CN1557160A - Mixed insecticide missible oil formulation with neem oil as synergist - Google Patents
Mixed insecticide missible oil formulation with neem oil as synergist Download PDFInfo
- Publication number
- CN1557160A CN1557160A CNA2004100234640A CN200410023464A CN1557160A CN 1557160 A CN1557160 A CN 1557160A CN A2004100234640 A CNA2004100234640 A CN A2004100234640A CN 200410023464 A CN200410023464 A CN 200410023464A CN 1557160 A CN1557160 A CN 1557160A
- Authority
- CN
- China
- Prior art keywords
- weight
- neem oil
- molecular weight
- content
- acetamiprid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002018 neem oil Substances 0.000 title claims abstract description 39
- 239000000203 mixture Substances 0.000 title claims abstract description 11
- 239000002917 insecticide Substances 0.000 title description 8
- 238000009472 formulation Methods 0.000 title description 2
- 239000003921 oil Substances 0.000 title 1
- 239000000575 pesticide Substances 0.000 claims abstract description 42
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 claims abstract description 19
- 239000005875 Acetamiprid Substances 0.000 claims abstract description 19
- 239000005906 Imidacloprid Substances 0.000 claims abstract description 18
- CWFOCCVIPCEQCK-UHFFFAOYSA-N chlorfenapyr Chemical compound BrC1=C(C(F)(F)F)N(COCC)C(C=2C=CC(Cl)=CC=2)=C1C#N CWFOCCVIPCEQCK-UHFFFAOYSA-N 0.000 claims abstract description 18
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229940056881 imidacloprid Drugs 0.000 claims abstract description 18
- 239000003960 organic solvent Substances 0.000 claims abstract description 8
- 239000003381 stabilizer Substances 0.000 claims abstract description 8
- NHOIBRJOQAYBJT-IMGVWCFESA-N nimbin Chemical compound C=1([C@@H]2C[C@H]3O[C@H]4[C@](C3=C2C)(C)[C@@H]([C@]2(C(=O)C=C[C@](C)([C@@H]2[C@H]4OC(C)=O)C(=O)OC)C)CC(=O)OC)C=COC=1 NHOIBRJOQAYBJT-IMGVWCFESA-N 0.000 claims abstract description 5
- ZQIYJHBQRBBBRZ-UHFFFAOYSA-N nimbin Natural products COC(=O)CC1C2C(C(OC(=O)C)C3OC4CC(C(=C4C13C)C)c5cocc5)C(C)(C=CC2=O)C(=O)OC ZQIYJHBQRBBBRZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 claims abstract description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 48
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 44
- 238000002360 preparation method Methods 0.000 claims description 37
- 239000006071 cream Substances 0.000 claims description 29
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 24
- CDMGNVWZXRKJNS-UHFFFAOYSA-N 2-benzylphenol Chemical compound OC1=CC=CC=C1CC1=CC=CC=C1 CDMGNVWZXRKJNS-UHFFFAOYSA-N 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 22
- 239000011575 calcium Substances 0.000 claims description 22
- 229910052791 calcium Inorganic materials 0.000 claims description 22
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 22
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 16
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 15
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 15
- 239000004202 carbamide Substances 0.000 claims description 15
- 239000011737 fluorine Substances 0.000 claims description 15
- 229910052731 fluorine Inorganic materials 0.000 claims description 15
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 4
