BR8705501A - Processo para regeneracao das solucoes catalisadoras de carbonilizacao;processo para carbonilizacao para acido acetico e processo para regeneracao de solucao catalisadora - Google Patents
Processo para regeneracao das solucoes catalisadoras de carbonilizacao;processo para carbonilizacao para acido acetico e processo para regeneracao de solucao catalisadoraInfo
- Publication number
- BR8705501A BR8705501A BR8705501A BR8705501A BR8705501A BR 8705501 A BR8705501 A BR 8705501A BR 8705501 A BR8705501 A BR 8705501A BR 8705501 A BR8705501 A BR 8705501A BR 8705501 A BR8705501 A BR 8705501A
- Authority
- BR
- Brazil
- Prior art keywords
- carbonilization
- regeneration
- solutions
- catalyst solution
- acetic acid
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 title 3
- 230000008929 regeneration Effects 0.000 title 2
- 238000011069 regeneration method Methods 0.000 title 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 abstract 1
- 230000006315 carbonylation Effects 0.000 abstract 1
- 238000005810 carbonylation reaction Methods 0.000 abstract 1
- 239000003729 cation exchange resin Substances 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 229910052744 lithium Inorganic materials 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0231—Halogen-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/08—Ion-exchange resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/40—Regeneration or reactivation
- B01J31/4015—Regeneration or reactivation of catalysts containing metals
- B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
- B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
- B01J31/4046—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals containing rhodium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/918,740 US4894477A (en) | 1986-10-14 | 1986-10-14 | Process for regenerating a carbonylation catalyst solution to remove corrosion metals and carbonylation of methanol to acetic acid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR8705501A true BR8705501A (pt) | 1988-05-24 |
Family
ID=25440880
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR8705501A BR8705501A (pt) | 1986-10-14 | 1987-10-14 | Processo para regeneracao das solucoes catalisadoras de carbonilizacao;processo para carbonilizacao para acido acetico e processo para regeneracao de solucao catalisadora |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US4894477A (pt) |
| EP (1) | EP0265140B1 (pt) |
| JP (1) | JPH0811199B2 (pt) |
| CN (2) | CN1017314B (pt) |
| AT (1) | ATE69176T1 (pt) |
| AU (1) | AU620020B2 (pt) |
| BR (1) | BR8705501A (pt) |
| CA (1) | CA1306237C (pt) |
| DD (1) | DD266282A5 (pt) |
| DE (1) | DE3774393D1 (pt) |
| ES (1) | ES2027299T3 (pt) |
| GR (1) | GR3003078T3 (pt) |
| HK (1) | HK33092A (pt) |
| MX (1) | MX165480B (pt) |
| SG (1) | SG20392G (pt) |
Families Citing this family (41)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5202481A (en) * | 1987-12-23 | 1993-04-13 | Hoechst Celanese Corporation | Purification of acetic acid produced by the low water carbonylation of methanol by treatment with ozone |
| US5155265A (en) * | 1987-12-23 | 1992-10-13 | Hoechst Celanese Corporation | Purification of acetic acid with ozone followed by treatment with activated carbon and/or an ion-exchange resin |
| DE3823645C1 (pt) * | 1988-07-13 | 1989-11-30 | Hoechst Ag | |
| DE3903909A1 (de) * | 1989-02-10 | 1990-08-16 | Hoechst Ag | Verfahren zur entfernung metallischer korrosionsprodukte aus einer bei der carbonylierung von methanol und/oder methylacetat und/oder dimethylether anfallenden, verunreinigten katalysatorloesung |
| US5218143A (en) * | 1989-02-23 | 1993-06-08 | The British Petroleum Company P.L.C. | Process for preparing carboxylic acids |
| GB8904125D0 (en) † | 1989-02-23 | 1989-04-05 | British Petroleum Co Plc | Process for preparing carboxylic acids |
| DE4034501A1 (de) * | 1990-10-30 | 1992-05-07 | Hoechst Ag | Verfahren zur entfernung metallischer korrosionsprodukte aus wasserfrei betriebenen carbonylierungsreaktionen |
| GB9122168D0 (en) * | 1991-10-18 | 1991-11-27 | Bp Chem Int Ltd | Process |
| GB9211671D0 (en) * | 1992-06-02 | 1992-07-15 | Bp Chem Int Ltd | Process |
| GB9305902D0 (en) * | 1993-03-22 | 1993-05-12 | Bp Chem Int Ltd | Process |
| CN1043013C (zh) * | 1993-06-24 | 1999-04-21 | 黑龙江省科学院石油化学研究所 | 醋酸溶液中钴锰离子的离子交换回收方法 |
| US5352415A (en) * | 1993-09-29 | 1994-10-04 | Hoechst Celanese Corporation | Control system for acetic acid manufacturing process |
| US5625095A (en) * | 1994-06-15 | 1997-04-29 | Daicel Chemical Industries, Ltd. | Process for producing high purity acetic acid |
| EP0920407B1 (en) * | 1995-10-27 | 2002-12-11 | Hoechst Celanese Corporation | Process for improving productivity of a carbonylation catalyst solution by removing corrosion metals |
| US6066762A (en) * | 1996-12-30 | 2000-05-23 | Chiyoda Corporation | Process for the production of carbonyl compound |
| GB0410289D0 (en) * | 2004-05-07 | 2004-06-09 | Bp Chem Int Ltd | Process |
| JP4657632B2 (ja) * | 2004-05-27 | 2011-03-23 | ダイセル化学工業株式会社 | カルボン酸の製造方法 |
| CN1309324C (zh) * | 2005-05-16 | 2007-04-11 | 索连江 | 保健食品香烟及其制备方法 |
| US8835681B2 (en) | 2010-06-14 | 2014-09-16 | Celanese International Corporation | Methanol carbonylation process with rhodium catalyst and a lanthanide metal co-catalyst |
| SG186330A1 (en) | 2010-06-14 | 2013-01-30 | Celanese Int Corp | Carbonylation process |
| US8785684B2 (en) | 2010-06-14 | 2014-07-22 | Celanese International Corporation | Methanol carbonylation process with rhodium catalyst, an iodide salt and a metallic co-catalyst selected from transition metals, indium, strontium, barium, zinc, tin and heteropoly acids |
| US8378141B2 (en) | 2010-08-16 | 2013-02-19 | Celanese International Corporation | Process and system for supplying vapor from drying column to light ends column |
| US8461379B2 (en) | 2010-10-12 | 2013-06-11 | Celanese International Corporation | Production of acetic acid comprising feeding at least one reactant to a recycle stream |
| TWI527793B (zh) | 2010-10-13 | 2016-04-01 | 瑟蘭斯國際股份有限公司 | 回收鹵素促進劑和移除過錳酸鹽還原化合物的製程 |
| US8637698B2 (en) | 2010-11-19 | 2014-01-28 | Celanese International Corporation | Production of acetic acid with an increased production rate |
| US9073843B2 (en) | 2010-12-15 | 2015-07-07 | Daicel Corporation | Process for producing acetic acid |
| US8697908B2 (en) * | 2011-05-05 | 2014-04-15 | Celanese International Corporation | Removal of amine compounds from carbonylation process stream containing corrosion metal contaminants |
| US8952196B2 (en) | 2011-05-05 | 2015-02-10 | Celanese International Corporation | Removal of aromatics from carbonylation process |
| TWI547477B (zh) | 2012-03-14 | 2016-09-01 | 大賽璐股份有限公司 | 醋酸之製造方法 |
| US8859810B2 (en) | 2012-08-21 | 2014-10-14 | Celanese International Corporation | Process for recovering permanganate reducing compounds from an acetic acid production process |
| JP6738330B2 (ja) * | 2014-11-14 | 2020-08-12 | セラニーズ・インターナショナル・コーポレーション | 鉄の除去による酢酸収量の改良法 |
| US9540302B2 (en) | 2015-04-01 | 2017-01-10 | Celanese International Corporation | Processes for producing acetic acid |
| US9540303B2 (en) * | 2015-04-01 | 2017-01-10 | Celanese International Corporation | Processes for producing acetic acid |
| KR20180010309A (ko) * | 2015-06-23 | 2018-01-30 | 라이온델바젤 아세틸, 엘엘씨 | 할라이드 함유 용액을 처리하기 위한 은 적재된 할라이드 제거 수지 |
| US9957216B2 (en) | 2015-11-13 | 2018-05-01 | Celanese International Corporation | Processes for producing acetic acid |
