AR030950A1 - Procedimiento para la regeneracion de catalizadores - Google Patents
Procedimiento para la regeneracion de catalizadoresInfo
- Publication number
- AR030950A1 AR030950A1 ARP010104504A ARP010104504A AR030950A1 AR 030950 A1 AR030950 A1 AR 030950A1 AR P010104504 A ARP010104504 A AR P010104504A AR P010104504 A ARP010104504 A AR P010104504A AR 030950 A1 AR030950 A1 AR 030950A1
- Authority
- AR
- Argentina
- Prior art keywords
- hydrogen
- compound
- heterogeneous catalyst
- adipodinitrile
- regeneration
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 230000008929 regeneration Effects 0.000 title abstract 3
- 238000011069 regeneration method Methods 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 6
- 239000001257 hydrogen Substances 0.000 abstract 5
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- 239000002638 heterogeneous catalyst Substances 0.000 abstract 4
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 abstract 4
- 150000002431 hydrogen Chemical class 0.000 abstract 4
- BTGRAWJCKBQKAO-UHFFFAOYSA-N adiponitrile Chemical compound N#CCCCCC#N BTGRAWJCKBQKAO-UHFFFAOYSA-N 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 238000005984 hydrogenation reaction Methods 0.000 abstract 2
- KBMSFJFLSXLIDJ-UHFFFAOYSA-N 6-aminohexanenitrile Chemical compound NCCCCCC#N KBMSFJFLSXLIDJ-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J38/00—Regeneration or reactivation of catalysts, in general
- B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
- B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
- B01J38/52—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids oxygen-containing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/90—Regeneration or reactivation
- B01J23/94—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/44—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers
- C07C209/48—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of carboxylic acids or esters thereof in presence of ammonia or amines, or by reduction of nitriles, carboxylic acid amides, imines or imino-ethers by reduction of nitriles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Procedimiento para la regeneracion de un catalizador heterogéneo usado para la obtencion de compuestos conteniendo grupos NH2 por hidrogenacion de compuestos que contienen por lo menos un enlace de carbono-nitrogeno no saturado, con hidrogeno, procedimiento que comprende las etapas: a) se interrumpe la alimentacion del compuesto a hidrogenar, y b) se trata el catalizador heterogéneo con un compuesto de la formula (1): R1R2N-CO-R3, en donde R1: significa hidrogeno, alquilo C1-4; R2, R3 significan, independientemente, hidrogeno, alquilo C1-4, o representan juntos un grupo alquileno C3-6, o sus mezclas a una presion en la region de 0,1 a 30 MPa y una temperatura en la region de 100 a 300 degree C, siendo preciso, que el compuesto de la formula 1 esté presente en forma líquida en el tratamiento. En dicho procedimiento se puede regenerar un catalizador heterogéneo usado para la hidrogenacion de adipodinitrilo, o adipodinitrilo en hexametilendiamina, o bien adipodinitrilo en una mezcla que contiene hexametilendiamina y 6-aminocapronitrilo. El catalizador heterogéneo puede contener como componente catalíticamente activo un compuesto de un elemento seleccionado del grupo que abarca hierro, cobalto y níquel o sus mezclas. La regeneracion puede realizarse en presencia de hidrogeno, o bien en la etapa a) se interrumpe la alimentacion del hidrogeno.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10047703A DE10047703A1 (de) | 2000-09-25 | 2000-09-25 | Verfahren zur Regenerierung von Katalysatoren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR030950A1 true AR030950A1 (es) | 2003-09-03 |
Family
ID=7657711
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP010104504A AR030950A1 (es) | 2000-09-25 | 2001-09-25 | Procedimiento para la regeneracion de catalizadores |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US6905997B2 (es) |
| EP (1) | EP1322420B1 (es) |
| JP (1) | JP2004508928A (es) |
| KR (1) | KR20030034205A (es) |
| CN (1) | CN1181923C (es) |
| AR (1) | AR030950A1 (es) |
| AT (1) | ATE391554T1 (es) |
| AU (1) | AU2002210509A1 (es) |
| BR (1) | BR0114081A (es) |
