CN1113000C - Colouring wall decorative material with/or without patterns and spots, and prepn. method - Google Patents
Colouring wall decorative material with/or without patterns and spots, and prepn. method Download PDFInfo
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- CN1113000C CN1113000C CN 99110969 CN99110969A CN1113000C CN 1113000 C CN1113000 C CN 1113000C CN 99110969 CN99110969 CN 99110969 CN 99110969 A CN99110969 A CN 99110969A CN 1113000 C CN1113000 C CN 1113000C
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- colour particles
- wall covering
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Images
Landscapes
- Finishing Walls (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
To reveal a clear single color tone by fixing two or more colors of respective color parts constituting a pattern of a colored wall face material with a pattern in a transparent binder in a state of mutually mixing/dispersing few kinds of colored coarse grains having the grain size being almost uniform in a specific range. Because of a single color tone of respective color parts constituting a pattern of a colored wall face material with a pattern, colored coarse grains are used by combining few kinds of optional colors, and three primary colors of colors or a combination of these three primary colors and a white color and/or a black color are particularly desirable. The grain size of the colored coarse grains of the respective colors is almost uniform, the central grain size is set in a range of 10 to 1000 m, and the respective color parts are fixed in a transparent binder in a mutually mixed/dispersed state. The same effect as a sketch in a picture can be obtained by mixing and dispersing the colored coarse grains of several colors having the almost uniform specific grain size, a clear single color tone can be revealed in the respective color parts of the wall face material, and contrast of the colors between the respective color parts becomes very clear.
Description
Technical field
The present invention relates to pattern-free or have pattern colored wall covering, contain the pattern-free of spot or have the colored wall covering of pattern and their manufacture method.
Background technology
Always, with the planar sprayed on material of sand (original text リ Application シ, English translated name lithin-applicant note) or ジ ュ ラ Network (japonic a kind of wall covering, the no suitable Chinese is translated with the English translated name and is claimed-applicant's note) and other wall covering when being processed into specific single tone, be in aqueous matrix coating such as synthetic resin emulsion, with other complex, simultaneously will be for example the pigment powder of the millimicron size particle diameter of 10～100nm degree monochromatic or cooperate more than two looks, to show tone.
On the other hand, in having the wall covering of pattern, for example, the wall covering of the pattern of the so-called stone such as " granite " nature of imitation etc., used the colour particles of big particle diameter, for example, coloured natural stone, on natural stone the particle of dyeing, the mm sizes such as resin sheet of dyeing artificially.
But, in the prior art of the colored wall covering of the pattern-free of above-mentioned use pigment, because toning is to use the micro pigment about 10～100nm to mix, so the occasion principle of mixing colours with the drawing pigment more than mixing 2 looks identical, color usually becomes muddy because of the mixing of pigment, and it is difficult showing distinct dark tone.
In addition, sesamoid speckle patterns such as performance black or white on the background color of such tone when containing the pattern-free colour wall covering of spot with formation, can not present the dark tone of distinctness because background color is easily muddy, and institute is so that speckle patterns is plain.
On the other hand, the colour particles that uses in the colored pattern wall covering of the above-mentioned patterns such as " granite " of imitation is because of constituting the particle that pattern uses the quite big particle diameter about 0.1～10mm.Thereby each colour particles all is the big particle diameter that naked eyes can be differentiated, and can not expect said function of the colour particles more than 2 looks being mixed the single tone of performance.
; what is called point in drawing is retouched mode (method of forming background colour with many little color dots); the set of the choice refreshments of several colors by having the certain limit particle diameter is during with the performance tone, and is then different with the situation that drawing pigment is mixed, and can show distinct tone.Therefore, the point of these colors, requiring has roughly homogeneous particle diameter, and can not be to resemble the pigment excessive smallly, can not be the big particle diameter that naked eyes can be differentiated.
Summary of the invention
The present invention is exactly that several colour particles of homogeneous particle diameter that will be by will having certain limit mix, and realizes that in colored wall covering the point of drawing retouches the effect of mode, and realizes dark tone in the transparent adhesives by these colour particles are fixed on.
The formation of the 1st invention
The 1st invention of the application is the colored wall covering of a kind of pattern-free, and it is by roughly homogeneous and the colour particles that is in a few species color in 10～1000 mu m ranges are fixed on the material that shows single tone in the transparent adhesives with the state that mutual mixing disperses with particle diameter.
The formation of the 2nd invention
The 2nd invention of the application is a kind of colored wall covering of pattern-free that contains spot, it is by making following 1) and 2) colour particles mix to be dispersed in the transparent aqueous matrix coating be implemented in by 1) present by 2 on the background color of the single tone of performance) material of the sesamoid speckle patterns of performance
1) particle diameter homogeneous and be in the colour particles of a few species color in 10～1000 mu m ranges roughly;
2) particle diameter is equivalent to above-mentioned 1) 2～10 times of colour particles and have be different from by 1) color of the single tone of performance or color of the same race but the different colour particles of the concentration of color.
