DE602008006438D1 - Verfahren zur herstellung von cyclohexylbenzol - Google Patents
Verfahren zur herstellung von cyclohexylbenzolInfo
- Publication number
- DE602008006438D1 DE602008006438D1 DE602008006438T DE602008006438T DE602008006438D1 DE 602008006438 D1 DE602008006438 D1 DE 602008006438D1 DE 602008006438 T DE602008006438 T DE 602008006438T DE 602008006438 T DE602008006438 T DE 602008006438T DE 602008006438 D1 DE602008006438 D1 DE 602008006438D1
- Authority
- DE
- Germany
- Prior art keywords
- cyclohexylbenzene
- benzene
- hydrogen
- reaction zone
- catalyst system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- HHNHBFLGXIUXCM-GFCCVEGCSA-N cyclohexylbenzene Chemical compound [CH]1CCCC[C@@H]1C1=CC=CC=C1 HHNHBFLGXIUXCM-GFCCVEGCSA-N 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 239000002184 metal Substances 0.000 abstract 2
- 238000002441 X-ray diffraction Methods 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/74—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition with simultaneous hydrogenation
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/46—Ruthenium, rhodium, osmium or iridium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/75—Cobalt
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
- C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
- C07C2529/74—Noble metals
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US97431207P | 2007-09-21 | 2007-09-21 | |
| PCT/US2008/072843 WO2009038900A1 (en) | 2007-09-21 | 2008-08-12 | Process for producing cyclohexylbenzene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE602008006438D1 true DE602008006438D1 (de) | 2011-06-01 |
Family
ID=40032532
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE602008006438T Active DE602008006438D1 (de) | 2007-09-21 | 2008-08-12 | Verfahren zur herstellung von cyclohexylbenzol |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US7847128B2 (de) |
| EP (1) | EP2200955B1 (de) |
| JP (1) | JP5192546B2 (de) |
| KR (1) | KR101151978B1 (de) |
| CN (1) | CN101754940B (de) |
| AT (1) | ATE506335T1 (de) |
| DE (1) | DE602008006438D1 (de) |
| TW (1) | TWI465289B (de) |
| WO (1) | WO2009038900A1 (de) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5529737B2 (ja) | 2007-08-15 | 2014-06-25 | エクソンモービル ケミカル パテンツ インコーポレイテッド | シクロヘキシルベンゼンの製造方法 |
| KR101151978B1 (ko) | 2007-09-21 | 2012-06-01 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 사이클로헥실벤젠의 제조방법 |
| CN101687728B (zh) | 2007-09-21 | 2013-05-29 | 埃克森美孚化学专利公司 | 生产环己基苯的方法 |
| WO2009102517A1 (en) * | 2008-02-12 | 2009-08-20 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
| US8178728B2 (en) | 2008-04-14 | 2012-05-15 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
| WO2009134516A1 (en) | 2008-05-01 | 2009-11-05 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
| WO2010014402A1 (en) | 2008-07-28 | 2010-02-04 | Exxonmobil Chemical Patents Inc. | Hydroalkylation of aromatic compounds using emm-12 |
| JP5461552B2 (ja) | 2008-07-28 | 2014-04-02 | エクソンモービル・ケミカル・パテンツ・インク | Ｅｍｍ−１３を用いるアルキル芳香族化合物の製造方法 |
| WO2010042273A1 (en) * | 2008-10-10 | 2010-04-15 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| US8519194B2 (en) | 2009-02-26 | 2013-08-27 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
| WO2010138248A2 (en) * | 2009-05-26 | 2010-12-02 | Exxonmobil Chemical Patents Inc. | Transalkylation of polycyclohexylbenzenes |
| IT1395594B1 (it) * | 2009-06-29 | 2012-10-16 | Polimeri Europa Spa | Processo per la preparazione di fenolo e cicloesanone |
| CN102741202B (zh) * | 2010-02-12 | 2015-11-25 | 埃克森美孚化学专利公司 | 氢化方法 |
| US9725401B2 (en) | 2010-08-25 | 2017-08-08 | Exxonmobil Chemical Patents Inc. | Processes for the production of esters |
| EP2616436B1 (de) * | 2010-09-14 | 2018-05-30 | ExxonMobil Chemical Patents Inc. | Oxidation von cyclohexylbenzol |
| CN103052610A (zh) * | 2010-09-14 | 2013-04-17 | 埃克森美孚化学专利公司 | 环己基苯组合物 |
| WO2012050751A1 (en) | 2010-10-11 | 2012-04-19 | Exxonmobil Chemical Patents Inc. | Activation and use of hydroalkylation catalysts |
| WO2012082229A1 (en) | 2010-12-17 | 2012-06-21 | Exxonmobil Chemical Patents Inc. | Composition comprising cyclohexylbenzene and 1 - phenyl - 1 -methylcyclopentane and use thereof in oxidation processes |
| WO2012082232A1 (en) | 2010-12-17 | 2012-06-21 | Exxonmobil Chemical Patenst Inc. | Process for producing cycloalkylaromatic compounds |
| US9233887B2 (en) | 2010-12-21 | 2016-01-12 | Exxonmobil Chemical Patents Inc. | Process for producing a monocycloalkyl-substituted aromatic compound |
| EP2675772B1 (de) * | 2011-02-18 | 2015-09-16 | ExxonMobil Chemical Patents Inc. | Verfahren zur herstellung von cyclohexylbenzen |
| WO2013043271A1 (en) * | 2011-09-23 | 2013-03-28 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
| WO2013058882A1 (en) | 2011-10-17 | 2013-04-25 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
| WO2013119407A1 (en) | 2012-02-08 | 2013-08-15 | Exxonmobil Chemical Patents Inc. | Process for producing cyclohexylbenzene |
| US9090528B2 (en) * | 2012-02-27 | 2015-07-28 | Exxonmobil Chemical Patents Inc. | Hydroalkylation process |
| EP2970045A4 (de) | 2013-03-14 | 2016-03-09 | Exxonmobil Chem Patents Inc | Methylsubstituierte biphenylverbindungen, deren herstellung und deren verwendung bei der herstellung von weichmachern |
| US9725377B2 (en) | 2013-03-14 | 2017-08-08 | Exxonmobil Chemical Patents Inc. | Hydroalkylation catalyst and process for use thereof |
| EP2970049B1 (de) | 2013-03-14 | 2019-10-16 | ExxonMobil Chemical Patents Inc. | Methylsubstituierte biphenylverbindungen, deren herstellung und deren verwendung bei der herstellung von weichmachern |
| US9464011B2 (en) | 2013-03-25 | 2016-10-11 | Exxonmobil Chemical Patents Inc. | Process for making alkylated aromatic compound |
| WO2014158985A1 (en) * | 2013-03-25 | 2014-10-02 | Exxonmobil Chemical Patents Inc. | Process for making alkylated aromatic compound |
| CN105829273B (zh) | 2013-12-20 | 2019-05-28 | 埃克森美孚化学专利公司 | 制备苯酚和/或环己酮的方法 |
| US10259759B2 (en) | 2013-12-20 | 2019-04-16 | Exxonmobil Chemical Patents Inc. | Cyclohexylbenzene composition |
| CN105233861B (zh) * | 2014-07-11 | 2019-07-09 | 中国石油化工股份有限公司 | 环己基苯催化剂以及环己基苯的合成方法 |
| CN105233862B (zh) * | 2014-07-11 | 2018-10-23 | 中国石油化工股份有限公司 | 环己基苯催化剂及其制备方法 |
| CN105582989B (zh) * | 2014-10-24 | 2019-08-06 | 中国石油化工股份有限公司 | 环己基苯合成用催化剂 |
| TWI600640B (zh) * | 2015-03-31 | 2017-10-01 | 艾克頌美孚化學專利股份有限公司 | 轉烷化之環己基苯甲基及聯苯化合物 |
| CN112221521B (zh) * | 2016-01-27 | 2024-05-17 | 中国石油化工股份有限公司 | 一种催化剂、其制备方法及制备环己基苯的方法 |
| CN107303500B (zh) * | 2016-04-25 | 2020-03-27 | 中国石化扬子石油化工有限公司 | 金属/h-mcm-22催化剂及其在生产环己基苯中的应用 |
| CN107303501B (zh) * | 2016-04-25 | 2020-02-21 | 中国石化扬子石油化工有限公司 | 金属/mcm-49催化剂及其在生产环己基苯中的应用 |
| CN110563543B (zh) * | 2018-06-06 | 2022-07-12 | 中国石油化工股份有限公司 | 合成环己基苯的方法 |
| CN110563534B (zh) * | 2018-06-06 | 2022-04-05 | 中国石油化工股份有限公司 | 加氢烷基化合成环己基苯的方法 |
| CN114950542B (zh) * | 2022-06-02 | 2023-12-22 | 江苏扬农化工集团有限公司 | 一种双金属负载型分子筛催化剂及其制备方法和用途 |
| CN119613212A (zh) * | 2023-09-12 | 2025-03-14 | 中国石油化工股份有限公司 | 一种苯加氢烷基化制备环己基苯的方法 |
| CN119899076A (zh) * | 2023-10-27 | 2025-04-29 | 中国石油化工股份有限公司 | 环己烯的生产方法 |
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| DE10015874A1 (de) | 2000-03-30 | 2001-10-11 | Creavis Tech & Innovation Gmbh | Verfahren zur Herstellung von aromatischen Alkoholen insbesondere Phenol |
| US6936744B1 (en) | 2000-07-19 | 2005-08-30 | Exxonmobil Chemical Patents, Inc. | Alkylaromatics production |
| JP2002102709A (ja) | 2000-09-29 | 2002-04-09 | Showa Denko Kk | 酸化化合物製造用結晶性ｍｗｗ型チタノシリケート触媒、該触媒の製造方法、及び該触媒を用いた酸化化合物の製造方法 |
| JP4241068B2 (ja) | 2002-03-07 | 2009-03-18 | 昭和電工株式会社 | Ｍｗｗ型ゼオライト物質の製造方法 |
| ES2246704B1 (es) | 2004-05-28 | 2007-06-16 | Universidad Politecnica De Valencia | Zeolita itq-30. |
| JP4457761B2 (ja) * | 2004-06-04 | 2010-04-28 | 宇部興産株式会社 | シクロヘキシルベンゼン製造用触媒及びシクロヘキシルベンゼンの製造方法 |
| WO2008016456A2 (en) | 2006-07-28 | 2008-02-07 | Exxonmobil Chemical Patents Inc. | Molecular sieve composition (emm-10), its method of making, and use for hydrocarbon conversions |
| US7959899B2 (en) | 2006-07-28 | 2011-06-14 | Exxonmobil Chemical Patents Inc. | Molecular sieve composition (EMM-10-P), its method of making, and use for hydrocarbon conversions |
| DK2056964T3 (da) | 2006-07-28 | 2019-05-06 | Exxonmobil Chemical Patents Inc | Hidtil ukendt molekylsigtesammensætning, fremgangsmåde til fremstilling deraf og fremgangsmåde til anvendelse deraf |
| JP5529737B2 (ja) * | 2007-08-15 | 2014-06-25 | エクソンモービル ケミカル パテンツ インコーポレイテッド | シクロヘキシルベンゼンの製造方法 |
| KR101151978B1 (ko) | 2007-09-21 | 2012-06-01 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 사이클로헥실벤젠의 제조방법 |
-
2008
- 2008-08-12 KR KR1020107006151A patent/KR101151978B1/ko not_active Expired - Fee Related
- 2008-08-12 EP EP08797656A patent/EP2200955B1/de not_active Not-in-force
- 2008-08-12 CN CN2008800250033A patent/CN101754940B/zh not_active Expired - Fee Related
- 2008-08-12 DE DE602008006438T patent/DE602008006438D1/de active Active
- 2008-08-12 US US12/663,303 patent/US7847128B2/en active Active
- 2008-08-12 AT AT08797656T patent/ATE506335T1/de not_active IP Right Cessation
- 2008-08-12 WO PCT/US2008/072843 patent/WO2009038900A1/en not_active Ceased
- 2008-08-12 JP JP2010521924A patent/JP5192546B2/ja not_active Expired - Fee Related
- 2008-08-18 TW TW097131436A patent/TWI465289B/zh not_active IP Right Cessation
-
2010
- 2010-10-14 US US12/904,215 patent/US7910779B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| JP5192546B2 (ja) | 2013-05-08 |
| US20100179351A1 (en) | 2010-07-15 |
| CN101754940B (zh) | 2013-05-08 |
| WO2009038900A1 (en) | 2009-03-26 |
| US7910779B2 (en) | 2011-03-22 |
| EP2200955A1 (de) | 2010-06-30 |
| CN101754940A (zh) | 2010-06-23 |
| KR20100044906A (ko) | 2010-04-30 |
| TWI465289B (zh) | 2014-12-21 |
| EP2200955B1 (de) | 2011-04-20 |
| JP2010536862A (ja) | 2010-12-02 |
| US20110028762A1 (en) | 2011-02-03 |
| KR101151978B1 (ko) | 2012-06-01 |
| TW200922689A (en) | 2009-06-01 |
| US7847128B2 (en) | 2010-12-07 |
| ATE506335T1 (de) | 2011-05-15 |
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