[go: up one dir, main page]

BR9810668A - Processos para formação de moldes e materiais sensìveis a radiação - Google Patents

Processos para formação de moldes e materiais sensìveis a radiação

Info

Publication number
BR9810668A
BR9810668A BR9810668-6A BR9810668A BR9810668A BR 9810668 A BR9810668 A BR 9810668A BR 9810668 A BR9810668 A BR 9810668A BR 9810668 A BR9810668 A BR 9810668A
Authority
BR
Brazil
Prior art keywords
heat
coating
diazide
developer
moieties
Prior art date
Application number
BR9810668-6A
Other languages
English (en)
Inventor
Christopher David Mccullough
Kevin Barry Ray
Alan Stanley Victor Monk
Stuart Bayes
Mark John Spowage
Original Assignee
Kodak Polychrome Graphics Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27268918&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR9810668(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from GBGB9714172.5A external-priority patent/GB9714172D0/en
Priority claimed from GBGB9714169.1A external-priority patent/GB9714169D0/en
Priority claimed from GBGB9809346.1A external-priority patent/GB9809346D0/en
Application filed by Kodak Polychrome Graphics Co filed Critical Kodak Polychrome Graphics Co
Publication of BR9810668A publication Critical patent/BR9810668A/pt

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/20Exposure; Apparatus therefor
    • G03F7/2022Multi-step exposure, e.g. hybrid; backside exposure; blanket exposure, e.g. for image reversal; edge exposure, e.g. for edge bead removal; corrective exposure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C1/00Forme preparation
    • B41C1/10Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme
    • B41C1/1008Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by removal or destruction of lithographic material on the lithographic support, e.g. by laser or spark ablation; by the use of materials rendered soluble or insoluble by heat exposure, e.g. by heat produced from a light to heat transforming system; by on-the-press exposure or on-the-press development, e.g. by the fountain of photolithographic materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/36Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using a polymeric layer, which may be particulate and which is deformed or structurally changed with modification of its' properties, e.g. of its' optical hydrophobic-hydrophilic, solubility or permeability properties
    • B41M5/368Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used using a polymeric layer, which may be particulate and which is deformed or structurally changed with modification of its' properties, e.g. of its' optical hydrophobic-hydrophilic, solubility or permeability properties involving the creation of a soluble/insoluble or hydrophilic/hydrophobic permeability pattern; Peel development
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/022Quinonediazides
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/022Quinonediazides
    • G03F7/023Macromolecular quinonediazides; Macromolecular additives, e.g. binders
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004Photosensitive materials
    • G03F7/022Quinonediazides
    • G03F7/023Macromolecular quinonediazides; Macromolecular additives, e.g. binders
    • G03F7/0233Macromolecular quinonediazides; Macromolecular additives, e.g. binders characterised by the polymeric binders or the macromolecular additives other than the macromolecular quinonediazides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C2210/00Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
    • B41C2210/02Positive working, i.e. the exposed (imaged) areas are removed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C2210/00Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
    • B41C2210/06Developable by an alkaline solution
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C2210/00Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
    • B41C2210/14Multiple imaging layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C2210/00Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
    • B41C2210/22Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation characterised by organic non-macromolecular additives, e.g. dyes, UV-absorbers, plasticisers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41CPROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C2210/00Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation
    • B41C2210/26Preparation or type or constituents of the imaging layers, in relation to lithographic printing forme preparation characterised by a macromolecular compound or binder obtained by reactions not involving carbon-to-carbon unsaturated bonds
    • B41C2210/262Phenolic condensation polymers, e.g. novolacs, resols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/46Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography characterised by the light-to-heat converting means; characterised by the heat or radiation filtering or absorbing means or layers
    • B41M5/465Infrared radiation-absorbing materials, e.g. dyes, metals, silicates, C black
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/0073Masks not provided for in groups H05K3/02 - H05K3/46, e.g. for photomechanical production of patterned surfaces
    • H05K3/0082Masks not provided for in groups H05K3/02 - H05K3/46, e.g. for photomechanical production of patterned surfaces characterised by the exposure method of radiation-sensitive masks

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Optics & Photonics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Photosensitive Polymer And Photoresist Processing (AREA)
  • Materials For Photolithography (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Ultra Sonic Daignosis Equipment (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Image Processing (AREA)
  • Vehicle Body Suspensions (AREA)
  • Holo Graphy (AREA)
  • Camera Bodies And Camera Details Or Accessories (AREA)
  • Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
  • Encapsulation Of And Coatings For Semiconductor Or Solid State Devices (AREA)

Abstract

"PROCESSOS PARA FORMAçãO DE MOLDES E MATERIAIS SENSìVEIS A RADIAçãO" Processo para produção de um molde resistente pre-determinado, sobre, por exemplo, um clichê litográfico, painel de circuito ou máscara, compreende a exposição da reprodução de um revestimento positivo de trabalho sensível a radiação empregando uma radiação apropriada, tal como, radiação de calor direto, radiação ultravioleta, radiação visível, radiação infravermelha ou radiação por feixe de elétrons. O processo é caracterizado pelo uso de um novo material polimérico que é funcionalizado por grupos Q para tornar o mesmo insolúvel em um revelador, porém, tal que, a exposição a radiação torna o mesmo solúvel. Os grupos Q não são grupos diazido como é convencional, porém são grupos que não liberam nitrogênio, quando expostos a radiação e possuem capacidade de ligação de hidrogênio. Exemplos de grupos Q são 2-naftilssulfonilóxi, 2-tienilssulfonilóxi, dansilóxi, p-toluenossulfonilóxi, benzilóxi e n-butilssulfonilóxi.
BR9810668-6A 1997-07-05 1998-07-02 Processos para formação de moldes e materiais sensìveis a radiação BR9810668A (pt)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GBGB9714172.5A GB9714172D0 (en) 1997-07-05 1997-07-05 Improvements in relation to pattern-forming methods
GBGB9714169.1A GB9714169D0 (en) 1997-07-05 1997-07-05 Improvements in relation to pattern-forming methods and radiation sensitive ma erials
GBGB9809346.1A GB9809346D0 (en) 1998-05-01 1998-05-01 Improvements in relation to pattern-forming methods and radiation sensitive materials
PCT/GB1998/001953 WO1999001795A2 (en) 1997-07-05 1998-07-02 Pattern-forming methods and radiation sensitive materials

Publications (1)

Publication Number Publication Date
BR9810668A true BR9810668A (pt) 2001-09-04

Family

ID=27268918

Family Applications (2)

Application Number Title Priority Date Filing Date
BR9810668-6A BR9810668A (pt) 1997-07-05 1998-07-02 Processos para formação de moldes e materiais sensìveis a radiação
BR9810545-0A BR9810545A (pt) 1997-07-05 1998-07-02 Métodos para a formação de configuração

Family Applications After (1)

Application Number Title Priority Date Filing Date
BR9810545-0A BR9810545A (pt) 1997-07-05 1998-07-02 Métodos para a formação de configuração

Country Status (8)

Country Link
US (2) US6218083B1 (pt)
EP (3) EP0953166B1 (pt)
JP (2) JP2002510404A (pt)
AT (1) ATE204388T1 (pt)
AU (1) AU8229498A (pt)
BR (2) BR9810668A (pt)
DE (1) DE69801363T2 (pt)
WO (2) WO1999001796A2 (pt)

Families Citing this family (89)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR9810668A (pt) * 1997-07-05 2001-09-04 Kodak Polychrome Graphics Co Processos para formação de moldes e materiais sensìveis a radiação
GB9806478D0 (en) * 1998-03-27 1998-05-27 Horsell Graphic Ind Ltd Pattern formation
IT1299220B1 (it) 1998-05-12 2000-02-29 Lastra Spa Composizione sensibile sia a radiazioni ir che a radiazioni uv e lastra litografica
US6534238B1 (en) 1998-06-23 2003-03-18 Kodak Polychrome Graphics, Llc Thermal digital lithographic printing plate
US6643001B1 (en) * 1998-11-20 2003-11-04 Revco, Inc. Patterned platelets
JP4417528B2 (ja) * 1999-05-24 2010-02-17 コダックグラフィックコミュニケーションズ株式会社 ポジ型感光性組成物及びポジ型感光性平版印刷版
US6255033B1 (en) 1999-07-30 2001-07-03 Creo, Ltd. Positive acting photoresist compositions and imageable element
US6251559B1 (en) 1999-08-03 2001-06-26 Kodak Polychrome Graphics Llc Heat treatment method for obtaining imagable coatings and imagable coatings
US6706466B1 (en) 1999-08-03 2004-03-16 Kodak Polychrome Graphics Llc Articles having imagable coatings
US6461794B1 (en) 1999-08-11 2002-10-08 Kodak Polychrome Graphics Llc Lithographic printing forms
US6232031B1 (en) 1999-11-08 2001-05-15 Ano-Coil Corporation Positive-working, infrared-sensitive lithographic printing plate and method of imaging
US6391524B2 (en) 1999-11-19 2002-05-21 Kodak Polychrome Graphics Llc Article having imagable coatings
US6296982B1 (en) 1999-11-19 2001-10-02 Kodak Polychrome Graphics Llc Imaging articles
US6300038B1 (en) 1999-11-19 2001-10-09 Kodak Polychrome Graphics Llc Articles having imagable coatings
US6534241B2 (en) 2000-01-12 2003-03-18 Howard A. Fromson Method of actinically imaging a semiconductor
US6355398B1 (en) * 2000-01-12 2002-03-12 Howard A. Fromson Method of actinically imaging
US20020081517A1 (en) * 2000-12-22 2002-06-27 Howard A. Fromson Actinically imageable and infrared heated printing plate
JP4753454B2 (ja) * 2000-05-11 2011-08-24 独立行政法人理化学研究所 光熱硬化性樹脂組成物
US6506533B1 (en) * 2000-06-07 2003-01-14 Kodak Polychrome Graphics Llc Polymers and their use in imagable products and image-forming methods
AU2001281317A1 (en) 2000-08-04 2002-02-18 Kodak Polychrome Graphics Co. Ltd. Lithographic printing form and method of preparation and use thereof
US6511790B2 (en) * 2000-08-25 2003-01-28 Fuji Photo Film Co., Ltd. Alkaline liquid developer for lithographic printing plate and method for preparing lithographic printing plate
US6558872B1 (en) 2000-09-09 2003-05-06 Kodak Polychrome Graphics Llc Relation to the manufacture of masks and electronic parts
WO2002034517A1 (en) 2000-10-26 2002-05-02 Kodak Polychrome Graphics Company, Ltd. Compositions comprising a pigment
US6506536B2 (en) * 2000-12-29 2003-01-14 Kodak Polychrome Graphics, Llc Imageable element and composition comprising thermally reversible polymers
JP4177106B2 (ja) * 2000-12-29 2008-11-05 イーストマン コダック カンパニー 熱可逆性ポリマーを含む2層式の画像形成可能なエレメント
US6777164B2 (en) 2001-04-06 2004-08-17 Kodak Polychrome Graphics Llc Lithographic printing forms
US6410208B1 (en) * 2001-04-18 2002-06-25 Gary Ganghui Teng Lithographic printing plates having a thermo-deactivatable photosensitive layer
US6677106B2 (en) * 2002-01-03 2004-01-13 Kodak Polychrome Graphics Llc Method and equipment for using photo- or thermally imagable, negatively working patterning compositions
US6599676B2 (en) * 2002-01-03 2003-07-29 Kodak Polychrome Graphics Llc Process for making thermal negative printing plate
US6723489B2 (en) 2002-01-30 2004-04-20 Kodak Polychrome Graphics Llp Printing form precursors
US20050003296A1 (en) * 2002-03-15 2005-01-06 Memetea Livia T. Development enhancement of radiation-sensitive elements
US7052117B2 (en) 2002-07-03 2006-05-30 Dimatix, Inc. Printhead having a thin pre-fired piezoelectric layer
US6858359B2 (en) 2002-10-04 2005-02-22 Kodak Polychrome Graphics, Llp Thermally sensitive, multilayer imageable element
DE10302111A1 (de) * 2003-01-21 2004-08-19 Kodak Polychrome Graphics Gmbh Bebilderbare Elemente und Zusammensetzungen für Bebilderung mittels UV-Bestrahlung
US6790590B2 (en) * 2003-01-27 2004-09-14 Kodak Polychrome Graphics, Llp Infrared absorbing compounds and their use in imageable elements
DE10307521A1 (de) 2003-02-21 2004-09-09 Kodak Polychrome Graphics Gmbh Wärmeempfindlicher positiv arbeitender Lithographie-Druckplattenläufer mit hoher Chemikalienbeständigkeit
DE10329262B3 (de) * 2003-06-23 2004-12-16 Infineon Technologies Ag Verfahren zur Behandlung eines Substrates und ein Halbleiterbauelement
JP4658805B2 (ja) * 2003-06-25 2011-03-23 山本化成株式会社 ポリメチン系エーテル化合物
EP1506858A3 (en) 2003-08-13 2005-10-12 Agfa-Gevaert Heat-sensitive lithographic printing plate precursor
US7425402B2 (en) 2003-08-13 2008-09-16 Agfa Graphics, N.V. Heat-sensitive lithographic printing plate precursor
US7205084B2 (en) 2003-12-18 2007-04-17 Agfa-Gevaert Heat-sensitive lithographic printing plate precursor
WO2005058605A1 (en) 2003-12-18 2005-06-30 Agfa-Gevaert Positive-working lithographic printing plate precursor
US7005227B2 (en) * 2004-01-21 2006-02-28 Intel Corporation One component EUV photoresist
DE102004003890A1 (de) * 2004-01-27 2005-08-11 Mitsubishi Polyester Film Gmbh Mittels elektromagnetischer Strahlung ein- oder mehrschichtige, orientierte strukturierbare Folie aus thermoplastischem Polymer, Verfahren zu ihrer Herstellung und ihre Verwendung
