MX2007008729A - Metodo para reformado por vapor de material carbonaceo. - Google Patents
Metodo para reformado por vapor de material carbonaceo.Info
- Publication number
- MX2007008729A MX2007008729A MX2007008729A MX2007008729A MX2007008729A MX 2007008729 A MX2007008729 A MX 2007008729A MX 2007008729 A MX2007008729 A MX 2007008729A MX 2007008729 A MX2007008729 A MX 2007008729A MX 2007008729 A MX2007008729 A MX 2007008729A
- Authority
- MX
- Mexico
- Prior art keywords
- carbonaceous material
- reforming
- synthesis gas
- steam reforming
- materials
- Prior art date
Links
- 239000003575 carbonaceous material Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 238000000629 steam reforming Methods 0.000 title abstract 2
- 238000002407 reforming Methods 0.000 abstract 5
- 230000015572 biosynthetic process Effects 0.000 abstract 3
- 238000003786 synthesis reaction Methods 0.000 abstract 3
- 238000010438 heat treatment Methods 0.000 abstract 2
- 239000011343 solid material Substances 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000009977 dual effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000007769 metal material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/721—Multistage gasification, e.g. plural parallel or serial gasification stages
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/005—Rotary drum or kiln gasifiers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/06—Continuous processes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/06—Continuous processes
- C10J3/16—Continuous processes simultaneously reacting oxygen and water with the carbonaceous material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
- C10K3/003—Reducing the tar content
- C10K3/006—Reducing the tar content by steam reforming
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2200/00—Details of gasification apparatus
- C10J2200/15—Details of feeding means
- C10J2200/158—Screws
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
- C10J2300/092—Wood, cellulose
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1861—Heat exchange between at least two process streams
- C10J2300/1884—Heat exchange between at least two process streams with one stream being synthesis gas
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Processing Of Solid Wastes (AREA)
- Carbon And Carbon Compounds (AREA)
- Muffle Furnaces And Rotary Kilns (AREA)
Abstract
Un metodo para reformado por vapor de material carbonaceo en gas de sintesis a traves de la utilizacion de un proceso de calentamiento de etapa unica en un horno giratorio a una temperatura de reformacion elevada de manera que el material carbonaceo experimenta conversion sustancialmente completa a gas de sintesis o por medio de la utilizacion de un proceso de calentamiento multi-etapa, de corriente doble del material carbonaceo hasta una temperatura de reformacion, por debajo de aquella a la cual se vaporizaran comunmente los materiales metalicos, para formar materiales gaseosos y solidos; ademas de reformar los materiales carbonaceos en un horno de reformacion de segunda etapa a una temperatura de reformacion elevada para formar el gas de sintesis; y separar carbon de madera del material solido para procesamiento adicional.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US64460105P | 2005-01-18 | 2005-01-18 | |
| PCT/CA2006/000060 WO2006076801A1 (en) | 2005-01-18 | 2006-01-18 | Method for steam reforming carbonaceous material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2007008729A true MX2007008729A (es) | 2008-03-04 |
Family
ID=36691949
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2007008729A MX2007008729A (es) | 2005-01-18 | 2006-01-18 | Metodo para reformado por vapor de material carbonaceo. |
Country Status (15)
| Country | Link |
|---|---|
| US (2) | US7794689B2 (es) |
| EP (1) | EP1877520B8 (es) |
| JP (2) | JP5474302B2 (es) |
| KR (2) | KR20130102646A (es) |
| CN (1) | CN101120076B (es) |
| AU (1) | AU2006207788A1 (es) |
| BR (1) | BRPI0606737B1 (es) |
| CA (1) | CA2581288C (es) |
| ES (1) | ES2441543T3 (es) |
| MX (1) | MX2007008729A (es) |
| NZ (1) | NZ556611A (es) |
| PL (1) | PL1877520T3 (es) |
| RU (1) | RU2424277C2 (es) |
| WO (1) | WO2006076801A1 (es) |
| ZA (1) | ZA200706523B (es) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0606737B1 (pt) | 2005-01-18 | 2016-04-26 | Enquest Power Corp | método para reformar material carbonáceo por vapor |
| US7998226B2 (en) * | 2005-11-02 | 2011-08-16 | Terry R. Galloway | Appliance for converting household waste into energy |
| WO2007103131A2 (en) * | 2006-03-02 | 2007-09-13 | Shaw Waste Solutions, Llc | Improved induction heater |
| JP2008260832A (ja) * | 2007-04-11 | 2008-10-30 | Micro Energy:Kk | 廃棄物再生処理方法及び廃棄物再生処理システム |
| DE102007032419B4 (de) | 2007-07-10 | 2013-02-21 | Outotec Oyj | Verfahren und Anlage zur Reduktion von eisenoxidhaltigen Feststoffen |
| JP5463006B2 (ja) * | 2008-03-14 | 2014-04-09 | Jx日鉱日石エネルギー株式会社 | 固体酸化物形燃料電池システムの運転方法 |
| US8184763B2 (en) * | 2009-01-13 | 2012-05-22 | Areva Sa | System and a process for producing at least one hydrocarbon fuel from a carbonaceous material |
| HUE035566T2 (en) | 2009-02-11 | 2018-05-28 | Natural Energy Systems Inc | Process for the conversion of organic material to methane rich fuel gas |
| CN101565634B (zh) * | 2009-05-22 | 2012-11-14 | 河南金土地煤气工程有限公司 | 单段环保风冷式煤气生产方法 |
| KR101133543B1 (ko) | 2009-10-06 | 2012-04-05 | 한밭대학교 산학협력단 | 탄소 수증기 개질장치를 포함한 연료전지 열병합 발전 시스템 |
| CA2777060A1 (en) * | 2009-10-15 | 2011-04-21 | Pyromex Holding Ag | High-temperature furnace and method for converting organic materials to synthesis gas |
| JP5553157B2 (ja) * | 2010-07-23 | 2014-07-16 | 富士通株式会社 | 油化方法及び装置 |
| US20120204962A1 (en) * | 2011-02-11 | 2012-08-16 | Evergreen Energy Inc. | System and Method for Improved Hydrothermal Upgrading of Carbonaceous Material |
| RU2507238C2 (ru) * | 2012-05-24 | 2014-02-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский национальный исследовательский технологический университет" | Способ получения синтез-газа из древесных отходов |
| RO130112A2 (ro) * | 2013-09-23 | 2015-03-30 | Vasile Celac | Procedeu şi instalaţie pentru obţinerea gazului de sinteză |
| EP3115336B2 (de) * | 2015-07-10 | 2022-01-05 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren und anlage zur kühlung von synthesegas |
| CN112368236B (zh) * | 2018-07-06 | 2023-03-28 | 株式会社翼工程服务 | 以生物质作为原料的氢气制造方法 |
| WO2021044318A1 (es) * | 2019-09-02 | 2021-03-11 | Araya Matteo Julio Cesar | Sistema y método para la obtención de energía a través del uso de hidrocarburos de calidad reducida e hidrógeno producido a partir del agua en la generación de energía de combustión |
| GB2616488B (en) | 2022-09-02 | 2024-11-06 | Sru Innovations Ltd | Steam treatment of waste |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2226578A (en) * | 1939-06-14 | 1940-12-31 | Socony Vacuum Oil Co Inc | Kiln |
| US4597772A (en) * | 1984-09-20 | 1986-07-01 | Wright-Malta Corporation | Fixed kiln with rotor steam gasifier |
| US5645744A (en) * | 1991-04-05 | 1997-07-08 | The Boeing Company | Retort for achieving thermal uniformity in induction processing of organic matrix composites or metals |
| US5245113A (en) * | 1991-05-23 | 1993-09-14 | Dynecology, Incorporated | Decontamination of PCB contaminated solids |
| JPH08112580A (ja) * | 1994-10-14 | 1996-05-07 | Nippon Steel Corp | 複合廃棄物の連続処理方法 |
| US5879566A (en) * | 1997-02-03 | 1999-03-09 | The Scientific Ecology Group, Inc. | Integrated steam reforming operation for processing organic contaminated sludges and system |
| US6205704B1 (en) * | 1998-03-09 | 2001-03-27 | William C. Crutcher | Method and apparatus for enhancing plant growth in greenhouses utilizing landfill gas |
| NL1009038C2 (nl) * | 1998-04-29 | 1999-11-01 | Stichting Energie | Werkwijze en inrichting voor het vormen van synthesegas. |
| US6005149A (en) * | 1998-08-18 | 1999-12-21 | Engineering, Separation & Recycling, Ltd. Co. | Method and apparatus for processing organic materials to produce chemical gases and carbon char |
| JP2000296378A (ja) * | 1999-04-13 | 2000-10-24 | Mitsubishi Heavy Ind Ltd | 廃棄物の処理方法 |
| CA2274390A1 (en) * | 1999-06-10 | 2000-12-10 | Questor Industries Inc. | Multistage chemical separation method and apparatus using pressure swing adsorption |
| AU6917100A (en) * | 1999-08-19 | 2001-03-13 | Manufacturing And Technology Conversion International, Inc. | System integration of a steam reformer and fuel cell |
| TWI241392B (en) * | 1999-09-20 | 2005-10-11 | Japan Science & Tech Agency | Apparatus and method for gasifying solid or liquid fuel |
| JP2001123175A (ja) * | 1999-10-25 | 2001-05-08 | Toyoda Techno Kk | 廃棄物の処理方法 |
| JP4427173B2 (ja) * | 2000-08-16 | 2010-03-03 | 三菱重工業株式会社 | 合成ガスの製造方法 |
| DE10055360B4 (de) * | 2000-11-08 | 2004-07-29 | Mühlen, Heinz-Jürgen, Dr.rer.Nat. | Verfahren zur Vergasung von flüssigen bis pastösen organischen Stoffen und Stoffgemischen |
| US6519926B2 (en) * | 2001-05-01 | 2003-02-18 | General Atomics | Hydrothermal conversion and separation |
| JP3764659B2 (ja) * | 2001-06-20 | 2006-04-12 | 新日本製鐵株式会社 | 樹脂主体廃棄物の再資源化方法 |
| US7220502B2 (en) * | 2002-06-27 | 2007-05-22 | Intellergy Corporation | Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions |
| US7132183B2 (en) * | 2002-06-27 | 2006-11-07 | Intellergy Corporation | Process and system for converting carbonaceous feedstocks into energy without greenhouse gas emissions |
| US20060076275A1 (en) * | 2002-07-12 | 2006-04-13 | Smith Anthon L | Process for the recovery of hydrocarbon fractions from hydrocarbonaceous solids |
| JP2004075852A (ja) * | 2002-08-19 | 2004-03-11 | Nippon Steel Corp | 炭素質資源のガス化方法及びその装置 |
| JP4246456B2 (ja) * | 2002-08-27 | 2009-04-02 | 株式会社 日本計画機構 | 有機系廃棄物からの水素回収方法 |
| CA2511342C (en) | 2002-09-10 | 2012-11-06 | Manufacturing And Technology Conversion International, Inc. | Steam reforming process and apparatus |
| US20050095183A1 (en) * | 2003-11-05 | 2005-05-05 | Biomass Energy Solutions, Inc. | Process and apparatus for biomass gasification |
| BRPI0606737B1 (pt) | 2005-01-18 | 2016-04-26 | Enquest Power Corp | método para reformar material carbonáceo por vapor |
| US9225632B2 (en) * | 2005-09-16 | 2015-12-29 | Hewlett Packard Enterprise Development Lp | Globally fair polling for packet switched routers using dynamically biased arbitration |
-
2006
- 2006-01-18 BR BRPI0606737A patent/BRPI0606737B1/pt not_active IP Right Cessation
- 2006-01-18 JP JP2007550648A patent/JP5474302B2/ja not_active Expired - Fee Related
- 2006-01-18 NZ NZ556611A patent/NZ556611A/en not_active IP Right Cessation
- 2006-01-18 MX MX2007008729A patent/MX2007008729A/es active IP Right Grant
- 2006-01-18 CA CA2581288A patent/CA2581288C/en not_active Expired - Lifetime
- 2006-01-18 PL PL06704095T patent/PL1877520T3/pl unknown
- 2006-01-18 EP EP20060704095 patent/EP1877520B8/en not_active Expired - Lifetime
- 2006-01-18 ES ES06704095T patent/ES2441543T3/es not_active Expired - Lifetime
- 2006-01-18 ZA ZA200706523A patent/ZA200706523B/xx unknown
- 2006-01-18 AU AU2006207788A patent/AU2006207788A1/en not_active Abandoned
- 2006-01-18 RU RU2007130998A patent/RU2424277C2/ru active
- 2006-01-18 CN CN200680002624.0A patent/CN101120076B/zh not_active Expired - Fee Related
- 2006-01-18 KR KR1020137020091A patent/KR20130102646A/ko not_active Withdrawn
- 2006-01-18 WO PCT/CA2006/000060 patent/WO2006076801A1/en not_active Ceased
- 2006-01-18 US US11/718,597 patent/US7794689B2/en active Active - Reinstated
-
2007
- 2007-08-17 KR KR1020077018874A patent/KR101343979B1/ko not_active Expired - Fee Related
-
2010
- 2010-09-13 US US12/881,057 patent/US9139787B2/en not_active Expired - Lifetime
-
2013
- 2013-08-16 JP JP2013169236A patent/JP2013253252A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| RU2007130998A (ru) | 2009-02-27 |
| US9139787B2 (en) | 2015-09-22 |
| ZA200706523B (en) | 2009-02-25 |
| KR20070110497A (ko) | 2007-11-19 |
| KR101343979B1 (ko) | 2013-12-24 |
| RU2424277C2 (ru) | 2011-07-20 |
| US20080112882A1 (en) | 2008-05-15 |
| CA2581288C (en) | 2018-02-20 |
| CN101120076B (zh) | 2014-09-10 |
| EP1877520A4 (en) | 2011-01-19 |
| US20110204294A1 (en) | 2011-08-25 |
| EP1877520A1 (en) | 2008-01-16 |
| EP1877520B1 (en) | 2013-10-09 |
| JP2008528708A (ja) | 2008-07-31 |
| AU2006207788A1 (en) | 2006-07-27 |
| EP1877520B8 (en) | 2013-11-13 |
| JP5474302B2 (ja) | 2014-04-16 |
| JP2013253252A (ja) | 2013-12-19 |
| BRPI0606737B1 (pt) | 2016-04-26 |
| KR20130102646A (ko) | 2013-09-17 |
| PL1877520T3 (pl) | 2014-04-30 |
| CA2581288A1 (en) | 2006-07-27 |
| ES2441543T3 (es) | 2014-02-05 |
| NZ556611A (en) | 2011-01-28 |
| US7794689B2 (en) | 2010-09-14 |
| WO2006076801A1 (en) | 2006-07-27 |
| BRPI0606737A2 (pt) | 2009-07-14 |
| CN101120076A (zh) | 2008-02-06 |
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