- 239000008158 vegetable oil Substances 0.000 claims description 4
- 240000000233 Melia azedarach Species 0.000 claims description 3
- IKJQENAHDRKFKL-UHFFFAOYSA-N 3-Epimeliantriol Natural products OC1OC(C(O)C(C)(O)C)CC1C1C2(C)CCC3C4(C)CCC(O)C(C)(C)C4CC=C3C2(C)CC1 IKJQENAHDRKFKL-UHFFFAOYSA-N 0.000 claims description 2
- MJNRBOGIPLCVIM-LJEOTECVSA-N 3-deacetylsalannin Chemical compound C=1([C@@H]2C[C@H]3O[C@H]4[C@](C3=C2C)(C)[C@@H]([C@]2(C)[C@@H]3[C@]([C@@H](C[C@@H]2OC(=O)C(\C)=C\C)O)(C)CO[C@H]34)CC(=O)OC)C=COC=1 MJNRBOGIPLCVIM-LJEOTECVSA-N 0.000 claims description 2
- PWFKLZWNGVGKBA-UHFFFAOYSA-N 6-O-Acetylnimbandiol Natural products CC(=O)OC1C2C(C)(O)C=CC(=O)C2(C)C(CC(=O)OC)C(C2=C3C)(C)C1OC2CC3C=1C=COC=1 PWFKLZWNGVGKBA-UHFFFAOYSA-N 0.000 claims description 2
- CTBHKOAPXBDFPX-PQYHCQQJSA-N 6-deacetylnimbin Chemical compound C=1([C@@H]2C[C@H]3O[C@H]4[C@](C3=C2C)(C)[C@@H]([C@]2(C(=O)C=C[C@](C)([C@@H]2[C@H]4O)C(=O)OC)C)CC(=O)OC)C=COC=1 CTBHKOAPXBDFPX-PQYHCQQJSA-N 0.000 claims description 2
- RZXLPPRPEOUENN-UHFFFAOYSA-N Chlorfenson Chemical compound C1=CC(Cl)=CC=C1OS(=O)(=O)C1=CC=C(Cl)C=C1 RZXLPPRPEOUENN-UHFFFAOYSA-N 0.000 claims description 2
- NHYIETFMKIFXQL-VPEHNIDMSA-N Meliantriol Chemical compound CC(C)(O)[C@@H](O)[C@@H]1O[C@@H](O)C[C@@H]1[C@H]1[C@]2(C)CC[C@@H]3[C@@]4(C)CC[C@H](O)C(C)(C)[C@@H]4CC=C3[C@@]2(C)CC1 NHYIETFMKIFXQL-VPEHNIDMSA-N 0.000 claims description 2
- PFQPGZDVNHHXLR-UHFFFAOYSA-N Nimbandiol Natural products OC1C2C(C)(O)C=CC(=O)C2(C)C(CC(=O)OC)C(C2=C3C)(C)C1OC2CC3C=1C=COC=1 PFQPGZDVNHHXLR-UHFFFAOYSA-N 0.000 claims description 2
- 239000000642 acaricide Substances 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 229940077388 benzenesulfonate Drugs 0.000 claims description 2
- WMLLQNMCBDBSNU-YWHYXYIKSA-N chembl1774411 Chemical compound C=1([C@@H]2C[C@H]3O[C@H]4[C@](C3=C2C)(C)[C@@H]([C@]2(C(=O)C=C[C@@](C)(O)[C@@H]2[C@H]4OC(C)=O)C)C(=O)OC)C=COC=1 WMLLQNMCBDBSNU-YWHYXYIKSA-N 0.000 claims description 2
- 238000005097 cold rolling Methods 0.000 claims description 2
- 125000002592 cumenyl group Chemical group C1(=C(C=CC=C1)*)C(C)C 0.000 claims description 2
- CTBHKOAPXBDFPX-UHFFFAOYSA-N desacetyl nimbin Natural products OC1C2C(C)(C(=O)OC)C=CC(=O)C2(C)C(CC(=O)OC)C(C2=C3C)(C)C1OC2CC3C=1C=COC=1 CTBHKOAPXBDFPX-UHFFFAOYSA-N 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 235000021588 free fatty acids Nutrition 0.000 claims description 2
- 125000005456 glyceride group Chemical group 0.000 claims description 2
- IKJQENAHDRKFKL-JJDPDEBESA-N meliantriol Natural products CC(C)(O)[C@@H](O)[C@H]1C[C@H]([C@H](O)O1)[C@@H]1CC[C@]2(C)C3=CC[C@H]4C(C)(C)[C@@H](O)CC[C@]4(C)[C@H]3CC[C@@]12C IKJQENAHDRKFKL-JJDPDEBESA-N 0.000 claims description 2
- QRZJOCOUPAQCQQ-JFDUINIKSA-N nimbandiol Chemical compound C=1([C@@H]2C[C@@H]3O[C@H]4[C@](C3=C2C)(C)[C@@H]([C@@]2(C(=O)C=C[C@@](C)(O)[C@@H]2[C@H]4O)C)C(=O)OC)C=COC=1 QRZJOCOUPAQCQQ-JFDUINIKSA-N 0.000 claims description 2
- CJHBVBNPNXOWBA-REXVOHEDSA-N salannin Chemical compound C=1([C@@H]2C[C@H]3O[C@H]4[C@](C3=C2C)(C)[C@@H]([C@]2(C)[C@@H]3[C@]([C@@H](C[C@@H]2OC(=O)C(\C)=C\C)OC(C)=O)(C)CO[C@H]34)CC(=O)OC)C=COC=1 CJHBVBNPNXOWBA-REXVOHEDSA-N 0.000 claims description 2
- IWERWMCSIQZTFD-UHFFFAOYSA-N salannin Natural products COC(=O)CC1C2(C)C(CC(OC(=O)C)C3(C)COC(C4OC5C(CC(=C5C14C)C)c6cocc6)C23)OC(=O)C(=CC)C IWERWMCSIQZTFD-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 231100000053 low toxicity Toxicity 0.000 abstract description 7
- 241000196324 Embryophyta Species 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- RGNPBRKPHBKNKX-UHFFFAOYSA-N hexaflumuron Chemical compound C1=C(Cl)C(OC(F)(F)C(F)F)=C(Cl)C=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F RGNPBRKPHBKNKX-UHFFFAOYSA-N 0.000 abstract description 3
- 230000000361 pesticidal effect Effects 0.000 abstract 4
- 230000000903 blocking effect Effects 0.000 abstract 1
- 239000000306 component Substances 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 18
- 241000238631 Hexapoda Species 0.000 description 11
- 231100000419 toxicity Toxicity 0.000 description 7
- 230000001988 toxicity Effects 0.000 description 7
- 230000000749 insecticidal effect Effects 0.000 description 6
- 229940079593 drug Drugs 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 241001124076 Aphididae Species 0.000 description 4
- 241001465754 Metazoa Species 0.000 description 4
- 241000607479 Yersinia pestis Species 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- 210000002784 stomach Anatomy 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 3
- 231100000225 lethality Toxicity 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- 241000256844 Apis mellifera Species 0.000 description 2
- 241000254173 Coleoptera Species 0.000 description 2
- 241000255925 Diptera Species 0.000 description 2
- 241000255777 Lepidoptera Species 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000003151 ovacidal effect Effects 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 241000254127 Bemisia tabaci Species 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- HRYILSDLIGTCOP-UHFFFAOYSA-N N-benzoylurea Chemical class NC(=O)NC(=O)C1=CC=CC=C1 HRYILSDLIGTCOP-UHFFFAOYSA-N 0.000 description 1
- -1 Nitromethylene compounds Chemical class 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 241000176086 Sogatella furcifera Species 0.000 description 1
- 241001454294 Tetranychus Species 0.000 description 1
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 1
- 230000000895 acaricidal effect Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000017448 oviposition Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 150000003233 pyrroles Chemical class 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The re-compounded pesticide is compounded with plant originated neem oil as synergist, acetamiprid, imidacloprid, hexaflumuron and chlorfenapyr as effective pesticidal components, surfactant, stabilizer, organic solvent, etc. Neem oil contains nimbin, amaroid and other pesticidal components and has also the effect of blocking epidermal air hole; and all of acetamiprid, imidacloprid, hexaflumuron and chlorfenapyr are efficient and low-toxicity pesticides. The composition of Neem oil and other effective pesticidal components has obvious pesticidal synergistic effect and less resistance, and the re-compounded pesticide has high efficiency, low toxicity, low residue and no pollution to agricultural product and environment.