DE102004003891A1 (de) * 2004-01-27 2005-08-11 Mitsubishi Polyester Film Gmbh Orientierte, mittels elektromagnetischer Strahlung strukturierbare Folie aus thermoplastischem Polyester, Verfahren zu ihrer Herstellung und ihre Verwendung
US7281778B2 (en) 2004-03-15 2007-10-16 Fujifilm Dimatix, Inc. High frequency droplet ejection device and method
US8491076B2 (en) 2004-03-15 2013-07-23 Fujifilm Dimatix, Inc. Fluid droplet ejection devices and methods
US7467587B2 (en) 2004-04-21 2008-12-23 Agfa Graphics, N.V. Method for accurate exposure of small dots on a heat-sensitive positive-working lithographic printing plate material
US7279263B2 (en) * 2004-06-24 2007-10-09 Kodak Graphic Communications Canada Company Dual-wavelength positive-working radiation-sensitive elements
EP1836056B1 (en) 2004-12-30 2018-11-07 Fujifilm Dimatix, Inc. Ink jet printing
US7678533B2 (en) 2005-06-30 2010-03-16 Agfa Graphics, N.V. Heat-sensitive lithographic printing plate precursor
ES2365930T3 (es) 2006-02-28 2011-10-13 Agfa Graphics N.V. Un precursor de plancha de impresión litográfica que funciona como positivo sensible al calor.
EP1854627A1 (en) 2006-05-12 2007-11-14 Agfa Graphics N.V. Method for making a lithographic printing plate
GB2439734A (en) * 2006-06-30 2008-01-09 Peter Andrew Reath Bennett Coating for a lithographic precursor and use thereof
US7988247B2 (en) 2007-01-11 2011-08-02 Fujifilm Dimatix, Inc. Ejection of drops having variable drop size from an ink jet printer
EP1985445B1 (en) 2007-04-27 2011-07-20 Agfa Graphics N.V. A lithographic printing plate precursor
ATE509764T1 (de) 2007-08-14 2011-06-15 Agfa Graphics Nv Verfahren zur herstellung einer lithographiedruckform
EP2065211B1 (en) 2007-11-30 2010-05-26 Agfa Graphics N.V. A method for treating a lithographic printing plate
EP2098376B1 (en) 2008-03-04 2013-09-18 Agfa Graphics N.V. A method for making a lithographic printing plate support
EP2106924B1 (en) 2008-03-31 2011-06-29 Agfa Graphics N.V. A method for treating a lithographic printing plate
EP2159049B1 (en) 2008-09-02 2012-04-04 Agfa Graphics N.V. A heat-sensitive positive-working lithographic printing plate precursor
EP2194429A1 (en) 2008-12-02 2010-06-09 Eastman Kodak Company Gumming compositions with nano-particles for improving scratch sensitivity in image and non-image areas of lithographic printing plates
EP2213690B1 (en) 2009-01-30 2015-11-11 Agfa Graphics N.V. A new alkali soluble resin
US20100227269A1 (en) 2009-03-04 2010-09-09 Simpson Christopher D Imageable elements with colorants
ES2381535T3 (es) 2009-06-18 2012-05-29 Agfa Graphics N.V. Precursor de plancha de impresión litográfica
EP2284005B1 (en) 2009-08-10 2012-05-02 Eastman Kodak Company Lithographic printing plate precursors with beta-hydroxy alkylamide crosslinkers
US8383319B2 (en) 2009-08-25 2013-02-26 Eastman Kodak Company Lithographic printing plate precursors and stacks
EP2293144B1 (en) 2009-09-04 2012-11-07 Eastman Kodak Company Method of drying lithographic printing plates after single-step-processing
US20110097666A1 (en) 2009-10-27 2011-04-28 Celin Savariar-Hauck Lithographic printing plate precursors
US20110108773A1 (en) * 2009-11-09 2011-05-12 YewSavin, Inc. Compositions for Depositions and Processing of Films for Electronic Applications
US20110111134A1 (en) * 2009-11-09 2011-05-12 YewSavin, Inc. Systems and Methods of Preparation of Photovoltaic Films and Devices
EP2329951B1 (en) 2009-12-04 2012-06-20 AGFA Graphics NV A lithographic printing plate precursor
EP2366545B1 (en) 2010-03-19 2012-12-05 Agfa Graphics N.V. A lithographic printing plate precursor
US20110236832A1 (en) 2010-03-26 2011-09-29 Celin Savariar-Hauck Lithographic processing solutions and methods of use
US20130298792A1 (en) 2011-01-25 2013-11-14 Agfa Graphics Nv Lithographic printing plate precursor
EP2489512B1 (en) 2011-02-18 2013-08-28 Agfa Graphics N.V. A lithographic printing plate precursor
US8632940B2 (en) 2011-04-19 2014-01-21 Eastman Kodak Company Aluminum substrates and lithographic printing plate precursors
ES2556055T3 (es) 2011-09-08 2016-01-12 Agfa Graphics Nv Método de fabricación de una plancha de impresión litográfica
BR112015015795A2 (pt) 2013-01-01 2017-07-11 Agfa Graphics Nv copolímeros de etilenovinil acetal e seu uso em precursores de chapas de impressão litográfica
EP2933278B1 (en) 2014-04-17 2018-08-22 Agfa Nv (Ethylene, vinyl acetal) copolymers and their use in lithographic printing plate precursors
ES2617557T3 (es) 2014-05-15 2017-06-19 Agfa Graphics Nv Copolímeros (de etileno, vinilacetal) y su uso en precursores de plancha de impresión litográfica
EP2955198B8 (en) 2014-06-13 2018-01-03 Agfa Nv Ethylene/vinyl acetal-copolymers and their use in lithographic printing plate precursors
EP2963496B1 (en) 2014-06-30 2017-04-05 Agfa Graphics NV A lithographic printing plate precursor including ( ethylene, vinyl acetal ) copolymers
ES2655798T3 (es) 2014-12-08 2018-02-21 Agfa Nv Sistema para reducir los residuos de ablación
EP3130465B1 (en) 2015-08-12 2020-05-13 Agfa Nv Heat-sensitive lithographic printing plate precursor
US20190072855A1 (en) 2016-03-16 2019-03-07 Agfa Nv Method for processing a lithographic printing plate
EP3637188A1 (en) 2018-10-08 2020-04-15 Agfa Nv An effervescent developer precursor for processing a lithographic printing plate precursor
EP3778253A1 (en) 2019-08-13 2021-02-17 Agfa Nv Method for processing a lithographic printing plate
EP4382306A1 (en) 2022-12-08 2024-06-12 Eco3 Bv Lithographic printing press make-ready method