| JP6786308B2 (ja) * | 2016-08-30 | 2020-11-18 | 月島環境エンジニアリング株式会社 | 陽イオン交換樹脂の再生方法、被処理液の処理方法及び陽イオン交換樹脂を含む処理設備 |
| CN109467499B (zh) * | 2018-08-03 | 2025-01-10 | 天津大学 | 聚乙烯醇母液回收过程中醋酸甲酯水解与醋酸精制的防腐工艺及装置 |
| CN110078612B (zh) * | 2019-06-06 | 2021-09-07 | 上海华谊（集团）公司 | 催化剂循环液的纯化方法 |
| CN110124755B (zh) * | 2019-06-06 | 2021-12-17 | 上海华谊（集团）公司 | 链烷酸的制造方法 |
| JP7641198B2 (ja) * | 2021-07-14 | 2025-03-06 | オルガノ株式会社 | リチウム水溶液の精製方法 |
| CN116159488B (zh) * | 2022-12-30 | 2025-09-30 | 上海浦景化工新材料有限公司 | 一种甲醇低压羰基化制备醋酸的系统及方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4007130A (en) * | 1975-12-29 | 1977-02-08 | Monsanto Company | Catalyst regeneration method |
| DE2614799C2 (de) * | 1976-04-06 | 1986-02-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Regenerierung von Rhodium enthaltenden Katalysatoren durch Behandeln von rhodiumhaltigen Destillationsrückständen von Hydroformylierungsgemischen |
| DE2950318C2 (de) * | 1979-12-14 | 1982-02-25 | Dynamit Nobel Ag, 5210 Troisdorf | Gewinnung und Wiederverwendung von Kobalt- oder Kobalt und Manganverbindungen aus dem Witten-DMT-Prozeß |
| US4388217A (en) * | 1980-11-24 | 1983-06-14 | Eastman Kodak Company | Process for the recovery of catalyst values |
| CA1228867A (en) * | 1984-05-03 | 1987-11-03 | G. Paull Torrence | Methanol carbonylation process |
-
1986
- 1986-10-14 US US06/918,740 patent/US4894477A/en not_active Expired - Lifetime
-
1987
- 1987-10-02 AU AU79319/87A patent/AU620020B2/en not_active Expired
- 1987-10-05 CA CA000548577A patent/CA1306237C/en not_active Expired - Lifetime
- 1987-10-13 AT AT87309013T patent/ATE69176T1/de not_active IP Right Cessation
- 1987-10-13 MX MX008816A patent/MX165480B/es unknown
- 1987-10-13 ES ES198787309013T patent/ES2027299T3/es not_active Expired - Lifetime
- 1987-10-13 EP EP87309013A patent/EP0265140B1/en not_active Expired - Lifetime
- 1987-10-13 DE DE8787309013T patent/DE3774393D1/de not_active Expired - Lifetime
- 1987-10-14 DD DD87307941A patent/DD266282A5/de not_active IP Right Cessation
- 1987-10-14 BR BR8705501A patent/BR8705501A/pt not_active IP Right Cessation
- 1987-10-14 JP JP62257478A patent/JPH0811199B2/ja not_active Expired - Fee Related
- 1987-10-14 CN CN87106904A patent/CN1017314B/zh not_active Expired
-
1991
- 1991-11-07 GR GR91401687T patent/GR3003078T3/el unknown
-
1992
- 1992-02-11 CN CN92100807A patent/CN1029841C/zh not_active Expired - Lifetime
- 1992-02-29 SG SG203/92A patent/SG20392G/en unknown
- 1992-05-07 HK HK330/92A patent/HK33092A/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| AU7931987A (en) | 1988-04-21 |
| EP0265140A1 (en) | 1988-04-27 |
| HK33092A (en) | 1992-05-15 |
| SG20392G (en) | 1992-04-16 |
| CN1017314B (zh) | 1992-07-08 |
| MX165480B (es) | 1992-11-13 |
| ATE69176T1 (de) | 1991-11-15 |
| DE3774393D1 (de) | 1991-12-12 |
| CN1029841C (zh) | 1995-09-27 |
| CN87106904A (zh) | 1988-07-20 |
| GR3003078T3 (en) | 1993-02-17 |
| JPH0811199B2 (ja) | 1996-02-07 |
| CA1306237C (en) | 1992-08-11 |
| CN1062721A (zh) | 1992-07-15 |
| EP0265140B1 (en) | 1991-11-06 |
| US4894477A (en) | 1990-01-16 |
| DD266282A5 (de) | 1989-03-29 |
| JPS63116746A (ja) | 1988-05-21 |
| ES2027299T3 (es) | 1992-06-01 |
| AU620020B2 (en) | 1992-02-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FB19 | Grant procedure suspended (art. 19) | ||
| FF | Decision: intention to grant | ||
| KD | Notifcation of receipt (letter patent) | ||
| HO | Change of classification |
Free format text: INT.CL. B01J 31/40;C07C 51/12 E 53/08 |
|
| FG9A | Patent or certificate of addition granted | ||
| B21A | Patent or certificate of addition expired [chapter 21.1 patent gazette] |
Free format text: PATENTE EXTINTA EM 25/08/2008 |