[go: up one dir, main page]

JP2000282175A - Ultra-high strength hot rolled steel sheet excellent in workability and method for producing the same - Google Patents

Ultra-high strength hot rolled steel sheet excellent in workability and method for producing the same

Info

Publication number
JP2000282175A
JP2000282175A JP9611099A JP9611099A JP2000282175A JP 2000282175 A JP2000282175 A JP 2000282175A JP 9611099 A JP9611099 A JP 9611099A JP 9611099 A JP9611099 A JP 9611099A JP 2000282175 A JP2000282175 A JP 2000282175A
Authority
JP
Japan
Prior art keywords
less
steel sheet
strength
workability
ultra
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9611099A
Other languages
Japanese (ja)
Inventor
Hidenao Kawabe
英尚 川辺
Akio Tosaka
章男 登坂
Osamu Furukimi
古君  修
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP9611099A priority Critical patent/JP2000282175A/en
Publication of JP2000282175A publication Critical patent/JP2000282175A/en
Pending legal-status Critical Current

Links

Landscapes

  • Heat Treatment Of Sheet Steel (AREA)

Abstract

(57)【要約】 (修正有) 【課題】 980 MPa以上の引張強度を達成するすとも
に、伸びフランジ性と強度延性バランスがともに優れ、
かつ低降伏比であるた、加工性に優れた超高強度熱延鋼
板およびその製造方法を提案する。 【解決手段】 C、Si、Mn、P、S、Nb、Ti、Cr、Al、
Ni、等を含有し、残部はFeからなり、この鋼スラブを連
続鋳造後、直ちに又は一旦冷却して、1100〜1300℃に加
熱したのち、仕上げ圧延終了温度 950〜800 ℃にて熱間
圧延し、圧延終了後 0.5秒以内に冷却を開始して、30℃
/sec 以上の冷却速度で冷却を行い、500 〜300 ℃で巻
取ることにより、体積分率で60〜90%未満のベイナイト
を主相、パーライト、フェライト、残留オーステナイ
ト、マルテンサイトのうちの少なくとも1種を第2相と
し、しかもベイナイト相の平均粒径を4μm未満とした
金属組織になす。
(57) [Summary] (Modified) [Problem] While achieving a tensile strength of 980 MPa or more, both stretch flangeability and strength-ductility balance are excellent.
An ultra-high-strength hot-rolled steel sheet having a low yield ratio and excellent workability and a method for producing the same are proposed. SOLUTION: C, Si, Mn, P, S, Nb, Ti, Cr, Al,
Ni, etc., the remainder is made of Fe.After continuous casting of this steel slab, immediately or once cooled and heated to 1100-1300 ° C, then hot-rolled at the finish rolling end temperature 950-800 ° C. Start cooling within 0.5 seconds after the end of rolling, and
By cooling at a cooling rate of at least 500 g / sec and winding at 500 to 300 ° C., bainite having a volume fraction of less than 60 to 90% is converted into at least one of the main phase, pearlite, ferrite, retained austenite, and martensite. The seed is used as the second phase and the bainite phase has a metal structure with an average particle size of less than 4 μm.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、自動車の耐衝突安
全性の向上を目的として使用される自動車部品、例えば
ドアインパクトビーム、バンパーなどに用いて好適な熱
延鋼板に関し、とくに引張強さTSが980 MPa 以上で、加
工性に優れる超高強度熱延鋼板およびその製造方法に関
するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hot-rolled steel sheet suitable for use in automobile parts, for example, door impact beams, bumpers, etc., used for the purpose of improving the collision safety of automobiles. The invention relates to an ultra-high strength hot-rolled steel sheet having a workability of not less than 980 MPa and excellent in workability and a method for producing the same.

【0002】[0002]

【従来の技術】最近、自動車の製造分野においては、車
体の軽量化を図り、しかも衝突時におけるキャビンの変
形を抑制し安全性を向上させるために、バンパーやイン
パクトビームなどの部品には高強度鋼板が使用されてき
ており、その強度もますます高強度化する傾向にある。
また、これら部品は、プレス成形、ロール成形、穴拡げ
加工、曲げ加工など種々の成形加工の工程を経て製造さ
れる。したがって、上記高強度鋼板には、これらの加工
性を具えた材料が必要となる。
2. Description of the Related Art In recent years, in the field of automobile manufacturing, parts such as bumpers and impact beams have been provided with high strength in order to reduce the weight of a vehicle body and to suppress deformation of a cabin during a collision to improve safety. Steel sheets have been used, and the strength of the steel sheets has been increasing.
These components are manufactured through various forming processes such as press forming, roll forming, hole expanding, and bending. Therefore, the high-strength steel plate requires a material having such workability.

【0003】ところで、鋼の強化機構には、従来から、
加工強化、組織強化、析出強化等が広く知られている。
しかし、これらの強化機構を利用すれば、鋼板の強度は
確保できるものの、一方で、加工性の低下を招くという
のが実情であった。具体的には、従来の高強度鋼板で
は、組織的不均一、硬質相と軟質相の局所的混在などの
ために、穴拡げ試験時に亀裂の起点となる場所が多数存
在することになり、これが穴拡げ性の低下を招いていた
のである。しかもこのような加工性は、高強度鋼になれ
ばなるほど、大きく低下するのが一般的であった。ま
た、低降伏比に最も有利と言われる組織強化を用いて
も、980 MPa 以上の強度では、十分低い降伏が得られ
なくなり、形状凍結性等に問題があった。このため、従
来の鋼板製造技術では、高強度化と引き替えに、延性、
曲げ性、伸びフランジ性、低降伏比などの加工特性を犠
牲にしなければならないのが実状であった。なお、加工
性を確保するために、熱処理によって組織の適正化を図
ることも考えられるが、そのためには例えば焼き戻し工
程等の調質処理を余分に付加しなければならず、必然的
にコスト上昇を招き採用の障害となっており、また、焼
戻し処理等によっては、降伏比が逆に低くなりすぎて強
度確保上好ましくない、という事態も生じる問題があっ
た。
[0003] By the way, the steel strengthening mechanism has conventionally been
Process strengthening, structure strengthening, precipitation strengthening and the like are widely known.
However, if these strengthening mechanisms are used, the strength of the steel sheet can be secured, but on the other hand, the workability is reduced. Specifically, in the conventional high-strength steel sheet, due to the structural nonuniformity, the local mixture of the hard phase and the soft phase, etc., there are many places where cracks start during the hole expansion test. This led to a decrease in hole expandability. Moreover, such workability generally decreases greatly as the strength of the steel increases. Further, even if the structure strengthening which is said to be most advantageous for the low yield ratio is used, if the strength is 980 MPa or more, a sufficiently low yield cannot be obtained, and there is a problem in shape freezing property and the like. For this reason, in the conventional steel plate manufacturing technology, ductility,
In fact, it was necessary to sacrifice processing characteristics such as bending property, stretch flangeability, and low yield ratio. In order to ensure workability, it is conceivable to optimize the structure by heat treatment. However, for this purpose, an extra tempering process such as a tempering process must be added, which inevitably results in cost reduction. However, there is a problem that the yield ratio may be too low depending on the tempering treatment or the like, which is not preferable for securing the strength.

【0004】高強度鋼板の技術として、例えば、特開平
5-105986号公報、特開昭60-181231号公報、特開昭50-15
06622号公報には、強度延性バランスが良好で、穴拡げ
性も優れた鋼板が開示されているが、これら開示技術に
おける引張強度は、いずれも980 MPaに満たないレベ
ルのものである。また特開平3-277742号公報および特開
平4-236741号公報には、引張強度980 MPa以上の鋼板
について開示されているが、穴拡げ率は低く、十分な加
工性を有するものであるとは言いがたい。
[0004] As a technique for high-strength steel sheets, for example, Japanese Patent Application Laid-Open
JP-A-5-105986, JP-A-60-181231, JP-A-50-15
Japanese Patent Application Laid-Open No. 06622 discloses a steel sheet having a good strength-ductility balance and excellent hole expandability, but the tensile strength in each of the disclosed techniques is at a level less than 980 MPa. Further, JP-A-3-277742 and JP-A-4-236741 disclose a steel sheet having a tensile strength of 980 MPa or more, but the hole expansion rate is low, and it is said that the steel sheet has sufficient workability. It's hard to say.