Family Cites Families (118)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL76414C (pt) 1949-07-23
US3046121A (en) 1949-07-23 1962-07-24 Azoplate Corp Process for the manufacture of printing plates and light-sensitive material suttablefor use therein
US3046119A (en) 1950-08-01 1962-07-24 Azoplate Corp Light sensitive material for printing and process for making printing plates
BE506677A (pt) 1950-10-31
NL78025C (pt) 1951-02-02
US2767092A (en) 1951-12-06 1956-10-16 Azoplate Corp Light sensitive material for lithographic printing
GB742557A (en) 1952-10-01 1955-12-30 Kalle & Co Ag Light-sensitive material for photomechanical reproduction and process for the production of images
GB772517A (en) 1954-02-06 1957-04-17 Kalle & Co Ag Improvements in or relating to photo-mechanical reproduction
NL95407C (pt) 1954-08-20
US2907665A (en) 1956-12-17 1959-10-06 Cons Electrodynamics Corp Vitreous enamel
NL247299A (pt) 1959-01-14
NL254616A (pt) 1959-08-05
US3105465A (en) 1960-05-31 1963-10-01 Oliver O Peters Hot water heater
US3206601A (en) 1963-05-21 1965-09-14 Keuffel & Esser Co Plastic film thermography
US3635709A (en) 1966-12-15 1972-01-18 Polychrome Corp Light-sensitive lithographic plate
GB1170495A (en) 1967-03-31 1969-11-12 Agfa Gevaert Nv Radiation-Sensitive Recording Material
GB1231789A (pt) 1967-09-05 1971-05-12
GB1245924A (en) 1967-09-27 1971-09-15 Agfa Gevaert Improvements relating to thermo-recording
US3837860A (en) 1969-06-16 1974-09-24 L Roos PHOTOSENSITIVE MATERIALS COMPRISING POLYMERS HAVING RECURRING PENDENT o-QUINONE DIAZIDE GROUPS
US3647443A (en) 1969-09-12 1972-03-07 Eastman Kodak Co Light-sensitive quinone diazide polymers and polymer compositions
JPS5024641B2 (pt) 1972-10-17 1975-08-18
US3891439A (en) 1972-11-02 1975-06-24 Polychrome Corp Aqueous developing composition for lithographic diazo printing plates
US3859099A (en) 1972-12-22 1975-01-07 Eastman Kodak Co Positive plate incorporating diazoquinone
CA1085212A (en) 1975-05-27 1980-09-09 Ronald H. Engebrecht Use of volatile carboxylic acids in improved photoresists containing quinone diazides
DE2543820C2 (de) 1975-10-01 1984-10-31 Hoechst Ag, 6230 Frankfurt Verfahren zur Herstellung von Flachdruckformen mittels Laserstrahlen
DE2607207C2 (de) 1976-02-23 1983-07-14 Hoechst Ag, 6230 Frankfurt Verfahren zur Herstellung von Flachdruckformen mit Laserstrahlen
GB1603920A (en) 1978-05-31 1981-12-02 Vickers Ltd Lithographic printing plates
JPS5560944A (en) 1978-10-31 1980-05-08 Fuji Photo Film Co Ltd Image forming method
DE3009873A1 (de) 1979-03-16 1980-09-25 Daicel Chem Photoempfindliche masse
JPS561045A (en) 1979-06-16 1981-01-08 Konishiroku Photo Ind Co Ltd Photosensitive composition
JPS561044A (en) 1979-06-16 1981-01-08 Konishiroku Photo Ind Co Ltd Photosensitive composition
JPS569740A (en) 1979-07-05 1981-01-31 Fuji Photo Film Co Ltd Image forming method
GB2082339B (en) 1980-08-05 1985-06-12 Horsell Graphic Ind Ltd Lithographic printing plates and method for processing
US4529682A (en) 1981-06-22 1985-07-16 Philip A. Hunt Chemical Corporation Positive photoresist composition with cresol-formaldehyde novolak resins
JPS58203433A (ja) 1982-05-21 1983-11-26 Fuji Photo Film Co Ltd 感光性組成物
JPS58224351A (ja) 1982-06-23 1983-12-26 Fuji Photo Film Co Ltd 感光性印刷版
US4469774A (en) * 1983-03-28 1984-09-04 E. I. Du Pont De Nemours And Company Positive-working photosensitive benzoin esters
US4609615A (en) 1983-03-31 1986-09-02 Oki Electric Industry Co., Ltd. Process for forming pattern with negative resist using quinone diazide compound
DE3325023A1 (de) 1983-07-11 1985-01-24 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung negativer kopien mittels eines materials auf basis von 1,2-chinondiaziden
US4708925A (en) 1984-12-11 1987-11-24 Minnesota Mining And Manufacturing Company Photosolubilizable compositions containing novolac phenolic resin
US4693958A (en) 1985-01-28 1987-09-15 Lehigh University Lithographic plates and production process therefor
DE3541534A1 (de) 1985-11-25 1987-05-27 Hoechst Ag Positiv arbeitendes strahlungsempfindliches gemisch
ZA872295B (pt) 1986-03-13 1987-09-22
US4684599A (en) 1986-07-14 1987-08-04 Eastman Kodak Company Photoresist compositions containing quinone sensitizer
DE3716848A1 (de) 1987-05-20 1988-12-01 Hoechst Ag Verfahren zur bebilderung lichtempfindlichen materials
EP0304313A3 (en) 1987-08-21 1990-08-22 Oki Electric Industry Company, Limited Pattern forming material
