[go: up one dir, main page]

BR9810341A - Catalisadores de carbeno de rutênio e ósmio - Google Patents

Catalisadores de carbeno de rutênio e ósmio

Info

Publication number
BR9810341A
BR9810341A BR9810341-5A BR9810341A BR9810341A BR 9810341 A BR9810341 A BR 9810341A BR 9810341 A BR9810341 A BR 9810341A BR 9810341 A BR9810341 A BR 9810341A
Authority
BR
Brazil
Prior art keywords
ruthenium
catalysts
osmium
osmium carbene
carbene catalysts
Prior art date
Application number
BR9810341-5A
Other languages
English (en)
Other versions
BR9810341B1 (pt
Inventor
Paul Adriaan Van Der Schaaf
Andreas Hafner
Andreas Muhlebach
Original Assignee
Ciba Sc Holding Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag
Publication of BR9810341A publication Critical patent/BR9810341A/pt
Publication of BR9810341B1 publication Critical patent/BR9810341B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/002—Osmium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/14—Other (co) polymerisation, e.g. of lactides or epoxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/825—Osmium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Patente de Invenção: <B>"CATALISADORES DE CARBENO DE RUTêNIO E óSMIO"<D>. A invenção refere-se a catalisadores de carbeno, de rutênio e ósmio penta- e hexacoordenados, em que um átomo de enxofre, oxigênio ou nitrogênio é ligado ao grupo carbeno que é coordenado com o átomo de rutênio central ou ósmio, à sua preparação e a seu uso para sintetização de polímeros, para metátese de fechamento de anel de olefinas e para isomerização de olefinas.
BRPI9810341-5A 1997-06-25 1998-06-13 catalisadores de carbeno de rutênio e composição compreendendo os mesmos. BR9810341B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CH1536/97 1997-06-25
CH153697 1997-06-25
PCT/EP1998/003573 WO1999000396A1 (en) 1997-06-25 1998-06-13 Ruthenium and osmium carbene catalysts

Publications (2)

Publication Number Publication Date
BR9810341A true BR9810341A (pt) 2000-09-05
BR9810341B1 BR9810341B1 (pt) 2011-09-06

Family

ID=4212726

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9810341-5A BR9810341B1 (pt) 1997-06-25 1998-06-13 catalisadores de carbeno de rutênio e composição compreendendo os mesmos.

Country Status (10)