| CA (1) | CA2422937A1 (es) |
| DE (2) | DE10047703A1 (es) |
| MX (1) | MXPA03001669A (es) |
| TW (1) | TW592825B (es) |
| WO (1) | WO2002024334A1 (es) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004003239A1 (de) * | 2004-01-21 | 2005-08-18 | Basf Ag | Verfahren zur Regenerierung eines Festbettkatalysators |
| DE102005061873A1 (de) * | 2005-12-23 | 2007-07-05 | Robert Bosch Gmbh | Verfahren und Steuergerät zum Betreiben eines integrierten SCR/DPF-Systems |
| FR2902425B1 (fr) * | 2006-06-20 | 2008-07-18 | Rhodia Recherches & Tech | Procede de fabrication de diamines primaires |
| JP5531961B2 (ja) | 2008-09-08 | 2014-06-25 | 三菱瓦斯化学株式会社 | キシリレンジアミンの製造方法 |
| EP2874743A1 (en) | 2012-07-19 | 2015-05-27 | Invista Technologies S.à.r.l. | Regeneration of a hydrogenation catalyst |
| WO2015038678A1 (en) * | 2013-09-13 | 2015-03-19 | Invista Technologies S.À R.L. | Hydrogenation of dinitriles for the preparation of diamines |
| WO2015038673A1 (en) * | 2013-09-13 | 2015-03-19 | Invista Technologies S.À R.L. | Hydrogenation of dinitriles for the preparation of diamines |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4322315A (en) * | 1980-04-25 | 1982-03-30 | Phillips Petroleum Company | Regeneration of a ruthenium containing hydrogenation catalyst |
| US5230791A (en) * | 1991-07-03 | 1993-07-27 | Texaco Inc. | Process for the reactivation of spent alumina-supported hydrotreating catalysts |
| FI94515B (fi) * | 1994-03-04 | 1995-06-15 | Finnish Chemicals Oy | Menetelmä hydrauskatalyytin reaktivoimiseksi |
| ZA954204B (en) * | 1994-06-01 | 1996-01-22 | Ashland Chemical Inc | A process for improving the effectiveness of a process catalyst |
| DE19614283A1 (de) | 1996-04-11 | 1997-10-16 | Basf Ag | Verfahren zur Herstellung von Aminen und Aminonitrilen |
| DE19630788C1 (de) | 1996-07-31 | 1997-09-11 | Basf Ag | Verfahren zur Herstellung von NH¶2¶-Gruppen enthaltenden Verbindungen |
| US6080883A (en) | 1997-04-04 | 2000-06-27 | Basf Aktiengesellschaft | Method of simultaneously producing 6-aminocapronitrile and hexamethylenediamine |
| FR2773086B1 (fr) * | 1997-12-29 | 2000-02-11 | Rhone Poulenc Fibres | Procede de regeneration d'un catalyseur d'hydrogenation procede d'hydrogenation de composes comprenant des fonctions nitriles |
| DE19809688A1 (de) | 1998-03-06 | 1999-09-09 | Basf Ag | Verfahren zur Herstellung von aliphatischen alpha-, omega-Diaminen |
-
2000
- 2000-09-25 DE DE10047703A patent/DE10047703A1/de not_active Withdrawn
-
2001
- 2001-09-20 MX MXPA03001669A patent/MXPA03001669A/es not_active Application Discontinuation
- 2001-09-20 JP JP2002528394A patent/JP2004508928A/ja not_active Withdrawn
- 2001-09-20 DE DE50113838T patent/DE50113838D1/de not_active Expired - Lifetime
- 2001-09-20 KR KR10-2003-7004216A patent/KR20030034205A/ko not_active Ceased
- 2001-09-20 AT AT01978378T patent/ATE391554T1/de not_active IP Right Cessation
- 2001-09-20 BR BR0114081-7A patent/BR0114081A/pt not_active IP Right Cessation
- 2001-09-20 CN CNB018163122A patent/CN1181923C/zh not_active Expired - Fee Related
- 2001-09-20 EP EP01978378A patent/EP1322420B1/de not_active Expired - Lifetime
- 2001-09-20 CA CA002422937A patent/CA2422937A1/en not_active Abandoned
- 2001-09-20 WO PCT/EP2001/010849 patent/WO2002024334A1/de not_active Ceased
- 2001-09-20 US US10/380,550 patent/US6905997B2/en not_active Expired - Fee Related
- 2001-09-20 AU AU2002210509A patent/AU2002210509A1/en not_active Abandoned
- 2001-09-25 AR ARP010104504A patent/AR030950A1/es active IP Right Grant
- 2001-09-25 TW TW090123602A patent/TW592825B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2422937A1 (en) | 2003-03-21 |
| JP2004508928A (ja) | 2004-03-25 |
| EP1322420B1 (de) | 2008-04-09 |
| CN1466490A (zh) | 2004-01-07 |
| DE50113838D1 (de) | 2008-05-21 |
| MXPA03001669A (es) | 2003-06-04 |
| ATE391554T1 (de) | 2008-04-15 |
| WO2002024334A1 (de) | 2002-03-28 |
| TW592825B (en) | 2004-06-21 |
| EP1322420A1 (de) | 2003-07-02 |
| US20030181313A1 (en) | 2003-09-25 |
| BR0114081A (pt) | 2003-07-29 |
| AU2002210509A1 (en) | 2002-04-02 |
| DE10047703A1 (de) | 2002-04-11 |
| US6905997B2 (en) | 2005-06-14 |
| KR20030034205A (ko) | 2003-05-01 |
| CN1181923C (zh) | 2004-12-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration |