BRPI0606737A2 - método para reformar material carbonáceo por vapor - Google Patents
método para reformar material carbonáceo por vaporInfo
- Publication number
- BRPI0606737A2 BRPI0606737A2 BRPI0606737-9A BRPI0606737A BRPI0606737A2 BR PI0606737 A2 BRPI0606737 A2 BR PI0606737A2 BR PI0606737 A BRPI0606737 A BR PI0606737A BR PI0606737 A2 BRPI0606737 A2 BR PI0606737A2
- Authority
- BR
- Brazil
- Prior art keywords
- carbonaceous material
- reforming
- synthesis gas
- stage
- materials
- Prior art date
Links
- 238000002407 reforming Methods 0.000 title abstract 7
- 239000003575 carbonaceous material Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- 230000015572 biosynthetic process Effects 0.000 abstract 3
- 238000003786 synthesis reaction Methods 0.000 abstract 3
- 238000010438 heat treatment Methods 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 2
- 239000011343 solid material Substances 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000007769 metal material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/005—Rotary drum or kiln gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/06—Continuous processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/06—Continuous processes
- C10J3/16—Continuous processes simultaneously reacting oxygen and water with the carbonaceous material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
- C10K3/003—Reducing the tar content
- C10K3/006—Reducing the tar content by steam reforming
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
- C10J2200/158—Screws
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
- C10J2300/092—Wood, cellulose
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Processing Of Solid Wastes (AREA)
- Carbon And Carbon Compounds (AREA)
- Muffle Furnaces And Rotary Kilns (AREA)
Abstract
MéTODO PARA REFORMAR MATERIAL CARBONáCEO POR VAPOR. Expõe-se um método para reformar material carbonáceo por vapor em um gás de síntese, mediante utilização de um processo de aquecimento de estágio único do material carbonáceo em um forno rotativo sob temperatura de reformação elevada, de forma que o material carbonáceo é submetido a conversão substancialmente completa para o gás de síntese ou por utilização de um processo de aquecimento de vários estágios, corrente dupla, do material carbonáceo para uma temperatura de reformação, abaixo da qual os materiais metálicos serão tipicamente vaporizados, para formarem materiais gasosos e sólidos; reformar ainda os materiais gasosos em um forno rotativo de segundo estágio sob uma temperatura de reformação elevada para formar gás de síntese; e separar o carbonizado de carvão em relação ao material sólido para processamento ulterior.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64460105P | 2005-01-18 | 2005-01-18 | |
| PCT/CA2006/000060 WO2006076801A1 (en) | 2005-01-18 | 2006-01-18 | Method for steam reforming carbonaceous material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0606737A2 true BRPI0606737A2 (pt) | 2009-07-14 |
| BRPI0606737B1 BRPI0606737B1 (pt) | 2016-04-26 |
Family
ID=36691949
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0606737A BRPI0606737B1 (pt) | 2005-01-18 | 2006-01-18 | método para reformar material carbonáceo por vapor |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US7794689B2 (pt) |
| EP (1) | EP1877520B8 (pt) |
| JP (2) | JP5474302B2 (pt) |
| KR (2) | KR20130102646A (pt) |
| CN (1) | CN101120076B (pt) |
| AU (1) | AU2006207788A1 (pt) |
| BR (1) | BRPI0606737B1 (pt) |
| CA (1) | CA2581288C (pt) |
| ES (1) | ES2441543T3 (pt) |
| MX (1) | MX2007008729A (pt) |
| NZ (1) | NZ556611A (pt) |
| PL (1) | PL1877520T3 (pt) |
| RU (1) | RU2424277C2 (pt) |
| WO (1) | WO2006076801A1 (pt) |
| ZA (1) | ZA200706523B (pt) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL1877520T3 (pl) | 2005-01-18 | 2014-04-30 | Bradam Group Llc | Sposób reformingu parowego materiału zawierającego węgiel |
| US7998226B2 (en) * | 2005-11-02 | 2011-08-16 | Terry R. Galloway | Appliance for converting household waste into energy |
| US20070210075A1 (en) * | 2006-03-02 | 2007-09-13 | John Self | Induction heater |
| JP2008260832A (ja) * | 2007-04-11 | 2008-10-30 | Micro Energy:Kk | 廃棄物再生処理方法及び廃棄物再生処理システム |
| DE102007032419B4 (de) | 2007-07-10 | 2013-02-21 | Outotec Oyj | Verfahren und Anlage zur Reduktion von eisenoxidhaltigen Feststoffen |
| JP5463006B2 (ja) * | 2008-03-14 | 2014-04-09 | Jx日鉱日石エネルギー株式会社 | 固体酸化物形燃料電池システムの運転方法 |
| US8184763B2 (en) * | 2009-01-13 | 2012-05-22 | Areva Sa | System and a process for producing at least one hydrocarbon fuel from a carbonaceous material |
| ES2645919T3 (es) | 2009-02-11 | 2017-12-11 | Natural Energy Systems Inc. | Proceso para la conversión de material orgánico en gas combustible rico en metano |
| CN101565634B (zh) * | 2009-05-22 | 2012-11-14 | 河南金土地煤气工程有限公司 | 单段环保风冷式煤气生产方法 |
| KR101133543B1 (ko) | 2009-10-06 | 2012-04-05 | 한밭대학교 산학협력단 | 탄소 수증기 개질장치를 포함한 연료전지 열병합 발전 시스템 |
| US20120217442A1 (en) * | 2009-10-15 | 2012-08-30 | Pyromex Holding Ag | High-temperature furnace and method for converting organic materials to synthesis gas |
| JP5553157B2 (ja) * | 2010-07-23 | 2014-07-16 | 富士通株式会社 | 油化方法及び装置 |
| US20120204962A1 (en) * | 2011-02-11 | 2012-08-16 | Evergreen Energy Inc. | System and Method for Improved Hydrothermal Upgrading of Carbonaceous Material |
| RU2507238C2 (ru) * | 2012-05-24 | 2014-02-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский национальный исследовательский технологический университет" | Способ получения синтез-газа из древесных отходов |
| RO130112A2 (ro) * | 2013-09-23 | 2015-03-30 | Vasile Celac | Procedeu şi instalaţie pentru obţinerea gazului de sinteză |
| ES2669494T5 (es) * | 2015-07-10 | 2022-04-28 | Air Liquide | Procedimiento e instalación para el enfriamiento de gas de síntesis |
| JP6590359B1 (ja) * | 2018-07-06 | 2019-10-16 | 株式会社翼エンジニアリングサービス | バイオマスを原料とする水素製造方法 |
| WO2021044318A1 (es) * | 2019-09-02 | 2021-03-11 | Araya Matteo Julio Cesar | Sistema y método para la obtención de energía a través del uso de hidrocarburos de calidad reducida e hidrógeno producido a partir del agua en la generación de energía de combustión |
| GB2616488B (en) | 2022-09-02 | 2024-11-06 | Sru Innovations Ltd | Steam treatment of waste |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2226578A (en) * | 1939-06-14 | 1940-12-31 | Socony Vacuum Oil Co Inc | Kiln |
| US4597772A (en) * | 1984-09-20 | 1986-07-01 | Wright-Malta Corporation | Fixed kiln with rotor steam gasifier |
| US5645744A (en) * | 1991-04-05 | 1997-07-08 | The Boeing Company | Retort for achieving thermal uniformity in induction processing of organic matrix composites or metals |
| US5245113A (en) * | 1991-05-23 | 1993-09-14 | Dynecology, Incorporated | Decontamination of PCB contaminated solids |
| JPH08112580A (ja) * | 1994-10-14 | 1996-05-07 | Nippon Steel Corp | 複合廃棄物の連続処理方法 |
| US5879566A (en) * | 1997-02-03 | 1999-03-09 | The Scientific Ecology Group, Inc. | Integrated steam reforming operation for processing organic contaminated sludges and system |
| US6205704B1 (en) * | 1998-03-09 | 2001-03-27 | William C. Crutcher | Method and apparatus for enhancing plant growth in greenhouses utilizing landfill gas |
| NL1009038C2 (nl) * | 1998-04-29 | 1999-11-01 | Stichting Energie | Werkwijze en inrichting voor het vormen van synthesegas. |
| US6005149A (en) * | 1998-08-18 | 1999-12-21 | Engineering, Separation & Recycling, Ltd. Co. | Method and apparatus for processing organic materials to produce chemical gases and carbon char |
| JP2000296378A (ja) * | 1999-04-13 | 2000-10-24 | Mitsubishi Heavy Ind Ltd | 廃棄物の処理方法 |
| CA2274390A1 (en) * | 1999-06-10 | 2000-12-10 | Questor Industries Inc. | Multistage chemical separation method and apparatus using pressure swing adsorption |
| DE60024288T2 (de) * | 1999-08-19 | 2006-08-17 | Manufacturing And Technology Conversion International, Inc. | Einen dampfreformer und eine brennstoffzelle enthaltendes integriertes system |
| TWI241392B (en) * | 1999-09-20 | 2005-10-11 | Japan Science & Tech Agency | Apparatus and method for gasifying solid or liquid fuel |
| JP2001123175A (ja) * | 1999-10-25 | 2001-05-08 | Toyoda Techno Kk | 廃棄物の処理方法 |