【0005】[0005]

【発明が解決しようとする課題】上述したように、強度
と加工性は相反する傾向を示すのが一般的であり、現状
では、伸びフランジ性をはじめとする良好な加工性を具
え、引張強度が980 MPa以上である超高張力鋼は知ら
れていない。また、かかる強度を具えた超高強度鋼板
は、ロール成形により所定の形状の製品に成形する際、
縁波、しわなどの成形不良を発生するという問題も抱え
ていた。本発明は、このような従来技術の問題を解決す
るための新規な熱延鋼板を提案するものであり、980 M
Pa以上の引張強度を達成するすともに、伸びフランジ
性と強度延性バランスがともに優れ、かつ低降伏比をも
具えた、加工性に優れた超高強度熱延鋼板およびその製
造方法を提案することにある。また、本発明が目指す目
標特性は、伸びフランジ性を表す指標として、TS×λ
(穴拡げ率)≧60000 MPa・%、強度延性バランスの
指標として、TS×El≧16000 MPa・%、また降伏
比YR:60〜70%とする。さらに、上記各材料特性に加
えて、薄鋼板をロール成形により所定の形状の製品に成
形する際に、縁波、しわなどの成形不良をも発生させな
い特性を持ち合わせることも目標とする。さらにまた、
本発明は、成形後における遅れ破壊が発生しないことを
目標の1つとする。
As described above, strength and workability generally show a tendency to contradict each other. At present, good workability such as stretch flangeability is provided, and tensile strength is high. There is no known ultra-high tensile steel having a 980 MPa or higher. In addition, when ultra-high strength steel sheet having such strength is formed into a product of a predetermined shape by roll forming,
There was also a problem that molding defects such as edge waves and wrinkles occurred. The present invention proposes a novel hot-rolled steel sheet to solve such problems of the prior art.
To provide an ultra-high-strength hot-rolled steel sheet excellent in workability that achieves a tensile strength of Pa or more, has excellent balance of stretch flangeability and strength-ductility, and also has a low yield ratio, and a method of manufacturing the same. It is in. The target characteristic aimed at by the present invention is TS × λ as an index indicating stretch flangeability.
(Hole expansion ratio) ≧ 60,000 MPa ·%, TS × El ≧ 16000 MPa ·% as an index of strength-ductility balance, and yield ratio YR: 60-70%. Furthermore, in addition to the above-mentioned respective material properties, it is also an object to provide a property that does not cause forming defects such as edge waves and wrinkles when a thin steel sheet is formed into a product having a predetermined shape by roll forming. Furthermore,
One of the objects of the present invention is to prevent the occurrence of delayed fracture after molding.

【0006】[0006]

【課題を解決するための手段】発明者らは、上記の目的
を達成すべく、鋼成分、製造条件、金属組織などの面か
ら鋭意実験を行い検討を重ねた。その結果、成分と製造
条件を適正範囲に制御して、組織を微細化するととも
に、体積分率を管理したベイナイト主体の組織とするこ
とにより、加工時のわれ発生起点が減少し、強度レベル
を低下させることなく、従来にはない優れた伸びフラン
ジ性と、高い強度延性バランスを付与でき、また降伏比
YR:60%〜70%を満たすことが可能となり、プレス成
形の改善がはかられ、波及的にロール成形における縁
波、しわ等の成形不良をも防止できることを知見した。
また同時に、かかる手段を採用することにより、遅れ破
壊等を発生することがなくなり、加工後部品の信頼性を
高めることも可能であることがわかった。
Means for Solving the Problems In order to achieve the above object, the present inventors have conducted intensive experiments from the viewpoints of steel composition, production conditions, metal structure and the like, and have repeated studies. As a result, by controlling the components and manufacturing conditions within the appropriate ranges, the structure is refined, and the bainite-based structure with controlled volume fraction reduces the origin of cracking during processing and reduces the strength level. Without lowering, it is possible to provide an excellent stretch flangeability and a high strength-ductility balance, which have not been achieved before, and it is possible to satisfy the yield ratio YR: 60% to 70%. It has been found that it is also possible to prevent forming defects such as edge waves and wrinkles in roll forming.
At the same time, it has been found that by employing such means, delayed fracture or the like does not occur, and the reliability of the processed part can be improved.

【0007】本発明はこのような知見に基づいて完成さ
れたものであり、その要旨とするところは次のとおりで
ある。 (1) C:0.05〜0.20wt%、Si:0.05〜0.50wt%、Mn:
1.0 〜3.5 wt%、P:0.05wt%以下、S:0.01wt%以
下、Nb:0.005 〜0.30wt%、Ti:0.001 〜0.100 wt%、
Cr:0.01〜1.0 wt%およびAl:0.1 wt%以下を含有し、
残部はFeおよび不可避的不純物の組成からなり、かつ上
記Si、P、Cr、Ti、NbおよびMnの各含有量は次式: 0.05≦((wt%)Si + (wt%) P) /((wt%)Cr + (wt
%)Ti + (wt%)Nb + (wt%)Mn)≦0.5 の関係を満たして含有し、金属組織が、体積分率で60〜
90%未満のベイナイトを主相とし、パーライト、フェラ
イト、残留オーステナイト、マルテンサイトのうちの少
なくとも1種を第2相とする組織であり、しかもベイナ
イト相の平均粒径が4μm未満であることを特徴とす
る、加工性に優れた超高強度熱延鋼板。
The present invention has been completed based on such findings, and the gist thereof is as follows. (1) C: 0.05 to 0.20 wt%, Si: 0.05 to 0.50 wt%, Mn:
1.0 to 3.5 wt%, P: 0.05 wt% or less, S: 0.01 wt% or less, Nb: 0.005 to 0.30 wt%, Ti: 0.001 to 0.100 wt%,
Cr: 0.01 to 1.0 wt% and Al: 0.1 wt% or less,
The balance is composed of Fe and unavoidable impurities, and the content of each of Si, P, Cr, Ti, Nb, and Mn is represented by the following formula: 0.05 ≦ ((wt%) Si + (wt%) P) / ( (wt%) Cr + (wt
%) Ti + (wt%) Nb + (wt%) Mn) ≦ 0.5, and the metal structure has a volume fraction of 60 to
A structure in which less than 90% of bainite is the main phase and at least one of pearlite, ferrite, retained austenite, and martensite is the second phase, and the average grain size of the bainite phase is less than 4 μm. Ultra-high strength hot rolled steel sheet with excellent workability.

【0008】(2)上記 (1)に記載の鋼板において、上記
成分の他にさらに、 A群; Cu:0.01〜1.0 wt%、Ni:0.01〜1.0 wt%、M
o:0.01〜1.0 wt%、V:0.01〜0.3 wt%、Zr:0.01〜
0.3 wt%およびB:0.0001〜0.0050wt% B群; Ca:0.0001〜0.0050wt%およびREM :0.0001〜
0.0050wt% のいずれか1群または2群から選ばれるいずれか1種ま
たは2種以上を含有することを特徴とする、加工性に優
れた超高強度熱延鋼板。
(2) In the steel sheet according to (1), in addition to the above components, Group A: Cu: 0.01 to 1.0 wt%, Ni: 0.01 to 1.0 wt%, M
o: 0.01 to 1.0 wt%, V: 0.01 to 0.3 wt%, Zr: 0.01 to
0.3 wt% and B: 0.0001-0.0050 wt% Group B; Ca: 0.0001-0.0050 wt% and REM: 0.0001-
An ultra-high-strength hot-rolled steel sheet excellent in workability, characterized by containing 0.0050 wt% of one or more selected from one or two groups.

【0009】(3) C:0.05〜0.20wt%、Si:0.05〜0.5
0wt%、Mn:1.0 〜3.5 wt%、P:0.05wt%以下、S:
0.01wt%以下、Nb:0.005 〜0.30wt%、Ti:0.001 〜0.
100 wt%、Cr:0.01〜1.0 wt%およびAl:0.1 wt%以下
を含有し、残部はFeおよび不可避的不純物の組成からな
り、かつ上記Si、P、Cr、Ti、NbおよびMnの各含有量は
次式: 0.05≦((wt%)Si + (wt%) P) /((wt%)Cr + (wt
%)Ti + (wt%)Nb + (wt%)Mn)≦0.5 の関係を満たして含有する鋼スラブを連続鋳造後、直ち
に又は一旦冷却して、1100〜1300℃に加熱したのち、仕
上げ圧延終了温度 950〜800 ℃にて熱間圧延し、圧延終
了後 0.5秒以内に冷却を開始して、30℃/sec 以上の冷
却速度で冷却を行い、500 〜300 ℃で巻取ることを特徴
とする、加工性に優れた超高強度熱延鋼板の製造方法。
(3) C: 0.05 to 0.20 wt%, Si: 0.05 to 0.5
0 wt%, Mn: 1.0 to 3.5 wt%, P: 0.05 wt% or less, S:
0.01 wt% or less, Nb: 0.005 to 0.30 wt%, Ti: 0.001 to 0.
100 wt%, Cr: 0.01 to 1.0 wt% and Al: 0.1 wt% or less, the balance being composed of Fe and unavoidable impurities, and containing each of the above Si, P, Cr, Ti, Nb and Mn The quantity is given by the following formula: 0.05 ≦ ((wt%) Si + (wt%) P) / ((wt%) Cr + (wt
%) Ti + (wt%) Nb + (wt%) Mn) ≦ 0.5 The steel slab containing the steel satisfying the relationship of 0.5 is continuously or immediately cooled or temporarily cooled, and then heated to 1100 to 1300 ° C., and then subjected to finish rolling. It is characterized by hot rolling at an end temperature of 950 to 800 ° C, cooling within 0.5 seconds after the end of rolling, cooling at a cooling rate of 30 ° C / sec or more, and winding at 500 to 300 ° C. To produce ultra-high strength hot rolled steel sheet with excellent workability.