JPH01201654A (ja) 1988-02-06 1989-08-14 Nippon Oil Co Ltd ポジ型フォトレジスト材料
US4962147A (en) 1988-05-26 1990-10-09 Hoechst Celanese Corporation Process for the suspension polymerization of 4-acetoxystyrene and hydrolysis to 4-hydroxystyrene polymers
DE3820001A1 (de) 1988-06-11 1989-12-14 Basf Ag Optisches aufzeichnungsmedium
US4877718A (en) 1988-09-26 1989-10-31 Rennsselaer Polytechnic Institute Positive-working photosensitive polyimide operated by photo induced molecular weight changes
JP2547626B2 (ja) 1988-10-07 1996-10-23 富士写真フイルム株式会社 モノマーの製造方法
EP0366590B2 (en) * 1988-10-28 2001-03-21 International Business Machines Corporation Highly sensitive positive photoresist compositions
DE68921146T2 (de) 1988-11-11 1995-06-14 Fuji Photo Film Co Ltd Lichtempfindliche Zusammensetzung.
JP2571115B2 (ja) 1989-01-17 1997-01-16 富士写真フイルム株式会社 感光性組成物の増感方法及び増感された感光性組成物
JP2871710B2 (ja) 1989-03-17 1999-03-17 株式会社きもと 画像形成方法
JP2661671B2 (ja) * 1989-03-20 1997-10-08 株式会社日立製作所 パタン形成材料とそれを用いたパタン形成方法
JPH02251962A (ja) 1989-03-27 1990-10-09 Matsushita Electric Ind Co Ltd 微細パターン形成材料およびパターン形成方法
US5200298A (en) 1989-05-10 1993-04-06 Fuji Photo Film Co., Ltd. Method of forming images
EP0410606B1 (en) 1989-07-12 1996-11-13 Fuji Photo Film Co., Ltd. Siloxane polymers and positive working light-sensitive compositions comprising the same
EP0424182B1 (en) 1989-10-19 1998-07-08 Fujitsu Limited Process for formation of resist patterns
GB9004337D0 (en) 1990-02-27 1990-04-25 Minnesota Mining & Mfg Preparation and use of dyes
DE4013575C2 (de) 1990-04-27 1994-08-11 Basf Ag Verfahren zur Herstellung negativer Reliefkopien
US5279918A (en) 1990-05-02 1994-01-18 Mitsubishi Kasei Corporation Photoresist composition comprising a quinone diazide sulfonate of a novolac resin
JP2729850B2 (ja) 1990-05-15 1998-03-18 富士写真フイルム株式会社 画像形成層
JP2639853B2 (ja) * 1990-05-18 1997-08-13 富士写真フイルム株式会社 新規キノンジアジド化合物及びそれを含有する感光性組成物
JP2645384B2 (ja) 1990-05-21 1997-08-25 日本ペイント株式会社 ポジ型感光性樹脂組成物
GB9012021D0 (en) * 1990-05-30 1990-07-18 Cookson Group Plc Light sensitive materials for lithographic plates
US5145763A (en) 1990-06-29 1992-09-08 Ocg Microelectronic Materials, Inc. Positive photoresist composition
US5085972A (en) 1990-11-26 1992-02-04 Minnesota Mining And Manufacturing Company Alkoxyalkyl ester solubility inhibitors for phenolic resins
JPH04359906A (ja) 1991-06-07 1992-12-14 Shin Etsu Chem Co Ltd ポリ(パラ−t−ブトキシカルボニルオキシスチレン)及びその製造方法
CA2066895A1 (en) * 1991-06-17 1992-12-18 Thomas P. Klun Aqueous developable imaging systems
US5258257A (en) 1991-09-23 1993-11-02 Shipley Company Inc. Radiation sensitive compositions comprising polymer having acid labile groups
US5437952A (en) 1992-03-06 1995-08-01 Konica Corporation Lithographic photosensitive printing plate comprising a photoconductor and a naphtho-quinone diazide sulfonic acid ester of a phenol resin
US5368977A (en) 1992-03-23 1994-11-29 Nippon Oil Co. Ltd. Positive type photosensitive quinone diazide phenolic resin composition
DE4321607A1 (de) 1992-06-30 1994-01-05 Kanzaki Paper Mfg Co Ltd Aufzeichnungsmaterial
CA2091286A1 (en) 1992-07-20 1994-01-21 John Grunwald Direct imaging process for forming resist pattern on a surface, and use thereof in fabricating printed boards
JPH07120928A (ja) * 1992-12-11 1995-05-12 Hitachi Ltd ポジ型感放射線組成物及びそれを用いたパタン形成方法
DE69406687T2 (de) 1993-01-25 1998-05-14 At & T Corp Ein Verfahren zum gesteuerten Entschützen von Polymeren und Verfahren zur Herstellung einer Vorrichtung welches diese zum Teil entschützten Polymere für Photoresiste benutzt
US5512418A (en) * 1993-03-10 1996-04-30 E. I. Du Pont De Nemours And Company Infra-red sensitive aqueous wash-off photoimaging element
US5372915A (en) 1993-05-19 1994-12-13 Eastman Kodak Company Method of making a lithographic printing plate containing a resole resin and a novolac resin in the radiation sensitive layer
DE4426820A1 (de) * 1993-07-29 1995-02-02 Fuji Photo Film Co Ltd Bilderzeugungsmaterial und Bilderzeugungsverfahren
GB9322705D0 (en) 1993-11-04 1993-12-22 Minnesota Mining & Mfg Lithographic printing plates
DE69512113T2 (de) 1994-03-14 2000-05-25 Kodak Polychrome Graphics Llc, Norwalk Strahlungsempfindliche Zusammensetzung, enthaltend ein Resolharz, ein Novolakharz, einen Infrarotabsorber und ein Triazin, und seine Verwendung in lithographischen Druckplatten
JP3317574B2 (ja) 1994-03-15 2002-08-26 富士写真フイルム株式会社 ネガ型画像記録材料
JP3461377B2 (ja) * 1994-04-18 2003-10-27 富士写真フイルム株式会社 画像記録材料
US5441850A (en) 1994-04-25 1995-08-15 Polaroid Corporation Imaging medium and process for producing an image
US5824451A (en) * 1994-07-04 1998-10-20 Fuji Photo Film Co., Ltd. Positive photosensitive composition
WO1996002021A1 (en) 1994-07-11 1996-01-25 Konica Corporation Original form for lithographic plate and process for preparing lithographic plate
US5466557A (en) 1994-08-29 1995-11-14 Eastman Kodak Company Radiation-sensitive composition containing a resole resin, a novolac resin, a latent bronsted acid, an infrared absorber and terephthalaldehyde and use thereof in lithographic printing plates
EP0706899A1 (en) 1994-10-13 1996-04-17 Agfa-Gevaert N.V. Thermal imaging element
GB9426206D0 (en) * 1994-12-23 1995-02-22 Horsell Plc Lithographic plate
US5491046A (en) 1995-02-10 1996-02-13 Eastman Kodak Company Method of imaging a lithographic printing plate
US5658708A (en) 1995-02-17 1997-08-19 Fuji Photo Film Co., Ltd. Image recording material
JPH0962005A (ja) 1995-06-14 1997-03-07 Fuji Photo Film Co Ltd ネガ型感光性組成物
US5641608A (en) 1995-10-23 1997-06-24 Macdermid, Incorporated Direct imaging process for forming resist pattern on a surface and use thereof in fabricating printing plates
JPH09120157A (ja) 1995-10-25 1997-05-06 Fuji Photo Film Co Ltd 湿し水不要感光性平版印刷版
US6132935A (en) 1995-12-19 2000-10-17 Fuji Photo Film Co., Ltd. Negative-working image recording material
JP3589365B2 (ja) 1996-02-02 2004-11-17 富士写真フイルム株式会社 ポジ画像形成組成物
EP0887182B1 (en) * 1996-04-23 2002-07-24 Kodak Polychrome Graphics Company Ltd. Heat-sensitive composition for making a lithographic printing form precursor
EP0803771A1 (en) 1996-04-23 1997-10-29 Agfa-Gevaert N.V. A method for making a lithopgrapic printing plate wherein an imaging element is used that comprises a thermosensitive mask
US5763134A (en) * 1996-05-13 1998-06-09 Imation Corp Composition comprising photochemical acid progenitor and specific squarylium dye
DE69608679D1 (de) 1996-07-19 2000-07-06 Agfa Gevaert Nv IR-Strahlungsempfindliches Bildaufzeichnungselement und Verfahren zur Herstellung von lithographischen Druckplatten mit diesem Element
JP3814961B2 (ja) * 1996-08-06 2006-08-30 三菱化学株式会社 ポジ型感光性印刷版
US5705309A (en) 1996-09-24 1998-01-06 Eastman Kodak Company Photosensitive composition and element containing polyazide and an infrared absorber in a photocrosslinkable binder
US5759742A (en) 1996-09-25 1998-06-02 Eastman Kodak Company Photosensitive element having integral thermally bleachable mask and method of use
US5705308A (en) * 1996-09-30 1998-01-06 Eastman Kodak Company Infrared-sensitive, negative-working diazonaphthoquinone imaging composition and element
US5858626A (en) 1996-09-30 1999-01-12 Kodak Polychrome Graphics Method of forming a positive image through infrared exposure utilizing diazonaphthoquinone imaging composition
EP0833204A1 (en) * 1996-09-30 1998-04-01 Eastman Kodak Company Infrared-sensitive diazonaphthoquinone imaging composition and element
EP0839647B2 (en) 1996-10-29 2014-01-22 Agfa Graphics N.V. Method for making a lithographic printing plate with improved ink-uptake
EP0864419B1 (en) 1997-03-11 2002-08-07 Agfa-Gevaert Method for making positive working lithographic printing plates
DE19712323A1 (de) 1997-03-24 1998-10-01 Agfa Gevaert Ag Strahlungsempfindliches Gemisch und damit hergestelltes Aufzeichnungsmaterial für Offsetdruckplatten
US5948591A (en) * 1997-05-27 1999-09-07 Agfa-Gevaert, N.V. Heat sensitive imaging element and a method for producing lithographic plates therewith
BR9810668A (pt) * 1997-07-05 2001-09-04 Kodak Polychrome Graphics Co Processos para formação de moldes e materiais sensìveis a radiação
JP3779444B2 (ja) 1997-07-28 2006-05-31 富士写真フイルム株式会社 赤外線レーザ用ポジ型感光性組成物
US6060217A (en) * 1997-09-02 2000-05-09 Kodak Polychrome Graphics Llc Thermal lithographic printing plates
US5919600A (en) * 1997-09-03 1999-07-06 Kodak Polychrome Graphics, Llc Thermal waterless lithographic printing plate
US6165691A (en) * 1997-12-19 2000-12-26 Agfa-Gevaert, N.V. Method for lithographic printing by use of a lithographic printing plate provided by a heat sensitive non-ablatable wasteless imaging element and a fountain containing water-insoluble compounds
US5985514A (en) * 1998-09-18 1999-11-16 Eastman Kodak Company Imaging member containing heat sensitive thiosulfate polymer and methods of use

