[go: up one dir, main page]

CN1045948A - Production method of a kind of polyester decorative lamination decoration board and products thereof - Google Patents

Production method of a kind of polyester decorative lamination decoration board and products thereof Download PDF

Info

Publication number
CN1045948A
CN1045948A CN 89105883 CN89105883A CN1045948A CN 1045948 A CN1045948 A CN 1045948A CN 89105883 CN89105883 CN 89105883 CN 89105883 A CN89105883 A CN 89105883A CN 1045948 A CN1045948 A CN 1045948A
Authority
CN
China
Prior art keywords
mill base
parts
production method
polyester
precipitated calcium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 89105883
Other languages
Chinese (zh)
Other versions
CN1025838C (en
Inventor
石汇玉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGYUAN PRACTICAL TECHNOLOGY INST
Original Assignee
GUANGYUAN PRACTICAL TECHNOLOGY INST
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUANGYUAN PRACTICAL TECHNOLOGY INST filed Critical GUANGYUAN PRACTICAL TECHNOLOGY INST
Priority to CN 89105883 priority Critical patent/CN1025838C/en
Publication of CN1045948A publication Critical patent/CN1045948A/en
Application granted granted Critical
Publication of CN1025838C publication Critical patent/CN1025838C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Images

Landscapes

  • Laminated Bodies (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of production method of using existing multiple board making polyester decorative lamination decoration board, and (series) product of producing with this method, it is characterized in that cutting repairing (putting in order) afterwards, add inserts with adhesive sheet material plate face is sealed processing at sheet material; The multiple not homochromy monochromatic polyester mill base of unsaturated polyester resin furnishing, after solidify handling, carry out the assembly support according to the pattern of desired facing and decorative pattern and was handling on the plate face that dries row film covering rolling process production finish coat through above-mentioned sealing.Compared with prior art have can produce multiple use decorate with the polyester decorative lamination decoration board, save expensive mylar do not need mould, without remover, can make the colorful facings of many richnesses and need not advantage such as grinding and polishing.Its product surface meets or exceeds mirror surface luster, and surface layer on probation is not for a long time found to come off and be out of shape, and can be widely used in industries such as building, furniture and industrial art.

Description

Production method of a kind of polyester decorative lamination decoration board and products thereof
The present invention is the production method of relevant a kind of polyester decorative lamination decoration board and the product of producing with this method thereof, belongs to polyester complex type artificial marble production technology, and it comprises the preparation of sheet material, the preparation and the curing processing of unsaturated polyester resin mill base.
At present, prior art is produced the polyester decorative lamination decoration board, be to make raw material with inorganic material such as polyester and rock ballasts, on mould, the vibrate method production of moulding of employing, this method: a kind of technology is to produce sheet material earlier, be coated with spray one deck polyester gel coat at this plate surface then, make product through grinding and polishing after waiting to solidify; Another kind of technology is that elder generation's coated one deck polyester gel coat shakes flatly at the bottom of mould, and the compound material vibration of support basic unit moulding makes product again.
The former because in the process that is coated with spray polyester and grinding and polishing, causes polyester to fly upward and loses and destroyed surperficial glued membrane, therefore, has the expensive polyester of waste and increases cost and the low defective of facing glossiness.The latter because surface layer forms at the bottom of mould by vibration, therefore, needs both to have had the equipment investment height with surface gloss very high mould and remover, has the drawback of demoulding difficulty again.
Above-mentioned process because its basic unit needs to make bonding agent with polyester, therefore, can not reduce product cost effectively.Simultaneously, all can not make marbling facing true to nature and colourful moire facing, because, the formation of these decorative patterns, various (look) polyester of the inhomogeneous mixing of needs, mill base suitably interpenetrates and swoons and dye, and above-mentioned process, the former surface detail is to form by its background color; The latter is because vibration (moving) causes color and pattern blurring; Therefore inaccessible.
A said method suitable for producing building trade polyester decorative lamination decoration board, as furniture and industrial art industry incrustation material, but be not suitable for, because, just in its basic unit, because the characteristic of rock ballast, it is very thin to make that this sheet material can not make, and simultaneously, seems very heavy again, and thin and light feature need for furniture and industrial art industry incrustation.
In other words, the production method of the polyester decorative lamination decoration board that prior art provides, the defective that exists the product scope of application of its production to be restricted again.
The objective of the invention is to overcome above-mentioned the deficiencies in the prior art and provide a kind of save polyester, technology simple, can make colourful facing decorative pattern, can satisfy multiple industry and decorate production method, and with the product of this method production with, polyester decorative lamination decoration board with low cost.
In order to achieve the above object, the present invention proposes, use existing multiple sheet material (plasterboard, plank, laminate, bamboo slag plate, particieboard or paper fiber etc.) as the base material of producing the polyester decorative lamination decoration board, this is feasible, because it can play the effect of typing and supporting equally, and no longer need to be used as the bonding agent of basic unit with expensive polyester, and can select basic unit's sheet material of varying strength and thickness according to different needs, therefore, reduced the cost of product and enlarged its scope of application.
But, utilize existing sheet material as the base material of producing the polyester decorative lamination decoration board, do not consider that some its original characteristic is impossible, for example its surface has the characteristic of lower density and the structure of loosening, and makes that it is inappropriate directly producing the polyester finish coat at this plate surface.
Therefore, in order to make existing sheet material be suitable for producing polyester decorative lamination decoration board material as base material, the present invention proposes to use adhesive to add inserts to mix to give and earlier sheet material plate face is handled, said processing has one to be intended to fill and lead up hackly surface, the ground floor sealing step in sealing capillary fiber hole and one are intended to form one deck glued membrane, seal step to stop (completely cut off) mylar to the second layer that bottom (basic unit) permeates, is convenient to form the finish coat of smooth and high gloss.In fact, after the plate face dries by the said method processing, obtained such result: give higher density in this sheet material (basic unit) surface and steady and sure structure, strengthened the adhesive force of mylar and sheet material, and reduced the consumption of polyester mill base.
After the above-mentioned processing of sheet material process, the present invention proposes, the multiple not homochromy monochromatic polyester mill base of unsaturated polyester resin furnishing, after solidifying processing, pattern and decorative pattern by desired facing carry out the assembly support on the plate face, and the row film hides rolling process and produces finish coat.
Because various monochromatic polyester mill bases can or carry out assembly with of the same colour, two looks more than two looks, and the characteristic that interpenetrating is arranged and swoon and dye between the not homochromy polyester mill base, therefore, can make colourful, that third dimension is strong facing pattern and decorative pattern; And the film covering has prevented the inhibition of airborne oxygen to the mylar polymerisation, and has formed one deck glued membrane at the handing-over interface of film and polyester, therefore, has guaranteed behind the demoulding that facing has a high glossiness.
In sum, the inventive method is characterised in that: cut repairing (putting in order) afterwards at sheet material, add the inserts mixing with adhesive sheet material plate face is sealed processing, said sealing is handled has a ground floor sealing step and a second layer sealing to handle; The multiple not homochromy monochromatic polyester mill base of unsaturated polyester resin furnishing, after solidifying processing, carry out the assembly support by the pattern of desired facing and decorative pattern and handling through above-mentioned sealing on the plate face that dries, the row film hides rolling process and produces finish coat.
The present invention recommends:
In the ground floor sealing step that the plate face closure is handled, adhesive is selected 107 commercially available glue for use, and inserts is selected commercially available precipitated calcium carbonate for use, and its best proportioning (weight %) is 60: 40; In the second layer sealing step, adhesive is selected commercially available 107 glue, urea-formaldehyde resin adhesive and white glue with vinyl for use, and inserts is the same, and its best proportioning (weight %) is 30-50: 30-40: 5-10: 15-20 in turn.
The monochromatic polyester mill base of unsaturated polyester resin furnishing white, black, redness, rust, yellow, bottle green and Lan Se, its formation and best component (weight) are:
White: 100 parts in mylar, precipitated calcium carbonate 8-9 part, titanium dioxide 8-9 part;
Black: 100 parts in mylar, precipitated calcium carbonate 8-9 part, iron oxide black 8-9 part;
Red: 100 parts in mylar, precipitated calcium carbonate 14-16 part, 0.4 part of toluidine red, husky yellow 0.1 part of the Chinese, 2 parts of titanium dioxides;
Rust: 100 parts in mylar, precipitated calcium carbonate 8-9 part, iron oxide red 8-9 part;
Yellow: 100 parts in mylar, precipitated calcium carbonate 11-12 part, chrome yellow
5-6 part;
Bottle green: 100 parts in mylar, precipitated calcium carbonate 8-9 part, iron oxide green 8-9 part;
Blue look: 100 parts in mylar, precipitated calcium carbonate 11-12 part, oxide tillandsia 5-6 part;
With in the above-mentioned monochromatic polyester mill base two or more, inhomogeneous mixing generates the chrysodor pattern in vessel, paint the mill base band that (support) goes out a rule reasonable organization with spoon slave plate face edge along a direction, cover glazing frame (film covering), along the roll extrusion of mill base band direction, can make marble pattern facing (layer) true to nature with blanket cylinder.
Following marble pattern facing, its best proportioning (weight %) is:
Shallow cloud ash marble pattern:
White colorant 95, black color paste 5;
Dark cloud ash marble pattern:
White colorant 85, black color paste 15;
Shallow blackish green marble pattern:
White colorant 95, bottle green mill base 3, black color paste 2;
Dark blackish green marble pattern:
White colorant 85, bottle green mill base 10, black color paste 5;
Shallow Cloudy Rosa marble pattern:
White colorant 95, red mill base 3, black color paste 2;
Dark Cloudy Rosa marble pattern:
White colorant 90, red mill base 7, black color paste 3.
With a kind of in the above-mentioned monochromatic polyester mill base, two or more is sprinkling upon on the plate face as the primary colours branch, intersperses the mill base of desired color again on primary colours, can make moire facing true to nature, that third dimension is strong.
Use separately above-mentioned monochromatic polyester mill base or become various secondary colo(u)r mill bases, can make colourful pure color facing with wherein redness, yellow and blue tone.
The present invention (embodiment) below with reference to accompanying drawings is further described:
Fig. 1 is a block diagram of the method according to this invention, and Fig. 2 is the schematic diagram of the product of use method production of the present invention.
With reference to Fig. 1, can see each operating procedure of a kind of production method of polyester decorative lamination decoration board, more particularly, above-mentioned technology that illustrates and feature of the present invention can be summarized as follows:
A) sheet material (plasterboard, plank, bamboo slag plate, particieboard or paper fiber etc.) is cut by required form and size,, then repair (putting in order) or scrape ash and fill and lead up if breakage is arranged;
B), press (weight %) proportioning of 60: 40 with 150-200g/m according to handled sheet material plate face area 2The reference consumption, the 107 commercially available glue that take by weighing constant weight mix accent (stirring) with precipitated calcium carbonate even, behind the even brushing one deck of sheet material plate face, places dry place and dry;
