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BRPI0408549A - catalisadores e processos de polimerização e de oligomerização - Google Patents

catalisadores e processos de polimerização e de oligomerização

Info

Publication number
BRPI0408549A
BRPI0408549A BRPI0408549-3A BRPI0408549A BRPI0408549A BR PI0408549 A BRPI0408549 A BR PI0408549A BR PI0408549 A BRPI0408549 A BR PI0408549A BR PI0408549 A BRPI0408549 A BR PI0408549A
Authority
BR
Brazil
Prior art keywords
polymerization
groups
group
nitrogen
catalysts
Prior art date
Application number
BRPI0408549-3A
Other languages
English (en)
Inventor
Vernon Charles Gibson
Atanas Kostadinov Tomov
Original Assignee
Innovene Europ Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Innovene Europ Ltd filed Critical Innovene Europ Ltd
Publication of BRPI0408549A publication Critical patent/BRPI0408549A/pt
Publication of BRPI0408549B1 publication Critical patent/BRPI0408549B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/02—Carriers therefor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/70—Iron group metals, platinum group metals or compounds thereof
    • C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
    • C08F4/7003—Bidentate ligand
    • C08F4/7004—Neutral ligand
    • C08F4/7006—NN
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

"CATALISADORES E PROCESSOS DE POLIMERIZAçãO E DE OLIGOMERIZAçãO". é proposto um catalisador de polimerização compreendendo (1) um composto de metal de transição da Fórmula A e opcionalmente (2) uma quantidade ativadora de um ativador de ácido de Lewis, Fórmula (A), em que Z é um grupo heterocíclico de cinco membros contendo pelo menos um átomo de carbono, pelo menos um átomo de nitrogênio e pelo menos um outro heteroátomo selecionado dentre nitrogênio, enxofre e oxigênio e os átomos restantes no anel sendo nitrogênio ou carbono; M é um metal do Grupo 3 a 11 da Tabela Periódica ou um metal lantanídeo; E¬ 1¬ e E¬ 2¬ são grupos bivalentes dentre (i) hidrocarboneto alifático, (ii) hidrocarboneto alicíclico, (iii) hidrocarboneto aromático, (iv) hidrocarboneto aromático substituído com alquila, (v) grupos heterocíclicos e (vi) derivados hetero-substituídos dos grupos (i) a (v) ; D¬ 1¬ e D¬ 2¬ São grupos doadores, X é um grupo aniónico, L é um grupo doador neutro; n = m = zero ou 1; y e z são zero ou números inteiros. Os catalisadores são úteis para a polimerização ou oligopolimerização de 1-olefinas.
BRPI0408549A 2003-03-20 2004-03-18 catalisadores e processos de polimerização e de oligomerização BRPI0408549B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0306430.0A GB0306430D0 (en) 2003-03-20 2003-03-20 Polymerisation and oligomerisation catalysts
PCT/GB2004/001184 WO2004083263A1 (en) 2003-03-20 2004-03-18 Polymerisation and oligomerisation catalysts

Publications (2)

Publication Number Publication Date
BRPI0408549A true BRPI0408549A (pt) 2006-03-07
BRPI0408549B1 BRPI0408549B1 (pt) 2020-01-21

Family

ID=9955183

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0408549A BRPI0408549B1 (pt) 2003-03-20 2004-03-18 catalisadores e processos de polimerização e de oligomerização

Country Status (15)

Country Link
US (1) US7229943B2 (pt)
EP (1) EP1603957B1 (pt)
JP (1) JP5401011B2 (pt)
KR (1) KR101273309B1 (pt)
CN (1) CN100491417C (pt)
AR (1) AR043667A1 (pt)
AU (1) AU2004222079B2 (pt)
BR (1) BRPI0408549B1 (pt)
CA (1) CA2519854C (pt)
GB (1) GB0306430D0 (pt)
MX (1) MXPA05009958A (pt)
RU (1) RU2343162C2 (pt)
TW (1) TWI359697B (pt)
WO (1) WO2004083263A1 (pt)
ZA (1) ZA200506886B (pt)

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TW201245157A (en) * 2011-03-15 2012-11-16 Sumitomo Chemical Co Metal complex and organic electronic device comprising same
WO2013036548A2 (en) 2011-09-07 2013-03-14 Dow Corning Corporation Zirconium containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
EP2753655B1 (en) 2011-09-07 2019-12-04 Dow Silicones Corporation Titanium containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
FR2979836B1 (fr) * 2011-09-08 2014-08-08 IFP Energies Nouvelles Nouvelle composition catalytique a base de nickel et procede d'oligomerisation des olefines utilisant ladite composition
WO2013043787A2 (en) 2011-09-20 2013-03-28 Dow Corning Corporation Ruthenium containing hydrosilylation catalysts and compositions containing the catalysts
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JP6117210B2 (ja) 2011-09-20 2017-04-19 ダウ コーニング コーポレーションＤｏｗ Ｃｏｒｎｉｎｇ Ｃｏｒｐｏｒａｔｉｏｎ イリジウムを含有するヒドロシリル化触媒及びその触媒を含有する組成物
WO2013052585A2 (en) 2011-10-04 2013-04-11 Dow Corning Corporation Iron(iii) containing complex and condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
US9139699B2 (en) 2012-10-04 2015-09-22 Dow Corning Corporation Metal containing condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts
EP2785454B1 (en) 2011-12-01 2019-10-09 Dow Silicones Corporation Hydrosilylation reaction catalysts and curable compositions and methods for their preparation and use
US10035127B2 (en) 2013-11-04 2018-07-31 The Regents Of The University Of California Metal-organic frameworks with a high density of highly charged exposed metal cation sites
CN106029674B (zh) 2014-02-19 2020-02-14 加利福尼亚大学董事会 耐酸性、耐溶剂性、以及耐热性金属有机骨架
KR20160134644A (ko) 2014-03-18 2016-11-23 더 리젠츠 오브 더 유니버시티 오브 캘리포니아 미세다공성 금속 유기 구조체의 정렬된 초격자로 구성된 메조스코픽 물질
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Also Published As

Publication number Publication date
GB0306430D0 (en) 2003-04-23
RU2343162C2 (ru) 2009-01-10
AR043667A1 (es) 2005-08-03
JP5401011B2 (ja) 2014-01-29
CA2519854C (en) 2011-11-22
RU2005132270A (ru) 2006-08-10
MXPA05009958A (es) 2006-03-09
EP1603957B1 (en) 2015-10-28
AU2004222079B2 (en) 2008-01-31
BRPI0408549B1 (pt) 2020-01-21
JP2006520834A (ja) 2006-09-14
EP1603957A1 (en) 2005-12-14
AU2004222079A1 (en) 2004-09-30
WO2004083263A1 (en) 2004-09-30
ZA200506886B (en) 2006-05-31
CN1761688A (zh) 2006-04-19
TW200427511A (en) 2004-12-16
US7229943B2 (en) 2007-06-12
TWI359697B (en) 2012-03-11
KR101273309B1 (ko) 2013-06-11
CA2519854A1 (en) 2004-09-30
KR20050118196A (ko) 2005-12-15
CN100491417C (zh) 2009-05-27
US20060094588A1 (en) 2006-05-04

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B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 21A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2822 DE 04-02-2025 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.