The formation of the 3rd invention
The 3rd invention of the application is a kind of colored wall covering that has pattern, it is the colored wall covering that has pattern that is formed by the pattern that the color more than two looks partly constitutes, it is by in constituting each color part of this pattern, and roughly homogeneous and the colour particles that is in a few species color in 10～1000 mu m ranges are fixed on the material that shows single tone in the transparent adhesives with the state that mutual mixing disperses with particle diameter.
The formation of the 4th invention
The 4th invention of the application is a kind of colored wall covering that has pattern that contains spot, and it is by making aforesaid right requirement 2 described 1) and 2) colour particles mix to be dispersed in the transparent aqueous matrix coating be implemented in by 1) present by 2 on the background color of the single tone of performance) the sesamoid speckle patterns of performance and partly constitute pattern material by the color more than two looks.
The formation of the 5th invention
The 5th invention of the application be, in any one of～the 4 invention of the 1st invention, the color scheme of the colour particles that above-mentioned mutual mixing disperses is the combination of three primary colors or this three primary colors and the white and/or the black of look.
The formation of the 6th invention
The application's the 6th invention be, colored wall covering of each described pattern-free of～the 5 invention of the 1st invention or the colored wall covering that has a pattern are the surfacings of stipulating among the JIS A6909.
The formation of the 7th invention
The 7th invention of the application be, in the 2nd invention or the 4th invention, by above-mentioned 2) speckle patterns of performance is the speckle patterns of white or dense colour.
The formation of the 8th invention
The 8th invention of the application is a kind of coating material, and it is that roughly homogeneous and the colour particles that is in a few species color in 10～1000 mu m ranges are mixed together and are dispersed in the material that obtains in the transparent aqueous matrix coating by making other necessary compounding ingredient and particle diameter.
The formation of the 9th invention
The 9th invention of the application is a kind of coating material, it be by make other necessary compounding ingredient and the 2nd invention 1) and 2) colour particles be mixed together and be dispersed in the material that obtains in the transparent aqueous matrix coating.
The formation of the 10th invention
The 10th invention of the application is a kind of manufacture method of colored wall covering, wherein, use the monochromatic color coating material of the 8th invention to make the colored wall covering of pattern-free of the 1st invention or make the colored wall covering that has pattern of the 3rd invention with the above coating material of 2 colors of the 8th invention.
The formation of the 11st invention
The 11st invention of the application is a kind of manufacture method of colored wall covering, wherein, use the monochromatic color coating material of the 9th invention to make the colored wall covering of the pattern-free that contains spot of the 2nd invention or use the above coating material of 2 colors of the 9th invention to make the colored wall covering that has pattern that contains spot of the 4th invention.
Effect, the effect of the 1st invention
In the 1st invention, by make have in 10～1000 mu m ranges colour particles of several colors of the regulation particle diameter of homogeneous roughly mix disperse to obtain and paint in point retouch same effect, present the tone of single distinctness.
The roughly homogeneous particle diameter of colored particles is during less than 10 μ m, and colour particles is when having wide size distribution, and the effect that point is retouched dies down, and the vividness of tone descends, the tone of the general easy muddiness that becomes history.When the roughly homogeneous particle diameter of colour particles surpassed 1000 μ m, each colour particles became the situation that vision can identification, has lost the function that said mixing by the colour particles more than 2 looks shows single tone.
Because these colour particles are fixed, therefore invested dark tone in the clear binder as parent.
Effect, the effect of the 2nd invention
In the colored wall covering of the pattern-free that contains spot of the 2nd invention, by 1) the distinct dark background color of colour particles performance of a few species color, simultaneously will be by 2) the sesamoid speckle patterns of colour particles performance present, so the pattern of this spot is very especially good-looking.
Effect, the effect of the 3rd invention
In the 3rd invention,, be to present and the single tone of certain dark distinctness that the 1st invention is same about the tone of each color part of the formation pattern in having the colored wall covering of pattern.Thereby the color contrast between each color part is also very distinct.
The roughly homogeneous particle diameter of colored particles is during less than 10 μ m or when surpassing 1000 μ m, and colour particles is when having wide size distribution since with the 1st reason that invention is identical, can not guarantee above-mentioned effect.
Effect, the effect of the 4th invention
In the colored wall covering that has pattern that contains spot of the 4th invention, each the color part that is used for constituting pattern at the colored wall covering that has pattern, make by 1) the background color of the distinct dark single tone of the colour particles performance of a few species color, and make by 2) the sesamoid speckle patterns of colour particles performance display, therefore, the contrast of the color between each color part becomes distinct, and these speckle patterns in each color part are especially good-looking simultaneously.
The effect of the 5th invention
In the 5th invention, the trichromatic colour particles that belongs to color is mixed to be disperseed, or adding therein to mix behind the colour particles of white and/or black disperses, and therefore makes can show well balanced tone attractive in appearance in the various colored wall covering of～the 4 invention of the 1st invention.
Effect, the effect of the 6th invention
According to the 6th invention, can provide a kind of distinctness certain dark tone pattern-free colored surface material or have the coloured surface material of pattern, perhaps contain the pattern-free coloured surface material of spot or have the colored surface material of pattern.
Effect, the effect of the 7th invention
In the 7th invention, with the colored wall covering of the pattern-free that contains spot of above-mentioned the 2nd invention or the 4th invention or have the speckle patterns of the colored wall covering of pattern, make black, white or have the speckle patterns of dense colour, just can realize speckle patterns attractive in appearance.
Effect, the effect of the 8th invention and the 9th invention
By using the monochromatic color coating material of the 8th invention, can make the colored wall covering of pattern-free of the 1st invention, by the coating material more than 2 colors that use the 8th invention, can make the colored wall covering that has pattern of the 3rd invention.
In addition, owing to use the monochromatic color coating material of the 9th invention, the colored wall covering of the pattern-free that contains spot of the 2nd invention can be made,, the colored wall covering that has pattern that contains spot of the 4th invention can be made owing to use the above coating material of 2 colors of the 9th invention.
Effect, the effect of the 10th invention and the 11st invention
According to the manufacture method of the 10th invention and the colored wall covering of the 11st invention, can make the colored wall covering of the pattern-free that contains spot of the colored wall covering of pattern-free of the 1st invention, the colored wall covering that has pattern of the 3rd invention, the 2nd invention or the colored wall covering that has pattern that contains spot of the 4th invention.
Description of drawings
Fig. 1 is the figure of manufacturing process that expression has the colored wall covering of pattern.
Fig. 2 is the figure of embodiment example that expression has the colored wall covering of pattern.
Fig. 3 is the photo that shows the colored wall covering of pattern-free of embodiment 1.
Fig. 4 is the photo that shows the colored wall covering of pattern-free of embodiment 2.
Fig. 5 is the photo that shows the colored wall covering of pattern-free of embodiment 3.
The explanation of symbol
1 finishing die
2,4 coating materials
The specific embodiment
Below to the 1st the invention～the 11 working of an invention mode describe.When placing an order title " the present invention ", refer to the blanket of～the 11 invention of the 1st invention.
The kind of colored wall covering
The colored wall covering of said pattern-free in～the 4 invention of the 1st invention, contain spot the colored wall covering of pattern-free, have the colored wall covering of pattern and contain the kind of the colored wall covering that has pattern of spot, so long as the wall covering that uses in the building etc. gets final product, this there are not other qualifications.It is as follows by kind 2,3 routine wall coverings to be shown: the thickening processing coating material of a kind of surfacing of the planar sprayed on material of synthetic resin emulsion sand or surperficial class ジ ュ ラ Network wall, the painted main material of use aggregate, in addition also can enumerate forming boards such as various plates, sheet, ceramic tile, by using the position example to go out 2,3 routine wall coverings, can enumerate: at the material of ceiling portion, above ground portion, the use of vertical plane wall wall part.
Colour particles
Colour particles is that silica sand, gypsum rubrum (originate in Japan, broken thing one applicant's note of pure white calcite set tissue) nature stone such as, ware matter crushed material, glass grain, aggregates such as resin sheet can use to have original the same particle specific color or that dye specific color.Preferred especially water-fast life and against weather are good, non-fading particle.
As colour particles, the particle of the arbitrary hue of a few species can be used in combination.Here said " a few species " about preferred 2 looks～5 looks, but also can be used about 6 looks～10 looks or more color as required.Particularly preferred color scheme is 3 primary colors of color, or one or the two combination of these 3 primary colors and white and black.In the toning of achromatic color system, only the combination of white and black also can.Except the combination of these basic colors, also can make primary colors color arbitrarily in addition combined.
As the method that on aggregate, above-mentioned specific color is dyeed, for example can utilize the black of carbon black, the redness of iron oxide red, the yellow of ochre, the blue look of the blue or green orchid of phthalein etc.Colouring method is arbitrarily, for example can freely utilize methods such as the sintering that applies back air dry, usefulness glaze is painted, calcining.
The particle diameter of the colour particles of each color is a homogeneous roughly, and its average grain diameter is in the scope of 10～1000 μ m.Particularly be in the scope of 80～300 μ m, this is realizing that in the distinct toning be preferred.
About above-mentioned particle diameter all once, so long as retouching effect to the point that can meet the demands, homogeneous gets final product, but an one preferred benchmark is, the colour particles of minimum grain size is 1/2 with respect to the size ratio of the colour particles of maximum particle diameter, another preferred benchmark is, in all scope that is in average grain diameter ± 30% more than 80% of colour particles.
The mixing of colour particles disperses
The colour particles of a few species color is fixed in the transparent adhesives with the state that mutual mixing disperses.Preferably make these colour particles with the distribution proportion mixing of homogeneous separately, even but the inhomogenous part of distribution proportion is partly arranged, so long as do not destroy as the degree of all toning balances just passable.
The number ratio of the colour particles of each color that is combined, different with the color order that is used to mix colours, unqualified to this.That is, for example the colour particles of red/orchid/Huang Sanse is being mixed when disperseing the desirable numerical value arbitrarily of X, Y, Z among its number ratio X/Y/Z.
Colour particles is with respect to the cooperation ratio of clear binder, for example the viewpoint from the construction is considered, must adjust according to the granularity of colour particles or the viscosity/viscosity of adhesive, and must change, therefore can not do same qualification according to degree as the depth perception of the toning of target.
Adhesive
As adhesive, can use known various adhesive arbitrarily, for example the synthetic resin solution of acetic acid esters, acrylate etc. or emulsion, silicate base metal salt solution, silicate base slaine dispersion etc.These adhesives in order to compose another kind of dark sensation to the colored wall covering of pattern-free, use transparent adhesives.Even its transparency with some muddinesses, but so long as can invest the degree of transparent feel in fact and just can satisfy.And use water white adhesive better, but can invest background color effect in the toning by the adhesive that uses colored transparent.
Pattern-free or have the coating material that uses in the manufacturing of colored wall covering of pattern
Used coating material in the manufacturing of the colored wall covering of pattern-free is to mix colours into the product that single tone obtains by making other necessary cooperation material be mixed together to be scattered in the transparent aqueous matrix coating with the colour particles of above-mentioned a few species color.In the manufacturing of the colored wall covering that has pattern, use the above toning of 2 kinds of colors to become the coating material of above-mentioned specific single tone.
As transparent aqueous matrix coating, can use the synthetic resin solution, emulsion, dispersion of various water white transparencies described in above-mentioned " adhesive " or colored transparent etc.Preferred especially synthetic resin emulsion.
Other compounding ingredient as cooperating in coating material can make known various additives such as water, tackifier, anticorrisive agent, activating agent arbitrarily.
For the toning effect that makes pattern-free or have a colored wall covering of pattern is more effectively brought into play, preferably in coating material, do not cooperate the solid-state aggregate beyond the colour particles, but if be necessary also can cooperate.The aggregate that for example also can cooperate the big particle diameter of minority except that colour particles again by the pattern of the aggregate of these big particle diameters performance point, is then mixed colours by colour particles to the part of the background color beyond it.
Contain the colored wall covering of pattern-free of spot or have the colored wall covering of pattern
Contain the colored wall covering of pattern-free of spot or have the colored wall covering of pattern, be for the colored wall covering of above-mentioned pattern-free or have the additional sesamoid speckle patterns of colored wall covering of pattern.
Specifically, be by making necessary other compounding ingredient and 1) be used for constituting the colour particles and 2 of the minority kind color of the colored wall covering of pattern-free) colour particles that is used to constitute sesamoid speckle patterns is mixed together and is scattered in transparent liquid matrix and mixes colours into the coating material that single tone obtains, by in the colored wall covering of the pattern-free that contains spot, use single color and containing in the colored wall covering that has pattern of spot use 2 colors with on modulate above-mentioned coating material.
As above-mentioned 2) colour particles, should have with by above-mentioned 1) the different types of color of tone of background color of a few species colour particles toning, even the perhaps color of same kind also is that with the naked eye can to determine be the color with different colours concentration at least.Particularly preferably be by above-mentioned 2) performance speckle patterns be black, white or speckle patterns with dense colour.Background color is the occasion of black for white or light achromatic color (gray tone etc.), speckle patterns, and perhaps background color be that the occasion etc. of the dense colour that light slightly yellowish green tone, blood orange tone etc. are colored, speckle patterns is or xenogenesis of the same race with it is also preferable.
The particle diameter of colour particles in addition, above-mentioned 2) preferably is equivalent to above-mentioned 1) 2～10 times of colour particles the time, can form good speckle patterns like this.Particularly preferably be, 1) the average grain diameter of colour particles be in the occasion of the scope of 10～1000 μ m, 2) the particle diameter of colour particles be in the scope of 20～5000 μ m and be equivalent to 1) more than 2 times of colour particles.
In addition, to above-mentioned 2) the cooperation ratio of colored particles do not do special qualification, but 1) and 2) all 100 weight portions of colored particles in, preferably account for 1～30 weight portion.
The colored wall covering of pattern-free or contain the manufacture method of the colored wall covering of pattern-free of spot
The colored wall covering of pattern-free or contain the colored wall covering of pattern-free of spot can be by making on the base material (sheet, plate body etc.) that above-mentioned this corresponding coating material is useful in wall covering.Can adopt known the whole bag of tricks as the method that is suitable for.For example can adopt spraying, roller coat, scraper to be coated with or the mode of flow coat, the method for screen printing adopts processing such as air dry or heated-air drying to handle then, but the mode of preferred especially spraying.
In addition, above-mentioned make the dry sclerosis of coating material like that after, also painting synthetic resin solution or synthetic resin emulsion are to form transparent coating thereon, perhaps lamination is made the lucite film.
Have the colored wall covering of pattern or contain the manufacture method of the colored wall covering that has pattern of spot
Have the colored wall covering of pattern or contain the colored wall covering that has pattern of spot, can be by going up with the pattern that forms regulation and make mixing colours into base material (sheet, plate body etc.) that single separately tone obtains more than two kinds above-mentioned application package material is used for wall covering.
