CN1371888A - Compound trace element chelated fertilizer and preparation method thereof - Google Patents
Compound trace element chelated fertilizer and preparation method thereof Download PDFInfo
- Publication number
- CN1371888A CN1371888A CN 01103973 CN01103973A CN1371888A CN 1371888 A CN1371888 A CN 1371888A CN 01103973 CN01103973 CN 01103973 CN 01103973 A CN01103973 A CN 01103973A CN 1371888 A CN1371888 A CN 1371888A
- Authority
- CN
- China
- Prior art keywords
- acid
- trace element
- amino acid
- hydrolysis
- humic acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011573 trace mineral Substances 0.000 title claims abstract description 21
- 235000013619 trace mineral Nutrition 0.000 title claims abstract description 21
- 239000003337 fertilizer Substances 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title claims abstract description 5
- 150000001875 compounds Chemical class 0.000 title claims description 10
- 239000004021 humic acid Substances 0.000 claims abstract description 22
- 150000001413 amino acids Chemical class 0.000 claims abstract description 20
- 239000007788 liquid Substances 0.000 claims abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 11
- 108090000623 proteins and genes Proteins 0.000 claims abstract description 7
- 102000004169 proteins and genes Human genes 0.000 claims abstract description 7
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000003446 ligand Substances 0.000 claims abstract description 6
- 239000003513 alkali Substances 0.000 claims abstract description 5
- 239000013522 chelant Substances 0.000 claims abstract description 5
- 239000002699 waste material Substances 0.000 claims abstract 3
- 230000007062 hydrolysis Effects 0.000 claims description 10
- 238000006460 hydrolysis reaction Methods 0.000 claims description 10
- 239000003245 coal Substances 0.000 claims description 9
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 5
- 210000003298 dental enamel Anatomy 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 210000003746 feather Anatomy 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 230000003472 neutralizing effect Effects 0.000 claims description 3
- 238000005903 acid hydrolysis reaction Methods 0.000 claims description 2
- 241000255789 Bombyx mori Species 0.000 claims 1
- 229910052802 copper Inorganic materials 0.000 claims 1
- 239000000284 extract Substances 0.000 claims 1
- 238000000605 extraction Methods 0.000 claims 1
- 210000000003 hoof Anatomy 0.000 claims 1
- 239000003295 industrial effluent Substances 0.000 claims 1
- 229910052809 inorganic oxide Inorganic materials 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 244000144977 poultry Species 0.000 claims 1
- 229910052761 rare earth metal Inorganic materials 0.000 claims 1
- 150000002910 rare earth metals Chemical class 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 235000013311 vegetables Nutrition 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000002689 soil Substances 0.000 abstract description 3
- 108010009736 Protein Hydrolysates Proteins 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 230000003301 hydrolyzing effect Effects 0.000 abstract 1
- 239000003415 peat Substances 0.000 abstract 1
- 235000001014 amino acid Nutrition 0.000 description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 11
- 239000002131 composite material Substances 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000006386 neutralization reaction Methods 0.000 description 5
- 239000002585 base Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000011121 sodium hydroxide Nutrition 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 210000003608 fece Anatomy 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000010871 livestock manure Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 235000018102 proteins Nutrition 0.000 description 2
- 238000007738 vacuum evaporation Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- -1 compound amino acid Chemical class 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The preparation method of complex type trace element chelate fertilizer incldues the following steps: adding trace element in waste protein, hydrolyzing with acid to produce amino acid trace element chelate sat liquid, then using alkali to extract humic acid liquid from peat and using it as neutralizer to remove acid from amino acid hydrolysate, at the same time produce trace element chealte using amino acid and humic acid as ligand. Because the difference of two ligands is large in properties of molecular weiht, chelating rate, solubility, decomposition speed in soil and absorption speed by plant, so that it can provide different trace elements for crops so as to can ensure the requirements of crops for trace elements.
Description
The present invention relates to a kind of compound trace element chelated fertilizer and preparation method thereof.