| JP4427173B2 (ja) * | 2000-08-16 | 2010-03-03 | 三菱重工業株式会社 | 合成ガスの製造方法 |
| DE10055360B4 (de) * | 2000-11-08 | 2004-07-29 | Mühlen, Heinz-Jürgen, Dr.rer.Nat. | Verfahren zur Vergasung von flüssigen bis pastösen organischen Stoffen und Stoffgemischen |
| US6519926B2 (en) * | 2001-05-01 | 2003-02-18 | General Atomics | Hydrothermal conversion and separation |
| JP3764659B2 (ja) * | 2001-06-20 | 2006-04-12 | 新日本製鐵株式会社 | 樹脂主体廃棄物の再資源化方法 |
| US7220502B2 (en) * | 2002-06-27 | 2007-05-22 | Intellergy Corporation | Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions |
| US7132183B2 (en) * | 2002-06-27 | 2006-11-07 | Intellergy Corporation | Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions |
| US20060076275A1 (en) * | 2002-07-12 | 2006-04-13 | Smith Anthon L | Process for the recovery of hydrocarbon fractions from hydrocarbonaceous solids |
| JP2004075852A (ja) * | 2002-08-19 | 2004-03-11 | Nippon Steel Corp | 炭素質資源のガス化方法及びその装置 |
| JP4246456B2 (ja) * | 2002-08-27 | 2009-04-02 | 株式会社 日本計画機構 | 有機系廃棄物からの水素回収方法 |
| WO2004024620A2 (en) * | 2002-09-10 | 2004-03-25 | Manufacturing And Technology Conversion International, Inc. | Steam reforming process and apparatus |
| US20050095183A1 (en) * | 2003-11-05 | 2005-05-05 | Biomass Energy Solutions, Inc. | Process and apparatus for biomass gasification |
| PL1877520T3 (pl) | 2005-01-18 | 2014-04-30 | Bradam Group Llc | Sposób reformingu parowego materiału zawierającego węgiel |
| US9225632B2 (en) | 2005-09-16 | 2015-12-29 | Hewlett Packard Enterprise Development Lp | Globally fair polling for packet switched routers using dynamically biased arbitration |
-
2006
- 2006-01-18 PL PL06704095T patent/PL1877520T3/pl unknown
- 2006-01-18 CN CN200680002624.0A patent/CN101120076B/zh not_active Expired - Fee Related
- 2006-01-18 CA CA2581288A patent/CA2581288C/en not_active Expired - Lifetime
- 2006-01-18 KR KR1020137020091A patent/KR20130102646A/ko not_active Withdrawn
- 2006-01-18 ES ES06704095T patent/ES2441543T3/es not_active Expired - Lifetime
- 2006-01-18 AU AU2006207788A patent/AU2006207788A1/en not_active Abandoned
- 2006-01-18 MX MX2007008729A patent/MX2007008729A/es active IP Right Grant
- 2006-01-18 JP JP2007550648A patent/JP5474302B2/ja not_active Expired - Fee Related
- 2006-01-18 RU RU2007130998A patent/RU2424277C2/ru active
- 2006-01-18 ZA ZA200706523A patent/ZA200706523B/xx unknown
- 2006-01-18 WO PCT/CA2006/000060 patent/WO2006076801A1/en not_active Ceased
- 2006-01-18 US US11/718,597 patent/US7794689B2/en active Active - Reinstated
- 2006-01-18 NZ NZ556611A patent/NZ556611A/en not_active IP Right Cessation
- 2006-01-18 EP EP20060704095 patent/EP1877520B8/en not_active Expired - Lifetime
- 2006-01-18 BR BRPI0606737A patent/BRPI0606737B1/pt not_active IP Right Cessation
-
2007
- 2007-08-17 KR KR1020077018874A patent/KR101343979B1/ko not_active Expired - Fee Related
-
2010
- 2010-09-13 US US12/881,057 patent/US9139787B2/en not_active Expired - Lifetime
-
2013
- 2013-08-16 JP JP2013169236A patent/JP2013253252A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EP1877520B8 (en) | 2013-11-13 |
| ZA200706523B (en) | 2009-02-25 |
| KR101343979B1 (ko) | 2013-12-24 |
| EP1877520B1 (en) | 2013-10-09 |
| CA2581288C (en) | 2018-02-20 |
| CN101120076A (zh) | 2008-02-06 |
| KR20130102646A (ko) | 2013-09-17 |
| BRPI0606737B1 (pt) | 2016-04-26 |
| US7794689B2 (en) | 2010-09-14 |
| US9139787B2 (en) | 2015-09-22 |
| US20080112882A1 (en) | 2008-05-15 |
| JP5474302B2 (ja) | 2014-04-16 |
| NZ556611A (en) | 2011-01-28 |
| WO2006076801A1 (en) | 2006-07-27 |
| US20110204294A1 (en) | 2011-08-25 |
| PL1877520T3 (pl) | 2014-04-30 |
| JP2013253252A (ja) | 2013-12-19 |
| CA2581288A1 (en) | 2006-07-27 |
| AU2006207788A1 (en) | 2006-07-27 |
| EP1877520A1 (en) | 2008-01-16 |
| EP1877520A4 (en) | 2011-01-19 |
| CN101120076B (zh) | 2014-09-10 |
| JP2008528708A (ja) | 2008-07-31 |
| KR20070110497A (ko) | 2007-11-19 |
| ES2441543T3 (es) | 2014-02-05 |
| RU2007130998A (ru) | 2009-02-27 |
| MX2007008729A (es) | 2008-03-04 |
| RU2424277C2 (ru) | 2011-07-20 |
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