BR9601208A - Precursor de catalisador sistema catalisador processo para a manufatura de poliolefinas composições de poliolefina e de polietileno - Google Patents
Precursor de catalisador sistema catalisador processo para a manufatura de poliolefinas composições de poliolefina e de polietilenoInfo
- Publication number
- BR9601208A BR9601208A BR9601208A BR9601208A BR9601208A BR 9601208 A BR9601208 A BR 9601208A BR 9601208 A BR9601208 A BR 9601208A BR 9601208 A BR9601208 A BR 9601208A BR 9601208 A BR9601208 A BR 9601208A
- Authority
- BR
- Brazil
- Prior art keywords
- manufacture
- polyethylene compositions
- precursor process
- catalyst system
- polyolefins
- Prior art date
Links
- 229920000098 polyolefin Polymers 0.000 title 2
- 239000004698 Polyethylene Substances 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 239000012018 catalyst precursor Substances 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 239000000203 mixture Substances 0.000 title 1
- -1 polyethylene Polymers 0.000 title 1
- 229920000573 polyethylene Polymers 0.000 title 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/412,964 US5527752A (en) | 1995-03-29 | 1995-03-29 | Catalysts for the production of polyolefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9601208A true BR9601208A (pt) | 1998-01-06 |
Family
ID=23635222
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9601208A BR9601208A (pt) | 1995-03-29 | 1996-03-29 | Precursor de catalisador sistema catalisador processo para a manufatura de poliolefinas composições de poliolefina e de polietileno |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US5527752A (pt) |
| EP (1) | EP0735057B1 (pt) |
| JP (1) | JP3157457B2 (pt) |
| KR (1) | KR100273946B1 (pt) |
| CN (2) | CN1138050A (pt) |
| AR (1) | AR001464A1 (pt) |
| AT (1) | ATE166073T1 (pt) |
| AU (1) | AU698339B2 (pt) |
| BR (1) | BR9601208A (pt) |
| CA (1) | CA2173007C (pt) |
| CZ (1) | CZ93896A3 (pt) |
| DE (1) | DE69600281T2 (pt) |
| EG (1) | EG21088A (pt) |
| ES (1) | ES2117471T3 (pt) |
| HU (1) | HUP9600822A3 (pt) |
| MY (2) | MY132199A (pt) |
| PL (1) | PL313555A1 (pt) |
| RU (1) | RU2142953C1 (pt) |
| SK (1) | SK42196A3 (pt) |
| TR (1) | TR199600261A2 (pt) |
| UA (1) | UA61874C2 (pt) |
| ZA (2) | ZA962558B (pt) |
Families Citing this family (96)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5631202A (en) | 1993-09-24 | 1997-05-20 | Montell Technology Company B.V. | Stereospecific metallocene catalysts with stereolocking α-CP substituents |
| US5707913A (en) * | 1994-06-15 | 1998-01-13 | Basf Aktiengesellschaft | Amidinato catalyst systems for the polymerization of olefins |
| KR100223078B1 (ko) * | 1994-12-13 | 1999-10-15 | 야마모토 카즈모토 | 올레핀 중합 촉매 |
| SG81898A1 (en) * | 1995-08-11 | 2001-07-24 | Sumitomo Chemical Co | Olefin polymerization catalyst component, olefin polymerization catalyst and process for producing olefin polymer |
| CA2188722A1 (en) * | 1995-10-26 | 1997-04-27 | George Norris Foster | Process for preparing an in situ polyethylene blend |
| EP0867454B1 (en) * | 1995-12-12 | 2001-03-21 | Idemitsu Kosan Company Limited | Polymerization catalyst and process for producing polymers |
| AR005066A1 (es) * | 1995-12-15 | 1999-04-07 | Union Carbide Chem Plastic | Un procedimiento para hacer un homopolimero, copolimero o terpolimero de polietileno con ramificacion de cadena larga, una composicion de polietilenoasi obtenida y un articulo de pelicula o moldeado por inyeccion que comprende dicha composicion. |
| US5665818A (en) * | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
| AU3603797A (en) * | 1996-03-27 | 1997-10-17 | Dow Chemical Company, The | Allyl containing metal complexes and olefin polymerization process |
| US6812184B1 (en) * | 1996-06-17 | 2004-11-02 | Exxonmobil Chemical Patents Inc. | Supported late transition metal catalyst systems |
