CN1267451A - Mineral oil-containing pesticide for protecting plant - Google Patents
Mineral oil-containing pesticide for protecting plant Download PDFInfo
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- CN1267451A CN1267451A CN 99103377 CN99103377A CN1267451A CN 1267451 A CN1267451 A CN 1267451A CN 99103377 CN99103377 CN 99103377 CN 99103377 A CN99103377 A CN 99103377A CN 1267451 A CN1267451 A CN 1267451A
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- Prior art keywords
- mineral oil
- pesticide
- oil
- agricultural chemicals
- machine oil
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- 239000002480 mineral oil Substances 0.000 title claims abstract description 16
- 235000010446 mineral oil Nutrition 0.000 title claims abstract description 14
- 239000000575 pesticide Substances 0.000 title claims abstract description 13
- 239000005660 Abamectin Substances 0.000 claims abstract description 10
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims abstract description 7
- 239000005906 Imidacloprid Substances 0.000 claims abstract description 5
- BUHNCQOJJZAOMJ-UHFFFAOYSA-N ZXI 8901 Chemical compound C=1C=C(OC(F)F)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=C(Br)C=C1 BUHNCQOJJZAOMJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- JLQUFIHWVLZVTJ-UHFFFAOYSA-N carbosulfan Chemical compound CCCCN(CCCC)SN(C)C(=O)OC1=CC=CC2=C1OC(C)(C)C2 JLQUFIHWVLZVTJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229940056881 imidacloprid Drugs 0.000 claims abstract description 5
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000005916 Methomyl Substances 0.000 claims abstract description 3
- QXAITBQSYVNQDR-ZIOPAAQOSA-N amitraz Chemical compound C=1C=C(C)C=C(C)C=1/N=C/N(C)\C=N\C1=CC=C(C)C=C1C QXAITBQSYVNQDR-ZIOPAAQOSA-N 0.000 claims abstract description 3
- 229960002587 amitraz Drugs 0.000 claims abstract description 3
- -1 etc.) Chemical compound 0.000 claims abstract description 3
- UHXUZOCRWCRNSJ-QPJJXVBHSA-N methomyl Chemical compound CNC(=O)O\N=C(/C)SC UHXUZOCRWCRNSJ-QPJJXVBHSA-N 0.000 claims abstract description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 24
- 239000010721 machine oil Substances 0.000 claims description 16
- 239000003921 oil Substances 0.000 claims description 15
- 239000003905 agrochemical Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 5
- 239000003120 macrolide antibiotic agent Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000003995 emulsifying agent Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- KAATUXNTWXVJKI-NSHGMRRFSA-N (1R)-cis-(alphaS)-cypermethrin Chemical compound CC1(C)[C@@H](C=C(Cl)Cl)[C@H]1C(=O)O[C@H](C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-NSHGMRRFSA-N 0.000 claims description 2
- XJFIKRXIJXAJGH-UHFFFAOYSA-N 5-chloro-1,3-dihydroimidazo[4,5-b]pyridin-2-one Chemical group ClC1=CC=C2NC(=O)NC2=N1 XJFIKRXIJXAJGH-UHFFFAOYSA-N 0.000 claims description 2
- 239000005945 Chlorpyrifos-methyl Substances 0.000 claims description 2
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 230000000740 bleeding effect Effects 0.000 claims description 2
- 150000004657 carbamic acid derivatives Chemical class 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- XQUXKZZNEFRCAW-UHFFFAOYSA-N fenpropathrin Chemical compound CC1(C)C(C)(C)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 XQUXKZZNEFRCAW-UHFFFAOYSA-N 0.000 claims description 2
- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 claims description 2
- YFVOXLJXJBQDEF-UHFFFAOYSA-N isocarbophos Chemical compound COP(N)(=S)OC1=CC=CC=C1C(=O)OC(C)C YFVOXLJXJBQDEF-UHFFFAOYSA-N 0.000 claims description 2
- 239000003350 kerosene Substances 0.000 claims description 2
- 239000002075 main ingredient Substances 0.000 claims description 2
- 238000005120 petroleum cracking Methods 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
- 239000002728 pyrethroid Substances 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- 230000000749 insecticidal effect Effects 0.000 claims 2