C) press the proportioning of (weight %) 30-50: 30-40: 5-10: 15-20 with 120-150g/m 2The reference consumption, take by weighing commercially available 107 glue, urea-formaldehyde resin adhesive, white glue with vinyl and the precipitated calcium carbonate of constant weight in turn, it is even with present technique field those of ordinary skill technique known Lauxite adhesive curing processing back and above-mentioned raw materials to be mixed together accent (stirring), behind even brushing one deck on the sheet material plate face that dries and sealing is handled through ground floor, place dry place and dry; The scope of the ratio of giving, it determines that principle is to decide according to handled plate construction density, along with the value that reduces (loosening) its adhesive of density is close to the high limit near the value of inserts to lower bound, consumption increases.
D), be characterised in that the following monochromatic slurry ester mill base of a unsaturated polyester resin furnishing as of method of the present invention, and best component (weight) is according to present technique field those of ordinary skill technique known preparation unsaturated polyester resin mill base:
White colorant: 100 parts in mylar, precipitated calcium carbonate 8-9 part, titanium dioxide 8-9 part;
Black color paste: 100 parts in mylar, precipitated calcium carbonate 8-9 part, iron oxide black 8-9 part;
Bottle green mill base: 100 parts in mylar, precipitated calcium carbonate 8-9 part, iron oxide green 8-9 part;
Red mill base: 100 parts in mylar, precipitated calcium carbonate 14-16 part, 0.4 part of toluidine red, husky yellow 0.1 part of the Chinese, 2 parts of titanium dioxides;
Iron oxide red mill base: 100 parts in mylar, precipitated calcium carbonate 8-9 part, iron oxide red 8-9 part;
Yellow mill base: 100 parts in mylar, precipitated calcium carbonate 11-12 part, chrome yellow 5-6 part;
Blue look mill base: 100 parts in mylar, precipitated calcium carbonate 11-12 part, oxide tillandsia 5-6 part;
E) through above-mentioned sealing handled the sheet material that dries face upward (treated side) be flat on the carriage, with 600g/m 2The reference consumption, select above-mentioned monochromatic polyester mill base for use, after being cured processing (add curing agent and promoter) according to present technique field those of ordinary skill technique known, pattern and decorative pattern by the expectation facing carry out the assembly support on the plate face, cover the glazing frame, cover whole plate faces with blanket cylinder (commercially available) roll extrusion until mill base and drive whole bubbles out of, leave standstill cold curing with pushing away;
Above-mentioned said carriage is actually the supporting shelf that frame is put sheet material, can use materials such as timber, angle bar or iron pipe to make, and it is neglected workshop and sheet material greatly and decides; Said glazing frame is the polyester film frame that stretches tight on quadrilateral frame (timber making) with transparent polyester film, and its size exceeds institute's cover plate face periphery and is advisable for 30 centimetres.
Generate the chrysodor decorative pattern with two or more the inhomogeneous mixing in vessel in the above-mentioned monochromatic polyester mill base, with spoon slave plate face edge along a direction draw a rule reasonable organization the mill base band, cover the glazing frame, along the roll extrusion of mill base band direction, can make marble pattern facing true to nature.
Following marble pattern facing, its best mill base proportioning (weight %) is:
Shallow cloud ash marble pattern:
White colorant 95, black color paste 5;
Dark cloud ash marbling:
White colorant 85, black color paste 15;
Shallow blackish green marble pattern:
White colorant 95, bottle green mill base 3, black color paste 2;
Dark blackish green marble pattern:
White colorant 85, bottle green mill base 10, black color paste 5;
Shallow Cloudy Rosa marble pattern:
White colorant 95, red mill base 3, black color paste 2;
Dark Cloudy Rosa marble pattern:
White colorant 90, red mill base 7, black color paste 3;
With a kind of in the above-mentioned monochromatic polyester mill base, two or more is sprinkling upon on the plate face as the primary colours branch, intersperses the mill base of desired color again on primary colours, can make moire facing true to nature, that third dimension is strong.
Use separately above-mentioned monochromatic polyester mill base or become various secondary colo(u)r mill bases, can make colourful pure color facing with wherein redness, yellow and blue tone.
F) treat that mill base solidifies after, slough the maintenance of glazing frame product.
With reference to Fig. 2, provided a kind of (series) product that the method according to this invention is produced, polyester finish coat (1) sees the one side of sheet material (2).
The method according to this invention is produced the polyester decorative lamination decoration board, compared with prior art has can produce multiple use and decorate and use the polyester decorative lamination decoration board, saves expensive mylar Do not need mould, without remover, can make colourful facing and need not the advantages such as grinding and polishing. Its product surface meets or exceeds mirror surface luster, and long-term on probation, surface layer is not found to come off and be out of shape, and can be widely used in the industries such as building, furniture and industrial art.

Claims (12)

1, a kind of production method of polyester decorative lamination decoration board, the preparation and the curing that comprise the preparation unsaturated polyester resin mill base of sheet material are handled, it is characterized in that cutting repairing (putting in order) afterwards at sheet material, add the inserts mixing with adhesive sheet material plate face is sealed processing, said sealing is handled a ground floor sealing step and a second layer sealing step: the multiple not homochromy monochromatic polyester mill base of unsaturated polyester resin furnishing, solidify handling the back carries out the assembly support by the pattern of desired facing and decorative pattern and was handling on the plate face that dries row film covering rolling process production finish coat through above-mentioned sealing.
2, production method according to claim 1 is characterized in that said adhesive and inserts, selects 107 glue and precipitated calcium carbonate for use in ground floor sealing step.
3, production method according to claim 2 is characterized in that said 107 glue and precipitated calcium carbonate, and its best proportioning (weight %) is 60: 40.
4, production method according to claim 1 is characterized in that said adhesive and inserts, in second layer sealing step, selects 107 glue for use, urea-formaldehyde resin adhesive, white glue with vinyl and precipitated calcium carbonate.
5, production method according to claim 4 is characterized in that said 107 glue, urea-formaldehyde resin adhesive, white glue with vinyl and precipitated calcium carbonate, and its best proportioning (weight %) is 30~50: 30~40: 5~10: 15~20 in turn.
6, production method according to claim 1 is characterized in that said multiple not homochromy monochromatic polyester mill base is: the monochromatic polyester mill base of white, black, redness, rust, yellow, bottle green and Lan Se.
7, production method according to claim 6 is characterized in that the best component (weight) of said monochromatic polyester mill base is:
White colorant: 100 parts in mylar, precipitated calcium carbonate 8~9,8~9 parts of titanium dioxides;
Black color paste: 100 parts in mylar, 8~9 parts of precipitated calcium carbonates, 8~9 parts of iron oxide blacks;
Red mill base: 100 parts in mylar, 14~16 parts of precipitated calcium carbonates, 0.4 part of toluidine red, husky yellow 0.1 part of the Chinese, 2 parts of titanium dioxides;
Dark green mill base: 100 parts in mylar, 8~9 parts of precipitated calcium carbonates, 8~9 parts of iron oxide greens;
Iron oxide red mill base: 100 parts in mylar, 8~9 parts of precipitated calcium carbonates, 8~9 parts of iron oxide reds;
Yellow mill base: 100 parts in mylar, 11~12 parts of precipitated calcium carbonates, 5~6 parts of chrome yellow;
Blue look mill base: 100 parts in mylar, 11~12 parts of precipitated calcium carbonates, 5~6 parts of oxide tillandsias;
8, production method according to claim 1, it is characterized in that a kind of mill base assembly support of marble pattern facing and the method for roll extrusion are: select for use two or more the inhomogeneous mixing in vessel in the described mill base of claim 7 to generate the chrysodor pattern, the mill base band of drawing a rule reasonable organization along a direction with spoon slave plate face edge is on the plate face, along the roll extrusion of mill base band direction.
9, production method according to claim 8 is characterized in that the best mill base proportioning (weight %) of following marble pattern facing is:
Shallow cloud ash marble pattern: white colorant 95, black color paste 5;
Dark cloud ash marble pattern: white colorant 85, black color paste 15;
Shallow blackish green marble pattern: white colorant 95, bottle green mill base 3, black color paste 2;
Dark blackish green marble pattern: white colorant 85, bottle green mill base 10, black color paste 5;
Shallow Cloudy Rosa marble pattern: white colorant 95, red mill base 3, black color paste 2;
Dark Cloudy Rosa marble pattern: white colorant 90, red mill base 7, black color paste 3;
10, production method according to claim 1, the mill base that it is characterized in that a kind of moire facing organizes the support method to be: select for use in the described mill base of claim 7 a kind of, two or more removes on the plate face as the primary colours branch, intersperses the mill base of desired color again on primary colours.
11, production method according to claim 1, the mill base assembly support method that it is characterized in that a kind of pure color facing is: use right 7 described mill bases or redness wherein, yellow and blue form and aspect to mix the various secondary colo(u)r mill bases of furnishing separately, be uniformly coated on the plate face.
12, a kind of (series) product of producing according to any one described production method of claim 1~11.
CN 89105883 1989-03-28 1989-03-28 Prodn. method of polyester-faced decorative plate and its prodt. Expired - Fee Related CN1025838C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 89105883 CN1025838C (en) 1989-03-28 1989-03-28 Prodn. method of polyester-faced decorative plate and its prodt.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 89105883 CN1025838C (en) 1989-03-28 1989-03-28 Prodn. method of polyester-faced decorative plate and its prodt.

Publications (2)

Publication Number Publication Date
CN1045948A true CN1045948A (en) 1990-10-10
CN1025838C CN1025838C (en) 1994-09-07

Family

ID=4856517

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 89105883 Expired - Fee Related CN1025838C (en) 1989-03-28 1989-03-28 Prodn. method of polyester-faced decorative plate and its prodt.

Country Status (1)

Country Link
CN (1) CN1025838C (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1308125C (en) * 2004-07-13 2007-04-04 福建省尤溪县三林木业有限公司 Processing method for cedar wood decorating fitment material
CN100436123C (en) * 2007-02-08 2008-11-26 林震能 Composite type background board and manufacture method thereof
CN100519170C (en) * 2003-09-26 2009-07-29 伊士曼化工公司 Method for blocking stains on a substrate to be coated
CN103788710A (en) * 2014-02-12 2014-05-14 铜陵瑞莱科技有限公司 Ferric oxide green pigment with light calcium carbonate
CN108455904A (en) * 2018-02-27 2018-08-28 利高工艺品(厦门)有限公司 A kind of parian and its manufacture craft
CN108927879A (en) * 2018-06-15 2018-12-04 浙江喜盈门家居科技股份有限公司 A kind of whole furniture processing method of parian style

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100519170C (en) * 2003-09-26 2009-07-29 伊士曼化工公司 Method for blocking stains on a substrate to be coated
CN1308125C (en) * 2004-07-13 2007-04-04 福建省尤溪县三林木业有限公司 Processing method for cedar wood decorating fitment material
CN100436123C (en) * 2007-02-08 2008-11-26 林震能 Composite type background board and manufacture method thereof
CN103788710A (en) * 2014-02-12 2014-05-14 铜陵瑞莱科技有限公司 Ferric oxide green pigment with light calcium carbonate
CN108455904A (en) * 2018-02-27 2018-08-28 利高工艺品(厦门)有限公司 A kind of parian and its manufacture craft
CN108455904B (en) * 2018-02-27 2021-08-24 利高工艺品(厦门)有限公司 Imitated marble and manufacturing process thereof
CN108927879A (en) * 2018-06-15 2018-12-04 浙江喜盈门家居科技股份有限公司 A kind of whole furniture processing method of parian style

Also Published As

Publication number Publication date
CN1025838C (en) 1994-09-07

Similar Documents

Publication Publication Date Title
CN101053971A (en) Method for producing artificial stone colorful products and products thereof
CN1045948A (en) Production method of a kind of polyester decorative lamination decoration board and products thereof
CN1654228A (en) Method for fabricating patterns on ceramic veneer in sand-blasting modus
CN1921991A (en) Artificial marble using multicolor chip and method for preparing the same
CN2173696Y (en) Composite stone-like slab
RU2151700C1 (en) Method for manufacture of decorative articles with application of filler manufactured of amber
GB2233640A (en) Mineral composition
CN1363475A (en) Artificial carved stone ornament
CN1361212A (en) Decorative repairing putty paste
CN112976619A (en) Method for manufacturing imitated wood couplet horizontal inscribed board by recycling waste plastics
CN1138535A (en) Decoration board
CN85109513A (en) The manufacturing process of composite intensified TERRAZZO
KR101242277B1 (en) Transparent chip containing light reflection material, artificial marble comprising the same, and the preparation method thereof
CN1673164A (en) Method for producing artificial stone
CN101844481A (en) Preparation method of artificial stone slab with imitative natural stone decorative patterns
CN101823281A (en) Method for preparing artificial stone slab with imitation natural stone pattern
CN1051325A (en) Zhuli layered plate and manufacturing process thereof
CN1113000C (en) Colouring wall decorative material with/or without patterns and spots, and prepn. method
CN1456437A (en) Architectural decoration and furniture plate made from plexiglass and producing method thereof
CN1156157A (en) Plastic material and its use
CN2589566Y (en) Novel wall brick for decoration
CN1063140C (en) Mural painting and making tech. thereof
CN1460601A (en) Natural marble colour etched picture and its making method
CN1203992C (en) Resin building faced decorative material with coated surface and producing method
CN201931909U (en) Ultraviolet light fluorine carbon solidification color decorative plate

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee