CN107879803A - One kind uses aminoacid chelating microelement water-soluble fertilizer - Google Patents
One kind uses aminoacid chelating microelement water-soluble fertilizer Download PDFInfo
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- CN107879803A CN107879803A CN201711200556.5A CN201711200556A CN107879803A CN 107879803 A CN107879803 A CN 107879803A CN 201711200556 A CN201711200556 A CN 201711200556A CN 107879803 A CN107879803 A CN 107879803A
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- amino acid
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- mass ratio
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- absorption enhancers
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- 235000001014 amino acid Nutrition 0.000 title claims abstract description 97
- 150000001413 amino acids Chemical class 0.000 title claims abstract description 68
- 239000003337 fertilizer Substances 0.000 title claims abstract description 55
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000011573 trace mineral Substances 0.000 claims abstract description 26
- 235000013619 trace mineral Nutrition 0.000 claims abstract description 26
- 238000010521 absorption reaction Methods 0.000 claims abstract description 20
- 239000003623 enhancer Substances 0.000 claims abstract description 18
- 239000011159 matrix material Substances 0.000 claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 14
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 12
- 235000018102 proteins Nutrition 0.000 claims abstract description 12
- 102000004169 proteins and genes Human genes 0.000 claims abstract description 12
- 108090000623 proteins and genes Proteins 0.000 claims abstract description 12
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004202 carbamide Substances 0.000 claims abstract description 8
- 239000007864 aqueous solution Substances 0.000 claims abstract description 6
- 229930191978 Gibberellin Natural products 0.000 claims abstract description 5
- IXORZMNAPKEEDV-UHFFFAOYSA-N gibberellic acid GA3 Natural products OC(=O)C1C2(C3)CC(=C)C3(O)CCC2C2(C=CC3O)C1C3(C)C(=O)O2 IXORZMNAPKEEDV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000003448 gibberellin Substances 0.000 claims abstract description 5
- 230000007062 hydrolysis Effects 0.000 claims abstract description 4
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 4
- -1 compound Amino acid Chemical class 0.000 claims description 27
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 20
- 238000006243 chemical reaction Methods 0.000 claims description 11
- 229910052742 iron Inorganic materials 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 6
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 229910052796 boron Inorganic materials 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- 229910052802 copper Inorganic materials 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 6
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 239000007921 spray Substances 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 239000011572 manganese Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 239000011609 ammonium molybdate Substances 0.000 claims description 3
- 229940010552 ammonium molybdate Drugs 0.000 claims description 3
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 3
- 229910021538 borax Inorganic materials 0.000 claims description 3
- 150000001638 boron Chemical class 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 3
- 159000000007 calcium salts Chemical class 0.000 claims description 3
- 229960004643 cupric oxide Drugs 0.000 claims description 3
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 3
- 150000002696 manganese Chemical class 0.000 claims description 3
- 150000002751 molybdenum Chemical class 0.000 claims description 3
- 235000011837 pasties Nutrition 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 239000004328 sodium tetraborate Substances 0.000 claims description 3
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 150000003751 zinc Chemical class 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- UYPJNXMDDIGUFY-UHFFFAOYSA-M N.[OH-].[Mn+] Chemical compound N.[OH-].[Mn+] UYPJNXMDDIGUFY-UHFFFAOYSA-M 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- 235000010755 mineral Nutrition 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 239000011260 aqueous acid Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000002738 chelating agent Substances 0.000 description 3
- 230000009920 chelation Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000003275 alpha amino acid group Chemical group 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 230000020477 pH reduction Effects 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- IMQLKJBTEOYOSI-GPIVLXJGSA-N Inositol-hexakisphosphate Chemical compound OP(O)(=O)O[C@H]1[C@H](OP(O)(O)=O)[C@@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@H](OP(O)(O)=O)[C@@H]1OP(O)(O)=O IMQLKJBTEOYOSI-GPIVLXJGSA-N 0.000 description 1
- IMQLKJBTEOYOSI-UHFFFAOYSA-N Phytic acid Natural products OP(O)(=O)OC1C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C(OP(O)(O)=O)C1OP(O)(O)=O IMQLKJBTEOYOSI-UHFFFAOYSA-N 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- BOMINLBVYNPVIK-UHFFFAOYSA-N azane;manganese(2+) Chemical compound N.[Mn+2] BOMINLBVYNPVIK-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 229940068041 phytic acid Drugs 0.000 description 1
- 235000002949 phytic acid Nutrition 0.000 description 1
- 239000000467 phytic acid Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C9/00—Fertilisers containing urea or urea compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses one kind to use aminoacid chelating microelement water-soluble fertilizer, including absorption enhancers and fertilizer matrix and trace-element fertilizer, the fertilizer matrix to be made up of urea and plant ash, and the mass ratio of the urea and plant ash is 20：80, the absorption enhancers are gibberellin, and the mass ratio of fertilizer matrix and absorption enhancers is 1000:1, it is that first protein raw materials are placed in reactor that the trace-element fertilizer, which makes, add 5mol/L hydrochloric acid, wherein protein raw materials and hydrochloric acid ratio are 1kg: 10L, hydrolyzed 6~10 hours at a temperature of 60 70 DEG C, after hydrolysis completely, with sodium hydroxide and remaining hydrochloric acid, complex amino acid aqueous solution is obtained；One kind aminoacid chelating microelement water-soluble fertilizer, cost is cheap, and operation production is simple, mass ratio between trace element can be controlled accurately, and the utilization rate of trace element is high, and plant easily absorbs, harm will not be produced to human body, plant, also will not contaminated land.
Description
Technical field
It is more particularly to a kind of to use aminoacid chelating microelement water-soluble fertilizer the present invention relates to fertilizer field.
Background technology
Into after 21st century, with the development that agricultural modernization produces, people, which look forward to fertilizer field, to be occurred
With multi-functional fertilizer, can improved soil improve crops yield quality, improve production efficiency, reduce production or
Improve working conditions, conservation of nature environment, be able to eat people favourable to health, non-harmful agricultural product.
The trace-element fertilizer that China applies at present is mostly mineral sulfates and chloride, these fertilizer individually or and its
After its fertilizer compound is manured into soil, nutrient can often occur fixes or deteriorates to indissoluble salt, causes micro- fertile utilization rate low very
To whole failures.Even some trace elements of foliage-spray such as ferrous iron, can also be oxidized to high price iron quickly, it is difficult to meet to make
The needs of thing growth, it is in recent years, external to produce the micro- fertilizer of Chelating state by the use of EDTA as chelating agent more, although fertilizer efficiency is obviously improved,
But EDTA, it stimulates skin, mucous membrane, causes asthma, the negative effect of skin breakouts is shown especially, is that one kind may cause
The material of allergy, and be not easy to store after EDTA chelatings, price is high.
The content of the invention
The technical problem to be solved in the present invention is to provide one kind to use aminoacid chelating microelement water-soluble fertilizer.
In order to solve the above-mentioned technical problem, the technical scheme is that one kind aminoacid chelating microelement is water-soluble
Fertilizer, including absorption enhancers and fertilizer matrix and trace-element fertilizer, the fertilizer matrix are made up of urea and plant ash,
The mass ratio of the urea and plant ash is 20：80, the absorption enhancers are gibberellin, and fertilizer matrix and absorption enhancers
Mass ratio is 1000:1, it is that first protein raw materials are placed in reactor that the trace-element fertilizer, which makes, adds 5mol/L salt
Acid, wherein protein raw materials and hydrochloric acid ratio are 1kg: 10L, are hydrolyzed 6~10 hours at a temperature of 60-70 DEG C, treat that hydrolysis is complete
Afterwards, with sodium hydroxide and remaining hydrochloric acid, obtain complex amino acid aqueous solution, by resulting complex amino acid aqueous solution according to
The mass ratio of trace element addition is divided into 7 parts, and the compound amino acid mixes to obtain amino acid calcium with calcium salt, described multiple
Amino acid is closed to mix to obtain amino acid boron with boron salt, the compound amino acid mixes to obtain amino acid copper with mantoquita,
The compound amino acid mixes to obtain amino acid iron with molysite, and the compound amino acid mixes to obtain ammonia with manganese salt
Base acid manganese, the compound amino acid mix to obtain amino-acid zinc with zinc salt, and the compound amino acid mixes with molybdenum salt
Obtain amino acid molybdenum, the micro- raw material of addition is iron oxide, zinc oxide, cupric oxide, calcium carbonate, manganese oxide ammonium molybdate
Gone again by dissolving with hydrochloric acid with borax and chelating amino acids, raw material is cheap and easily-available, and technique is simple, by amino acid calcium, amino acid
Boron, amino acid copper, amino acid iron, manganese amino acid, amino-acid zinc and amino acid molybdenum mix by concentrating, wash, after dry and crushing
It is combined, fertilizer matrix, absorption enhancers and trace-element fertilizer is remixed, and their mass ratio 1000：1：1000.
Further, the fertilizer matrix and absorption enhancers are by mixer uniform stirring, and are added in whipping process
Water is stirred for 1 hour, then dried up to turning into pasty state.
Further, during the chelating amino acids metal, the metal salt of addition and the mol ratio of compound amino acid are 1：2.
Further, the micro- raw material of the addition is iron oxide, zinc oxide, cupric oxide, calcium carbonate, is aoxidized
Manganese ammonium molybdate and borax is gone again by dissolving with hydrochloric acid and chelating amino acids.
Further, the pH of the chelatropic reaction is between 7.0~7.5, and reaction temperature is 40 DEG C, and the reaction time is 1h,
The pH of the amino acid iron chelatropic reaction is between 6.0~6.5.
Further, the fertilizer is dissolved in water, and mass ratio is 1：10, spray in the morning.
The beneficial effects of the invention are as follows：One kind aminoacid chelating microelement water-soluble fertilizer, cost is cheap, operation
Production is simple, and chelating agent is amino acid, is obtained by protein acidification, and the raw material of protein is unlimited, for production
Chelating amino acids agent reduces cost, and during chelating, each trace element is independent to carry out chelatropic reaction, adds chelating
Rate, the dosage of trace element is saved, and the mass ratio between trace element can be controlled accurately, amino-acid chelate can be kept away
Exempt from the negative effect caused by the phytic acid in plant absorbs with fiber for free metal ion, improve micro plain utilization
Rate, and it is nontoxic.
Embodiment
The embodiment of the present invention is described further below.Herein it should be noted that for these implementations
The explanation of mode is used to help understand the present invention, but does not form limitation of the invention.In addition, this hair disclosed below
As long as involved technical characteristic does not form conflict can and is mutually combined each other in bright each embodiment.