- 230000000895 acaricidal effect Effects 0.000 claims 1
- 238000013329 compounding Methods 0.000 claims 1
- 238000003912 environmental pollution Methods 0.000 claims 1
- 239000012530 fluid Substances 0.000 claims 1
- 238000009472 formulation Methods 0.000 claims 1
- 241000607479 Yersinia pestis Species 0.000 abstract description 4
- 239000005946 Cypermethrin Substances 0.000 abstract 1
- 239000000642 acaricide Substances 0.000 abstract 1
- ONHBDDJJTDTLIR-UHFFFAOYSA-N azocyclotin Chemical compound C1CCCCC1[Sn](N1N=CN=C1)(C1CCCCC1)C1CCCCC1 ONHBDDJJTDTLIR-UHFFFAOYSA-N 0.000 abstract 1
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229960005424 cypermethrin Drugs 0.000 abstract 1
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 abstract 1
- 230000035515 penetration Effects 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 230000000241 respiratory effect Effects 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 11
- 239000008096 xylene Substances 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 7
- 241000238631 Hexapoda Species 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 description 3
- 241000500437 Plutella xylostella Species 0.000 description 3
- 229950008167 abamectin Drugs 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 239000004495 emulsifiable concentrate Substances 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 241001124076 Aphididae Species 0.000 description 2
- 241001600407 Aphis <genus> Species 0.000 description 2
- 241000594033 Liriomyza bryoniae Species 0.000 description 2
- RMIXHJPMNBXMBU-UHFFFAOYSA-N Nonactin Natural products CC1C(=O)OC(C)CC(O2)CCC2C(C)C(=O)OC(C)CC(O2)CCC2C(C)C(=O)OC(C)CC(O2)CCC2C(C)C(=O)OC(C)CC2CCC1O2 RMIXHJPMNBXMBU-UHFFFAOYSA-N 0.000 description 2
- 241000187392 Streptomyces griseus Species 0.000 description 2
- 241001454293 Tetranychus urticae Species 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 241001182720 Cacopsylla pyrisuga Species 0.000 description 1
- 241001498622 Cixius wagneri Species 0.000 description 1
- CTZNINKRTKCWGU-UHFFFAOYSA-N Dinactin Natural products CC1C(=O)OC(C)CC(O2)CCC2C(C)C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(C)CC2CCC1O2 CTZNINKRTKCWGU-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000255967 Helicoverpa zea Species 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- YPUPRVWRYDPGCW-UHFFFAOYSA-N Monactin Natural products CC1C(=O)OC(C)CC(O2)CCC2C(C)C(=O)OC(C)CC(O2)CCC2C(C)C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(C)CC2CCC1O2 YPUPRVWRYDPGCW-UHFFFAOYSA-N 0.000 description 1
- 241000409991 Mythimna separata Species 0.000 description 1
- RMIXHJPMNBXMBU-QIIXEHPYSA-N Nonactin Chemical compound C[C@H]([C@H]1CC[C@H](O1)C[C@@H](OC(=O)[C@@H](C)[C@@H]1CC[C@@H](O1)C[C@@H](C)OC(=O)[C@H](C)[C@H]1CC[C@H](O1)C[C@H](C)OC(=O)[C@H]1C)C)C(=O)O[C@H](C)C[C@H]2CC[C@@H]1O2 RMIXHJPMNBXMBU-QIIXEHPYSA-N 0.000 description 1
- 241000255969 Pieris brassicae Species 0.000 description 1
- 241001468227 Streptomyces avermitilis Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- NKNPHSJWQZXWIX-DCVDGXQQSA-N Tetranactin Chemical compound C[C@H]([C@H]1CC[C@H](O1)C[C@@H](OC(=O)[C@@H](C)[C@@H]1CC[C@@H](O1)C[C@@H](CC)OC(=O)[C@H](C)[C@H]1CC[C@H](O1)C[C@H](CC)OC(=O)[C@H]1C)CC)C(=O)O[C@H](CC)C[C@H]2CC[C@@H]1O2 NKNPHSJWQZXWIX-DCVDGXQQSA-N 0.000 description 1
- NKNPHSJWQZXWIX-UHFFFAOYSA-N Tetranactin Natural products CC1C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(CC)CC2CCC1O2 NKNPHSJWQZXWIX-UHFFFAOYSA-N 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- ZBDGIMZKOJALMU-MVWQHRGOSA-N dinactin Chemical compound C[C@@H]([C@@H]1CC[C@@H](O1)C[C@@H](OC(=O)[C@@H](C)[C@H]1CC[C@H](O1)C[C@@H](C)OC(=O)[C@@H](C)[C@@H]1CC[C@@H](O1)C[C@H](CC)OC(=O)[C@H]1C)CC)C(=O)O[C@H](C)C[C@@H]2CC[C@H]1O2 ZBDGIMZKOJALMU-MVWQHRGOSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 210000001339 epidermal cell Anatomy 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- YPUPRVWRYDPGCW-GGOMOPATSA-N monactin Chemical compound C[C@H]([C@H]1CC[C@H](O1)C[C@@H](OC(=O)[C@@H](C)[C@@H]1CC[C@@H](O1)C[C@@H](C)OC(=O)[C@H](C)[C@H]1CC[C@H](O1)C[C@H](C)OC(=O)[C@H]1C)CC)C(=O)O[C@H](C)C[C@H]2CC[C@@H]1O2 YPUPRVWRYDPGCW-GGOMOPATSA-N 0.000 description 1
- 230000035772 mutation Effects 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- DFQMKYUSAALDDY-MQEBUAKTSA-N trinactin Chemical compound C[C@@H]([C@@H]1CC[C@@H](O1)C[C@H](OC(=O)[C@H](C)[C@H]1CC[C@H](O1)C[C@H](CC)OC(=O)[C@@H](C)[C@@H]1CC[C@@H](O1)C[C@@H](CC)OC(=O)[C@@H]1C)CC)C(=O)O[C@@H](C)C[C@@H]2CC[C@H]1O2 DFQMKYUSAALDDY-MQEBUAKTSA-N 0.000 description 1
- DFQMKYUSAALDDY-UHFFFAOYSA-N trinactin Natural products CC1C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(CC)CC(O2)CCC2C(C)C(=O)OC(C)CC2CCC1O2 DFQMKYUSAALDDY-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The pesticide-miticide is compound with mineral oil and pesticide, which may be avermectin, linyangmycin, organophosphates (such as carbosulfan and methomyl), pyrethroids (such as high-effect cypermethrin, brofluthrinate, etc.), imidacloprid, amitraz and azocyclotin. It features that the mineral oil can enclose respiratory spiracle of pest, promote the penetration of pesticide component to the cutex cell of pest and thus raise the pesticide effect and may be used in preventing and killing various pests in agriculture.
Description
The present invention relates to mineral oil and chemical pesticide be used for control of insect after composite, belong to the agricultural chemical insecticide field.
Mineral oils is used in the anti-system aspect of pest very early, be used for preventing and treating the orchard insect that survives the winter as 95% machine oil emulsion, mineral oils effect characteristics are that it can seal the pore of insect body surface in order to breathe, insect is suffocated, can impel the epidermal cell infiltration of other agricultural chemicals in the complex preparation again, thereby make it give full play to drug effect to crop and insect.(chief editor " the newly organized agricultural chemicals handbook sequel P of The Institute for the Control of Agrochemicals of the Ministry of Agriculture,PRC
202-206).
The objective of the invention is composite by mineral oil and chemical pesticide, reduce chemical pesticide to the pollution of environment with reduce production costs.Below be specific descriptions of the present invention:
Other agricultural chemicals among the present invention comprises that Avermectin, macro tetrolide, organic phosphates have chlopyrifos, chlorpyrifos-methyl, isocarbophos, fenthion, carbamates has carbosulfan, Methomyl, pyrethroid has beta-cypermethrin, brofluthrinate, cyfloxylate, fenpropathrin, sumicidin, and other chemical pesticide refers to Imidacloprid, Amitraz, azacyclotin.
Mineral oil of the present invention is the petroleum cracking product, comprises machine oil, kerosene, and Main Ingredients and Appearance is the mixture of liquid saturated and unsaturated aliphatic hydrocarbon.
That emulsifier kind of the present invention has is cationic, anionic and nonionic, described bleeding agent mainly are JFC, and described solvent comprises dimethylbenzene, ethanol, acetone, isopropyl alcohol.
Avermectin is the tunning of A Foman streptomycete Streptomyces avermitilis among the present invention, the mixture that it is made up of eight quite similar homologues of structure.Be AvermectinA
1a, A
1b, A
2a, A
2b, B
1a, B
1b, B
2a, B
2b, that generally use is B more
1a, B
1bMixture, the also available ointment that contains above each component among the present invention.
Macro tetrolide among the present invention is the mite farm antibiotics extremely that is produced by streptomyces griseus Liuyang mutation Streptomyces griseus var iiuyanggensis fermentation, being made up of five components is tetranactin, Trinactin, dinactin, monactin, nonactin.
Compounded cream among the present invention compares with existing commercially available missible oil, the results are shown in Table 1 and table 2.
With several missible oil at one time, the place carries out field control effectiveness test, the equal dilute with water spraying of various missible oil, and respectively at observing and calculated preventive effect behind the medicine in 1 day, 3 days, 7 days, 14 days.
Table 1, several missible oil compare the field efficacy of diamond-back moth
| Medicament | Extension rate | Preventive effect behind the medicine (%) | ||
| Behind the medicine 1 day | Behind the medicine 3 days | Behind the medicine 7 days | ||
| Example 1 missible oil | 1000 | 77.7 | 92.5 | 80.2 |
| 0.2% abamectin emulsifiable concentrate | 1000 | 53.8 | 71.1 | 57.6 |
Annotate: 0.2% abamectin emulsifiable concentrate in the table 1 is commercially available abamectin emulsifiable concentrate (New Tech. Development General Co., Beijing Agriculture Univ.'s production).
Table 2, several missible oil are to the cotten aphid field efficacy relatively
| Medicament | Extension rate | Medicine post-equalization preventive effect | ||
| Behind the medicine 1 day | Behind the medicine 3 days | Behind the medicine 7 days | ||
| Example 4 missible oil | 1000 | 95.9 | 94.9 | 94.6 |
| 0.2% good year winter missible oil | 2500 | 93.0 | 93.5 | 90.6 |
Annotate: good year winter missible oil of table 2 is commercially available carbosulfan missible oil (production of U.S. FMC Corp.).
By the result of this example as seen, use less dosage can obtain quite or better effect of common using dosage with the composite agricultural chemicals of mineral oil, explanation can reduce its usage amount add mineral oil in chemical pesticide after, has reduced the pollution of chemical pesticide to environment thereby reduced production cost.
Realize that technical scheme of the present invention is:
Example 1
This example is that preparation contains Avermectin 0.2%, the missible oil of machine oil 25%.
The oily liquid 2.0kg (containing Avermectin 0.20kg) that will contain Avermectin 10% with the 10kg xylene soluble after, add 50kgOP-10, mix No. 38 machine oil that the back adds 30kg thoroughly, 2kgJFC adds 100 liters of dimethylbenzene promptly behind the mixing.
This product is mainly used in insects such as control diamond-back moth, cabbage caterpillar, liriomyza bryoniae, pear sucker.
Example 2
This example is that preparation contains macro tetrolide 15%, the compounded cream of machine oil 50%.
With the former powder of macro tetrolide (purity 90%) 83.3kg, with the Tween-80 that adds 25kg after 50 liters of xylene soluble, stir evenly the back and add 250kg30 machine oil, add dimethylbenzene to 500 behind the mixing liter promptly.
This product is mainly used in control two spotted spider mite and vegetables evil mite.
Example 3
This example is that preparation contains Le Siben (chlopyrifos) 40%, the compounded cream of machine oil 15%.
To find pleasure in this basis powder (purity 90%) 222kg, and, stir evenly the back and add 75kg30 machine oil, add dimethylbenzene to 500 behind the mixing liter promptly with adding the 150kg Tween-80 after 80 liters of xylene soluble.
This product is mainly used in control scale insect, mythimna separata, aphid, thrips and mite class etc.
Example 4
This example is that preparation contains carbosulfan 5%, the missible oil of machine oil 25%.
6.25kg fourth sulphur crude oil (purity 80%) is used xylene soluble, add 5 liters of xylene soluble after, add 10kgOP-10, add No. 30 machine oil of 25kg then, the JFC of 5kg adds to 100 liters promptly with dimethylbenzene.
This product is mainly used in and anti-eliminates aphis, cotton bollworm, diamond-back moth, liriomyza bryoniae, plant hopper etc.
Example 5
This example is that preparation contains brofluthrinate 5%, the missible oil of machine oil 70%.
The former powder of 31.25kg brofluthrinate (purity 80%) is used xylene soluble, add 50 liters of xylene soluble after, add 50kgOP-21, add No. 38 machine oil of 350kg, the JFCA of 5kg then, add to 500 liters promptly with dimethylbenzene.
This product is mainly used in and anti-eliminates aphis, heart-eating worm, two spotted spider mite etc.
Example 6
This example is that preparation contains Imidacloprid 1%, the missible oil of machine oil 24%.
Will the former powder of 1.25kg Imidacloprid (purity 80%) with the OP-10 that adds 10kg after the 12kg xylene soluble, the OP-21 of 2kg, the JFC of 2kg adds No. 32 machine oil of 24kg behind the mixing, add to 100 liters with dimethylbenzene.
Claims (4)
1, a kind ofly contain the Insecticidal and acaricidal agent that mineral oil and other agriculture chemical compounding form, formulation is a missible oil, it is characterized in that: the adding of mineral oil, and the insecticidal effect of other agricultural chemicals is obviously improved, thereby reduced use cost, lowered the agricultural chemicals environmental pollution.
2, mineral oil according to claim 1 is the petroleum cracking product, mainly refers to machine oil and kerosene, it is characterized in that Main Ingredients and Appearance is the mixture of liquid saturated and unsaturated aliphatic hydrocarbon, No. 30 and No. 38 commonly used of machine oil.
3, other agricultural chemicals according to claim 1 comprise: Avermectin, macro tetrolide, organic phosphates (chlopyrifos, chlorpyrifos-methyl, isocarbophos, fenthion), carbamates (carbosulfan, Methomyl), pyrethroid (beta-cypermethrin, brofluthrinate, cyfloxylate, fenpropathrin, sumicidin) and the above agricultural chemicals of other chemical pesticide (Imidacloprid, Amitraz, azacyclotin) are the commercially available prod.
4, the desinsection that contains mineral oil according to claim 1, the content that kills mite Recompounded pesticide mineral oil in fluid are 3-90%, other pesticide concentration is 0.05-40%, that the emulsifier kind has is cationic, anionic, nonionic, emulsifier content are 3-50%, bleeding agent (as JFC) is 0-5%, and remaining solvent is (dimethylbenzene, ethanol, isopropyl alcohol, an acetone).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99103377 CN1267451A (en) | 1999-03-23 | 1999-03-23 | Mineral oil-containing pesticide for protecting plant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 99103377 CN1267451A (en) | 1999-03-23 | 1999-03-23 | Mineral oil-containing pesticide for protecting plant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1267451A true CN1267451A (en) | 2000-09-27 |
Family
ID=5271250
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99103377 Pending CN1267451A (en) | 1999-03-23 | 1999-03-23 | Mineral oil-containing pesticide for protecting plant |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1267451A (en) |
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| WO2006094371A3 (en) * | 2005-03-09 | 2007-06-28 | Fmc Quimica Do Brasil Ltda | Carbosulfane-based pesticidal compositions, process for preparing same, process for controlling insects/mites/nematodes, and use of said compositions |
| CN100348106C (en) * | 2005-08-27 | 2007-11-14 | 福建省泉州德盛农药有限公司 | Highly contented azocyclotin oil emulsion and its preparation method |
| CN101305717B (en) * | 2008-06-20 | 2011-07-20 | 戴康华 | Insecticidal spray EC and its preparation method |
| CN103222461A (en) * | 2013-05-22 | 2013-07-31 | 广西田园生化股份有限公司 | Environment-friendly mixed solvent used for pyrethroid pesticide preparation |
| CN103583559A (en) * | 2013-11-22 | 2014-02-19 | 济南凯因生物科技有限公司 | Suspoemulsion of theta-cypermethrin and benfuracarb and application thereof |
| CN104304283A (en) * | 2014-10-15 | 2015-01-28 | 济南新起点医药科技有限公司 | Water dispersible granules containing amitraz and application |
| CN104397012A (en) * | 2014-11-14 | 2015-03-11 | 济南新起点医药科技有限公司 | Wettable pulvis containing beta-cypermethrin and application |
| CN104838946A (en) * | 2015-05-07 | 2015-08-19 | 枞阳县弘阳园林绿化有限公司 | Citron planting method |
| CN105165808A (en) * | 2015-07-02 | 2015-12-23 | 河北岗恩生物科技有限公司 | Benzene series solvent substitute sulfonated kerosene and application thereof in carbosulfan emulsifiable concentrate |
| CN105165807A (en) * | 2015-07-02 | 2015-12-23 | 河北岗恩生物科技有限公司 | Benzene series solvent substitute sulfonated kerosene and application thereof in chlorpyrifos emulsifiable concentrate |
| CN105165809A (en) * | 2015-07-02 | 2015-12-23 | 河北天发化工科技有限公司 | Benzene series solvent substitute sulfonated kerosene and application thereof in cyhalothrin emulsifiable concentrate |
| CN105191915A (en) * | 2015-07-02 | 2015-12-30 | 河北天发化工科技有限公司 | Benzene-series solvent substitute sulfonated kerosene and application of sulfonated kerosene in beta-cypermethrin emulsifiable concentrate |
| CN105191914A (en) * | 2015-07-02 | 2015-12-30 | 河北岗恩生物科技有限公司 | Benzene-series solvent substitute sulfonated kerosene and application of sulfonated kerosene in trifluralin emulsifiable concentrate |
| CN105532653A (en) * | 2016-01-22 | 2016-05-04 | 河北天发化工科技有限公司 | Carbosulfan mineral emulsifiable concentrate and preparation method thereof |
| CN107751233A (en) * | 2017-09-21 | 2018-03-06 | 南通盛赫园林古建筑工程有限公司 | A kind of agricultural chemicals for removing trees insect |
| CN108835126A (en) * | 2018-06-27 | 2018-11-20 | 四川福思达生物技术开发有限责任公司 | A kind of agricultural insecticidal composite and its application containing nicotine compound and mineral oil |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006094371A3 (en) * | 2005-03-09 | 2007-06-28 | Fmc Quimica Do Brasil Ltda | Carbosulfane-based pesticidal compositions, process for preparing same, process for controlling insects/mites/nematodes, and use of said compositions |
| CN100348106C (en) * | 2005-08-27 | 2007-11-14 | 福建省泉州德盛农药有限公司 | Highly contented azocyclotin oil emulsion and its preparation method |
| CN101305717B (en) * | 2008-06-20 | 2011-07-20 | 戴康华 | Insecticidal spray EC and its preparation method |
| CN103222461A (en) * | 2013-05-22 | 2013-07-31 | 广西田园生化股份有限公司 | Environment-friendly mixed solvent used for pyrethroid pesticide preparation |
| CN103583559A (en) * | 2013-11-22 | 2014-02-19 | 济南凯因生物科技有限公司 | Suspoemulsion of theta-cypermethrin and benfuracarb and application thereof |
| CN104304283A (en) * | 2014-10-15 | 2015-01-28 | 济南新起点医药科技有限公司 | Water dispersible granules containing amitraz and application |
| CN104304283B (en) * | 2014-10-15 | 2016-08-24 | 青岛青知企业管理咨询有限公司 | A kind of water dispersible granules containing Amitraz and application |
| CN104397012B (en) * | 2014-11-14 | 2016-04-20 | 济南新起点医药科技有限公司 | A kind of wetting powder and application containing beta-cypermethrin |
| CN104397012A (en) * | 2014-11-14 | 2015-03-11 | 济南新起点医药科技有限公司 | Wettable pulvis containing beta-cypermethrin and application |
| CN104838946A (en) * | 2015-05-07 | 2015-08-19 | 枞阳县弘阳园林绿化有限公司 | Citron planting method |
| CN105165808A (en) * | 2015-07-02 | 2015-12-23 | 河北岗恩生物科技有限公司 | Benzene series solvent substitute sulfonated kerosene and application thereof in carbosulfan emulsifiable concentrate |
| CN105191915A (en) * | 2015-07-02 | 2015-12-30 | 河北天发化工科技有限公司 | Benzene-series solvent substitute sulfonated kerosene and application of sulfonated kerosene in beta-cypermethrin emulsifiable concentrate |
| CN105191914A (en) * | 2015-07-02 | 2015-12-30 | 河北岗恩生物科技有限公司 | Benzene-series solvent substitute sulfonated kerosene and application of sulfonated kerosene in trifluralin emulsifiable concentrate |
| CN105165809A (en) * | 2015-07-02 | 2015-12-23 | 河北天发化工科技有限公司 | Benzene series solvent substitute sulfonated kerosene and application thereof in cyhalothrin emulsifiable concentrate |
| CN105165807A (en) * | 2015-07-02 | 2015-12-23 | 河北岗恩生物科技有限公司 | Benzene series solvent substitute sulfonated kerosene and application thereof in chlorpyrifos emulsifiable concentrate |
| CN105191915B (en) * | 2015-07-02 | 2018-08-14 | 河北天发生物科技有限公司 | A kind of benzene-series solvent replacements sulfonated kerosene and its application in Beta-cypermethrin EC |
| CN105532653A (en) * | 2016-01-22 | 2016-05-04 | 河北天发化工科技有限公司 | Carbosulfan mineral emulsifiable concentrate and preparation method thereof |
| CN107751233A (en) * | 2017-09-21 | 2018-03-06 | 南通盛赫园林古建筑工程有限公司 | A kind of agricultural chemicals for removing trees insect |
| CN108835126A (en) * | 2018-06-27 | 2018-11-20 | 四川福思达生物技术开发有限责任公司 | A kind of agricultural insecticidal composite and its application containing nicotine compound and mineral oil |
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