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CN1330786C - Strength of extension 780 MPa grade complex phase steel plate and mfg. method thereof - Google Patents

Strength of extension 780 MPa grade complex phase steel plate and mfg. method thereof Download PDF

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CN1330786C
CN1330786C CNB200510130899XA CN200510130899A CN1330786C CN 1330786 C CN1330786 C CN 1330786C CN B200510130899X A CNB200510130899X A CN B200510130899XA CN 200510130899 A CN200510130899 A CN 200510130899A CN 1330786 C CN1330786 C CN 1330786C
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steel plate
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strength
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CN1793401A (en
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刘彦春
王国栋
刘相华
李艳梅
朱伏先
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Northeastern University China
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Abstract

The present invention relates to a complex phase steel plate with the tensile strength of 780MPa, which comprises the chemical constituents of the weight percent: 0.13 to 0.17% of C, 0.20 to 0.40% of Si, 1.30 to 1.50% of Mn, 0.02 to 0.03% of Nb and Fe as the rest. The complex phase steel plate has a complex phase structure of granular bainite and martensite, wherein the volume ratio of granular bainite is from 90 to 95%, and the volume ratio of martensite is from 10 to 5%. The yield strength is from 525 to 550MPa, the tensile strength is from 785 to 795MPa, and the total elongation percentage after fracture is from 20 to 25%. Rolling and cooling control technology is utilized for rolling, the initial rolling temperature is controlled to be from 1100 to 1150 DEG C, and the finish rolling temperature is from 800 to 850 DEG C. The cooling speed of the first section is controlled to be from 40 to 70 DEG C/s, and the temperature after cooling is from 550 to 610 DEG C. The cooling speed of the second section is from 220 to 360 DEG C/s, and the coiling temperature is from 20 to 250 DEG C. After being cooled, the steel plate is coiled, and the thickness of the steel plate is controlled to be from 3 to 4.5mm.

Description

一种抗拉强度780MPa级复相钢板及制造方法A composite steel plate with a tensile strength of 780MPa and its manufacturing method

技术领域technical field

本发明属于轧钢技术领域,涉及汽车结构件的高强度钢制造,具体涉及一种抗拉强度780MPa级复相钢板及制造方法。The invention belongs to the technical field of steel rolling, and relates to the manufacture of high-strength steel for automotive structural parts, in particular to a multiphase steel plate with a tensile strength of 780MPa and a manufacturing method.

背景技术Background technique

高强度汽车用热轧钢板的开发,一直是国内外材料工作研究的热点之一。一般使用的铁素体+珠光体热轧钢板最大强度为500MPa级,虽然增加Nb或Ti等微合金化元素可进一步提高强度,但成形性将变差,因而限制了其应用。为进一步提高强度,开发了双相钢。双相高强度钢特点是在细小的铁素体基体上分布约15%硬相,并通过固溶原子进一步强化,铁素体-贝氏体和双相铁素体-马氏体钢的抗拉强度在550~650MPa之间。由于成形性的限制,双相钢无法达到800MPa级水平。为满足更高强度及成形性能的要求,又开发了含残余奥氏体的800MPa级三相TRIP钢,在变形过程中残余奥氏体应变诱发转变为马氏体,在提高强度的同时,提高成形性能。但目前可商业化生产的直接热轧双相钢与TRIP钢都采用复杂合金化的办法,存在成本高、工艺难度大等问题,不利于推广,国内尚不能大规模生产。The development of high-strength hot-rolled steel sheets for automobiles has always been one of the hot spots in the research of materials work at home and abroad. Generally used ferrite + pearlite hot-rolled steel plate has a maximum strength of 500MPa. Although adding microalloying elements such as Nb or Ti can further increase the strength, the formability will deteriorate, thus limiting its application. To further increase strength, dual phase steels have been developed. The characteristic of dual-phase high-strength steel is that about 15% of the hard phase is distributed on the fine ferrite matrix, and it is further strengthened by solid solution atoms. The resistance of ferrite-bainite and dual-phase ferrite-martensitic steel The tensile strength is between 550-650MPa. Due to the limitation of formability, dual-phase steel cannot reach the 800MPa level. In order to meet the requirements of higher strength and formability, the 800MPa three-phase TRIP steel containing retained austenite was developed. During the deformation process, the residual austenite strain-induced transformation into martensite, which improves the strength while improving Formability. However, the direct hot-rolled dual-phase steel and TRIP steel that can be commercially produced at present all use complex alloying methods, which have problems such as high cost and difficult process, which is not conducive to promotion, and large-scale production is not yet possible in China.

考虑到环境问题和能源问题,新型的高强度汽车结构件用热轧钢板的化学成分将趋向于简单的C-Si-Mn系钢(或添加微量的合金元素);开发控轧及控冷新工艺,综合利用细晶强化和相变强化方式提高钢材强度极限。Considering environmental issues and energy issues, the chemical composition of new high-strength automotive structural parts hot-rolled steel plates will tend to be simple C-Si-Mn series steel (or add trace alloy elements); develop controlled rolling and controlled cooling new Technology, comprehensive use of fine grain strengthening and phase transformation strengthening methods to improve the strength limit of steel.

发明内容Contents of the invention

针对现有高强度汽车用热轧钢板及其生产工艺存在的问题,本发明提供一种抗拉强度780MPa级复相钢板及制造方法。Aiming at the problems existing in the existing high-strength automobile hot-rolled steel plate and its production process, the invention provides a multi-phase steel plate with a tensile strength of 780MPa and a manufacturing method.

本发明以普通C-Mn系钢成分为基础,添加微量合金元素,采用适当的控制冷却工艺,开发高强度汽车结构件用热轧钢板。该抗拉强度780MPa级粒状贝氏体与马氏体复相钢板,其主要化学成分按质量百分数为:0.13~0.17%C、0.20~0.40%Si、1.30~1.50%Mn,0.02~0.03%Nb,余量为Fe。组织为粒状贝氏体与马氏体复相组织,其中:粒状贝氏体体积分数为90~95%,马氏体体积分数为10~5%;屈服强度为525~550MPa,抗拉强度为785~795MPa,断后总伸长率为20~25%。The invention is based on the composition of common C-Mn series steel, adds trace alloy elements, adopts appropriate controlled cooling process, and develops hot-rolled steel plate for high-strength automobile structural parts. The tensile strength 780MPa grade granular bainite and martensitic composite steel plate, its main chemical composition is: 0.13-0.17% C, 0.20-0.40% Si, 1.30-1.50% Mn, 0.02-0.03% Nb , the balance being Fe. The structure is a composite structure of granular bainite and martensite, in which: the volume fraction of granular bainite is 90-95%, the volume fraction of martensite is 10-5%; the yield strength is 525-550MPa, and the tensile strength is 785~795MPa, the total elongation after breaking is 20~25%.

本发明采用上述化学成分的、厚度为80~250mm的钢坯,通过热轧及两段快速冷却工艺生产抗拉强度780MPa级复相钢板,具体按以下步骤进行:The present invention adopts steel slabs with the above-mentioned chemical composition and a thickness of 80 to 250 mm to produce a multi-phase steel plate with a tensile strength of 780 MPa through hot rolling and two-stage rapid cooling processes, specifically according to the following steps:

(1)将钢坯加热至1150~1250℃,保温2~2.5小时。(1) Heat the billet to 1150-1250°C and keep it warm for 2-2.5 hours.

(2)保温后进行热轧,控制开轧温度1100~1150℃,终轧温度800~850℃。(2) Hot rolling is carried out after heat preservation, the temperature of starting rolling is controlled at 1100-1150°C, and the temperature of finishing rolling is 800-850°C.

(3)热轧后进行两段式控制冷却,控制第-段冷却速度40~70℃/s,冷却后温度550~610℃;第二段冷却速度220~360℃/s,终冷温度(即卷取温度)20~250℃。(3) Two-stage controlled cooling is carried out after hot rolling, the cooling rate of the first stage is controlled at 40-70°C/s, and the temperature after cooling is 550-610°C; the cooling rate of the second stage is 220-360°C/s, and the final cooling temperature ( Namely coiling temperature) 20 ~ 250 ℃.

(4)冷却后进行卷取,卷取温度20~250℃,控制钢板厚度3~4.5mm。(4) Coil after cooling, the coiling temperature is 20-250°C, and the thickness of the steel plate is controlled to be 3-4.5mm.

本发明对于抗拉强度780MPa级热轧钢板提供了一种新的组织状态,即:粒状贝氏体与马氏体复相组织。其中:粒状贝氏体体积分数为90~95%,马氏体体积分数为10~5%。屈服强度为525~550MPa,抗拉强度为785~795MPa,断后总伸长率为20~25%,具有可观的强度和塑性综合性能。The invention provides a new structure state for the hot-rolled steel plate with a tensile strength of 780MPa, that is, the composite phase structure of granular bainite and martensite. Among them: the volume fraction of granular bainite is 90-95%, and the volume fraction of martensite is 10-5%. The yield strength is 525-550MPa, the tensile strength is 785-795MPa, the total elongation after breaking is 20-25%, and has considerable strength and plastic comprehensive properties.

附图说明Description of drawings

附图为本发明抗拉强度780MPa级粒状贝氏体与马氏体复相钢板典型金相组织照片。其中:(a)为硝酸酒精溶液腐蚀后组织照片;(b)为LEPERA试剂(1%Na2S2O5水溶液+4%苦味酸酒精溶液)腐蚀后组织照片,照片中亮白色组织为马氏体。The accompanying drawing is a photo of a typical metallographic structure of a granular bainite and martensitic composite steel plate with a tensile strength of 780 MPa in the present invention. Among them: (a) is the photo of the tissue corroded by nitric acid alcohol solution; (b) is the photo of the tissue corroded by LEPERA reagent (1% Na 2 S 2 O 5 aqueous solution + 4% picric acid alcohol solution), the bright white tissue in the photo is horse body.

具体实施方式Detailed ways

选择表1所示化学成分钢为原料,坯料尺寸为80mm(厚)×70mm(宽)×140mm(长)。在热轧轧机上,轧制成厚度规格为3~4.5mm的钢板,轧后采用两阶段快速冷却工艺,冷却工艺如表2,力学性能与组织分数如表3。Select the steel with the chemical composition shown in Table 1 as the raw material, and the blank size is 80mm (thickness) × 70mm (width) × 140mm (length). In the hot rolling mill, the steel plate with a thickness specification of 3-4.5 mm was rolled, and a two-stage rapid cooling process was adopted after rolling. The cooling process is shown in Table 2, and the mechanical properties and microstructure scores are shown in Table 3.

表1实施例实测化学成分(质量分数%,余量为Fe)Table 1 embodiment measured chemical composition (mass fraction %, balance is Fe)

    成分编号   Ingredient number     C C     Mn Mn     Si Si     Nb Nb     S0 S0     0.15 0.15     1.40 1.40     0.20 0.20     0.02 0.02     S1 S1     0.13 0.13     1.30 1.30     0.22 0.22     0.022 0.022     S2 S2     0.17 0.17     1.47 1.47     0.36 0.36     0.024 0.024     S4 S4     0.15 0.15     1.50 1.50     0.40 0.40     0.03 0.03

表2实施例实测冷却工艺参数Table 2 embodiment measured cooling process parameters

编号serial number 加热温度 heating temperature 保温时间 Holding time   开轧温度 Starting temperature 终轧温度 Finishing temperature 第一段冷却后温度 Temperature after the first stage of cooling 第一段冷却速度 The first cooling rate 终冷温度final cooling temperature   第二段冷却速度 The second cooling rate   (℃) (℃)     小时 Hour   (℃) (℃)   (℃) (℃)     (℃) (℃)     (℃/s) (℃/s)     (℃) (℃)     (℃/s) (℃/s)   S0-1 S0-1   1150 1150     2 2   1100 1100   825 825     560 560     60 60     200 200     330 330   S0-2 S0-2   1250 1250     2.5 2.5   1150 1150   830 830     580 580     65 65     170 170     345 345   S1-1 S1-1   1160 1160     2.2 2.2   1150 1150   850 850     610 610     40 40     250 250     360 360   S1-2 S1-2   1180 1180     2.3 2.3   1140 1140   835 835     590 590     49 49     150 150     220 220   S2-1 S2-1   1200 1200     2.1 2.1   1120 1120   815 815     575 575     70 70     85 85     245 245   S2-2 S2-2   1220 1220     2.4 2.4   1100 1100   800 800     550 550     50 50     20 20     265 265   S4-1 S4-1   1230 1230     2.5 2.5   1125 1125   840 840     585 585     55 55     50 50     250 250   S4-2 S4-2   1240 1240     2.5 2.5   1130 1130   820 820     570 570     45 45     120 120     300 300