Chelated trace element of compound amino acid generally uses and obtains good effect of increasing production in China as foliage fertilizer, but as it then is not reported as the base manure trace element supplement.One of reason is the little fertile cost height of amino acid, because of its solubleness is big, is easily taken away loss by water after entering soil, and amino acid is the nutritive substance of various microorganisms in the soil, can be digested and assimilated by microorganism, thereby reduce the effect of utilizing of amino-acid trace element.Former two is amino-acid chelate production cost height therefore, although utilize discarded albumen and reduced production cost, in and spent acid consume a large amount of liquid caustic soda, the neutralization back generates a large amount of inorganic salt, and cost is raise, quality reduces.
The present invention utilizes alkali lye to extract earlier humic acids in the mud coal, again with it as neutralizing agent, the amino acid hydrolysis that neutralizes is with acid.The humic acids that generates as good trace element chelated dose, makes it " alkali is dual-purpose " simultaneously.Humic acids only could dissolve under the meta-alkalescence condition, and in PH＞7 o'clock, the inorganic salt hydrolysis of trace element generates precipitation of hydroxide, is difficult to and the humic acids chelating.And PH＜7 o'clock, humic acids does not dissolve, and is more difficult as ligand chelating dissolved metal ion.The present invention again with solubleness bigger alkaline humic acid solution plays chelating, neutralization reaction with chelating amino acids with trace element under acidic conditions, solved humic acids problem of difficult chelated microelement all under acid-base condition.Because the molecular weight of humic acids microelement chelate is big, stable performance, be difficult for by microbial consumption, can prolong the time of utilizing for farm crop, effectively reduce production cost, obtain the effect of killing two birds with one stone, make this compound inner complex both can be used for doing foliage fertilizer, water fertilizing, drip irrigation fertilizer can be used as base manure again, also can be composite with other composite fertilizer, BB fertilizer.Overcome amino acid because of the cost height, easily run off and be difficult to the shortcoming used as base manure, had both amino acid, humic acids advantage, had bigger use range and better effect of increasing production than single ligand as ligand.
For achieving the above object, the technical solution used in the present invention is:
1. producing of composite aminoacid chelating liquid: will discard protein 10 00kg and add in 3000 liters of enamel reactors, and add hydrochloric acid 1500～2000kg of 30～35%, the passageway is steam heated to 100 ℃ of hydrolysis.After the protein dissolving, add trace element 100～150kg (inorganic salt are converted into the element meter) under 100～110 ℃, continue hydrolysis after 4～8 hours, remove spent acid, be composite aminoacid chelating liquid with vacuum-evaporation.
2. producing of humic acid solution: at 10m
3Iron flask in add 2% NaOH solution 8m
3, stir, add mud coal 1T again, be heated to boiling, kept 2 hours, surplus heat is filtered with plate-and-frame filter press.Filtrate through vacuum concentration to 2m
3, be the humic acids concentrated solution.
3. the composite aminoacid chelating liquid that will produce is controlled PH5-6 with the neutralization of humic acids concentrated solution, is dried with spray drying device, is finished product.
In conjunction with the embodiments, the present invention is further described:
Example 1:
Take by weighing the 1000kg feather stem and join 3000 liters of enamel reactors, be heated to 100 ℃, hydrolysis 2 hours is all dissolved to feather stem, adds ZnSO
47H
2O 200kg, FeSO
47H
2O200kg, MnSO
4H
2O 200kg, CuSO
45H
2O 50kg continues hydrolysis 5 hours down at 100～110 ℃, and vacuum-evaporation deacidifies to 500 liters, makes composite aminoacid chelating liquid A.Other gets mud coal 1000kg, stirs to add down 7m is housed
3In the iron flask of 2% NaOH solution, lead directly to and be steam heated to boiling, kept 2 hours, surplus heat is removed insolubles with plate-and-frame filter press.Solution with vacuum concentration to 2m
3, make humic acid solution B, B liquid is added the A neutralization, make PH reach 5-6 and continue to be concentrated into glue, suction spraying machine drying is compound trace element chelated fertilizer required for the present invention.