| US5959044A (en) * | 1996-07-08 | 1999-09-28 | Villar; Juan Carlos | Method of controlling continuous ethylene-limited metallocene-catalyzed copolymerization systems |
| CA2264141A1 (en) * | 1996-09-04 | 1998-03-12 | Jorge Soto | Incorporation of free radical inhibitors in polyolefins |
| JP2001500550A (ja) * | 1996-09-12 | 2001-01-16 | ビーピー ケミカルズ リミテッド | 重合触媒 |
| AU4913597A (en) * | 1996-11-01 | 1998-05-29 | Union Carbide Chemicals & Plastics Technology Corporation | Reduction of fouling in olefin polymerization systems |
| US5912202A (en) * | 1997-01-10 | 1999-06-15 | Union Carbide Chemicals & Plastics Technology Corporation | Olefin polymerization catalyst composition having increased activity |
| ZA9711220B (en) * | 1997-01-10 | 1998-06-23 | Union Carbide Chem Plastic | Method of controlling olefin polymerization catalyst composition activity. |
| US5747406A (en) * | 1997-01-10 | 1998-05-05 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for the production of olefin polymers |
| EP0861853A1 (en) | 1997-02-27 | 1998-09-02 | ENICHEM S.p.A. | Catalyst and process for the syndiotactic polymerization of vinylaromatic compounds |
| US6228794B1 (en) | 1997-03-14 | 2001-05-08 | University Of Iowa Research Foundation | Cationic group 13 complexes incorporating bidentate ligands as polymerization catalysts |
| US5777120A (en) * | 1997-03-14 | 1998-07-07 | University Of Iowa Research Foundation | Cationic aluminum alkyl complexes incorporating amidinate ligands as polymerization catalysts |
| US6160072A (en) * | 1997-05-02 | 2000-12-12 | Ewen; John A. | Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes |
| WO1999002570A1 (en) | 1997-07-08 | 1999-01-21 | Bp Chemicals Limited | Supported polymerisation catalyst |
| KR100240519B1 (ko) * | 1997-09-11 | 2000-01-15 | 유현식 | 새로운 올레핀 중합용 킬레이트 촉매 및 이를 이용한 올레핀중합 방법 |
| US6069213A (en) * | 1997-12-16 | 2000-05-30 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed catalyst system |
| US5998558A (en) * | 1997-12-29 | 1999-12-07 | Union Carbide Chemicals & Plastics Technology Corporation | Ethylene polymers having enhanced processing ease |
| US6069109A (en) * | 1998-07-01 | 2000-05-30 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the production of half-sandwich transition metal based catalyst precursors |
| US6187712B1 (en) | 1998-09-16 | 2001-02-13 | Univation Technologies, Llc | Catalyst composition for the polymerization of olefins |
| US6258903B1 (en) * | 1998-12-18 | 2001-07-10 | Univation Technologies | Mixed catalyst system |
| US6281316B1 (en) | 1999-03-22 | 2001-08-28 | Union Carbide Chemicals & Plastics Technology Corporation | Enhanced crosslinking terpolymer |
| AU2407800A (en) | 1999-10-28 | 2001-05-08 | University Of Maryland At College Park, The | Stereospecific living polymerization of olefins by a novel ziegler-natta catalyst composition |
| US6340730B1 (en) | 1999-12-06 | 2002-01-22 | Univation Technologies, Llc | Multiple catalyst system |
| US6281306B1 (en) | 1999-12-16 | 2001-08-28 | Univation Technologies, Llc | Method of polymerization |
| US6444605B1 (en) | 1999-12-28 | 2002-09-03 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed metal alkoxide and cycloalkadienyl catalysts for the production of polyolefins |
| US6399531B1 (en) | 1999-12-28 | 2002-06-04 | Union Carbide Chemicals & Plastics Technology Corporation | Hybrid ziegler-natta and cycloalkadienyl catalysts for the production of polyolefins |
| US20020107343A1 (en) * | 2001-02-08 | 2002-08-08 | Mitsui Chemicals, Inc. | Ethylene polymer, preparation process thereof and molded articles of the same |
| GB0111443D0 (en) * | 2001-05-10 | 2001-07-04 | Borealis Tech Oy | Olefin polymerisation process |
| WO2003008459A1 (en) * | 2001-07-20 | 2003-01-30 | University Of Maryland, College Park | Method for production of multimodal polyolefins of tunable composition, molecular weight, and polydispersity |
| ITMI20011688A1 (it) * | 2001-08-02 | 2003-02-02 | Enichem Spa | Catalizzatore e suo impiego nella sintesi di acqua ossigenata |
| JP5013444B2 (ja) * | 2001-09-18 | 2012-08-29 | 旭化成ケミカルズ株式会社 | 環状オレフィン系共重合触媒および共重合体の製造方法 |
| DE02772548T1 (de) * | 2001-10-26 | 2004-11-11 | Epichem Ltd., Wirral | Vorlaeuferverbindungen für chemische dampfphasenabscheidung |
| CA2485168A1 (en) * | 2002-05-06 | 2003-11-20 | Union Carbide Chemicals & Plastics Technology Corporation | Mixed catalyst compositions for the production of polyolefins |
| US6896843B2 (en) | 2002-08-30 | 2005-05-24 | Kimberly-Clark Worldwide, Inc. | Method of making a web which is extensible in at least one direction |
| KR101113341B1 (ko) | 2002-10-15 | 2012-09-27 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체 |
| US7041759B2 (en) * | 2002-11-20 | 2006-05-09 | The University Of Maryland, College Park | Method for the preparation of well-defined metal acetamidinate-based catalysts on solid supports |
| KR100477943B1 (ko) * | 2002-12-05 | 2005-03-21 | 주식회사 엘지화학 | 극성 작용기를 포함하는 고리형 올레핀 중합 방법 |
| US7183364B2 (en) * | 2002-12-20 | 2007-02-27 | University Of Maryland, College Park | Process for preparation of polyolefins via degenerative transfer polymerization |
| US7541412B2 (en) * | 2002-12-20 | 2009-06-02 | University Of Maryland, College Park | Process for preparation of polyolefins via degenerative transfer polymerization |
| US7226880B2 (en) * | 2002-12-31 | 2007-06-05 | Kimberly-Clark Worldwide, Inc. | Breathable, extensible films made with two-component single resins |
| RU2339650C2 (ru) | 2003-03-21 | 2008-11-27 | Дау Глобал Текнолоджиз, Инк. | Способ полимеризации олефинов с регулируемой морфологией |
| US7932196B2 (en) | 2003-08-22 | 2011-04-26 | Kimberly-Clark Worldwide, Inc. | Microporous stretch thinned film/nonwoven laminates and limited use or disposable product applications |
| US7220478B2 (en) | 2003-08-22 | 2007-05-22 | Kimberly-Clark Worldwide, Inc. | Microporous breathable elastic films, methods of making same, and limited use or disposable product applications |
| US7270723B2 (en) | 2003-11-07 | 2007-09-18 | Kimberly-Clark Worldwide, Inc. | Microporous breathable elastic film laminates, methods of making same, and limited use or disposable product applications |
| US6982304B2 (en) * | 2003-12-22 | 2006-01-03 | Union Carbide Chemicals & Plastics Technology Corporation | Blow molding resins with improved ESCR |
| US20070073012A1 (en) * | 2005-09-28 | 2007-03-29 | Pannell Richard B | Method for seed bed treatment before a polymerization reaction |
| US7985811B2 (en) * | 2004-01-02 | 2011-07-26 | Univation Technologies, Llc | Method for controlling sheeting in gas phase reactors |
| US20050148742A1 (en) * | 2004-01-02 | 2005-07-07 | Hagerty Robert O. | Method for controlling sheeting in gas phase reactors |
| DE102004020525A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Katalysatorsystem zur Olefinpolymerisation, dessen Herstellung und Verwendung |
| KR100733923B1 (ko) | 2004-07-07 | 2007-07-02 | 주식회사 엘지화학 | 극성 작용기를 갖는 고리형 올레핀 중합체 제조용 촉매시스템, 이를 이용한 중합체 제조방법과 이 방법에 의해제조된 올레핀 중합체 및 상기 중합체를 포함하는 광학이방성 필름 |
| CA2473378A1 (en) * | 2004-07-08 | 2006-01-08 | Nova Chemicals Corporation | Novel borate activator |
| KR101224323B1 (ko) | 2004-12-17 | 2013-01-21 | 다우 글로벌 테크놀로지스 엘엘씨 | 레올로지 개질된 폴리에틸렌 조성물 |
| US7868088B2 (en) * | 2005-03-17 | 2011-01-11 | University Of Maryland, College Park | Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby |
| US8513366B2 (en) * | 2005-03-17 | 2013-08-20 | University Of Maryland, College Park | Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby |
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| US7714082B2 (en) * | 2005-10-04 | 2010-05-11 | Univation Technologies, Llc | Gas-phase polymerization process to achieve a high particle density |
| GB2432363B (en) * | 2005-11-16 | 2010-06-23 | Epichem Ltd | Hafnocene and zirconocene precursors, and use thereof in atomic layer deposition |
| CN101341155B (zh) * | 2005-12-06 | 2012-03-07 | Tri化学研究所股份有限公司 | 铪系化合物、形成铪系薄膜的材料和形成铪系薄膜的方法 |
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| CN101443405B (zh) * | 2006-04-07 | 2012-11-14 | 陶氏环球技术有限责任公司 | 聚烯烃组合物、由其制成的制品及其制备方法 |
| US7446167B2 (en) * | 2006-04-13 | 2008-11-04 | Fina Technology, Inc. | Catalyst deactivation agents and methods for use of same |
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1995
- 1995-03-29 US US08/412,964 patent/US5527752A/en not_active Expired - Fee Related
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1996
- 1996-03-27 MY MYPI96001150A patent/MY132199A/en unknown
- 1996-03-28 UA UA96031215A patent/UA61874C2/uk unknown
- 1996-03-28 CN CN96108011A patent/CN1138050A/zh active Pending
- 1996-03-28 EG EG27096A patent/EG21088A/xx active
- 1996-03-29 KR KR1019960009330A patent/KR100273946B1/ko not_active Expired - Fee Related
- 1996-03-29 BR BR9601208A patent/BR9601208A/pt not_active IP Right Cessation
- 1996-03-29 ZA ZA962558A patent/ZA962558B/xx unknown
- 1996-03-29 JP JP09961596A patent/JP3157457B2/ja not_active Expired - Fee Related
- 1996-03-29 DE DE69600281T patent/DE69600281T2/de not_active Expired - Fee Related
- 1996-03-29 CZ CZ96938A patent/CZ93896A3/cs unknown
- 1996-03-29 RU RU96106049/04A patent/RU2142953C1/ru not_active IP Right Cessation
- 1996-03-29 MY MYPI96001189A patent/MY115009A/en unknown
- 1996-03-29 HU HU9600822A patent/HUP9600822A3/hu unknown
- 1996-03-29 ZA ZA962557A patent/ZA962557B/xx unknown
- 1996-03-29 TR TR96/00261A patent/TR199600261A2/xx unknown
- 1996-03-29 AU AU50381/96A patent/AU698339B2/en not_active Ceased
- 1996-03-29 EP EP96302268A patent/EP0735057B1/en not_active Expired - Lifetime
- 1996-03-29 CA CA002173007A patent/CA2173007C/en not_active Expired - Fee Related
- 1996-03-29 AR AR33596396A patent/AR001464A1/es unknown
- 1996-03-29 ES ES96302268T patent/ES2117471T3/es not_active Expired - Lifetime
- 1996-03-29 SK SK421-96A patent/SK42196A3/sk unknown
- 1996-03-29 AT AT96302268T patent/ATE166073T1/de not_active IP Right Cessation
- 1996-03-29 PL PL96313555A patent/PL313555A1/xx unknown
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- 1997-05-26 CN CN97105424A patent/CN1173506A/zh active Pending
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| CA2173007A1 (en) | 1996-09-30 |
| KR960035724A (ko) | 1996-10-24 |
| ZA962558B (en) | 1996-10-03 |
| PL313555A1 (en) | 1996-09-30 |
| EP0735057A1 (en) | 1996-10-02 |
| EP0735057B1 (en) | 1998-05-13 |
| HU9600822D0 (en) | 1996-05-28 |
| CA2173007C (en) | 1999-08-24 |
| US5527752A (en) | 1996-06-18 |
| HUP9600822A3 (en) | 1997-09-29 |
| UA61874C2 (en) | 2003-12-15 |
| JPH08269121A (ja) | 1996-10-15 |
| EG21088A (en) | 2000-10-31 |
| MY115009A (en) | 2003-03-31 |
| JP3157457B2 (ja) | 2001-04-16 |
| RU2142953C1 (ru) | 1999-12-20 |
| ES2117471T3 (es) | 1998-08-01 |
| ZA962557B (en) | 1996-10-24 |
| ATE166073T1 (de) | 1998-05-15 |
| CZ93896A3 (en) | 1996-10-16 |
| MY132199A (en) | 2007-09-28 |
| DE69600281D1 (de) | 1998-06-18 |
| TR199600261A2 (tr) | 1996-10-21 |
| AR001464A1 (es) | 1997-10-22 |
| CN1138050A (zh) | 1996-12-18 |
| SK42196A3 (en) | 1997-03-05 |
| DE69600281T2 (de) | 1998-09-24 |
| AU698339B2 (en) | 1998-10-29 |
| CN1173506A (zh) | 1998-02-18 |
| KR100273946B1 (ko) | 2000-12-15 |
| AU5038196A (en) | 1996-10-10 |
| HUP9600822A2 (en) | 1997-04-28 |
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