali, sesamin, Butacide, sulfoxide.
3. a kind of matrine capsaicin composite pesticide according to claim 1 is characterized in that bleeding agent is selected from any of high bleeding agent 961, Laurocapram, JFC-2, JFC-S.
4. a kind of matrine capsaicin composite pesticide according to claim 1 is characterized in that stabilizing agent is selected from any of modified castor oil, sulfurized castor oil, ethylenediamine tetra-acetic acid, benzenediol.
5 a kind of matrine capsaicin composite pesticides according to claim 1 is characterized in that emulsifier is selected from any of agricultural newborn 100#, 600#.
6. a kind of matrine capsaicin composite pesticide according to claim 1, it is characterized in that preservative is selected from that sorbic acid, sorbierite, benzoic acid are received, ethyl acetate any
7. a kind of matrine capsaicin composite pesticide according to claim 1, its feature is selected from any of ethylene glycol, glycerine, propane diols at antifreezing agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510024661 CN1663380A (en) | 2005-03-28 | 2005-03-28 | Matrine and capsaicin composite pesticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510024661 CN1663380A (en) | 2005-03-28 | 2005-03-28 | Matrine and capsaicin composite pesticide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1663380A true CN1663380A (en) | 2005-09-07 |
Family
ID=35034832
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510024661 Pending CN1663380A (en) | 2005-03-28 | 2005-03-28 | Matrine and capsaicin composite pesticide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1663380A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101849540A (en) * | 2010-06-04 | 2010-10-06 | 安徽陆野农化有限责任公司 | A kind of capsicum biopesticide produced by using capsicum resin waste residue (pectin) and its preparation method and application |
| CN102484993A (en) * | 2010-12-02 | 2012-06-06 | 华南农业大学 | Synergistic pesticide composition of matrine and tea saponin |
| CN102484994A (en) * | 2010-12-02 | 2012-06-06 | 华南农业大学 | Synergy composition of matrine and chlorantraniliprole |
| CN102885093A (en) * | 2012-10-18 | 2013-01-23 | 童照夫 | Habitual green pesticide liquid |
| CN103814914A (en) * | 2014-02-19 | 2014-05-28 | 李�杰 | Capsaicin insecticide and its preparation method |
| CN104604939A (en) * | 2015-01-08 | 2015-05-13 | 馥稷生物科技发展（上海）有限公司 | Pesticide composite containing sophocarpidine |
| CN106386885A (en) * | 2016-08-31 | 2017-02-15 | 广东博识环境化学研究所（有限合伙） | Preparation process of mandarin orange peel composite plant agricultural insecticide |
| CN106417300A (en) * | 2016-09-27 | 2017-02-22 | 海南博士威农用化学有限公司 | Insecticide synergia aid |
| CN106508985A (en) * | 2016-12-14 | 2017-03-22 | 安徽扬子化工有限公司 | Efficient plant pesticide |
| CN106973960A (en) * | 2017-03-30 | 2017-07-25 | 袁长吉 | Tuber of stemona capsicum insecticide and preparation method thereof |
| CN108522561A (en) * | 2018-05-04 | 2018-09-14 | 内蒙古庆丰元生物制剂有限公司 | A kind of plant insecticide composition and preparation method thereof containing matrine |
| US20240041040A1 (en) * | 2022-07-20 | 2024-02-08 | The United States Of America, As Represented By The Secretary Of Agriculture | Rodent repellent compositions |
-
2005
- 2005-03-28 CN CN 200510024661 patent/CN1663380A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101849540A (en) * | 2010-06-04 | 2010-10-06 | 安徽陆野农化有限责任公司 | A kind of capsicum biopesticide produced by using capsicum resin waste residue (pectin) and its preparation method and application |
| CN101849540B (en) * | 2010-06-04 | 2013-07-03 | 安徽陆野农化有限责任公司 | Capsicum bio-pesticide produced by using capsicum resin waste residue (pectin) and preparation method and application thereof |
| CN102484994B (en) * | 2010-12-02 | 2014-08-27 | 华南农业大学 | Synergy composition of matrine and chlorantraniliprole |
| CN102484993A (en) * | 2010-12-02 | 2012-06-06 | 华南农业大学 | Synergistic pesticide composition of matrine and tea saponin |
| CN102484994A (en) * | 2010-12-02 | 2012-06-06 | 华南农业大学 | Synergy composition of matrine and chlorantraniliprole |
| CN102885093A (en) * | 2012-10-18 | 2013-01-23 | 童照夫 | Habitual green pesticide liquid |
| CN103814914A (en) * | 2014-02-19 | 2014-05-28 | 李�杰 | Capsaicin insecticide and its preparation method |
| CN104604939A (en) * | 2015-01-08 | 2015-05-13 | 馥稷生物科技发展（上海）有限公司 | Pesticide composite containing sophocarpidine |
| CN106386885A (en) * | 2016-08-31 | 2017-02-15 | 广东博识环境化学研究所（有限合伙） | Preparation process of mandarin orange peel composite plant agricultural insecticide |
| CN106417300A (en) * | 2016-09-27 | 2017-02-22 | 海南博士威农用化学有限公司 | Insecticide synergia aid |
| CN106508985A (en) * | 2016-12-14 | 2017-03-22 | 安徽扬子化工有限公司 | Efficient plant pesticide |
| CN106973960A (en) * | 2017-03-30 | 2017-07-25 | 袁长吉 | Tuber of stemona capsicum insecticide and preparation method thereof |
| CN108522561A (en) * | 2018-05-04 | 2018-09-14 | 内蒙古庆丰元生物制剂有限公司 | A kind of plant insecticide composition and preparation method thereof containing matrine |
| US20240041040A1 (en) * | 2022-07-20 | 2024-02-08 | The United States Of America, As Represented By The Secretary Of Agriculture | Rodent repellent compositions |
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