Description
Technical field the invention belongs to a kind of mixed insecticide, relates to formulation of pesticide and preparation technique.
Background technology is because the human long-term insecticide that relies on single type, insect is easy to generate pesticide resistance, causes the chemical insecticide consumption sharply to increase, and not only increases the weight of peasant's financial burden, and can cause environment and pollution of agricultural products, have a large amount of mixed insecticides in the market, but great majority are big to the person poultry toxicity for being mixed between the chemical pesticide, easily cause pollution, and after long-time the use, insect also is easy to generate pesticide resistance.
Acetamiprid (acetamiprid) is a pyridine compounds and their, is a kind of novel pesticide.It except have tag and stomach poison function, also have stronger osmosis, and show quick-acting insecticidal powers, the lasting period is long, can reach about 20 days.This product is to the people, animal low toxicity, and is little to natural enemy lethality, lower to fish toxicity, little to the honeybee influence, be applicable to the control fruit tree, the Semiptera insect makes soil treatment with granule on the vegetables, can prevent and treat soil insect, at present, be used to prevent and treat aphid on the various crops in China.Imidacloprid (imidacloprid) is the Nitromethylene compounds, is a kind of novel pesticide.It has tag, stomach toxicity and systemic action, little to the people, animal low toxicity to natural enemy lethality, lower to fish toxicity, little to the honeybee influence, be applicable to control Semiptera, coleoptera, diptera and lepidoptera pest.At present, be used to prevent and treat aphid on the various crops, Trialeurodes vaporariorum Westwood, rice fulgorid etc. in China.
Fluorine bell urea (hexaflumuron) is a process for preparation of benzoylurea compounds, is chitin synthesis inhibitor, has very high desinsection and ovicidal activity, can prevent and treat coleoptera, diptera, Homoptera and lepidoptera pest.This product belongs to the environmental type agricultural chemicals to the people, animal low toxicity.
Chlorfenapyr (chlorfenapyr) is a kind of new pyrrole class Insecticidal and acaricidal agent, various pests is had tag and stomach poison function, and is little to natural enemy lethality to the people, animal low toxicity to crop safety, belongs to the environmental type agricultural chemicals.
More than several agricultural chemicals because long-term single use, very fast generation resistance, the peasant has to increase working concentration and access times, having increased control cost and pest resistance to insecticide further increases.
Neem oil is the vegetable oil that seal chinaberry seed obtains by cold rolling lixiviate, itself removes to contain glyceride (80-95%), outside free fatty acid (4-20%) and small amounts of inorganic and the organic salt, also contains pesticide and miticide actility composition bitter principle nimbin (C
30H
36O
9Molecular weight 540), salannin (C
34H
44O
9Molecular weight 596), meliantriol (C
30H
50O
5Molecular weight 490) and a small amount of nimbandiol (C
26H
32O
7Molecular weight 456), desacetylsalannin (C
32H
42O
8Molecular weight 554), desacetylnimbin (C
28H
34O
8Molecular weight 498), 6-acetylnimbandiol (C
28H
34O
8Molecular weight 498) and nimbin A (C
32H
40O
11Molecular weight 600) etc., according to international latest report, these active ingredients can be prevented and treated 413 kinds of insects.Its mechanism of action is different from the chemical pesticide of conventional organic synthesis.Seal chinaberry compound is by food refusal, walks quickly and keeps away, stop the children (if) worm casts off a skin and grows, walks quickly and keeps away and reduces the adult egg laying amount, also there are certain tagging, stomach toxicity and ovicidal action the while.The same with mineral oil with other vegetable oil, neem oil also has the effect that insect and mite class pore make insect be choked to death of stopping up.Neem oil is as a vegetable oil, from nature, has good compatibility with natural environment, toxicity is low, be difficult for causing environment and pollution of agricultural products, insect is not easy again to develop immunity to drugs, and mixed pesticide such as itself and Acetamiprid, Imidacloprid, fluorine bell urea, chlorfenapyr has significant synergies to insect, the objective of the invention is to develop a class with plant resource composition neem oil as synergist, be the insecticide of insecticidal active ingredient with Acetamiprid etc.
Summary of the invention the present invention be with plant resource composition neem oil as synergist, be the insecticide of insecticidal active ingredient with Acetamiprid, Imidacloprid, fluorine bell urea, chlorfenapyr.
The present invention utilizes neem oil to be synergist, is that main active ingredient is mixed with Acetamiprid, Imidacloprid, fluorine bell urea, chlorfenapyr respectively, and allocates appropriate amount of addition agent into and be prepared into the compounded pesticides cream preparation.
Each component content proportioning (weight) is in the compounded pesticides cream preparation: neem oil content is 10-60%; Acetamiprid (or Imidacloprid or fluorine bell urea or chlorfenapyr) content is 2.5-20%; Surface-active contents is 10%; Stabiliser content is 0.5-5.0%; Remaining is organic solvent.
Wherein surface active agent composition is to be selected from: the polyethenoxy ether class of nonionic, as benzylphenol APEO, phenethyl cumenyl phenol polyethenoxy ether, the alkyl benzene sulfonate of anionic is as in alkyl benzene calcium sulfonate, the phenethyl phenolic ether sulfonate one or more; Stabilizer component is to be selected from: 2, and 6-di-t-butyl Pyrogentisinic Acid; The organic solvent component is to be selected from: one or more in dimethylbenzene, dimethyl formamide, the acetone.
Each composition optimal proportion (weight) is in the compounded pesticides cream preparation: neem oil content is 20-40%; Acetamiprid (or Imidacloprid or fluorine bell urea or chlorfenapyr) content is 2.5-5%; Surface-active contents is 10%; Stabiliser content is 2.5%; Remaining is organic solvent.
The compounded pesticides cream preparation adopts conventional farm chemical emulsion preparation processing technology to get final product in preparation process.
Compare with prior art, the present invention has following advantage and good effect:
1, both are composite has significant synergies to insect.
2, efficient, low toxicity, low-residual do not pollute agricultural product and environment.
3, insecticidal spectrum is wide, and insect is not easy to produce resistance.
Embodiment compounded pesticides cream preparation is to be active insecticidal components by neem oil and Acetamiprid, Imidacloprid, fluorine bell urea, chlorfenapyr.Be equipped with surfactant, stabilizing agent, organic solvent etc. again.Improve retention rate and the osmosis of medicament on crop and polypide, thereby improve control efficiency.The inventor uses the neem oil of different content allocation plan and Acetamiprid, Imidacloprid, fluorine bell urea, chlorfenapyr and other auxiliary agent vegetable aphid etc. has been carried out Toxicity Determination test and field biological effect small plot experiment.
In order to understand essence of an invention better, describe the technology contents of invention below in detail with example, but content of the present invention is not limited thereto.