【0010】(4)上記 (3)に記載の方法において、上記
成分の他にさらに、 A群; Cu:0.01〜1.0 wt%、Ni:0.01〜1.0 wt%、M
o:0.01〜1.0 wt%、V:0.01〜0.3 wt%、Zr:0.01〜
0.3 wt%およびB:0.0001〜0.0050wt% B群; Ca:0.0001〜0.0050wt%およびREM :0.0001〜
0.0050wt% のいずれか1群または2群から選ばれるいずれか1種ま
たは2種以上を含有することを特徴とする、加工性に優
れた超高強度熱延鋼板の製造方法。
(4) In the method described in (3) above, in addition to the above-mentioned components, Group A: Cu: 0.01 to 1.0 wt%, Ni: 0.01 to 1.0 wt%, M
o: 0.01 to 1.0 wt%, V: 0.01 to 0.3 wt%, Zr: 0.01 to
0.3 wt% and B: 0.0001-0.0050 wt% Group B; Ca: 0.0001-0.0050 wt% and REM: 0.0001-
A method for producing an ultra-high-strength hot-rolled steel sheet excellent in workability, characterized by containing 0.0050 wt% of one or more selected from any one or two groups.

【0011】[0011]

【発明の実施の形態】次に、上記要旨構成のとおりに限
定した理由について説明する。 C:0.05〜0.20wt% Cは、低温変態相を利用して鋼を強化するために必要不
可欠な元素である。引張強度 980MPa以上を得るには
0.05wt%以上の含有が必要であるが、0.2 wt%を超えて
含有すると、溶接性が劣化するので、C量は0.05〜0.20
wt%の範囲とする。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Next, a description will be given of the reason why the above-mentioned configuration is limited. C: 0.05 to 0.20 wt% C is an indispensable element for strengthening steel by utilizing a low-temperature transformation phase. To obtain tensile strength of 980MPa or more
Although the content of 0.05 wt% or more is necessary, if the content exceeds 0.2 wt%, the weldability deteriorates.
wt% range.

【0012】Si:0.05〜0.50wt% Siは、強度向上に寄与する元素であり、その効果は0.05
wt%未満では発揮されない。一方、0.50wt%を超えて含
有させると、フェライト変態が促進され、低温変態相に
よる強化が不十分となり、また強度を上げても降伏比が
高くなる傾向にある。よって、Si量は0.05〜0.50wt%の
範囲で含有させる。
Si: 0.05-0.50 wt% Si is an element that contributes to strength improvement, and its effect is 0.05%.
It is not exhibited at less than wt%. On the other hand, when the content exceeds 0.50 wt%, the ferrite transformation is promoted, the strengthening by the low-temperature transformation phase becomes insufficient, and the yield ratio tends to increase even if the strength is increased. Therefore, the amount of Si is contained in the range of 0.05 to 0.50 wt%.

【0013】Mn:1.0 〜3.5 wt% Mnは、ベイナイト組織を得るために重要な役割を担って
いる元素である。熱延終了後の冷却過程において、他の
変態相の生成を抑制し、安定的にベイナイト主体の組織
となすには1.0 wt%以上のMn量が必要であるが、3.5 wt
%を超えて含有させても、前記効果は飽和する。よっ
て、Mn量は1.0 〜3.5 wt%の範囲で添加する。
Mn: 1.0 to 3.5 wt% Mn is an element that plays an important role in obtaining a bainite structure. In the cooling process after the end of hot rolling, the amount of Mn of 1.0 wt% or more is required to suppress the formation of other transformed phases and to stably form a bainite-based structure.
%, The effect is saturated. Therefore, the amount of Mn is added in the range of 1.0 to 3.5 wt%.

【0014】P:0.05wt%以下 Pは、強度の向上に寄与するとともに、鋼中の蓄積水素
に起因する水素脆性および遅れ破壊を防止する効果を有
する元素である。しかし、過多に含有させると、組織の
不均一をもたらし、鋳造時の凝固偏析が著しく、内部割
れや加工性の劣化を招くことになるので0.05wt%以下の
範囲で含有させる。
P: 0.05 wt% or less P is an element that contributes to improvement in strength and has an effect of preventing hydrogen embrittlement and delayed fracture caused by hydrogen accumulated in steel. However, if it is contained excessively, the structure becomes non-uniform, solidification segregation during casting is remarkable, and internal cracks and workability are deteriorated.

【0015】S:0.01wt%以下 Sは、鋼中で非金属介在物として存在し、伸びフランジ
成形時の応力集中源となるため、その含有量は低いこと
が望まれる。S含有量が0.01wt%以下の範囲では、超高
強度であっても、穴拡げ性に大きな悪影響を及ぼさない
ので0.01wt%を上限として含んでもよい。
S: 0.01 wt% or less Since S exists as nonmetallic inclusions in steel and becomes a source of stress concentration during stretch flange forming, its content is desired to be low. When the S content is 0.01 wt% or less, even if the strength is very high, it does not significantly affect the hole expandability, so the upper limit may be 0.01 wt%.

【0016】Nb:0.005 〜0.30wt% Nbは、NbCなどの析出物の存在形態、再結晶温度に影響
する元素である。とくに本発明では、Nbは組織の微細均
一化に有効に作用するほか、降伏強度の低下の原因とな
る軟質なフェライト、パーライト相の生成を抑制し、低
温変態相であるベイナイト主体となる組織とすることに
より、高強度にもかかわらず高い伸び、穴拡げ性をもた
らすという効果を有している。このような効果は0.005
wt%以上の添加で発現するが、0.30wt%を超えて含有さ
せると鋼中に硬質な析出物を多量形成し、伸びフランジ
性を低下させる。よって、Nb量は0.005 〜0.30wt%の範
囲とする。なお、好ましくは0.01〜0.1 wt%とする。
Nb: 0.005 to 0.30 wt% Nb is an element which affects the form of precipitates such as NbC and the recrystallization temperature. In particular, in the present invention, Nb effectively acts on fine uniformity of the structure, suppresses the formation of soft ferrite and pearlite phase that cause a decrease in yield strength, and the structure mainly composed of bainite, which is a low-temperature transformation phase. By doing so, it has the effect of providing high elongation and hole expandability despite high strength. Such an effect is 0.005
It appears when it is added in an amount of not less than wt%, but when it is added more than 0.30 wt%, a large amount of hard precipitates are formed in the steel, and the stretch flangeability is reduced. Therefore, the Nb content is in the range of 0.005 to 0.30 wt%. In addition, it is preferably 0.01 to 0.1 wt%.

【0017】Ti:0.001 〜0.100 wt% Tiは、Nbと同様に、析出物の存在形態、再結晶温度に影
響し、組織の微細均一化をもたらし、降伏強度、伸び、
穴拡げ性の各特性を向上させるために有効な元素であ
る。これらの好ましい効果は、0.001 wt%以上の添加で
得られる。また、このTiを上記Nbと併用して添加する
と、フェライト変態が起きない最小の冷却速度が小さく
なり、焼入れ性が向上するという効果がもたらされる。
一方、0.100wt%を超えるTiを含有させると、硬質な炭
化物等を形成し、伸びフランジ性を低下させるため、Ti
量は0.001 〜0.100 wt%とする。なお、好ましくは 0.0
05〜0.05wt%とする。
Ti: 0.001 to 0.100 wt% Ti, like Nb, affects the form of the precipitates and the recrystallization temperature, brings about a fine and uniform structure, yield strength, elongation,
It is an element effective for improving each property of hole expansion. These favorable effects can be obtained by adding 0.001 wt% or more. Also, when this Ti is added in combination with the above-mentioned Nb, the minimum cooling rate at which ferrite transformation does not occur is reduced, and the effect of improving hardenability is brought about.
On the other hand, if more than 0.100 wt% of Ti is contained, a hard carbide or the like is formed, and the stretch flangeability is reduced.
The amount is 0.001 to 0.100 wt%. Incidentally, preferably 0.0
05 to 0.05 wt%.

【0018】Cr:0.01〜1.0 wt% Crは、伸びを大きく低下させたりYSを大きく上昇させ
たりすることなく、強度を向上させるのに有効な元素で
あるが、0.01wt%未満ではその効果は少なく、また1.0
wt%を超えて多量に含有させてもさらなる効果はなく、
経済的に不利になる。よって、Cr量は0.01〜1.0 wt%と
する。なお、好ましくは0.05〜0.5 wt%とする。
Cr: 0.01 to 1.0 wt% Cr is an element effective for improving the strength without greatly reducing the elongation or greatly increasing YS, but the effect is less than 0.01 wt% when Cr is less than 0.01 wt%. Less, also 1.0
There is no further effect even if it is contained in a large amount exceeding wt%,
Economically disadvantaged. Therefore, the Cr content is set to 0.01 to 1.0 wt%. Incidentally, the content is preferably 0.05 to 0.5 wt%.

【0019】Al:0.1 wt%以下 Alは、脱酸および炭化物形成元素の歩留りを向上させる
ために有効な元素であるが、0.1 wt%を超えて添加して
も効果が飽和するのみでなく、加工性の劣化のほかに表
面性状も劣化するので 0.1wt%以下とする。
Al: 0.1 wt% or less Al is an effective element for improving the yield of deoxidizing and carbide forming elements. However, even if added in excess of 0.1 wt%, not only does the effect become saturated, Since the surface properties deteriorate as well as the workability, the content should be 0.1 wt% or less.

【0020】Cu:0.01〜1.0 wt%、Ni:0.01〜1.0 wt
%、Mo:0.01〜1.0 wt%、V:0.01〜0.3 wt%、Zr:0.
01〜0.3 wt%およびB:0.0001〜0.0050wt% これらの元素は、鋼板の強度を上昇させるに有効な元素
であり、その効果はいずれの元素とも0.01wt%以上で得
られる。また、VおよびZrは、前記効果に加えて、局部
伸びを向上させる元素でもある。しかし、これら元素の
うち、Cu、Ni、Moではそれぞれ1.0 wt%超えて、また
V、Zrではそれぞれ0.3 wt%を超えて添加しても、さら
なる効果は得られず、徒にコストの上昇を招くことにな
る。よって、Cu、Ni、Moの各元素は0.01〜1.0 wt%、V
およびZrは0.01〜0.3 wt%の範囲で添加する。なお、い
ずれの元素とも、単独でも複合添加でも同様の挙動を示
す。Bも、強度の向上に有効な元素である。Bを添加す
ることにより、熱延終了後の急冷時において、軟質相の
生成を抑制しベイナイト相を形成することが容易とな
る。このような効果を得るためには、0.0001wt%以上の
添加が必要であるが、0.0050wt%を超えて添加してもさ
らなる効果が得られないので、0.0050wt%を上限として
添加する。
Cu: 0.01-1.0 wt%, Ni: 0.01-1.0 wt%
%, Mo: 0.01 to 1.0 wt%, V: 0.01 to 0.3 wt%, Zr: 0.
01 to 0.3 wt% and B: 0.0001 to 0.0050 wt% These elements are effective elements for increasing the strength of the steel sheet, and the effect can be obtained at 0.01 wt% or more with any of the elements. V and Zr are elements that improve local elongation in addition to the above-mentioned effects. However, among these elements, adding more than 1.0 wt% for Cu, Ni, and Mo, and adding more than 0.3 wt% for V and Zr, respectively, does not provide any further effect and increases costs. Will be invited. Therefore, each element of Cu, Ni, and Mo is 0.01-1.0 wt%, V
And Zr are added in the range of 0.01 to 0.3 wt%. It should be noted that any of these elements shows the same behavior when used alone or in combination. B is also an element effective for improving the strength. By adding B, the formation of a soft phase can be suppressed and a bainite phase can be easily formed during rapid cooling after the end of hot rolling. In order to obtain such an effect, it is necessary to add 0.0001% by weight or more. However, even if it exceeds 0.0050% by weight, no further effect can be obtained, so 0.0050% by weight is added as an upper limit.

【0021】 Ca:0.0001〜0.0050wt%、REM :0.0001〜0.0050wt% CaおよびREM は、硫化物等の析出物を球状化して、鋭角
的な析出物を減少させ、応力集中を減少させることによ
り、伸びフランジ性の低下を抑制する効果を有してい
る。これらの元素の添加量が、それぞれ0.0001wt%未満
では添加の効果が発揮されず、一方0.0050wt%を超えて
添加してもその効果が飽和する。よって、Ca、REM と
も、0.0001〜0.0050wt%の範囲で添加する。
Ca: 0.0001 to 0.0050 wt%, REM: 0.0001 to 0.0050 wt% Ca and REM are formed by spheroidizing precipitates such as sulfides, reducing sharp precipitates, and reducing stress concentration. And has an effect of suppressing a decrease in stretch flangeability. If the addition amount of each of these elements is less than 0.0001 wt%, the effect of addition is not exhibited, while if the addition exceeds 0.0050 wt%, the effect is saturated. Therefore, both Ca and REM are added in the range of 0.0001 to 0.0050 wt%.

【0022】0.05≦((wt%)Si + (wt%) P) /((wt
%)Cr + (wt%)Ti + (wt%)Nb + (wt%)Mn)≦0.5 所望のYRを得るには、後述する組織制御を行う必要が
ある。Si、Pなどフェライト生成促進元素を多量に含有
すると、熱延後の連続冷却中および巻き取り中にフェラ
イト相、パーライト相などの生成量が増加し、ベイナイ
ト相の体積分率が減少するので、伸びの低下やYRの低
下を招く。一方、Cr、Ti、Nbなどパーライトの生成を抑
制する炭化物形成元素も重要な役割を担っており、これ
らの元素の含有が少ないと、パーライトの生成が促進さ
れ、やはりベイナイト相の体積分率が減少し、伸びの低
下や、YRの低下を招く。また、Mnは、オーステナイト
安定化元素であり、連続冷却中のフェライトの生成を抑
制し、ベイナイト相の生成を促進する一方、過多になる
と、ベイナイト相の体積分率が増加し、高YR化させる
作用を有している。このような各元素の作用を考慮して
検討したところ、目標としたYRを得るには、((wt%)S
i + (wt%) P) /((wt%)Cr + (wt%)Ti + (wt%)N
b + (wt%)Mn)の値を0.05〜0.5 の範囲に制御すること
が必要である。すなわち、成分バランスをかかる範囲に
調整し、適正条件のもとで圧延することによって、体積
分率で60〜90%未満のベイナイト(主相)と、パーライ
ト、フェライト、残留オーステナイトのうちの少なくと
も1種からなる第2相の組織にすることが可能になる。
0.05 ≦ ((wt%) Si + (wt%) P) / ((wt
%) Cr + (wt%) Ti + (wt%) Nb + (wt%) Mn) ≦ 0.5 In order to obtain a desired YR, it is necessary to control the structure described later. If a large amount of ferrite formation promoting elements such as Si and P are contained, the amount of ferrite phase, pearlite phase, etc. generated during continuous cooling and rolling after hot rolling increases, and the volume fraction of bainite phase decreases, This leads to a decrease in elongation and a decrease in YR. On the other hand, carbide-forming elements such as Cr, Ti, and Nb that suppress the production of pearlite also play an important role, and when the content of these elements is small, the production of pearlite is promoted, and the volume fraction of the bainite phase is also reduced. It causes a decrease in elongation and a decrease in YR. In addition, Mn is an austenite stabilizing element, which suppresses the formation of ferrite during continuous cooling and promotes the formation of a bainite phase. On the other hand, when it is excessive, the volume fraction of the bainite phase increases and the YR is increased. Has an action. Investigations have been made in consideration of the effects of each of these elements. As a result, to obtain the target YR, ((wt%) S
i + (wt%) P) / ((wt%) Cr + (wt%) Ti + (wt%) N
It is necessary to control the value of (b + (wt%) Mn) in the range of 0.05 to 0.5. That is, by adjusting the component balance to such a range and rolling under appropriate conditions, at least one of bainite (main phase) having a volume fraction of less than 60 to 90%, pearlite, ferrite, and retained austenite is obtained. It becomes possible to have a second phase of tissue.

【0023】金属組織:ベイナイト相の体積分率が多す
ぎると高YS化する傾向がある。強度、YRなどの特性
を満たすためには、ベイナイト相体積分率を60〜90%未
満とする必要がある。というのは、ベイナイト相体積分
率が60%未満では局部変形能の劣化および穴拡げ性の低
下が生じ、一方この分率が90%以上になるとYRが高く
なりプレス成形性の低下、またロール成形での成形不良
(縁波、しわの発生)がもたらされるからである。ベイ
ナイト相の平均粒径を4μm未満にすることも目標とす
る材質特性を満たすために必要である。結晶粒径が微細
化し、組織が均一化すると、従来にない優れた強度一穴
拡げ率バランスを得ることが可能になる。なお、ベイナ
イト組織の平均粒径は、フェライトの平均粒径の求め方
(JIS G0552 )に準じて算出したもので、圧延方向およ
び圧延直角方向で各板厚断面の全厚みに渡って測定した
値の平均から求めたものとする。
Metal structure: If the volume fraction of the bainite phase is too large, YS tends to be high. In order to satisfy properties such as strength and YR, the bainite phase volume fraction needs to be 60 to less than 90%. This is because if the bainite phase volume fraction is less than 60%, the local deformability and the hole expandability deteriorate, whereas if this fraction exceeds 90%, the YR increases and the press formability decreases, and the rollability decreases. This is because poor molding (generation of edge waves and wrinkles) is caused in molding. It is also necessary to make the average particle size of the bainite phase less than 4 μm in order to satisfy the target material properties. When the crystal grain size is reduced and the structure is made uniform, it is possible to obtain a superior strength-to-hole expansion ratio balance which has not been achieved in the past. The average grain size of the bainite structure was calculated according to the method for determining the average grain size of ferrite (JIS G0552), and was a value measured over the entire thickness of each section in the rolling direction and the direction perpendicular to the rolling direction. Shall be determined from the average of

【0024】このようなベイナイト相体積分率を60〜90
%とした相構成とベイナイト粒径を満たすことにより、
980 MPa以上の超高強度で、伸びフランジ性に優れ、
延性に優れた総合的な材質バランスを達成でき、良好な
プレス成形(穴拡げ加工)とロール成形性を発揮でき
る。本発明では、このような優れた特性として、TS×
λ(穴拡げ率)≧60000 MPa・%、TS×El≧1600
0 MPa・%、降伏比YR:60〜70%が達成できる。な
お、YRが60未満では、ロール成形時縁波が生じ成形不
良を生じ、70%を超えるとロール成形後の曲げ加工時に
しわが発生する。
The bainite phase volume fraction is set to 60 to 90.
%, And by satisfying the bainite grain size,
Ultra high strength of 980 MPa or more, excellent stretch flangeability,
A comprehensive material balance with excellent ductility can be achieved, and good press forming (hole expanding) and roll formability can be exhibited. In the present invention, TS ×
λ (hole expansion rate) ≧ 60000 MPa ·%, TS × El ≧ 1600
0 MPa ·% and a yield ratio YR of 60 to 70% can be achieved. If YR is less than 60, an edge wave is generated at the time of roll forming, resulting in poor forming. If it exceeds 70%, wrinkles occur during bending after roll forming.