Concrete using method is not done special qualification, can adopt known the whole bag of tricks arbitrarily, for example has to use the bull spray gun, the coating material more than two looks is packed in other jar of branch by separately nozzle application, formed method of patterning by a spray-coating.
In addition, the application of spray gun that also can be by using single nozzle or with the application of trowel with the coating material of each color respectively application form pattern, perhaps with after the comprehensive application of the coating material of a color, again at the coating material of other color of specific part recoat (the part of recoat is not the pattern of initial color).
In addition, also can shown in Fig. 1 (a), have like that on the finishing die 1 of arbitrary graphic pattern male and fomale(M﹠F), such shown in Fig. 1 (b), the coating material 2 of coating single color is concavo-convex all to cover it, the base material 3 of overlapping sheet again, such shown in Fig. 1 (c) then, with it by peeling counter-rotating on the finishing die 1, such shown in Fig. 1 (d) then, the coating material 4 that is coated with other color is to cover the concavo-convex all of coating material 2, after the drying,, make by the color part of coating material 2 and the color of coating material 4 with the protuberance that exposes coating material 2 partly to constitute pattern arbitrarily by grind the layer of coating material 4 with suitable method.
And after formation had the colored wall covering of pattern, also painting synthetic resin solution or synthetic resin emulsion were to form transparent coating thereon, and perhaps lamination is made the lucite film.
The pattern kind that has on the colored wall covering of pattern does not limit, and the artificial pattern (globule pattern, band pattern etc.) that both can be random pattern also can be the pattern of the natural various rocks of imitation.
Embodiment
The Production Example of the colored wall covering of the pattern-free of the yellowish green tone of embodiment 1-
Preparation is by acrylic acid ester emulsion (solid state component 50%) 100 weight portions, water 100 weight portions and contain 100 parts of the transparent aqueous complexs that additive 4 weight portions of tackifier, anticorrisive agent, activating agent etc. constitute, to wherein adding colour particles for 400 parts, abundant hybrid modulation coating material with weight ratio.
This colour particles, it is the product that obtains as follows, promptly, with a kind of average grain diameter be 100 μ m and size distribution be the silica sand of roughly homogeneous particle diameter of 50～210 μ m as raw material, in order to ochre as the emulsion coatings of pigment composition dye yellow particle 2 weight portions, in order to phthalein blue or green blue as the emulsion coatings of pigment composition dye blue look particle 1 weight portion, gypsum rubrum is pulverized the average grain diameter that obtains is that cold water sand 7 weight portions that 260 μ m and size distribution are in 50～300 μ m disperse to mix.
Then, above-mentioned coating material is sprayed on the thickness that reaches 2mm on the flat substrates of polyester nonwoven, carries out application.Carry out 20 minutes heated-air drying so that it solidifies at 100 ℃, manufacture the colored wall covering of pattern-free of the yellowish green tone of embodiment 1.
The photo of the colored wall covering of this pattern-free is shown in Fig. 3, presents the distinct yellowish green tone of dark pattern-free.
The Production Example of the colored wall covering of the pattern-free of embodiment 2-blood orange tone
Preparation is by acrylic acid ester emulsion (solid state component 50%) 100 weight portions, water 100 weight portions and contain 100 parts of the transparent aqueous complexs that additive 4 weight portions of tackifier, anticorrisive agent, activating agent etc. constitute, to wherein adding colour particles for 400 parts, fully mix to be modulated into coating material with weight ratio.
This colour particles, it is the product that obtains as follows, that is, with a kind of average grain diameter be 100 μ m and size distribution be 50～210 μ m roughly homogeneous particle diameter silica sand as raw material, in order to carbon black as the emulsion coatings of pigment composition dye black particle 0.5 weight portion, to dye red particle 3.5 weight portions, gypsum rubrum is pulverized the average grain diameter that obtains as the emulsion coatings of pigment composition in order to iron oxide red be that cold water sand 3.5 weight portions that 260 μ m and size distribution are in 50～300 μ m disperse to mix.
Then, above-mentioned coating material is sprayed to the thickness that reaches 2mm on the flat substrates of polyester nonwoven, carry out application, carry out 20 minutes heated-air drying so that it solidifies at 100 ℃ again, produce the colored wall covering of pattern-free of the blood orange tone of embodiment 2.
The colored wall covering of this pattern-free, its photo is shown in Fig. 4, presents distinct dark pattern-free blood orange tone.
The Production Example of the colored wall covering of the pattern-free of embodiment 3-gray tone
Preparation is by acrylic acid ester emulsion (solid state component 50%) 100 weight portions, water 100 weight portions and contain 100 parts of the transparent aqueous complexs that additive 4 weight portions of tackifier, anticorrisive agent, activating agent etc. constitute, to wherein adding colour particles for 400 parts, fully mix to be modulated into coating material with weight ratio.
This colour particles, it is the product that obtains as follows, promptly, with a kind of average grain diameter be 100 μ m and size distribution be the silica sand of roughly homogeneous particle diameter of 50～210 μ m as raw material, in order to carbon black as the emulsion coatings of pigment composition dye black particle 1 weight portion, to dye yellow particle 0.5 weight portion, gypsum rubrum is ground into average grain diameter as the emulsion coatings of pigment composition in order to ochre be that the ratio of 200 μ m and size distribution 8.5 parts of weight of cold water sand of being in 30～300 μ m disperses to mix.
Then, above-mentioned coating material is sprayed to the thickness that reaches 2mm on the flat substrates of polyester nonwoven, carry out application, carry out 20 minutes heated-air drying so that it solidifies, produce the colored wall covering of pattern-free of the gray tone of embodiment 3 at 100 ℃.
The colored wall covering of this pattern-free, its photo is shown in Fig. 5, presents distinct dark pattern-free gray tone.
Embodiment 4-has the Production Example of the colored wall covering of pattern
Respectively the coating material with yellowish green tone of modulation and the occasion same composition of embodiment 1, with the coating material with blood orange tone of the occasion same composition of embodiment 2 and with the coating material with gray tone of the occasion same composition of embodiment 3.
Then, the coating material of these 3 kinds of tones is sprayed on the flat substrates of nonwoven of polyester and reach 2mm thickness, carry out application, make it to form mutually the pattern of regulation, make it to solidify 100 ℃ of heated-air dryings of carrying out 20 minutes again, the color part that produces the color part of color part, blood orange tone of yellowish green tone and gray tone is mixed mutually and is deposited and form the colored wall covering that has pattern of predetermined pattern.
This has the colored wall covering of pattern, and each above-mentioned color partly presents the single tone of distinct dark yellowish green tone, blood orange tone and gray tone, so each color part is with distinct contrast.
Claims (21)
1, the colored wall covering of a kind of pattern-free, it is characterized in that, it be by with particle diameter in 10～1000 mu m ranges and have by following (a) or (b) colour particles of a few species color of the uniform particle diameter degree of regulation, to spread all over the wall covering all surfaces, mixing the state of filling in dispersion and tight ground mutually is fixed in the water white adhesive, make colored wall covering present the colored wall covering of pattern-free that above-mentioned a few species color becomes the pattern-free tone of one integrated mass, wherein
(a) colour particles of minimum grain size is 1/2 for the size ratio of the colour particles of maximum particle diameter,
(b) particle diameter of all particle more than 80% of colour particles average grain diameter ± 30% with interior scope in.
2, a kind of colored wall covering of pattern-free that contains spot, it is characterized in that, it is by making following 1) and 2) colour particles, other compounding ingredient with necessity, be fixed in the water white adhesive with all surfaces that spreads all over wall covering, the state that mixing disperses and fill on tight ground mutually, make by 1) pattern-free of performance and be to present by 2 on the background color of specified hue) the sesamoid speckle patterns of performance, wherein
1) colour particles of the color of a few species, its particle diameter are in 10～1000 mu m ranges and average grain diameter ± 30% of uniform particle diameter degree stipulate in interior scope at to(for) the particle diameter of the particle more than 80% that the size ratio of the colour particles of maximum particle diameter is 1/2, colour particles is all of the colour particles with minimum grain size;
2) have with by above-mentioned 1) the different color of the color that obtains of colour particles toning or identical color but the concentration of its color can with the naked eye identify different colour particles at least, and the particle diameter that this colour particles has is 1) 2～10 times of colour particles.
3, a kind of colored wall covering that has pattern, this wall material is the colored wall covering that has pattern that is formed by the pattern that two looks above color partly constitutes, it is characterized in that, it is in constituting each color part of this pattern, by making particle diameter in 10～1000 mu m ranges and have following (a) or (b) colour particles of a few species color of the uniform particle diameter degree of regulation, to spread all over all surfaces of above-mentioned each color part, mixing the state of filling in dispersion and tight ground mutually is fixed in the transparent adhesives, make wall covering present the colored wall covering that has pattern that above-mentioned a few species color becomes each color single tone partly of one integrated mass
(a) colour particles of minimum grain size is 1/2 for the size ratio of the colour particles of maximum particle diameter,
(b) particle diameter of all particle more than 80% of colour particles average grain diameter ± 30% with interior scope in.
4, a kind of colored wall covering that has pattern that contains spot, this wall material is the colored wall covering that has pattern that is formed by the pattern that the color more than two looks partly constitutes, it is characterized in that, in constituting each color part of this pattern, by making following 1) and 2) colour particles, other compounding ingredient with necessity, to spread all over all surfaces of above-mentioned each color part, mixing the state of filling in dispersion and tight ground mutually is fixed in the water white adhesive, make by 1) present sesamoid speckle patterns on the pattern-free of performance and the background color of specified hue by 2 performances
1) colour particles of a few species color, the uniform particle diameter degree that its particle diameter is in 10～1000 mu m ranges and colour particles with (a) minimum grain size is stipulated in interior scope at average grain diameter ± 30% for the particle diameter of the particle more than 80% that the size ratio of the colour particles of maximum particle diameter is 1/2, colour particles is all;
2) have with by above-mentioned 1) the different color of the color that obtains of colour particles toning or identical color but the concentration of its color can with the naked eye identify different colour particles at least, and the particle diameter that this colour particles has is 1) 2～10 times of colour particles.
5, the colored wall covering of the described pattern-free of claim 1, the combination of the color in the colour particles of the color of above-mentioned a few species are three primary colors or the combination of this three primary colors and white or black or the combinations of this three primary colors and white and black of look.
6, the described colored wall covering of pattern-free that contains spot of claim 2, the combination of the color in the colour particles of the color of above-mentioned a few species are three primary colors or the combination of this three primary colors and white or black or the combinations of this three primary colors and white and black of look.
7, the described colored wall covering that has pattern of claim 3, the combination of the color in the colour particles of the color of above-mentioned a few species are three primary colors or the combination of this three primary colors and white or black or the combinations of this three primary colors and white and black of look.
8, the described colored wall covering that has pattern that contains spot of claim 4, the combination of the color in the colour particles of the color of above-mentioned a few species are three primary colors or the combination of this three primary colors and white or black or the combinations of this three primary colors and white and black of look.
9, the colored wall covering of the described pattern-free of claim 1, this material is the surfacing of stipulating among the JIS A6909 of Japanese Industrial Standards.
10, the described colored wall covering of pattern-free that contains spot of claim 2, this material is the surfacing of regulation among the JIS A of Japanese Industrial Standards 6909.
11, the described colored wall covering that has pattern of claim 3, this material are the surfacings of regulation among the JISA of Japanese Industrial Standards 6909.
12, the described colored wall covering that has pattern that contains spot of claim 4, this material are the surfacings of regulation among the JIS A of Japanese Industrial Standards 6909.
13, the colored wall covering of the described pattern-free of claim 5, this material is the surfacing of stipulating among the JIS A6909 of Japanese Industrial Standards.
14, the colored wall covering of the described pattern-free that contains patch of claim 2 is by above-mentioned 2) speckle patterns of performance is the speckle patterns of black, white or dense colour.
15, the described colored wall covering that has pattern that contains spot of claim 4 is by above-mentioned 2) performance speckle patterns be the speckle patterns of black, white or dense colour.
16, a kind of coating material, it is characterized in that, in containing the water white aqueous matrix coating of adhesive ingredients, mix and be dispersed with other necessary compounding ingredient and particle diameter in 10～1000 mu m ranges and have following (a) or (b) colour particles of a few species color of the uniform particle diameter degree of regulation
(a) colour particles of minimum grain size is 1/2 for the size ratio of the colour particles of maximum particle diameter,
(b) particle diameter of all particle more than 80% of colour particles average grain diameter ± 30% with interior scope in.
17, a kind of coating material is characterized in that, mixes to be dispersed with other necessary compounding ingredient and down described 1 in containing the water white aqueous matrix coating of adhesive ingredients) and 2) colour particles,
1) colour particles of the color of a few species, its particle diameter are in 10～1000 mu m ranges and average grain diameter ± 30% of uniform particle diameter degree stipulate in interior scope at to(for) the particle diameter of the particle more than 80% that the size ratio of the colour particles of maximum particle diameter is 1/2, colour particles is all of the colour particles with minimum grain size;
2) have with by above-mentioned 1) the different color of the color that obtains of colour particles toning or identical color but the concentration of its color can with the naked eye identify different colour particles at least, and the particle diameter that this colour particles has is 1) 2～10 times of colour particles.
18, a kind of manufacture method of colored wall covering, this method may further comprise the steps: use following monochromatic color coating material on the base material of wall covering, the described coating material of dry then sclerosis is made the colored wall covering of following pattern-free,
Monochromatic color coating material is in containing the water white aqueous matrix coating of adhesive ingredients, mix and to be dispersed with other necessary compounding ingredient and particle diameter in 10～1000 mu m ranges and have following (a) or (b) coating material of a kind of color of the colour particles of a few species color of the uniform particle diameter degree of regulation
(a) colour particles of minimum grain size is 1/2 for the size ratio of the colour particles of maximum particle diameter,
(b) particle diameter of all particle more than 80% of colour particles average grain diameter ± 30% with interior scope in;
The colored wall covering of pattern-free is by the colour particles with above-mentioned a few species color, be fixed in the water white adhesive to spread all over the state of filling in wall covering all surfaces, mutual mixing dispersion and tight ground, make colored wall covering present the colored wall covering of pattern-free that above-mentioned a few species color becomes the pattern-free tone of one integrated mass.
19, a kind of manufacture method of colored wall covering, this method may further comprise the steps: at the coating material of using on the base material of wall covering more than the 2 following colors, the described coating material of dry then sclerosis is made the following colored wall covering that has pattern,
The above coating material of 2 colors is to mix to be dispersed with other necessary compounding ingredient and particle diameter in 10～1000 mu m ranges and have following (a) or (b) 2 kinds of coating materials more than the color of the colour particles of a few species color of the uniform particle diameter degree of regulation in containing the water white aqueous matrix coating of adhesive ingredients
(a) colour particles of minimum grain size is 1/2 for the size ratio of the colour particles of maximum particle diameter,
(b) particle diameter of all particle more than 80% of colour particles average grain diameter ± 30% with interior scope in;
The colored wall covering that has pattern is the colored wall covering that has the pattern that partly is made of two looks above color, in constituting each color part of pattern, by making the colour particles of above-mentioned a few species color, be fixed in the transparent adhesives with all surfaces that spreads all over above-mentioned each color part, the state that mixing disperses and fill on tight ground mutually, make wall covering present the single tone that above-mentioned a few species color becomes each color part of one integrated mass.
20, a kind of manufacture method of colored wall covering, this method may further comprise the steps: use following monochromatic color coating material on the base material of wall covering, the described coating material of dry then sclerosis is made the following colored wall covering of pattern-free that contains spot,
Monochromatic color coating material is to mix to be dispersed with other necessary compounding ingredient and down described 1 in containing the water white aqueous matrix coating of adhesive ingredients) and 2) a kind of coating material of color of colour particles,
1) colour particles of the color of a few species, its particle diameter are in 10～1000 mu m ranges and average grain diameter ± 30% of uniform particle diameter degree stipulate in interior scope at to(for) the particle diameter of the particle more than 80% that the size ratio of the colour particles of maximum particle diameter is 1/2, colour particles is all of the colour particles with minimum grain size;
2) tool deposit with by above-mentioned 1) the different color of the color that obtains of colour particles toning or identical color but the concentration of its color can with the naked eye identify different colour particles at least, and the particle diameter that this colour particles has is 1) 2～10 times of colour particles;
The colored wall covering of pattern-free that contains spot is by making above-mentioned 1) and 2) colour particles, other compounding ingredient with necessity, with all surfaces that spreads all over wall covering, mix and disperse and the state that fills on tight ground is fixed in the water white adhesive mutually, have by 1) pattern-free of performance and be to present by 2 on the background color of specified hue) the pattern-free colour wall covering that contains spot of the sesamoid speckle patterns of performance.
21, a kind of manufacture method of colored wall covering, this method may further comprise the steps: at the coating material of using on the base material of wall covering more than the 2 following colors, the described coating material of dry then sclerosis is made the following colored wall covering that has pattern that contains spot
The above coating material of 2 colors is to mix to be dispersed with other necessary compounding ingredient and down described 1 in containing the water white aqueous matrix coating of adhesive ingredients) and 2) 2 colors of colour particles more than coating material,
1) colour particles of the color of a few species, its particle diameter are in 10～1000 mu m ranges and average grain diameter ± 30% of uniform particle diameter degree stipulate in interior scope at to(for) the particle diameter of the particle more than 80% that the size ratio of the colour particles of maximum particle diameter is 1/2, colour particles is all of the colour particles with minimum grain size;
2) have with by above-mentioned 1) the different color of the color that obtains of colour particles toning or identical color but the concentration of its color can with the naked eye identify different colour particles at least, and the particle diameter that this colour particles has is 1) 2～10 times of colour particles;
The colored wall covering that has pattern that contains spot is the colored wall covering that has pattern with the pattern that partly is made of the color more than two looks, in constituting each color part of this pattern, by make above-mentioned state 1) and 2) colour particles, other compounding ingredient with necessity, with all surfaces that spreads all over above-mentioned each color part, mix and disperse and the state that fills on tight ground is fixed in the water white adhesive mutually, make by 1) present the sesamoid speckle patterns that shows by 2 on the pattern-free of performance and the background color of specified hue.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP201317/1998 | 1998-06-30 | ||
| JP10201317A JP3047291B2 (en) | 1998-06-30 | 1998-06-30 | Patternless colored wall material, its manufacturing method, and spotted colored wall material |
| JP153593/1999 | 1999-06-01 | ||
| JP15359399A JP3509632B2 (en) | 1999-06-01 | 1999-06-01 | Pattern-attached color wall material, spotted pattern-attached color wall material, and methods for producing them |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1247260A CN1247260A (en) | 2000-03-15 |
| CN1113000C true CN1113000C (en) | 2003-07-02 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 99110969 Expired - Fee Related CN1113000C (en) | 1998-06-30 | 1999-06-30 | Colouring wall decorative material with/or without patterns and spots, and prepn. method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1113000C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102259086B (en) * | 2010-05-26 | 2014-08-20 | 四国化研(上海)有限公司 | Surface pattern forming method |
| CN103459471B (en) * | 2011-03-31 | 2016-04-27 | 积水化成品工业株式会社 | Colored resin particle, its production method and its use |
| CN113232426B (en) * | 2021-04-21 | 2022-11-01 | 佛山市美嘉陶瓷设备有限公司 | Ink jet machine for multicolor printing and printing method thereof |
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1999
- 1999-06-30 CN CN 99110969 patent/CN1113000C/en not_active Expired - Fee Related
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| CN1247260A (en) | 2000-03-15 |
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