Country Link
US (1) US6407190B1 (pt)
EP (1) EP0993465B1 (pt)
JP (1) JP3930058B2 (pt)
KR (1) KR100569619B1 (pt)
AU (1) AU8626698A (pt)
BR (1) BR9810341B1 (pt)
CA (1) CA2290953C (pt)
DE (1) DE69809552T2 (pt)
MX (1) MX221283B (pt)
WO (1) WO1999000396A1 (pt)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6696597B2 (en) 1998-09-01 2004-02-24 Tilliechem, Inc. Metathesis syntheses of pheromones or their components
US7507854B2 (en) 1998-09-01 2009-03-24 Materia, Inc. Impurity reduction in Olefin metathesis reactions
US6900347B2 (en) 1998-09-01 2005-05-31 Tilliechem, Inc. Impurity inhibition in olefin metathesis reactions
JP2002020395A (ja) * 2000-07-04 2002-01-23 Sekisui Chem Co Ltd 新規な高メタセシス活性の有機金属錯体化合物、これを含有してなるメタセシス反応触媒、この触媒を用いた重合方法、並びにこの重合方法により得られた樹脂組成物
WO2002024713A1 (de) * 2000-09-19 2002-03-28 Basf Aktiengesellschaft Dikationische rutheniumkomplexe und deren verwendung zu metathesereaktionen von olefinen
US7015276B2 (en) 2000-10-02 2006-03-21 Sekisui Chemical Co., Ltd. Melt-moldable thermoplastic norbornene resin composition and molded article and optical film both comprising the same
MXPA02002378A (es) 2001-03-12 2002-09-24 Ciba Sc Holding Ag "romp con grupos alcoxi eter".
JP4643091B2 (ja) * 2001-08-24 2011-03-02 カリフォルニア インスティテュート オブ テクノロジー ６配位ルテニウムまたはオスミウム金属カルベンメタセシス触媒
JP4138417B2 (ja) * 2001-09-28 2008-08-27 積水化学工業株式会社 有機金属化合物の合成方法
AU2003232067A1 (en) 2002-05-06 2003-11-17 Kerr Corporation Composition curable by metathesis reaction
US8722828B2 (en) * 2003-01-31 2014-05-13 Zeon Corporation Process for continuous production of cycloolefin resins, and sheets or films thereof, using ring opening metathesis polymerization
JP2004307455A (ja) 2003-02-17 2004-11-04 Sekisui Chem Co Ltd ゼロ価遷移金属錯体及びこれを出発物質とする有機金属化合物の合成方法
US7060769B2 (en) * 2003-05-06 2006-06-13 Kerr Corporation Method of curing composition by metathesis reaction using reaction control agent
US7173097B2 (en) 2003-05-06 2007-02-06 Kerr Corporation Metathesis-curable composition with a reaction control agent
US7060770B2 (en) * 2003-05-06 2006-06-13 Kerr Corporation Metathesis-curable composition with a reaction control agent
US7683148B2 (en) 2003-05-06 2010-03-23 Kerr Corporation Metathesis-curable composition with a reaction control agent
EP1765839B1 (en) * 2004-06-09 2017-01-25 UTI Limited Partnership Transition metal carbene complexes containing a cationic substituent as catalysts of olefin metathesis reactions
US7645443B2 (en) * 2004-11-15 2010-01-12 Kerr Corporation Polyether-based composition curable by metathesis reaction
US7625551B2 (en) * 2004-11-15 2009-12-01 Kerr Corporation Polyether-based dental impression material curable by metathesis reaction
US7001590B1 (en) 2004-11-15 2006-02-21 Kerr Corporation Metathesis-curable composition
JP2007246900A (ja) 2006-02-21 2007-09-27 Kerr Corp 官能性オレフィン基で末端封止されたアルコキシ−シロキサンポリエーテルカルボキシレートの製造方法
US8241575B2 (en) 2008-01-28 2012-08-14 The Johns Hopkins University Molecularly imprinted polymer sensor device
CA2737921C (en) 2008-09-22 2019-01-15 Aileron Therapeutics, Inc. Methods for preparing purified alpha-helical peptidomimetic macrocycle compositions with low metal ppm levels
US20120035331A1 (en) * 2009-04-28 2012-02-09 Korea Institute Of Science And Technology Polyalkylthiophene block copolymer and a method of preparing the same through a ring-opening metathesis polymerization reaction
WO2012076426A1 (de) 2010-12-08 2012-06-14 Basf Se Verfahren zur herstellung einer wässrigen polymerisatdispersion
US20120149840A1 (en) * 2010-12-08 2012-06-14 Univ. of Southern Mississippi Res. Foundation Process for producing an aqueous polymer dispersion
US8900671B2 (en) 2011-02-28 2014-12-02 General Electric Company Method for manufacture of an infused spar cap using a low viscosity matrix material
IN2014CN00746A (pt) 2011-07-12 2015-04-03 Basf Se
US8993819B2 (en) 2011-07-12 2015-03-31 Basf Se Process for preparing cycloheptene
US8940940B2 (en) 2012-06-13 2015-01-27 Basf Se Process for preparing macrocyclic ketones
KR101961985B1 (ko) 2013-06-27 2019-03-25 바스프 에스이 유전체로서의 복분해 중합체
US11407843B2 (en) 2017-12-08 2022-08-09 Arlanxeo Deutschland Gmbh Process for producing nitrile rubbers using ruthenium complex catalysts
WO2021060551A1 (ja) * 2019-09-27 2021-04-01 出光興産株式会社 オレフィン系樹脂及びホットメルト接着剤
EP4045560A1 (en) 2019-10-14 2022-08-24 3M Innovative Properties Company Compositions comprising cyclic olefins and thermally conductive filler
US12312509B2 (en) 2019-12-20 2025-05-27 3M Innovative Properties Company Adhesive article comprising polymer and polymerizable cyclic olefins, adhesive compositions and methods

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU691645B2 (en) * 1992-04-03 1998-05-21 California Institute Of Technology High activity ruthenium or osmium metal carbene complexes for olefin metathesis reactions and synthesis thereof
US5312940A (en) 1992-04-03 1994-05-17 California Institute Of Technology Ruthenium and osmium metal carbene complexes for olefin metathesis polymerization

Also Published As

Publication number Publication date
DE69809552D1 (de) 2003-01-02
MX9911933A (es) 2000-03-31
US6407190B1 (en) 2002-06-18
CA2290953A1 (en) 1999-01-07
KR20010014233A (ko) 2001-02-26
KR100569619B1 (ko) 2006-04-11
EP0993465A1 (en) 2000-04-19
DE69809552T2 (de) 2003-07-17
AU8626698A (en) 1999-01-19
MX221283B (es) 2004-07-07
BR9810341B1 (pt) 2011-09-06
JP2002506452A (ja) 2002-02-26
WO1999000396A1 (en) 1999-01-07
CA2290953C (en) 2008-03-25
JP3930058B2 (ja) 2007-06-13
EP0993465B1 (en) 2002-11-20

Similar Documents

Publication Publication Date Title
BR9810341A (pt) Catalisadores de carbeno de rutênio e ósmio
BR9810488A (pt) Novos catalisadores.
FI934917L (fi) Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö
FR2742986B1 (fr) Compositions cosmetiques pour le cheveu ou la peau a base de copolyesters sulfones a motifs polyorganosiloxanes
MX17762A (es) Catalizadores para la polimerizacion de olefinas.
AU3272895A (en) High activity ruthenium or osmium metal carbene complexes for olefin metathesis reactions and synthesis thereof
DE59912097D1 (de) Alkylidenkomplexe des rutheniums mit n-heterozyklischen carbenliganden; verwendung als katalysatoren für die olefin-metathese
BR9804807A (pt) Compostos metalocenos e catalisadores para a polimeraza-Æo de olefinas
BR9712320A (pt) Trava para bomba dispensadora
DE50106562D1 (de) Kosmetische und pharmazeutische Öl-in-Wasser-Emulsionen von polyethermodifizierten Polysiloxanen
BR9608451A (pt) Catalisador compreendendo cobalto e maganés e/ou vanádio processos para a preparação de catalisador e de hidrocarbonetos e uso do catalisador
FI955687L (fi) Tuettuja metalloseeni-katalyytti-järjestelmiä olefiinien polymeroimista varten, niiden valmistus ja käyttö
BR9507072A (pt) Catalisador adequado para hidrogenar compostos orgânicos uso do catalisador e processos para preparar catalisadores um óleo branco medicinal parafinas medicinais elevadamente puras e misturas de hidrocarbonetos livres de compostos aromáticos ou com baixo teor de compostos aromáticos
DE69231795D1 (de) Polymerisierbare mischungen, die katalysatoren fuer die olefin-metathese und cokatalysatoren enthalten, und ihre anwendung
FI972230A7 (fi) Uusi homogeeninen olefiinien polymerointikatalysaattorikoostumus
FI943238L (fi) Kantajalla olevia katalysaattoreita olefiinien polymerointiin
BR0314856A (pt) Complexos de rutênio como (pré) catalisadores para reações de metátese
DE69114309D1 (de) Bestandteile und Katalysatoren für die Olefinpolymerisation.
AU4532989A (en) Improved titania catalysts, their preparation and use in fischer-tropsch synthesis
DE69113642D1 (de) Bestandteile und Katalysatoren für die Olefinpolymerisation.
DE69618893D1 (de) Rhenium und Aluminium enthaltende Katalysatoren, ihre Herstellung und Verwendung für die Metathese von Olefinen
ZA97566B (en) Olefin addition polymerization catalyst composition
ITMI910521A1 (it) Procedimento per la preparazione di un componente solido di catalizzatore per la co polimerizzazione dell&#39;etilene.
DE69809531D1 (de) Bestandteile und katalysatoren für die olefinpolymerisation
DE3787345D1 (de) Thermisch aktiviertes Zweikomponenten-Metathesekatalysatorsystem.

Legal Events

Date Code Title Description
B07A Technical examination (opinion): publication of technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: INDEFERIMENTO DO PRESENTE PEDIDO, TENDO POR BASE OS ARTIGOS 8O E 13 DA LPI 9279 DE 14/05/96

B12B Appeal: appeal against refusal
B16A Patent or certificate of addition of invention granted

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 06/09/2011, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 19A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)