【0025】次に製造条件について説明する。スラブは
成分のマクロ的な偏析を防止する上で連続鋳造法で製造
することが望ましいが、造塊法、薄スラブ鋳造法によっ
て製造することも可能である。製造後のスラブは、いっ
たん室温まで冷却し、その後再度加熱する従来法の工程
はもちろん、温片のままで加熱炉に挿入してから圧延す
る直送圧延、あるいはわずかの保熱を行い直ちに圧延す
る直接圧延などの省エネルギープロセス工程も問題なく
適用できる。ただし、初期組織の均一かつ微細化という
観点からすれば、直送圧延などを行なう場合でも一旦、
γ→α変態を終了させたのちに再加熱を行なうほうが望
ましい。
Next, the manufacturing conditions will be described. The slab is desirably manufactured by a continuous casting method in order to prevent macroscopic segregation of components, but it is also possible to manufacture the slab by an ingot making method or a thin slab casting method. After production, the slabs are cooled to room temperature and then heated again. Energy saving process steps such as direct rolling can be applied without any problem. However, from the viewpoint of uniformity and fineness of the initial structure, even when performing direct rolling, etc., once,
It is more desirable to reheat after completing the γ → α transformation.

【0026】 ・スラブ加熱温度(SRT):1100〜1300℃ スラブ加熱温度は、結晶粒の均一微細化をはかるため、
1300℃以下のできるかぎり低温とすることが好ましい
が、仕上げ圧延温度を確保することも必要であるので、
1100〜1300℃の範囲とする。なお、好ましくは1200℃以
下とする。 ・仕上げ圧延終了温度: 800〜950 ℃ 仕上げ圧延終了温度が 800℃未満では圧延時の変形抵抗
が大きく、また組織の不均一化がおこる。一方 950℃よ
り高温では微細均一な組織が得られなくなる。よって、
仕上げ圧延終了温度は 800〜950 ℃の範囲とする。
Slab heating temperature (SRT): 1100 to 1300 ° C. The slab heating temperature is set so that crystal grains can be uniformly refined.
It is preferable to keep the temperature as low as possible below 1300 ° C, but it is also necessary to secure the finish rolling temperature,
It should be in the range of 1100-1300 ° C. Note that the temperature is preferably set to 1200 ° C. or less.・ Finishing finish temperature: 800-950 ° C If the finish rolling end temperature is less than 800 ° C, the deformation resistance during rolling is large and the structure becomes non-uniform. On the other hand, if the temperature is higher than 950 ° C., a fine and uniform structure cannot be obtained. Therefore,
The finish rolling finish temperature is in the range of 800 to 950 ° C.

【0027】・熱間圧延終了後の冷却 熱延終了後は0.5 秒以内に冷却を開始し、30℃/sec 以
上の冷却速度で強制冷却する。熱延終了後に放冷する
と、最終的に得られる熱延板の結晶粒径が粗大となる。
ベイナイトの平均粒径を4μm未満にするためには、熱
延終了後0.5 秒以内に強制的に冷却する必要がある。こ
のときの冷却速度は、熱延終了後の組織を決定するので
極めて重要である。冷却速度が30℃/sec 未満では、軟
質なフェライト相などベイナイト相以外の相が生成す
る。30℃/sec 以上の速度で冷却することにより、ベイ
ナイトを主相とする均一微細な組織を得ることが可能に
なる。 ・巻き取り温度:300 〜500 ℃ 巻き取り温度が低温すぎると、硬質なマルテンサイト相
が生成し、ベイナイト主体の均一な組織にならないの
で、十分な加工性が得られなくなる。一方、巻き取り温
度が高温過ぎると、低温変態相が軟化し、さらに結晶粒
が粗大化するので強度などの特性が不十分となる。
Cooling after completion of hot rolling After completion of hot rolling, cooling is started within 0.5 seconds, and forced cooling is performed at a cooling rate of 30 ° C./sec or more. When left to cool after completion of hot rolling, the crystal grain size of the finally obtained hot rolled sheet becomes coarse.
In order to reduce the average grain size of bainite to less than 4 μm, it is necessary to forcibly cool within 0.5 seconds after the end of hot rolling. The cooling rate at this time is extremely important because it determines the structure after the completion of hot rolling. If the cooling rate is lower than 30 ° C./sec, a phase other than the bainite phase such as a soft ferrite phase is formed. By cooling at a rate of 30 ° C./sec or more, it is possible to obtain a uniform and fine structure having bainite as a main phase. -Winding temperature: 300-500 ° C If the winding temperature is too low, a hard martensite phase is formed, and a bainite-based uniform structure is not obtained, so that sufficient workability cannot be obtained. On the other hand, if the winding temperature is too high, the low-temperature transformation phase softens and the crystal grains become coarse, so that properties such as strength become insufficient.

【0028】図1は、伸びフランジ性(穴拡げ率)と引
張強度との関係を、本発明と従来のものとで比較して示
したものである。発明鋼板は、0.08〜0.15wt%C−0.20
wt%Si−3.0 wt%Mn−0.04wt%Al−0.04wt%Nb−0.020
wt%Ti−0.10wt%Cr−0.020 wt%P−0.0020wt%Sの鋼
スラブを、スラブ加熱温度を1150℃、仕上げ圧延終了温
度を900 ℃、熱延終了後の冷却開始を0.3 秒以内、冷却
速度を85℃/sec、巻取温度を350 〜400 ℃としたもので
あり、比較鋼板は主として加熱温度、冷却速度、巻取温
度などの条件で発明とは異なっている。図1から、本発
明に従う熱延鋼板は980 MPa 以上の引張強度が得られて
いることはもちろん、穴拡げ率が比較鋼板よりも格段に
向上していることがわかる。
FIG. 1 shows the relationship between the stretch flangeability (hole expansion ratio) and the tensile strength of the present invention and the conventional one. The invention steel plate is 0.08-0.15wt% C-0.20
wt% Si-3.0 wt% Mn-0.04 wt% Al-0.04 wt% Nb-0.020
wt% Ti-0.10wt% Cr-0.020wt% P-0.0020wt% S steel slab, slab heating temperature is 1150 ℃, finish rolling end temperature is 900 ℃, cooling start after hot rolling is completed within 0.3 seconds, The cooling rate was 85 ° C./sec and the winding temperature was 350 to 400 ° C. The comparative steel sheet differs from the invention mainly in the conditions of the heating temperature, cooling rate, winding temperature and the like. From FIG. 1, it can be seen that the hot-rolled steel sheet according to the present invention has not only a tensile strength of 980 MPa or more, but also has a much higher hole expansion ratio than the comparative steel sheet.

【0029】[0029]

【実施例】実施例1 表1に示す成分と残部が実質的にFeからなる成分組成の
連続鋳造スラブ(スラブ厚260 mm)を、室温まで冷却
後、1048℃〜1116℃に加熱し、仕上げ圧延終了温度を87
0 〜900 ℃とする熱間圧延を行い、熱延終了後0.4 秒以
内に、冷却速度を60〜70℃/sec として冷却し、 360〜
310 ℃で巻き取り、2.0 mmの熱延鋼板とした。得られ
た熱延鋼板について、以下の材料特性を実施した。 ・穴拡げ率:初期直径d0 =10mmの穴を打抜き、60°
の円錐ポンチを上昇させ穴を拡げた際に、亀裂が板厚貫
通したところでポンチ上昇を止め、亀裂貫通後の打抜き
穴径dを測定し、穴拡げ率(%)=((d−d0 )/d
0 )×100 として算出した。 ・縁波の有無:ハット形状(成形高さ50mm、ポンチ肩
10mmφ、ダイス肩10mmφ)にロール成形後、端面形
状を目視で判定した。 ・曲げ加工:鋼板を一旦断面形状が角形閉断面(コーナ
ーR10mmφ、断面サイズ100 mm×60mm)のパイプ
状に成形したものを曲率半径500 mmで曲げ加工を行
い、しわ発生の有無を目視で判定した。 ・遅れ破壊試験:直径50mmφのポンチで絞り比1.80の
円筒に深絞り加工し、これを純水中に浸漬して約1週間
経過後の割れ発生の有無で評価した。表2に試験結果を
示す。
EXAMPLE 1 A continuous cast slab (slab thickness 260 mm) having a composition shown in Table 1 and a balance of substantially Fe was cooled to room temperature, heated to 1048 ° C. to 1116 ° C., and finished. Rolling end temperature 87
Hot rolling is performed at 0 to 900 ° C, and within 0.4 seconds after the completion of hot rolling, cooling is performed at a cooling rate of 60 to 70 ° C / sec.
It was wound at 310 ° C. to obtain a 2.0 mm hot-rolled steel sheet. The following material characteristics were implemented for the obtained hot-rolled steel sheet.・ Hole expansion rate: punching a hole with initial diameter d 0 = 10 mm, 60 °
When the hole was expanded by raising the conical punch, the punch was stopped from rising when the crack penetrated the plate, and the punched hole diameter d after the crack was penetrated was measured. The hole expansion ratio (%) = ((d−d 0) ) / D
0 ) × 100.・ Presence or absence of edge wave: Hat shape (molding height 50mm, punch shoulder
After roll-forming into 10 mmφ and a die shoulder of 10 mmφ), the end face shape was visually determined. -Bending: The steel sheet is formed into a pipe with a square cross-section (corner R10 mmφ, cross-section size 100 mm x 60 mm) and bent at a radius of curvature of 500 mm, and the presence or absence of wrinkles is visually determined. did. Delayed fracture test: Deep drawing was performed on a cylinder having a drawing ratio of 1.80 with a punch having a diameter of 50 mmφ, and this was immersed in pure water and evaluated for the occurrence of cracks after about one week. Table 2 shows the test results.