Embodiment one: produce 30% compounded pesticides cream preparation
Neem oil 10% (weight)
Acetamiprid 20% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment two: produce 30% compounded pesticides cream preparation
Neem oil 25% (weight)
Acetamiprid 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment three: produce 40% compounded pesticides cream preparation
Neem oil 35% (weight)
Acetamiprid 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment four: produce 50% compounded pesticides cream preparation
Neem oil 47% (weight)
Acetamiprid 3% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment five: produce 62.5% compounded pesticides cream preparation
Neem oil 60% (weight)
Acetamiprid 2.5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment six: produce 30% compounded pesticides cream preparation
Neem oil 10% (weight)
Imidacloprid 20% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment seven: produce 30% compounded pesticides cream preparation
Neem oil 25% (weight)
Imidacloprid 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment eight: produce 40% compounded pesticides cream preparation
Neem oil 35% (weight)
Imidacloprid 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment nine: produce 50% compounded pesticides cream preparation
Neem oil 47% (weight)
Imidacloprid 3% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment ten: produce 62.5% compounded pesticides cream preparation
Neem oil 60% (weight)
Imidacloprid 2.5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 11: produce 30% compounded pesticides cream preparation
Neem oil 10% (weight)
Fluorine bell urea 20% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 12: produce 30% compounded pesticides cream preparation
Neem oil 25% (weight)
Fluorine bell urea 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 13: produce 40% compounded pesticides cream preparation
Neem oil 35% (weight)
Fluorine bell urea 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 14: produce 50% compounded pesticides cream preparation
Neem oil 47% (weight)
Fluorine bell urea 3% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Dimethyl formamide 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 15: produce 62.5% compounded pesticides cream preparation
Neem oil 60% (weight)
Fluorine bell urea 2.5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Acetone 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 16: produce 30% compounded pesticides cream preparation
Neem oil 10% (weight)
Chlorfenapyr 20% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Acetone 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 17: produce 30% compounded pesticides cream preparation
Neem oil 25% (weight)
Chlorfenapyr 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Acetone 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 18: produce 40% compounded pesticides cream preparation
Neem oil 35% (weight)
Chlorfenapyr 5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Acetone 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 19: produce 50% compounded pesticides cream preparation
Neem oil 47% (weight)
Chlorfenapyr 3% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Acetone 5% (weight)
Dimethylbenzene remainder (weight)
Embodiment 20: produce 62.5% compounded pesticides cream preparation
Neem oil 60% (weight)
Chlorfenapyr 2.5% (weight)
Benzylphenol APEO 5% (weight)
Alkyl benzene calcium sulfonate 5% (weight)
2,6-di-t-butyl Pyrogentisinic Acid 2.5% (weight)
Acetone 5% (weight)
Dimethylbenzene remainder (weight)
Preparation of the present invention (embodiment four) is to the control efficiency of vegetable aphid:
| Medicament | Working concentration | Proofread and correct preventive effect (%) | ||
| Behind the medicine 1 day | Behind the medicine 3 days | Medicine 7 days | ||
| Embodiment four | 2000 times | ????96.8 | ????100 | ????100 |
| Embodiment four | 2500 times | ????93.5 | ????98.2 | ????97.4 |
| Embodiment four | 3000 times | ????90.5 | ????97.3 | ????95.6 |
More than handle crop safety.
Preparation of the present invention (embodiment eight) is to the control efficiency of Bemisia tabaci:
| Medicament | Working concentration | Proofread and correct preventive effect (%) | ||
| Behind the medicine 1 day | Behind the medicine 3 days | Medicine 7 days | ||
| Embodiment eight | 2000 times | ????95.8 | ????96.8 | ????97.0 |
| Embodiment eight | 2500 times | ????93.5 | ????94.2 | ????95.4 |
| Embodiment eight | 3000 times | ????90.5 | ????91.3 | ????92.5 |
More than handle crop safety.
Preparation of the present invention (embodiment 14) is to the control efficiency of diamond-back moth:
| Medicament | Working concentration | Proofread and correct preventive effect (%) | ||
| Behind the medicine 1 day | Behind the medicine 3 days | Medicine 7 days | ||
| Embodiment 14 | 1000 times | ????73.8 | ????85.5 | ????93.5 |
| Embodiment 14 | 1500 times | ????65.5 | ????82.5 | ????90.4 |
| Embodiment 14 | 2000 times | ????60.5 | ????77.3 | ????85.6 |
More than handle crop safety.
Preparation of the present invention (embodiment 18) is to the control efficiency of apple tetranychus:
| Medicament | Working concentration | Proofread and correct preventive effect (%) | ||
| Behind the medicine 1 day | Behind the medicine 3 days | Medicine 7 days | ||
| Embodiment 18 | 2000 times | 85.8 | ????95.2 | ????98.5 |
| Embodiment 18 | 2500 times | 73.5 | ????90.2 | ????95.4 |
| Embodiment 18 | 3000 times | 65.5 | ????86.3 | ????88.6 |
More than handle crop safety.
Claims (4)
1. a class is the compounded pesticides cream preparation of synergist with the neem oil, and it is characterized in that each component content proportioning (weight) is in the compounded pesticides cream preparation: neem oil content is 10-60%; Acetamiprid (or Imidacloprid or fluorine bell urea or chlorfenapyr) content is 2.5-20%; Surface-active contents is 10%; Stabiliser content is 0.5-5.0%; Remaining is organic solvent.
2. neem oil according to claim 1 is the vegetable oil that is obtained by cold rolling lixiviate by the seed that prints chinaberry, itself remove and contain glyceride (80-95%), outside free fatty acid (4-20%) and small amounts of inorganic and the organic salt, also contain pesticide and miticide actility composition bitter principle nimbin (C
30H
36O
9Molecular weight 540), salannin (C
34H
44O
9Molecular weight 596), meliantriol (C
30H
50O
5Molecular weight 490) and a small amount of nimbandiol (C
26H
32O
7Molecular weight 456), desacetylsalannin (C
32H
42O
8Molecular weight 554), desacetylnimbin (C
28H
34O
8Molecular weight 498), 6-acetylnimbandiol (C
28H
34O
8Molecular weight 498) and nimbin A (C
32H
40O
11Molecular weight 600) etc.
3. surface active agent composition according to claim 1 is to be selected from: the polyethenoxy ether class of nonionic, as benzylphenol APEO, phenethyl cumenyl phenol polyethenoxy ether, the alkyl benzene sulfonate of anionic is as in alkyl benzene calcium sulfonate, the phenethyl phenolic ether sulfonate one or more; Stabilizer component is to be selected from: 2, and 6-di-t-butyl Pyrogentisinic Acid; The organic solvent component is to be selected from: one or more in dimethylbenzene, dimethyl formamide, the acetone.
4. each composition optimal proportion (weight) is in the compounded pesticides cream preparation according to claim 1: neem oil content is 20-40%; Acetamiprid (or Imidacloprid or fluorine bell urea or chlorfenapyr) content is 2.5-5%; Surface-active contents is 10%; Stabiliser content is 2.5%; Remaining is organic solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2004100234640A CN1557160A (en) | 2004-02-09 | 2004-02-09 | Mixed insecticide missible oil formulation with neem oil as synergist |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2004100234640A CN1557160A (en) | 2004-02-09 | 2004-02-09 | Mixed insecticide missible oil formulation with neem oil as synergist |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1557160A true CN1557160A (en) | 2004-12-29 |
Family
ID=34352147
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2004100234640A Pending CN1557160A (en) | 2004-02-09 | 2004-02-09 | Mixed insecticide missible oil formulation with neem oil as synergist |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1557160A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101228878B (en) * | 2007-01-25 | 2010-09-22 | 青岛海利尔药业有限公司 | An insecticidal composition containing chlorfenapyr and hexaflumuron |
| CN106332919A (en) * | 2016-08-27 | 2017-01-18 | 梁小萍 | Pesticide for preventing Arbela dea and preparing method thereof |
| CN106332911A (en) * | 2016-08-27 | 2017-01-18 | 梁小萍 | Pesticide for preventing litchi geometrid moths and preparing method thereof |
| CN106332918A (en) * | 2016-08-27 | 2017-01-18 | 梁小萍 | Pesticide for preventing olethreutes leucaspis meyrick in litchi and preparing method thereof |
| CN106342935A (en) * | 2016-08-27 | 2017-01-25 | 梁小萍 | Pesticide for preventing and treating litchi spotted cerambycid and preparation method thereof |
| CN106342936A (en) * | 2016-08-27 | 2017-01-25 | 梁小萍 | Pesticide for preventing and treating Oligonychus litchii and preparation method thereof |
| CN106417289A (en) * | 2016-08-27 | 2017-02-22 | 梁小萍 | Pesticide for preventing and controlling litchi whiteflies and preparation method thereof |
| CN106417288A (en) * | 2016-08-27 | 2017-02-22 | 卢婷 | Conopomorpha litchielle bradly control pesticide and preparation method thereof |
| CN106417285A (en) * | 2016-08-27 | 2017-02-22 | 梁小萍 | Pesticide for control of lichee lump gall mite and preparation method thereof |
| CN106465714A (en) * | 2016-08-27 | 2017-03-01 | 梁小萍 | A kind of pesticide of preventing and treating Sphecosesia litchivora and preparation method thereof |
| CN108094426A (en) * | 2017-12-01 | 2018-06-01 | 陕西日日新生物科技有限公司 | A kind of plant source type pesticide synergistic agent and preparation method thereof |
| CN113796374A (en) * | 2021-01-27 | 2021-12-17 | 仲恺农业工程学院 | Pesticide containing neem oil special for flight control and preparation method thereof |
| US11779022B2 (en) * | 2017-12-27 | 2023-10-10 | Mclaughlin Gormley King Company | Mixtures of sabadilla alkaloids and neem oil and uses thereof |
-
2004
- 2004-02-09 CN CNA2004100234640A patent/CN1557160A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101228878B (en) * | 2007-01-25 | 2010-09-22 | 青岛海利尔药业有限公司 | An insecticidal composition containing chlorfenapyr and hexaflumuron |
| CN106417289A (en) * | 2016-08-27 | 2017-02-22 | 梁小萍 | Pesticide for preventing and controlling litchi whiteflies and preparation method thereof |
| CN106332911A (en) * | 2016-08-27 | 2017-01-18 | 梁小萍 | Pesticide for preventing litchi geometrid moths and preparing method thereof |
| CN106332918A (en) * | 2016-08-27 | 2017-01-18 | 梁小萍 | Pesticide for preventing olethreutes leucaspis meyrick in litchi and preparing method thereof |
| CN106342935A (en) * | 2016-08-27 | 2017-01-25 | 梁小萍 | Pesticide for preventing and treating litchi spotted cerambycid and preparation method thereof |
| CN106342936A (en) * | 2016-08-27 | 2017-01-25 | 梁小萍 | Pesticide for preventing and treating Oligonychus litchii and preparation method thereof |
| CN106332919A (en) * | 2016-08-27 | 2017-01-18 | 梁小萍 | Pesticide for preventing Arbela dea and preparing method thereof |
| CN106417288A (en) * | 2016-08-27 | 2017-02-22 | 卢婷 | Conopomorpha litchielle bradly control pesticide and preparation method thereof |
| CN106417285A (en) * | 2016-08-27 | 2017-02-22 | 梁小萍 | Pesticide for control of lichee lump gall mite and preparation method thereof |
| CN106465714A (en) * | 2016-08-27 | 2017-03-01 | 梁小萍 | A kind of pesticide of preventing and treating Sphecosesia litchivora and preparation method thereof |
| CN108094426A (en) * | 2017-12-01 | 2018-06-01 | 陕西日日新生物科技有限公司 | A kind of plant source type pesticide synergistic agent and preparation method thereof |
| US11779022B2 (en) * | 2017-12-27 | 2023-10-10 | Mclaughlin Gormley King Company | Mixtures of sabadilla alkaloids and neem oil and uses thereof |
| CN113796374A (en) * | 2021-01-27 | 2021-12-17 | 仲恺农业工程学院 | Pesticide containing neem oil special for flight control and preparation method thereof |
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