Also Published As

Publication number Publication date
US6537735B1 (en) 2003-03-25
ATE204388T1 (de) 2001-09-15
EP0996869A1 (en) 2000-05-03
EP1103373A3 (en) 2001-07-18
WO1999001795A3 (en) 1999-04-15
DE69801363T2 (de) 2002-05-23
EP0953166B1 (en) 2001-08-16
WO1999001796A3 (en) 1999-03-25
WO1999001795A8 (en) 1999-05-20
WO1999001796A2 (en) 1999-01-14
EP1103373A2 (en) 2001-05-30
JP2002510404A (ja) 2002-04-02
JP2002511955A (ja) 2002-04-16
DE69801363D1 (de) 2001-09-20
EP0953166A2 (en) 1999-11-03
US6218083B1 (en) 2001-04-17
WO1999001795A2 (en) 1999-01-14
BR9810545A (pt) 2000-09-05
AU8229498A (en) 1999-01-25

Similar Documents

Publication Publication Date Title
BR9810668A (pt) Processos para formação de moldes e materiais sensìveis a radiação
EP0887667A3 (en) Method of making a patterned retarder, patterned retarder and illumination source
TWI247944B (en) Manufacturing device and manufacturing method for light guide board of flat panel lighting device
BR9607693A (pt) Fórmula, processo e aparelho para encapsulação
EP0392868A3 (en) Method of producing light control plate which induces scattering of light at different angles
CA2272919A1 (en) Credit card with magnifying lens
AU2396697A (en) Heat-sensitive composition and method of making a lithographic printing form with it
MY130595A (en) Methods for preparing integral black matrix/color filter elements
EP0768512A3 (en) A process for fabricating a device using polarized light to determine film thickness
RU2009112394A (ru) Защитные изделия и устройства, содержащие кодированные голографические микропластины, и способы их изготовления
SE7610739L (sv) Forfarande for framstellning av plantryckformar medelst laserstralar
GR76013B (pt)
JPH10293395A5 (pt)
US3554751A (en) Presensitized positive-working lithographic plate and method for making same
EP0917000A3 (en) Positive resist composition and method for forming a resist pattern
EP0131893A3 (en) Process for producing supports for photographic paper
ES2126558T3 (es) Composicion fotosensible electrodepositable que forman materia para fotoreserva.
ES2184468T3 (es) Procedimiento de fabricacion de etiquetas de seguridad.
US5664497A (en) Laser symbolization on copper heat slugs
WO2002010857A3 (en) Process for making a periodic profile
JPS5983110A (ja) パタ−ン状回折格子の複製方法
BR9812465A (pt) Método de fotolitografia inteligente
US43821A (en) Improvement in photo-galvanography
EP0385583A3 (en) A method of forming an embossed character on an ic card
JPS6423258A (en) Photosensitive body for copy printing and copy printing method using same

Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 02/07/1998, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 16A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2261 DE 06-05-2014 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.