The present invention provides a kind of technical scheme：One kind uses aminoacid chelating microelement water-soluble fertilizer, including absorption enhancers
With fertilizer matrix and trace-element fertilizer, fertilizer matrix is made up of urea and plant ash, and the mass ratio of urea and plant ash is
20：80, absorption enhancers are gibberellin, and the mass ratio of fertilizer matrix and absorption enhancers is 1000:1, fertilizer matrix absorbs with promoting
Agent adds water until turning into pasty state by mixer uniform stirring in whipping process, is stirred for 1 hour, then dries
It is dry, prevent that local concentration is too high in order to which absorption enhancers are uniformly mixed, it is first to be placed in protein raw materials that trace-element fertilizer, which makes,
In reactor, 5mol/L hydrochloric acid is added, wherein protein raw materials and hydrochloric acid ratio are 1kg: 10L, the water at a temperature of 60-70 DEG C
Solution 6~10 hours, after hydrolysis completely, with sodium hydroxide and remaining hydrochloric acid, obtaining complex amino acid aqueous solution, will obtained by
Complex amino acid aqueous solution be divided into 7 parts according to the mass ratio of trace element addition, compound amino acid mixes with calcium salt
To amino acid calcium, compound amino acid mixes to obtain amino acid boron with boron salt, and compound amino acid mixes to obtain with mantoquita
Amino acid copper, compound amino acid mix to obtain amino acid iron with molysite, and compound amino acid mixes to obtain ammonia with manganese salt
Base acid manganese, compound amino acid mix to obtain amino-acid zinc with zinc salt, and compound amino acid mixes to obtain amino with molybdenum salt
Sour molybdenum, during chelating amino acids metal, the metal salt of addition and the mol ratio of compound amino acid are 1：2, chelation percent is high, Bu Huizao
Wasted into metal salt, for the pH of chelatropic reaction between 7.0~7.5, reaction temperature is 40 DEG C, and the reaction time is 1h, and chelation percent is high
It will not cause to waste, the pH of amino acid iron chelatropic reaction prevents from producing iron hydroxide during chelating between 6.0~6.5
Precipitation, by amino acid calcium, amino acid boron, amino acid copper, amino acid iron, manganese amino acid, amino-acid zinc and amino acid molybdenum through overrich
Contracting, washing, dry and mixed after crushing, fertilizer matrix, absorption enhancers and trace-element fertilizer are remixed, and it
Mass ratio 1000：1：1000, fertilizer is dissolved in water, and mass ratio is 1：10, spray in the morning, aqueous solvent plant is made
Thing easily absorbs, and it is high to micro- utilization rate that spray plant in the morning.
The present invention can play following effect：
(1) aminoacid chelating microelement, plant absorption rate is high, and nontoxic；
(2) chelating agent is amino acid, is obtained by protein acidification, and the raw material of protein is unlimited, is reduced
Cost；
(3) each trace element is independent carries out chelatropic reaction, adds chelation percent, saves the dosage of trace element, and
Mass ratio between trace element can be controlled accurately；
(4) micro gibberellin is added with, absorption of the plant to trace element can be stimulated, adds the profit of trace element
With rate.
Embodiments of the present invention are explained in detail above, but the invention is not restricted to described embodiment.It is right
For those skilled in the art, in the case where not departing from the principle of the invention and spirit, these embodiments are carried out more
Kind change, modification, replacement and modification, still fall within protection scope of the present invention and are related to irrigation technology field.
Claims (6)
1. one kind uses aminoacid chelating microelement water-soluble fertilizer, including absorption enhancers and fertilizer matrix and trace-element fertilizer,
It is characterized in that：The fertilizer matrix is made up of urea and plant ash, and the mass ratio of the urea and plant ash is 20：80,
The absorption enhancers are gibberellin, and the mass ratio of fertilizer matrix and absorption enhancers is 1000:1, the trace-element fertilizer system
Work is that first protein raw materials are placed in reactor, adds 5mol/L hydrochloric acid, and wherein protein raw materials and hydrochloric acid ratio are 1kg:
10L, hydrolyzed 6~10 hours at a temperature of 60-70 DEG C, after hydrolysis completely, with sodium hydroxide and remaining hydrochloric acid, obtain compound ammonia
Base aqueous acid, resulting complex amino acid aqueous solution is divided into 7 parts according to the mass ratio of trace element addition, it is described compound
Amino acid mixes to obtain amino acid calcium with calcium salt, and the compound amino acid mixes to obtain amino acid boron, institute with boron salt
State compound amino acid to mix to obtain amino acid copper with mantoquita, the compound amino acid mixes to obtain amino acid with molysite
Iron, the compound amino acid mix to obtain manganese amino acid with manganese salt, and the compound amino acid mixes to obtain with zinc salt
Amino-acid zinc, the compound amino acid mixes to obtain amino acid molybdenum with molybdenum salt, by amino acid calcium, amino acid boron, amino acid
Copper, amino acid iron, manganese amino acid, amino-acid zinc and amino acid molybdenum mix by concentrating, wash, after dry and crushing,
Fertilizer matrix, absorption enhancers and trace-element fertilizer are remixed, and their mass ratio 1000：1：1000.
2. one kind according to claim 1 uses aminoacid chelating microelement water-soluble fertilizer, it is characterised in that：The fertilizer
Matrix and absorption enhancers add water until turning into pasty state by mixer uniform stirring in whipping process, are stirred for 1 small
When, then dry.
3. one kind according to claim 1 uses aminoacid chelating microelement water-soluble fertilizer, it is characterised in that：The amino
During sour chelated mineral, the metal salt of addition and the mol ratio of compound amino acid are 1：2.
4. one kind according to claim 1 uses aminoacid chelating microelement water-soluble fertilizer, it is characterised in that：The addition
Micro- raw material be iron oxide, zinc oxide, cupric oxide, calcium carbonate, manganese oxide ammonium molybdate and borax pass through dissolving with hydrochloric acid
Go again and chelating amino acids.
5. one kind according to claim 1 uses aminoacid chelating microelement water-soluble fertilizer, it is characterised in that：The chelating
The pH of reaction is between 7.0~7.5, and reaction temperature is 40 DEG C, and the reaction time is 1h, and the pH of the amino acid iron chelatropic reaction exists
Between 6.0~6.5.
6. one kind according to claim 1 uses aminoacid chelating microelement water-soluble fertilizer, it is characterised in that：The fertilizer
It is dissolved in water, and mass ratio is 1：10, spray in the morning.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711200556.5A CN107879803A (en) | 2017-11-27 | 2017-11-27 | One kind uses aminoacid chelating microelement water-soluble fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711200556.5A CN107879803A (en) | 2017-11-27 | 2017-11-27 | One kind uses aminoacid chelating microelement water-soluble fertilizer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107879803A true CN107879803A (en) | 2018-04-06 |
Family
ID=61775364
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711200556.5A Pending CN107879803A (en) | 2017-11-27 | 2017-11-27 | One kind uses aminoacid chelating microelement water-soluble fertilizer |
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| Country | Link |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023230428A1 (en) * | 2022-05-24 | 2023-11-30 | Statera Ag, Llc | Agriculturally useful mineral amino acid complexes |
| CN118146050A (en) * | 2024-01-24 | 2024-06-07 | 江苏方祥生物科技有限公司 | Fertilizer using yellow water as raw material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003022782A1 (en) * | 2001-09-12 | 2003-03-20 | N.S. Hjelte Ab | A new iron chelate composition |
| CN101781151A (en) * | 2010-03-16 | 2010-07-21 | 北京中研美华生化研究所 | Amino acid chelated medium and trace element water-soluble fertilizer in and preparation method thereof |
| CN102503650A (en) * | 2011-09-02 | 2012-06-20 | 单茂莹 | Amino acid chelated fertilizer and preparation method thereof |
-
2017
- 2017-11-27 CN CN201711200556.5A patent/CN107879803A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003022782A1 (en) * | 2001-09-12 | 2003-03-20 | N.S. Hjelte Ab | A new iron chelate composition |
| CN101781151A (en) * | 2010-03-16 | 2010-07-21 | 北京中研美华生化研究所 | Amino acid chelated medium and trace element water-soluble fertilizer in and preparation method thereof |
| CN102503650A (en) * | 2011-09-02 | 2012-06-20 | 单茂莹 | Amino acid chelated fertilizer and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2023230428A1 (en) * | 2022-05-24 | 2023-11-30 | Statera Ag, Llc | Agriculturally useful mineral amino acid complexes |
| CN118146050A (en) * | 2024-01-24 | 2024-06-07 | 江苏方祥生物科技有限公司 | Fertilizer using yellow water as raw material and preparation method thereof |
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Application publication date: 20180406 |