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BRPI0601404A - processo de preparação de carbeto e nitreto misto moldado e sua aplicação como catalisador em processos de hidrotratamento - Google Patents

processo de preparação de carbeto e nitreto misto moldado e sua aplicação como catalisador em processos de hidrotratamento

Info

Publication number
BRPI0601404A
BRPI0601404A BRPI0601404-6A BRPI0601404A BRPI0601404A BR PI0601404 A BRPI0601404 A BR PI0601404A BR PI0601404 A BRPI0601404 A BR PI0601404A BR PI0601404 A BRPI0601404 A BR PI0601404A
Authority
BR
Brazil
Prior art keywords
preparation
catalyst
application
carbide
preparation process
Prior art date
Application number
BRPI0601404-6A
Other languages
English (en)
Inventor
Jose Augusto Jorge Rodrigues
Victor Luis Dos Santos T Silva
Marisa Aparecida Zacharias
Carlos Alexandre Miglioli
Original Assignee
Petroleo Brasileiro Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Petroleo Brasileiro Sa filed Critical Petroleo Brasileiro Sa
Priority to BRPI0601404A priority Critical patent/BRPI0601404B1/pt
Priority to ARP070101592A priority patent/AR060459A1/es
Priority to US11/785,417 priority patent/US20070284289A1/en
Publication of BRPI0601404A publication Critical patent/BRPI0601404A/pt
Publication of BRPI0601404B1 publication Critical patent/BRPI0601404B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/22—Carbides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/24—Nitrogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J33/00—Protection of catalysts, e.g. by coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C10G45/46—Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)

Abstract

PROCESSO DE PREPARAçãO DE CARBETO E NITRETO MISTO MOLDADO E SUA APLICAçãO COMO CATALISADOR EM PROCESSOS DE HIDROTRATAMENTO A presente invenção trata de um processo de preparo de novos catalisadores à base de óxidos mistos de metais de transição, que envolve a preparação de precursores e a síntese destes materiais na forma oxidada, a partir da preparação de um sol-gel formado com sais inorgânicos desses metais. A invenção propõe um avanço no preparo destes catalisadores à base de carbetos e nitretos mistos de metais de transição, proporcionando uma rota alternativa ao processo de síntese por reação no estado sólido. O produto final, na forma extrudada, possui propriedades texturais e mecânicas superiores às obtidas pelas técnicas conhecidas do estado da arte, e, com melhor atividade catalítica para reações de hidrotratamento.
BRPI0601404A 2006-04-17 2006-04-17 processo de preparação de carbetos, nitretos e sulfetos mistos moldados e sua aplicação como catalisadores em processos de hidrotratamento BRPI0601404B1 (pt)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BRPI0601404A BRPI0601404B1 (pt) 2006-04-17 2006-04-17 processo de preparação de carbetos, nitretos e sulfetos mistos moldados e sua aplicação como catalisadores em processos de hidrotratamento
ARP070101592A AR060459A1 (es) 2006-04-17 2007-04-13 Proceso de preparacion de carburo y nitruro mixto moldeado, catalizador de carburo y nitruro mixto moldeado, y proceso de hidrotratamiento de una corriente de hidrocarburos
US11/785,417 US20070284289A1 (en) 2006-04-17 2007-04-17 Process to prepare mixed molded carbide and nitrite material and its application as a catalyst in hydrotreatment processes

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BRPI0601404A BRPI0601404B1 (pt) 2006-04-17 2006-04-17 processo de preparação de carbetos, nitretos e sulfetos mistos moldados e sua aplicação como catalisadores em processos de hidrotratamento

Publications (2)

Publication Number Publication Date
BRPI0601404A true BRPI0601404A (pt) 2007-12-18
BRPI0601404B1 BRPI0601404B1 (pt) 2018-10-09

Family

ID=38820811

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0601404A BRPI0601404B1 (pt) 2006-04-17 2006-04-17 processo de preparação de carbetos, nitretos e sulfetos mistos moldados e sua aplicação como catalisadores em processos de hidrotratamento

Country Status (3)

Country Link
US (1) US20070284289A1 (pt)
AR (1) AR060459A1 (pt)
BR (1) BRPI0601404B1 (pt)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101722014B (zh) * 2008-10-28 2011-06-22 中国石油化工股份有限公司 加氢脱硫催化剂及其制备方法和应用
US8158094B2 (en) * 2009-05-12 2012-04-17 The United States Of America, As Represented By The Secretary Of The Navy Methods of preparing metal carbides
US20130045865A1 (en) * 2011-01-31 2013-02-21 The Regents Of The University Of Michigan High activity early transition metal carbide and nitride based catalysts
US9012349B1 (en) * 2013-11-01 2015-04-21 Ut-Battelle Llc Method of synthesizing bulk transition metal carbide, nitride and phosphide catalysts
CN109790024B (zh) * 2016-10-05 2023-04-14 埃克森美孚化学专利公司 制备金属氮化物和金属碳化物的方法
WO2018067276A1 (en) * 2016-10-05 2018-04-12 Exxonmobil Chemical Patents Inc. Method for producing metal nitrides and metal carbides

Family Cites Families (12)

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Publication number Priority date Publication date Assignee Title
US3330697A (en) * 1963-08-26 1967-07-11 Sprague Electric Co Method of preparing lead and alkaline earth titanates and niobates and coating method using the same to form a capacitor
US4271041A (en) * 1979-02-08 1981-06-02 The Board Of Trustees Of Leland Stanford Junior University High surface area molybdenum oxycarbide catalysts
US4325843A (en) * 1980-12-08 1982-04-20 Shell Oil Company Process for preparing a supported tungsten carbide composition
US4325842A (en) * 1980-12-08 1982-04-20 Shell Oil Company Process for preparing a supported molybdenum carbide composition
US4515763A (en) * 1981-07-15 1985-05-07 Board Of Trustees Of Leland Stanford Jr. Univeristy High specific surface area carbides and nitrides
US4977123A (en) * 1988-06-17 1990-12-11 Massachusetts Institute Of Technology Preparation of extrusions of bulk mixed oxide compounds with high macroporosity and mechanical strength
US5200060A (en) * 1991-04-26 1993-04-06 Amoco Corporation Hydrotreating process using carbides and nitrides of group VIB metals
US5451557A (en) * 1994-02-24 1995-09-19 Akzo Nobel N.V. Precursor for forming metal carbide catalysts
US5573991A (en) * 1994-02-24 1996-11-12 Akzo Nobel N.V. Preparation of metal carbide catalyst supported on carbon
US6534437B2 (en) * 1999-01-15 2003-03-18 Akzo Nobel N.V. Process for preparing a mixed metal catalyst composition
AR043242A1 (es) * 2003-02-24 2005-07-20 Shell Int Research Preparacion y uso de una composicion de catalizador
BRPI0601405B1 (pt) * 2006-04-17 2017-06-13 Petroleo Brasileiro S.A. - Petrobras Preparation process of molded mixed precursor for obtaining carbide, nitride and sulfet

Also Published As

Publication number Publication date
AR060459A1 (es) 2008-06-18
BRPI0601404B1 (pt) 2018-10-09
US20070284289A1 (en) 2007-12-13

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B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

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