表3实施例力学性能与组织体积分数Table 3 Example Mechanical Properties and Tissue Volume Fraction

编号serial number 钢板厚度Steel plate thickness Re Re Rm R m AA 体积分数 Volume fraction GBGB Mm     (mm) (mm) (MPa) (MPa) (MPa) (MPa)   (%) (%)   % %   % %   S1-1 S1-1     4.5 4.5 550 550 785 785   20 20   95 95   5 5   S1-2 S1-2     4.0 4.0 532 532 795 795   23 twenty three   90 90   10 10   S2-1 S2-1     3.0 3.0 525 525 790 790   24 twenty four   90 90   10 10   S2-2 S2-2     4.2 4.2 535 535 795 795   25 25   95 95   5 5

其中:Re-屈服强度;Rm-抗拉强度;A-断后总伸长率(不定标距);GB-粒状贝氏体;M-马氏体Among them: Re -yield strength; R m -tensile strength; A-total elongation after fracture (indefinite gauge length); GB-granular bainite; M-martensite

Claims (2)

1、一种抗拉强度780MPa级复相钢板,其化学成分按质量百分数为:0.13~0.17%C、0.20~0.40%Si、1.30~1.50%Mn、0.02~0.03%Nb,余量为Fe;组织为粒状贝氏体与马氏体复相组织,其中:粒状贝氏体体积分数为90~95%,马氏体体积分数为10~5%;钢板厚度规格3~4.5mm,屈服强度为525~550MPa,抗拉强度为785~795MPa,断后总伸长率为20~25%。1. A composite steel plate with a tensile strength of 780MPa, the chemical composition of which is: 0.13-0.17% C, 0.20-0.40% Si, 1.30-1.50% Mn, 0.02-0.03% Nb, and the balance is Fe; The structure is a composite structure of granular bainite and martensite, in which: the volume fraction of granular bainite is 90-95%, the volume fraction of martensite is 10-5%; the thickness of the steel plate is 3-4.5mm, and the yield strength is 525~550MPa, the tensile strength is 785~795MPa, and the total elongation after breaking is 20~25%. 2、权利要求1所述的抗拉强度780MPa级复相钢板的制造方法,其特征在于工艺步骤及工艺参数为:2. The method for manufacturing a composite steel plate with a tensile strength of 780 MPa as claimed in claim 1, characterized in that the process steps and process parameters are: (1)将权利要求1所述化学成分的钢坯加热至1150~1250℃,保温2~2.5小时;(1) heating the steel slab of chemical composition described in claim 1 to 1150~1250 ℃, heat preservation 2~2.5 hours; (2)保温后进行热轧,控制开轧温度1100~1150℃,终轧温度800~850℃;(2) Hot rolling is carried out after heat preservation, the starting rolling temperature is controlled at 1100-1150°C, and the final rolling temperature is 800-850°C; (3)热轧后进行两段式控制冷却,控制第一段冷却速度40~70℃/s,冷却后温度550~610℃;第二段冷却速度220~360℃/s,终冷温度即卷取温度20~250℃;(3) Two-stage controlled cooling is carried out after hot rolling, the cooling rate of the first stage is controlled at 40-70°C/s, and the temperature after cooling is 550-610°C; the cooling rate of the second stage is 220-360°C/s, and the final cooling temperature is Coiling temperature 20~250℃; (4)冷却后进行卷取,卷取温度20~250℃,控制钢板厚度3~4.5mm。(4) Coil after cooling, the coiling temperature is 20-250°C, and the thickness of the steel plate is controlled to be 3-4.5mm.
CNB200510130899XA 2005-12-27 2005-12-27 Strength of extension 780 MPa grade complex phase steel plate and mfg. method thereof Expired - Fee Related CN1330786C (en)

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CN105950984B (en) * 2016-05-06 2018-03-27 武汉钢铁有限公司 Tensile strength 650MPa level hot rolling Multiphase Steels and its production method
CN106591696B (en) * 2016-10-31 2018-03-06 首钢总公司 Hot rolled steel with excellent flanging performance and production method thereof
JP6521197B2 (en) * 2017-03-30 2019-05-29 Jfeスチール株式会社 High strength steel plate for sour line pipe, manufacturing method thereof and high strength steel pipe using high strength steel plate for sour line pipe
CN107557548B (en) * 2017-09-13 2019-01-22 天津商业大学 Microstructure control method of martensite + granular bainite multiphase strengthened low-alloy ultra-high strength steel

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