【0030】実施例2 次に、表1中の鋼スラブHを用い、表3に示す各条件で
熱延鋼板を製造した。得られた熱延鋼板について、同様
な試験を行い材料特性を調査した。その結果を併せて表
3に示す。
Example 2 Next, using the steel slab H in Table 1, a hot-rolled steel sheet was manufactured under the conditions shown in Table 3. Similar tests were performed on the obtained hot-rolled steel sheets to investigate the material properties. Table 3 also shows the results.

【0031】[0031]

【表1】 [Table 1]

【0032】[0032]

【表2】 [Table 2]

【0033】[0033]

【表3】 [Table 3]

【0034】本発明に従えば、 980MPa以上の引張強
度を有し、延性、穴拡げ性バランスが従来になく優れた
超高強度熱延鋼板が得られることがわかる。
According to the present invention, it can be seen that an ultra-high strength hot rolled steel sheet having a tensile strength of 980 MPa or more, and having an excellent balance between ductility and hole expandability, which has not been achieved conventionally, can be obtained.

【0035】[0035]

【発明の効果】以上説明したように、本発明によれば、
引張強度が 980MPa以上でありながら、伸びフランジ
成形性と強度延性バランスがともに優れ、かつ低降伏比
をも具えた、加工性に優れる超高強度熱延鋼板を提供す
ることができる。また、本発明によれば、ロール成形に
より発生しやすい、縁波、しわなどの成形不良も防止で
きる。したがって、本発明は、自動車の強度メンバーや
インパクトビームなどの製造に際して、一層の軽量化や
コストの低減等に大きく寄与する。
As described above, according to the present invention,
It is possible to provide an ultra-high-strength hot-rolled steel sheet excellent in workability, having both excellent stretch flange formability and strength-ductility balance and having a low yield ratio while having a tensile strength of 980 MPa or more. Further, according to the present invention, it is possible to prevent molding defects such as edge waves and wrinkles which are likely to be generated by roll molding. Therefore, the present invention greatly contributes to further weight reduction and cost reduction in manufacturing a strength member of an automobile, an impact beam, and the like.

【図面の簡単な説明】[Brief description of the drawings]

【図1】穴拡げ率と引張強度との関係を示すグラフであ
る。
FIG. 1 is a graph showing a relationship between a hole expansion ratio and a tensile strength.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 古君 修 千葉県千葉市中央区川崎町1番地 川崎製 鉄株式会社技術研究所内 Fターム(参考) 4K037 EA01 EA02 EA05 EA06 EA09 EA11 EA13 EA15 EA16 EA17 EA19 EA20 EA23 EA25 EA27 EA31 EA32 EA35 EA36 EB05 EB07 EB08 EB11 FA02 FA03 FC03 FC04 FD04 FE01 FE06 JA06  ────────────────────────────────────────────────── ─── Continuing from the front page (72) Inventor Osamu Furukun 1 Kawasaki-cho, Chuo-ku, Chiba-shi, Chiba F-term in the Technical Research Laboratory, Kawasaki Steel Co., Ltd. 4K037 EA01 EA02 EA05 EA06 EA09 EA11 EA13 EA15 EA16 EA17 EA19 EA20 EA23 EA25 EA27 EA31 EA32 EA35 EA36 EB05 EB07 EB08 EB11 FA02 FA03 FC03 FC04 FD04 FE01 FE06 JA06

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 C:0.05〜0.20wt%、 Si:0.05〜0.50wt%、 Mn:1.0 〜3.5 wt%、 P:0.05wt%以下、 S:0.01wt%以下、 Nb:0.005 〜0.30wt%、 Ti:0.001 〜0.100wt %、 Cr:0.01〜1.0 wt%および Al:0.1 wt% 以下 を含有し、残部はFeおよび不可避的不純物の組成からな
り、かつ上記Si、P、Cr、Ti、NbおよびMnの各含有量は
次式: 0.05≦((wt%)Si + (wt%) P) /((wt%)Cr + (wt
%)Ti + (wt%)Nb + (wt%)Mn)≦0.5 の関係を満たして含有し、金属組織が、体積分率で60〜
90%未満のベイナイトを主相とし、パーライト、フェラ
イト、残留オーステナイト、マルテンサイトのうちの少
なくとも1種を第2相とする組織であり、しかもベイナ
イト相の平均粒径が4μm未満であることを特徴とす
る、加工性に優れた超高強度熱延鋼板。
1. C: 0.05 to 0.20 wt%, Si: 0.05 to 0.50 wt%, Mn: 1.0 to 3.5 wt%, P: 0.05 wt% or less, S: 0.01 wt% or less, Nb: 0.005 to 0.30 wt% , Ti: 0.001 to 0.100 wt%, Cr: 0.01 to 1.0 wt% and Al: 0.1 wt% or less, with the balance being Fe and inevitable impurities, and the above Si, P, Cr, Ti, Nb Each content of Mn and Mn is represented by the following formula: 0.05 ≦ ((wt%) Si + (wt%) P) / ((wt%) Cr + (wt
%) Ti + (wt%) Nb + (wt%) Mn) ≦ 0.5, and the metal structure has a volume fraction of 60 to
A structure in which less than 90% of bainite is the main phase and at least one of pearlite, ferrite, retained austenite, and martensite is the second phase, and the average grain size of the bainite phase is less than 4 μm. Ultra-high strength hot rolled steel sheet with excellent workability.
【請求項2】請求項1に記載の鋼板において、上記成分
の他にさらに、 のいずれか1群または2群から選ばれるいずれか1種ま
たは2種以上を含有することを特徴とする、加工性に優
れた超高強度熱延鋼板。
2. The steel sheet according to claim 1, further comprising: An ultra-high-strength hot-rolled steel sheet excellent in workability, characterized by containing one or more selected from any one group or two groups.
【請求項3】 C:0.05〜0.20wt%、 Si:0.05〜0.50wt%、 Mn:1.0 〜3.5 wt%、 P:0.05wt%以下、 S:0.01wt%以下、 Nb:0.005 〜0.30wt%、 Ti:0.001 〜0.100wt %、 Cr:0.01〜1.0 wt%および Al:0.1 wt% 以下 を含有し、残部はFeおよび不可避的不純物の組成からな
り、かつ上記Si、P、Cr、Ti、NbおよびMnの各含有量は
次式: 0.05≦((wt%)Si + (wt%) P) /((wt%)Cr + (wt
%)Ti + (wt%)Nb + (wt%)Mn)≦0.5 の関係を満たして含有する鋼スラブを鋳造後、直ちに又
は一旦冷却して、1100〜1300℃に加熱したのち、仕上げ
圧延終了温度 950〜800 ℃にて熱間圧延し、圧延終了後
0.5秒以内に冷却を開始して、30℃/sec 以上の冷却速
度で冷却を行い、500〜300 ℃で巻取ることを特徴とす
る、加工性に優れた超高強度熱延鋼板の製造方法。
3. C: 0.05 to 0.20 wt%, Si: 0.05 to 0.50 wt%, Mn: 1.0 to 3.5 wt%, P: 0.05 wt% or less, S: 0.01 wt% or less, Nb: 0.005 to 0.30 wt% , Ti: 0.001 to 0.100 wt%, Cr: 0.01 to 1.0 wt% and Al: 0.1 wt% or less, with the balance being Fe and inevitable impurities, and the above Si, P, Cr, Ti, Nb Each content of Mn and Mn is represented by the following formula: 0.05 ≦ ((wt%) Si + (wt%) P) / ((wt%) Cr + (wt
%) Ti + (wt%) Nb + (wt%) Mn) ≦ 0.5 After casting the steel slab containing it, satisfying the relation, immediately or once cooled, heated to 1100-1300 ° C, and finished rolling. Hot-rolled at a temperature of 950 to 800 ° C, after rolling
A method for manufacturing an ultra-high-strength hot-rolled steel sheet excellent in workability, characterized by starting cooling within 0.5 seconds, cooling at a cooling rate of 30 ° C / sec or more, and winding at 500 to 300 ° C. .
【請求項4】 請求項3に記載の方法において、上記成
分の他にさらに、 のいずれか1群または2群から選ばれるいずれか1種ま
たは2種以上を含有することを特徴とする、加工性に優
れた超高強度熱延鋼板の製造方法。
4. The method according to claim 3, further comprising: A method for producing an ultra-high-strength hot-rolled steel sheet excellent in workability, characterized by containing one or more selected from any one group or two groups.
JP9611099A 1999-04-02 1999-04-02 Ultra-high strength hot rolled steel sheet excellent in workability and method for producing the same Pending JP2000282175A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9611099A JP2000282175A (en) 1999-04-02 1999-04-02 Ultra-high strength hot rolled steel sheet excellent in workability and method for producing the same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9611099A JP2000282175A (en) 1999-04-02 1999-04-02 Ultra-high strength hot rolled steel sheet excellent in workability and method for producing the same

Publications (1)

Publication Number Publication Date
JP2000282175A true JP2000282175A (en) 2000-10-10

Family

ID=14156262

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9611099A Pending JP2000282175A (en) 1999-04-02 1999-04-02 Ultra-high strength hot rolled steel sheet excellent in workability and method for producing the same

Country Status (1)

Country Link
JP (1) JP2000282175A (en)

Cited By (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2002068703A1 (en) * 2001-02-27 2002-09-06 Nkk Corporation Hot dip zinc plated steel sheet having high strength and method for producing the same
EP1391526A3 (en) * 2002-08-20 2004-04-21 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Dual phase steel sheet with good bake-hardening properties
WO2005031024A1 (en) * 2003-09-30 2005-04-07 Nippon Steel Corporation High-yield-ratio high-strength thin steel sheet and high-yield-ratio high-strength hot-dip galvanized thin steel sheet excelling in weldability and ductility as well as high-yield-ratio high-strength alloyed hot-dip galvanized thin steel sheet and process for producing the same
WO2006103991A1 (en) * 2005-03-28 2006-10-05 Kabushiki Kaisha Kobe Seiko Sho High strength hot rolled steel sheet excellent in bore expanding workability and method for production thereof
CN1330786C (en) * 2005-12-27 2007-08-08 东北大学 Strength of extension 780 MPa grade complex phase steel plate and mfg. method thereof
JP2007277729A (en) * 2007-06-11 2007-10-25 Jfe Steel Kk High-strength hot-dip galvanized steel sheet and manufacturing method thereof
JP2008266695A (en) * 2007-04-17 2008-11-06 Nakayama Steel Works Ltd High strength hot rolled steel sheet and method for producing the same
WO2009021898A1 (en) * 2007-08-15 2009-02-19 Thyssenkrupp Steel Ag Dual-phase steel, flat product made of such dual-phase steel and method for producing a flat product
US7591977B2 (en) 2004-01-28 2009-09-22 Kabuhsiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) High strength and low yield ratio cold rolled steel sheet and method of manufacturing the same
JP2009263774A (en) * 2008-04-03 2009-11-12 Nippon Steel Corp Low yield ratio type high burring high strength hot rolled steel sheet, and method for producing the same
EP2105515A3 (en) * 2008-03-28 2010-03-24 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) High strength plate with 980 MPa or above tensile strength excellent in bending workability
JP2010180446A (en) * 2009-02-04 2010-08-19 Jfe Steel Corp High-strength hot-rolled steel plate and method for manufacturing the same
JP2010533791A (en) * 2007-07-19 2010-10-28 アルセロールミタル・フランス Method for producing a steel sheet having high resistance characteristics and ductility characteristics and the steel sheet thus obtained
US20100273024A1 (en) * 2007-08-15 2010-10-28 Thyssenkrupp Steel Europe Ag Dual-phase steel, flat product made of a dual-phase steel of this type and processes for the production of a flat product
WO2011152541A1 (en) 2010-05-31 2011-12-08 Jfeスチール株式会社 High-strength hot-rolled steel plate exhibiting excellent stretch flangeability and fatigue resistance properties, and production method therefor
KR101185340B1 (en) 2010-10-27 2012-09-26 현대제철 주식회사 Ultra high strength hot-rolled steel with excellent balance of strength-ductility and method of manufacturing the same
CN102844454A (en) * 2010-03-31 2012-12-26 株式会社神户制钢所 Hot dipped galvanized steel sheet and alloyed hot-dip galvanized steel sheet, each having excellent processability, high yield ratio and high strength
US20130000798A1 (en) * 2008-12-26 2013-01-03 Jfe Steel Corporation Steel material excellent in resistance of ductile crack initiation from welded heat affected zone and base material and method for manufacturing the same
WO2013065298A1 (en) 2011-11-01 2013-05-10 Jfeスチール株式会社 High-strength hot-rolled steel sheet having excellent bending characteristics and low-temperature toughness and method for producing same
CN103160758A (en) * 2011-12-19 2013-06-19 株式会社神户制钢所 High-yield-ratio and high-strength steel sheet excellent in workability
CN103255342A (en) * 2013-05-28 2013-08-21 宝山钢铁股份有限公司 600Mpa-grade high-strength hot continuous rolling structural steel and manufacturing method thereof
JP2013163827A (en) * 2012-02-09 2013-08-22 Nippon Steel & Sumitomo Metal Corp High-strength cold-rolled steel sheet, high-strength galvanized steel sheet, and high-strength alloying hot-dip galvanized steel sheet, excellent in bendability, and method for manufacturing the same
JP2015160985A (en) * 2014-02-27 2015-09-07 Jfeスチール株式会社 High strength hot rolled steel sheet and method for producing the same
EP3114246A4 (en) * 2014-02-05 2018-04-04 Arcelormittal S.A. Hot formable, air hardenable, weldable, steel sheet
US20180105919A1 (en) * 2015-03-24 2018-04-19 Jfe Steel Corporation Steel for nitrocarburizing and nitrocarburized component, and methods of producing same
CN109023036A (en) * 2017-06-12 2018-12-18 鞍钢股份有限公司 Ultrahigh-strength hot-rolled complex-phase steel plate and production method thereof
US20200165708A1 (en) * 2016-02-10 2020-05-28 Jfe Steel Corporation High-strength galvanized steel sheet and method of producing the same
JP2021031703A (en) * 2019-08-20 2021-03-01 日本製鉄株式会社 Thin steel sheet and its manufacturing method
US20210340642A1 (en) * 2018-09-28 2021-11-04 Arcelormittal Hot rolled steel sheet and a method of manufacturing thereof
US11242593B2 (en) 2016-11-30 2022-02-08 Jfe Steel Corporation Steel for nitrocarburizing, and component

Cited By (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002256386A (en) * 2001-02-27 2002-09-11 Nkk Corp High strength hot-dip galvanized steel sheet and method for producing the same
EP1367143A4 (en) * 2001-02-27 2004-07-21 Jfe Steel Corp HOT ZINC-PLATED STEEL SHEET WITH HIGH RESISTANCE AND PROCESS FOR PRODUCING THE SAME
US6869691B2 (en) 2001-02-27 2005-03-22 Nkk Corporation High strength hot-dip galvanized steel sheet and method for manufacturing the same
WO2002068703A1 (en) * 2001-02-27 2002-09-06 Nkk Corporation Hot dip zinc plated steel sheet having high strength and method for producing the same
US9194015B2 (en) 2002-08-20 2015-11-24 Kobe Steel, Ltd. Dual phase steel sheet with good bake-hardening properties
EP1391526A3 (en) * 2002-08-20 2004-04-21 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Dual phase steel sheet with good bake-hardening properties
WO2005031024A1 (en) * 2003-09-30 2005-04-07 Nippon Steel Corporation High-yield-ratio high-strength thin steel sheet and high-yield-ratio high-strength hot-dip galvanized thin steel sheet excelling in weldability and ductility as well as high-yield-ratio high-strength alloyed hot-dip galvanized thin steel sheet and process for producing the same
US8747577B2 (en) 2003-09-30 2014-06-10 Nippon Steel & Sumitomo Metal Corporation High yield ratio and high-strength thin steel sheet superior in weldability and ductility, high-yield ratio high-strength hot-dip galvanized thin steel sheet, high-yield ratio high-strength hot-dip galvannealed thin steel sheet, and methods of production of same
US8084143B2 (en) 2003-09-30 2011-12-27 Nippon Steel Corporation High-yield-ratio and high-strength thin steel sheet superior in weldability and ductility, high-yield-ratio high-strength hot-dip galvanized thin steel sheet, high-yield ratio high-strength hot-dip galvannealed thin steel sheet, and methods of production of same
US7591977B2 (en) 2004-01-28 2009-09-22 Kabuhsiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) High strength and low yield ratio cold rolled steel sheet and method of manufacturing the same
US8486205B2 (en) 2005-03-28 2013-07-16 Kobe Steel, Ltd. High strength hot rolled steel sheet excellent in bore expanding workability and method for production thereof
US8038809B2 (en) 2005-03-28 2011-10-18 Kobe Steel, Ltd. High strength hot rolled steel sheet excellent in bore expanding workability and method for production thereof
WO2006103991A1 (en) * 2005-03-28 2006-10-05 Kabushiki Kaisha Kobe Seiko Sho High strength hot rolled steel sheet excellent in bore expanding workability and method for production thereof
CN1330786C (en) * 2005-12-27 2007-08-08 东北大学 Strength of extension 780 MPa grade complex phase steel plate and mfg. method thereof
KR101446354B1 (en) * 2007-04-17 2014-10-01 가부시끼 가이샤 나까야마 세이꼬쇼 High-strength hot-rolled steel sheet and manufacturing method thereof
JP2008266695A (en) * 2007-04-17 2008-11-06 Nakayama Steel Works Ltd High strength hot rolled steel sheet and method for producing the same
JP2007277729A (en) * 2007-06-11 2007-10-25 Jfe Steel Kk High-strength hot-dip galvanized steel sheet and manufacturing method thereof
US10428400B2 (en) 2007-07-19 2019-10-01 Arcelormittal France Steel sheet having high tensile strength and ductility
JP2010533791A (en) * 2007-07-19 2010-10-28 アルセロールミタル・フランス Method for producing a steel sheet having high resistance characteristics and ductility characteristics and the steel sheet thus obtained
US10214792B2 (en) 2007-07-19 2019-02-26 Arcelormittal France Process for manufacturing steel sheet
JP2010535946A (en) * 2007-08-15 2010-11-25 ティッセンクルップ スチール ヨーロッパ アクチェンゲゼルシャフト Dual-phase steel, flat products made of this type of dual-phase steel and methods for producing flat products
JP2010535947A (en) * 2007-08-15 2010-11-25 ティッセンクルップ スチール ヨーロッパ アクチェンゲゼルシャフト Flat product made of two-phase steel and two-phase steel and method for producing flat product
US20100273024A1 (en) * 2007-08-15 2010-10-28 Thyssenkrupp Steel Europe Ag Dual-phase steel, flat product made of a dual-phase steel of this type and processes for the production of a flat product
EP2031081A1 (en) * 2007-08-15 2009-03-04 ThyssenKrupp Steel AG Dual-phase steel, flat product made of such dual-phase steel and method for manufacturing a flat product
WO2009021898A1 (en) * 2007-08-15 2009-02-19 Thyssenkrupp Steel Ag Dual-phase steel, flat product made of such dual-phase steel and method for producing a flat product
EP2105515A3 (en) * 2008-03-28 2010-03-24 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) High strength plate with 980 MPa or above tensile strength excellent in bending workability
JP2009263774A (en) * 2008-04-03 2009-11-12 Nippon Steel Corp Low yield ratio type high burring high strength hot rolled steel sheet, and method for producing the same
US20130000798A1 (en) * 2008-12-26 2013-01-03 Jfe Steel Corporation Steel material excellent in resistance of ductile crack initiation from welded heat affected zone and base material and method for manufacturing the same
JP2010180446A (en) * 2009-02-04 2010-08-19 Jfe Steel Corp High-strength hot-rolled steel plate and method for manufacturing the same
CN102844454A (en) * 2010-03-31 2012-12-26 株式会社神户制钢所 Hot dipped galvanized steel sheet and alloyed hot-dip galvanized steel sheet, each having excellent processability, high yield ratio and high strength
US9222155B2 (en) 2010-05-31 2015-12-29 Jfe Steel Corporation Method for manufacturing high strength hot-rolled steel sheet having excellent stretch flangeability and fatigue resistance
WO2011152541A1 (en) 2010-05-31 2011-12-08 Jfeスチール株式会社 High-strength hot-rolled steel plate exhibiting excellent stretch flangeability and fatigue resistance properties, and production method therefor
KR101185340B1 (en) 2010-10-27 2012-09-26 현대제철 주식회사 Ultra high strength hot-rolled steel with excellent balance of strength-ductility and method of manufacturing the same
WO2013065298A1 (en) 2011-11-01 2013-05-10 Jfeスチール株式会社 High-strength hot-rolled steel sheet having excellent bending characteristics and low-temperature toughness and method for producing same
US9752216B2 (en) 2011-11-01 2017-09-05 Jfe Steel Corporation High-strength hot rolled steel sheet with excellent bendability and low-temperature toughness, and method for manufacturing the same
CN103160758A (en) * 2011-12-19 2013-06-19 株式会社神户制钢所 High-yield-ratio and high-strength steel sheet excellent in workability
JP2013163827A (en) * 2012-02-09 2013-08-22 Nippon Steel & Sumitomo Metal Corp High-strength cold-rolled steel sheet, high-strength galvanized steel sheet, and high-strength alloying hot-dip galvanized steel sheet, excellent in bendability, and method for manufacturing the same
CN103255342A (en) * 2013-05-28 2013-08-21 宝山钢铁股份有限公司 600Mpa-grade high-strength hot continuous rolling structural steel and manufacturing method thereof
EP3114246A4 (en) * 2014-02-05 2018-04-04 Arcelormittal S.A. Hot formable, air hardenable, weldable, steel sheet
JP2015160985A (en) * 2014-02-27 2015-09-07 Jfeスチール株式会社 High strength hot rolled steel sheet and method for producing the same
US20180105919A1 (en) * 2015-03-24 2018-04-19 Jfe Steel Corporation Steel for nitrocarburizing and nitrocarburized component, and methods of producing same
US11959177B2 (en) 2015-03-24 2024-04-16 Jfe Steel Corporation Steel for nitrocarburizing and nitrocarburized component, and methods of producing same
US20200165708A1 (en) * 2016-02-10 2020-05-28 Jfe Steel Corporation High-strength galvanized steel sheet and method of producing the same
US11242593B2 (en) 2016-11-30 2022-02-08 Jfe Steel Corporation Steel for nitrocarburizing, and component
CN109023036A (en) * 2017-06-12 2018-12-18 鞍钢股份有限公司 Ultrahigh-strength hot-rolled complex-phase steel plate and production method thereof
US20210340642A1 (en) * 2018-09-28 2021-11-04 Arcelormittal Hot rolled steel sheet and a method of manufacturing thereof
JP2022502571A (en) * 2018-09-28 2022-01-11 アルセロールミタル Hot-rolled steel sheet and its manufacturing method
JP2023139168A (en) * 2018-09-28 2023-10-03 アルセロールミタル Hot rolled steel plate and its manufacturing method
US12325889B2 (en) * 2018-09-28 2025-06-10 Arcelormittal Hot rolled steel sheet and a method of manufacturing thereof
JP2021031703A (en) * 2019-08-20 2021-03-01 日本製鉄株式会社 Thin steel sheet and its manufacturing method
JP7389322B2 (en) 2019-08-20 2023-11-30 日本製鉄株式会社 Thin steel plate and its manufacturing method

Similar Documents

Publication Publication Date Title
JP2000282175A (en) Ultra-high strength hot rolled steel sheet excellent in workability and method for producing the same
JP4411221B2 (en) Low yield ratio high-strength cold-rolled steel sheet and plated steel sheet excellent in elongation and stretch flangeability, and manufacturing method thereof
JP3219820B2 (en) Low yield ratio high strength hot rolled steel sheet and method for producing the same
KR20070061859A (en) High strength steel sheet with excellent elongation and hole expandability and manufacturing method
KR20160023930A (en) Hot stamp molded article, method for producing hot stamp molded article, energy absorbing member, and method for producing energy absorbing member
CN102906296A (en) Hot-rolled steel sheet with high tensile strength and superior processability and method for producing same
JP2006070346A (en) Hot-press steel sheet having excellent hydrogen embrittlement resistance, automotive member and method for producing the same
JP3433687B2 (en) High-strength hot-rolled steel sheet excellent in workability and method for producing the same
CN112760554A (en) High-strength steel with excellent ductility and manufacturing method thereof
JPH1161326A (en) High-strength steel sheet for automobiles excellent in collision safety and formability and manufacturing method thereof
JP3901039B2 (en) Ultra-high strength cold-rolled steel sheet having excellent formability and method for producing the same
JPH11350038A (en) Method for producing composite structure type high tensile cold rolled steel sheet excellent in ductility and stretch flangeability
JP2001220647A (en) High strength cold rolled steel sheet excellent in workability and method for producing the same
JP2001226741A (en) High-strength cold-rolled steel sheet excellent in stretch flangeability and its manufacturing method
JP2001234282A (en) High tensile hot rolled steel sheet excellent in warm press formability and method for producing the same
JPH1161327A (en) High-strength steel sheet for automobiles excellent in collision safety and formability, and its manufacturing method
JP2001226744A (en) High-strength hot-rolled steel sheet excellent in bake hardenability and impact resistance and method for producing the same
JP2003105446A (en) High strength hot rolled steel sheet and method for producing the same
JP4205893B2 (en) High-strength hot-rolled steel sheet excellent in press formability and punching workability and manufacturing method thereof
JP4492111B2 (en) Manufacturing method of super high strength steel plate with good shape
JP2002097545A (en) High-workability, high-strength steel sheet excellent in shape freezing property and impact energy absorption capacity during processing and manufacturing method thereof
JP2000336455A (en) High ductility hot rolled steel sheet and method for producing the same
JP2621744B2 (en) Ultra-high tensile cold rolled steel sheet and method for producing the same
JP3168665B2 (en) Hot-rolled high-strength steel sheet with excellent workability and its manufacturing method
JP3954411B2 (en) Manufacturing method of high-strength hot-rolled steel sheet with excellent material uniformity and hole expandability