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BR9916437A - Processo de hidrocianação de compostos orgânicos - Google Patents

Processo de hidrocianação de compostos orgânicos

Info

Publication number
BR9916437A
BR9916437A BR9916437-0A BR9916437A BR9916437A BR 9916437 A BR9916437 A BR 9916437A BR 9916437 A BR9916437 A BR 9916437A BR 9916437 A BR9916437 A BR 9916437A
Authority
BR
Brazil
Prior art keywords
organic compounds
phase
solid phase
aqueous phase
ethylenically unsaturated
Prior art date
Application number
BR9916437-0A
Other languages
English (en)
Inventor
Paolo Burattin
Pierre Coqueret
Marc Huser
Original Assignee
Rhodia Polyamide Intermediates
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Polyamide Intermediates filed Critical Rhodia Polyamide Intermediates
Publication of BR9916437A publication Critical patent/BR9916437A/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/30—Preparation of carboxylic acid nitriles by reactions not involving the formation of cyano groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
    • B01J2231/342—Aldol type reactions, i.e. nucleophilic addition of C-H acidic compounds, their R3Si- or metal complex analogues, to aldehydes or ketones
    • B01J2231/343—Aldol type reactions, i.e. nucleophilic addition of C-H acidic compounds, their R3Si- or metal complex analogues, to aldehydes or ketones to prepare cyanhydrines, e.g. by adding HCN or TMSCN
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/52—Isomerisation reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96—Water
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

"PROCESSO DE HIDROCIANAçãO DE COMPOSTOS ORGâNICOS" A presente invenção refere-se a um processo de hidrocianação de compostos orgânicos com instaurações etilênicas para notadamente a obtenção de nitrilas e, mais particularmente, a hidrocianação de diolefinas ou olefinas substituídas para a fabricação de dinitrilas, e/ou a isomerização de nitrilas obtidas por hidrocianação. Ela se refere mais particularmente a uma hidrocianação catalisada por um composto a base de níquel. Assim, o catalisador usado neste processo de fabricação é tratado na saída da reação por cianeto de hidrogênio para recuperar e redissolver o níquel precipitado sob a forma de hidróxido de níquel. O processo permite regenerar o catalisador e aumentar a duração de vida de uma carga de catalisador. Por outro lado, ela permite diminuir a poluição das instalações do processo.
BR9916437-0A 1998-12-22 1999-12-21 Processo de hidrocianação de compostos orgânicos BR9916437A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9816468A FR2787446B1 (fr) 1998-12-22 1998-12-22 Procede d'hydrocyanation de composes organiques a insaturations ethyleniques
PCT/FR1999/003231 WO2000037431A1 (fr) 1998-12-22 1999-12-21 Procede d'hydrocyanation de composes organiques a insaturations ethyleniques

Publications (1)

Publication Number Publication Date
BR9916437A true BR9916437A (pt) 2001-09-04

Family

ID=9534529

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9916437-0A BR9916437A (pt) 1998-12-22 1999-12-21 Processo de hidrocianação de compostos orgânicos

Country Status (17)

Country Link
US (1) US6469194B2 (pt)
EP (1) EP1140801B1 (pt)
JP (1) JP4060532B2 (pt)
KR (1) KR20010089687A (pt)
CN (1) CN1173935C (pt)
AT (1) ATE289585T1 (pt)
BR (1) BR9916437A (pt)
CA (1) CA2356381A1 (pt)
CZ (1) CZ20012249A3 (pt)
DE (1) DE69923867D1 (pt)
FR (1) FR2787446B1 (pt)
MX (1) MXPA01006383A (pt)
PL (1) PL348298A1 (pt)
SK (1) SK9102001A3 (pt)
TW (1) TW453985B (pt)
WO (1) WO2000037431A1 (pt)
ZA (1) ZA200105887B (pt)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2819250B1 (fr) * 2001-01-05 2004-12-03 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
FR2829763B1 (fr) * 2001-09-18 2004-12-03 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles
MY134370A (en) * 2002-07-10 2007-12-31 Basf Ag Recycling of a lewis acid
FR2842196B1 (fr) * 2002-07-15 2006-01-13 Rhodia Polyamide Intermediates Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
FR2849027B1 (fr) * 2002-12-23 2005-01-21 Rhodia Polyamide Intermediates Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques
FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
US7973174B2 (en) 2005-10-18 2011-07-05 Invista North America S.A.R.L. Process of making 3-aminopentanenitrile
MX2008011640A (es) 2006-03-17 2008-09-22 Invista Tech Sarl Metodo para la purificacion de triorganofosfitos por tratamiento con un aditivo basico.
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US7880028B2 (en) 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
EP2146930A2 (en) 2007-05-14 2010-01-27 INVISTA Technologies S.à.r.l. High efficiency reactor and process
WO2008157218A1 (en) 2007-06-13 2008-12-24 Invista Technologies S.A.R.L. Process for improving adiponitrile quality
WO2009091790A1 (en) 2008-01-15 2009-07-23 Invista Technologies S.A.R.L. Hydrocyanation of pentenenitriles
CN101910119B (zh) 2008-01-15 2013-05-29 因温斯特技术公司 用于制备和精制3-戊烯腈，和用于精制2-甲基-3-丁烯腈的方法
FR2932476B1 (fr) * 2008-06-17 2010-07-30 Rhodia Operations Procede de fabrication de composes nitriles a partir de composes a insaturation ethylenique
US8247621B2 (en) 2008-10-14 2012-08-21 Invista North America S.A.R.L. Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols
JP5615920B2 (ja) 2009-08-07 2014-10-29 インヴィスタ テクノロジーズ エスアエルエル ジエステルを形成するための水素化およびエステル化
HK1199630A1 (en) 2011-12-21 2015-07-10 因温斯特技术公司 Extraction solvent control for reducing stable emulsions
WO2013095851A1 (en) 2011-12-21 2013-06-27 Invista North America S.A R.L. Extraction solvent control for reducing stable emulsions
JP2015505304A (ja) 2011-12-21 2015-02-19 インヴィスタ テクノロジーズ エスアエルエル 安定なエマルジョンを減じるための抽出溶媒制御
CN103804227B (zh) * 2014-02-17 2016-02-10 重庆中平紫光科技发展有限公司 一种烯腈混合液直接异构化合成2-甲基-2-丁烯腈的方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1621910A1 (de) 1967-09-06 1971-06-24 Bayer Ag Verfahren zum Beschichten mit Polyurethanen
FR2338253A1 (fr) 1976-01-13 1977-08-12 Rhone Poulenc Ind Procede d'hydrocyanation de composes organiques insatures comportant au moins une double liaison ethylenique
US4082811A (en) 1977-02-23 1978-04-04 E. I. Du Pont De Nemours And Company Recovery of metal and triarylborane catalyst components from olefin hydrocyanation residue
US4539302A (en) * 1984-04-30 1985-09-03 E. I. Du Pont De Nemours And Company Recovery of zerovalent nickel complexes
US4990645A (en) * 1990-06-27 1991-02-05 E. I. Du Pont De Nemours And Company Hydrocyanation process
FR2711987B1 (fr) * 1993-11-03 1995-12-15 Rhone Poulenc Chimie Procédé d'hydrocyanation de nitriles insaturés en dinitriles.
FR2727637B1 (fr) 1994-12-06 1997-01-03 Rhone Poulenc Chimie Procede de preparation electrochimique de catalyseurs a base de metal de transition et de phosphine
FR2739378B1 (fr) * 1995-09-29 1997-10-31 Rhone Poulenc Fibres Procede d'hydrocyanation de composes organiques a insaturation ethylenique
FR2743011B1 (fr) 1995-12-29 1998-02-20 Rhone Poulenc Fibres Procede de preparation electrochimique de catalyseurs a base de metal de transition et de phosphine

Also Published As

Publication number Publication date
US20020022736A1 (en) 2002-02-21
WO2000037431A1 (fr) 2000-06-29
JP2002533321A (ja) 2002-10-08
PL348298A1 (en) 2002-05-20
KR20010089687A (ko) 2001-10-08
TW453985B (en) 2001-09-11
EP1140801B1 (fr) 2005-02-23
US6469194B2 (en) 2002-10-22
ATE289585T1 (de) 2005-03-15
DE69923867D1 (de) 2005-03-31
ZA200105887B (en) 2002-10-17
MXPA01006383A (es) 2002-06-04
CN1173935C (zh) 2004-11-03
SK9102001A3 (en) 2001-12-03
JP4060532B2 (ja) 2008-03-12
FR2787446A1 (fr) 2000-06-23
CN1333745A (zh) 2002-01-30
CA2356381A1 (fr) 2000-06-29
EP1140801A1 (fr) 2001-10-10
CZ20012249A3 (cs) 2001-11-14
FR2787446B1 (fr) 2001-02-02

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Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 6O E 7O ANUIDADES.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1913 DE 04/09/2007.