Example 2:
Take by weighing the 1000kg cotton cake dregs, join 3000 liters of enamel reactors, add the H of 1800kg35%
2SO
4, being heated to 100～110 ℃, hydrolysis 8 hours is aminoacids solution A.Other gets 7m
32% KOH adds 10m
3Iron flask in, stir progressively to add down and be crushed to 100 purpose mud coals.Lead directly to and be steam heated to boiling, and stirred 2 hours, filter, remove the lixiviating insolubles, solution is humic acids B.B liquid is progressively added the solution A neutralization, regulate PH and reach 5-6, add MnSO
4H
2O, 600kg carry out chelatropic reaction under 100 ℃, be compound humic acids manganese liquid C, with C liquid spray tower drying, are compound chelating manganese fertilizer required for the present invention.
Claims (8)
1. compound trace element chelated fertilizer and preparation method thereof, be that waste protein is added trace element, with generating amino acid trace element chelated salt liquid after the acid hydrolysis, the humic acid liquid of getting in the mud coal with the alkali lixiviate is made neutralizing agent again, remove the acid of amino acid hydrolyticsolution, control PH=5-6.Generate the microelement chelate that the amino acid humic acids is a ligand simultaneously.
2. waste protein according to claim 1 can be that the people sends out, hair, hoof, angle, the grouts of vegetables oil, silkworm chrysalis and the protein that reclaims of pig hair, feather, ox horn and all fowl poultry kinds from industrial effluent.
3. trace element according to claim 1 can be Fe, the inorganic salt of Cu, Zn, Mn, B, rare earth or oxide compound.
4. can be H according to the described hydrolysis of claim 1 with acid
2SO
4, HCL, H
3PO
4And any two or three mixed acid of three kinds of acid.
5. can be weathered coal, humic acids content 20～65% according to the described mud coal of claim 1.
6. neutralizing agent according to claim 1 can be humic acids, the xanthohumic acid liquid that the lixiviate mud coal extracts.
7. the method for hydrolysis amino acid according to claim 1, be to discard protein 10 to add the enamel reactor for 0 part, add 150～250 parts of concentration again and be 15～40% acid solution, add micro-inorganic salt or oxide compound after 1～2 hour 100～110 ℃ of following hydrolysis, continued hydrolysis, chelating 2～8 hours.
8. be to be that 1～10% alkali lye adds mud coal or weathered coal with concentration according to the described humic acids extraction process of claim 1, be heated to 80～105 ℃, lixiviate 1～4 hour generates alkaline humate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01103973 CN1371888A (en) | 2001-02-19 | 2001-02-19 | Compound trace element chelated fertilizer and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 01103973 CN1371888A (en) | 2001-02-19 | 2001-02-19 | Compound trace element chelated fertilizer and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1371888A true CN1371888A (en) | 2002-10-02 |
Family
ID=4653589
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 01103973 Pending CN1371888A (en) | 2001-02-19 | 2001-02-19 | Compound trace element chelated fertilizer and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1371888A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102206109A (en) * | 2010-03-29 | 2011-10-05 | 史蒂芬·苏克 | A preparation method of keratin fertilizer with colloidal humic acid additive and keratin fertilizer with humic acid additive |
| CN103232282A (en) * | 2012-09-28 | 2013-08-07 | 石河子大学 | Amino acid composite drip-irrigation fertilizer |
| CN103601600A (en) * | 2013-06-19 | 2014-02-26 | 中农舜天生态肥业有限公司 | Double-enzyme synergized sustain-released urea and preparation method thereof |
| CN103708892A (en) * | 2013-12-27 | 2014-04-09 | 四川通丰科技有限公司 | Production method of amino acid secondary element fertilizer |
| CN106083449A (en) * | 2016-06-07 | 2016-11-09 | 潍坊学院 | A kind of method that waste water produced with poultry feather processing feather powder prepares organic liquid compound fertilizer for water preparation |
| CN106431769A (en) * | 2016-10-26 | 2017-02-22 | 秦皇岛五弦维爱科技开发有限公司 | Fertilizer synergist containing amino acid and preparation method of fertilizer synergist |
| CN108929149A (en) * | 2018-06-28 | 2018-12-04 | 广西浙缘农业科技有限公司 | A method of Liquid organic fertilizer is prepared using bagasse paper-making pulping black liquor |
-
2001
- 2001-02-19 CN CN 01103973 patent/CN1371888A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102206109A (en) * | 2010-03-29 | 2011-10-05 | 史蒂芬·苏克 | A preparation method of keratin fertilizer with colloidal humic acid additive and keratin fertilizer with humic acid additive |
| CN102206109B (en) * | 2010-03-29 | 2015-01-28 | 史蒂芬·苏克 | Preparation method of keratin fertilizer with colloidal humic acid additive and keratin fertilizer with humic acid additive |
| CN103232282A (en) * | 2012-09-28 | 2013-08-07 | 石河子大学 | Amino acid composite drip-irrigation fertilizer |
| CN103601600A (en) * | 2013-06-19 | 2014-02-26 | 中农舜天生态肥业有限公司 | Double-enzyme synergized sustain-released urea and preparation method thereof |
| CN103708892A (en) * | 2013-12-27 | 2014-04-09 | 四川通丰科技有限公司 | Production method of amino acid secondary element fertilizer |
| CN103708892B (en) * | 2013-12-27 | 2015-12-09 | 四川通丰科技有限公司 | A kind of method for producing amino acid middle element fertilizer |
| CN106083449A (en) * | 2016-06-07 | 2016-11-09 | 潍坊学院 | A kind of method that waste water produced with poultry feather processing feather powder prepares organic liquid compound fertilizer for water preparation |
| CN106431769A (en) * | 2016-10-26 | 2017-02-22 | 秦皇岛五弦维爱科技开发有限公司 | Fertilizer synergist containing amino acid and preparation method of fertilizer synergist |
| CN108929149A (en) * | 2018-06-28 | 2018-12-04 | 广西浙缘农业科技有限公司 | A method of Liquid organic fertilizer is prepared using bagasse paper-making pulping black liquor |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103553749B (en) | Method for producing amino acid agricultural fertilizer through compound enzyme hydrolysis of fish skins and fish scales | |
| CN101671263A (en) | Method for preparing novel amino acid chelate | |
| CN101248839A (en) | Composite aminoacid chelating microelement pre-mix material and preparation method thereof | |
| CN104041675A (en) | Simple preparation method for amino acid microelement chelate | |
| CN107083410A (en) | The preparation method of compound amino acid and its chelate | |
| CN101993257B (en) | Method for preparation of high-activity compound organic fertilizer by waste acid liquid of D-glucosamine hydrochloride | |
| CN103044145A (en) | Technology for directly producing organic chelating compound fertilizer through pelleting by ammonia-acid method | |
| CN103044167A (en) | Technology for producing organic chelating polyelement compound fertilizer through guniting | |
| CN1371888A (en) | Compound trace element chelated fertilizer and preparation method thereof | |
| CN103708892A (en) | Production method of amino acid secondary element fertilizer | |
| CN1312238A (en) | Amino acid chelate fertilizer producing process | |
| CN109652093B (en) | Soil conditioner and preparation method and application thereof | |
| CN1468831A (en) | Application of amino acid-trace element chelate in composite fertilizer | |
| CN1061019C (en) | Amino-acid complex fertilizer and its mfg. method | |
| CN102464511A (en) | Preparation method of broussonetia papyrifera leaf fertilizer | |
| CN1420119A (en) | Process for preparing humic acid | |
| CN1785922A (en) | Amino acid silicon foliage fertilizer | |
| CN1089328C (en) | Amino acid granular compound fertilizer and its producing method | |
| CN1621393A (en) | Minim calcium element chelated foliage fertilizer | |
| CN1091430A (en) | The preparation method of built amino-acid chelate | |
| CN1785927A (en) | Composite intermediate and microelement chelated fertilizer and its production method | |
| CN1115311A (en) | Method for treatment of rapeseed cake dregs | |
| CN1467179A (en) | High-nitrogen organic fertilizer and production method thereof | |
| CN107879803A (en) | One kind uses aminoacid chelating microelement water-soluble fertilizer | |
| CN1371890A (en) | Compound intermediate trace element chelated fertilizer and productive method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |