BRPI0815326A2 - Composição de catalisador e processo de polimerização - Google Patents
Composição de catalisador e processo de polimerizaçãoInfo
- Publication number
- BRPI0815326A2 BRPI0815326A2 BRPI0815326-4A2A BRPI0815326A BRPI0815326A2 BR PI0815326 A2 BRPI0815326 A2 BR PI0815326A2 BR PI0815326 A BRPI0815326 A BR PI0815326A BR PI0815326 A2 BRPI0815326 A2 BR PI0815326A2
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst composition
- polymerization process
- polymerization
- catalyst
- composition
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1809—Controlling processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1872—Details of the fluidised bed reactor
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0272—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing elements other than those covered by B01J31/0201 - B01J31/0255
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/128—Mixtures of organometallic compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2213—At least two complexing oxygen atoms present in an at least bidentate or bridging ligand
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2400/00—Characteristics for processes of polymerization
- C08F2400/02—Control or adjustment of polymerization parameters
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Emergency Medicine (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US95788807P | 2007-08-24 | 2007-08-24 | |
| US60/957,888 | 2007-08-24 | ||
| PCT/US2008/073882 WO2009029487A1 (en) | 2007-08-24 | 2008-08-21 | Self-limiting catalyst system with controlled aluminum rto sca ratio and method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0815326A2 true BRPI0815326A2 (pt) | 2015-02-10 |
| BRPI0815326B1 BRPI0815326B1 (pt) | 2019-10-08 |
Family
ID=39768748
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0815290A BRPI0815290A2 (pt) | 2007-08-24 | 2008-08-21 | processo para polimerizar uma ou mais olefinas em um reator de fase gasosa e reator de polimerização em fase gasosa |
| BRPI0815326-4A BRPI0815326B1 (pt) | 2007-08-24 | 2008-08-21 | Composição de catalisador |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0815290A BRPI0815290A2 (pt) | 2007-08-24 | 2008-08-21 | processo para polimerizar uma ou mais olefinas em um reator de fase gasosa e reator de polimerização em fase gasosa |
Country Status (11)
| Country | Link |
|---|---|
| US (3) | US8324327B2 (pt) |
| EP (2) | EP2185599B1 (pt) |
| JP (1) | JP5576281B2 (pt) |
| KR (2) | KR101576308B1 (pt) |
| CN (3) | CN101848946B (pt) |
| BR (2) | BRPI0815290A2 (pt) |
| ES (1) | ES2711342T3 (pt) |
| MX (3) | MX347799B (pt) |
| PL (2) | PL2185609T3 (pt) |
| RU (1) | RU2470947C2 (pt) |
| WO (2) | WO2009029486A2 (pt) |
Families Citing this family (47)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX347799B (es) | 2007-08-24 | 2017-05-15 | W R Grace & Co -Conn | Sistema de catalizador auto-limitante con proporcion de aluminio a sca controlada y metodo. |
| WO2009141831A2 (en) * | 2008-05-21 | 2009-11-26 | Reliance Industries Limited | A catalyst system for polymerization of olefins |
| EP2315789B1 (en) * | 2008-08-21 | 2015-09-02 | W.R. Grace & CO. - CONN. | Catalyst composition with mixed selectivity control agent and polymerisation method using it |
| KR101686253B1 (ko) | 2008-08-21 | 2016-12-13 | 더블유.알. 그레이스 앤드 캄파니-콘. | 고 용융 유동 내충격성 프로필렌 공중합체 및 방법 |
| WO2010078485A1 (en) | 2008-12-31 | 2010-07-08 | Dow Global Technologies Inc. | Propylene-based polymer, articles, and process for producing same |
| MY153117A (en) | 2008-12-31 | 2014-12-31 | Grace W R & Co | Procatalyst composition with substituted 1,2-phenylene aromatic diester internal donor and method |
| CN101554595B (zh) | 2009-05-18 | 2011-02-02 | 中国石油化工股份有限公司 | 一种烯烃聚合用催化剂载体及其制备方法和应用 |
| RU2576519C2 (ru) | 2009-12-02 | 2016-03-10 | У.Р.Грейс Энд Ко.-Конн. | Дикарбонатные соединения с двумя мостиковыми атомами как внутренние доноры в катализаторах для получения полипропилена |
| WO2011068775A1 (en) | 2009-12-02 | 2011-06-09 | Dow Global Technologies Inc. | Three and four atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture |
| EP2516489B1 (en) | 2009-12-21 | 2014-07-02 | W.R. Grace & CO. - CONN. | Gas-phase polymerization process having multiple flow regimes |
| US20120116029A1 (en) * | 2010-11-08 | 2012-05-10 | Van Egmond Jan W | Method for polymerizing polypropylene |
| US9382342B2 (en) | 2010-12-21 | 2016-07-05 | W. R. Grace & Co.-Conn. | Procatalyst composition with alkoxyalkyl 2-propenoate internal electron donor and polymer from same |
| US9382343B2 (en) | 2010-12-21 | 2016-07-05 | W. R. Grace & Co.-Conn. | Procatalyst composition with alkoxypropyl ester internal electron donor and polymer from same |
| US20120157645A1 (en) * | 2010-12-21 | 2012-06-21 | Linfeng Chen | Procatalyst Composition with Alkoxypropyl Ester Internal Electron Donor and Polymer From Same |
| US20120157295A1 (en) | 2010-12-21 | 2012-06-21 | Linfeng Chen | Process for Producing Procatalyst Composition with Alkoxyalkyl Ester Internal Electron Donor and Product |
| CN102174134B (zh) * | 2011-01-27 | 2013-07-24 | 大唐国际化工技术研究院有限公司 | 制备高熔融指数聚丙烯的催化剂组合物、制备方法和用途 |
| US10647790B2 (en) | 2011-06-30 | 2020-05-12 | W. R. Grace & Co.-Conn. | Process for gas-phase polymerization having high bed bulk density |
| CN103044583B (zh) * | 2011-10-13 | 2015-10-28 | 中国石油化工股份有限公司 | 烯烃聚合物及其制备方法 |
| CN104066755B (zh) * | 2011-11-15 | 2017-07-14 | 格雷斯公司 | 用于聚合聚丙烯的方法 |
| EP2607384A1 (en) | 2011-12-21 | 2013-06-26 | Basell Poliolefine Italia S.r.l. | Catalyst system for the polymerization of olefins |
| JP6466395B2 (ja) * | 2013-03-14 | 2019-02-06 | ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット | プロピレン/ブテンインターポリマー生成システム及び方法 |
| US9988475B2 (en) | 2013-08-19 | 2018-06-05 | Dow Global Technologies Llc | Method for producing one or more ethylene-based polymers |
| TWI639626B (zh) * | 2013-09-30 | 2018-11-01 | 中國石油化工科技開發有限公司 | Catalyst composition for olefin polymerization and application thereof |
| PL3068809T3 (pl) * | 2013-11-15 | 2021-07-19 | W.R. Grace & Co. - Conn. | Polimer na bazie propylenu z częścią o zmniejszonej masie cząsteczkowej |
| CN105705528B (zh) * | 2013-11-15 | 2018-11-09 | 陶氏环球技术有限责任公司 | 聚烯烃组合物和产生其的方法 |
| RU2731442C2 (ru) * | 2013-11-21 | 2020-09-02 | У.Р. Грейс Энд Ко.-Конн | Получение полимеров на основе пропилена с высоким содержанием сомономера |
| KR102267271B1 (ko) | 2013-11-26 | 2021-06-18 | 더블유.알. 그레이스 앤드 캄파니-콘. | 프로필렌 충격 공중합체의 제조 및 생성물 |
| CN104774281A (zh) * | 2014-01-09 | 2015-07-15 | 金成豪 | 用于烯烃聚合的催化剂组合物及其应用 |
| CA3035247A1 (en) | 2016-08-30 | 2018-03-08 | W.R. Grace & Co. - Conn. | Polyolefins with low ash content and method of making same |
| RU2692246C1 (ru) * | 2017-06-15 | 2019-06-24 | Индийская Нефтяная Корпорация Лимитэд | Внешний донор для полимеризации олефинов |
| CN109096418A (zh) * | 2017-06-21 | 2018-12-28 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂和烯烃聚合方法 |
| CN109096420B (zh) * | 2017-06-21 | 2021-05-11 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂和烯烃聚合方法 |
| CN109096424A (zh) * | 2017-06-21 | 2018-12-28 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂和烯烃聚合方法 |
| CN109096421A (zh) * | 2017-06-21 | 2018-12-28 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂和烯烃聚合方法 |
| CN109096417A (zh) * | 2017-06-21 | 2018-12-28 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂和烯烃聚合方法 |
| US11613592B2 (en) | 2018-02-07 | 2023-03-28 | Reliance Industries Limited | Ziegler-Natta catalyst system with self-extinguishing properties suitable for olefin polymerization |
| CN108409896B (zh) * | 2018-04-04 | 2021-02-05 | 朴蓝聚烯烃科技发展(上海)有限公司 | 齐格勒-纳塔催化剂组合物及其应用 |
| JP2021525289A (ja) | 2018-05-28 | 2021-09-24 | ボレアリス エージー | 光起電(pv)モジュール用装置 |
| WO2020064190A1 (en) | 2018-09-26 | 2020-04-02 | Borealis Ag | Propylene copolymer composition with excellent optical and mechanical properties |
| CN109517099B (zh) * | 2018-11-27 | 2021-07-30 | 山东鲁晶化工科技有限公司 | 一种外给电子体、烯烃聚合催化剂体系及其应用 |
| CN113573806A (zh) * | 2019-03-15 | 2021-10-29 | 格雷斯公司 | 用于制备不具有细粒的烯烃聚合物的催化剂体系 |
| CA3183731A1 (en) | 2020-06-29 | 2022-01-06 | Zhiru MA | Phthalate-free polypropylene homopolymer having high stiffness properties |
| KR20240042049A (ko) * | 2021-08-09 | 2024-04-01 | 더블유.알. 그레이스 앤드 캄파니-콘. | 침강 벌크 밀도가 향상된 폴리올레핀 입상 수지의 제조 방법 |
| US20250235842A1 (en) * | 2021-10-06 | 2025-07-24 | W.R. Grace & Co.-Conn | Gas-phase process for making polypropylene random copolymers |
| WO2025124978A1 (en) * | 2023-12-11 | 2025-06-19 | Sabic Global Technologies B.V. | Self-extinguishing catalyst system for propylene polymerization |
| WO2025259662A1 (en) | 2024-06-11 | 2025-12-18 | Dow Global Technologies Llc | Methods of producing films with matte finish |
| WO2025259663A1 (en) | 2024-06-11 | 2025-12-18 | Dow Global Technologies Llc | Methods of producing films with improved mechanical properties |
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|---|---|---|---|---|
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| DE3247919A1 (de) * | 1982-12-24 | 1984-06-28 | Basf Ag, 6700 Ludwigshafen | Verfahren zum herstellen von homo- und copolymerisaten von (alpha)-monoolefinen mittels einer ziegler-natta-katalysatorsystems |
| US4746762A (en) | 1985-01-17 | 1988-05-24 | Mobil Oil Corporation | Upgrading light olefins in a turbulent fluidized catalyst bed reactor |
| IN168393B (pt) | 1986-02-28 | 1991-03-23 | Shell Oil Co | |
| DE3866906D1 (de) * | 1987-03-23 | 1992-01-30 | Idemitsu Petrochemical Co | Verfahren zur herstellung von polyolefinen. |
| JPH0796573B2 (ja) | 1987-03-31 | 1995-10-18 | 出光石油化学株式会社 | プロピレン重合体の製造方法 |
| US5093415A (en) | 1987-05-19 | 1992-03-03 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing stereoregular polymers having a narrow molecular weight distribution |
| US4882380A (en) | 1987-07-07 | 1989-11-21 | Union Carbide Chemicals And Plastics Company Inc. | Process for the production of impact polypropylene copolymers |
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