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BR0011184A - Processo para a hidro-oxidação de olefinas a óxidos de olefinas usando catalisador de ouro oxidado, composição de catalisador e método para preparar uma composição de catalisador - Google Patents

Processo para a hidro-oxidação de olefinas a óxidos de olefinas usando catalisador de ouro oxidado, composição de catalisador e método para preparar uma composição de catalisador

Info

Publication number
BR0011184A
BR0011184A BR0011184-8A BR0011184A BR0011184A BR 0011184 A BR0011184 A BR 0011184A BR 0011184 A BR0011184 A BR 0011184A BR 0011184 A BR0011184 A BR 0011184A
Authority
BR
Brazil
Prior art keywords
catalyst
catalyst composition
olefin
hydro
oxidation
Prior art date
Application number
BR0011184-8A
Other languages
English (en)
Other versions
BR0011184B1 (pt
Inventor
Alex Kuperman
Robert G Bownan
Howard W Clark
George E Hartwell
Brian J Schoeman
Henridk E Tuinstra
Garmt R Meima
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of BR0011184A publication Critical patent/BR0011184A/pt
Publication of BR0011184B1 publication Critical patent/BR0011184B1/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C27/00—Processes involving the simultaneous production of more than one class of oxygen-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B01J35/77—Compounds characterised by their crystallite size
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

"PROCESSO PARA A HIDRO-OXIDAçãO DE OLEFINAS A óXIDOS DE OLEFINAS USANDO CATALISADOR DE OURO OXIDADO, COMPOSIçãO DE CATALISADOR E MéTODO PARA PREPARAR UMA COMPOSIçãO DE CATALISADOR". A presente invenção refere-se a um processo e um catalisador para a hidro-oxidação de uma olefina tendo três ou mais átomos de carbono, tais como propileno, para formar um óxido de olefina, tal como óxido de propileno. O processo envolve contatar a olefina com oxigênio sob condições de reação na presença de hidrogênio e um catalisador. O catalisador contêm ouro oxidado disperso em um suporte contendo titânio, preferivelmente, um suporte tendo uma pluralidade de ambientes de coordenação de titânio, por exemplo, titânio enxertado sobre um titanossilicato. A seletividade ao óxido de olefina é alta a uma boa conversão de olefina. O catalisador usa hidrogênio eficientemente e exibe uma longa vida útil.
BRPI0011184-8A 1999-04-08 2000-04-07 processo para a hidro-oxidaÇço de olefinas a àxidos de olefinas usando catalisador de ouro oxidado, composiÇço de catalisador e mÉtodo para preparar uma composiÇço de catalisador. BR0011184B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12839499P 1999-04-08 1999-04-08
PCT/US2000/009419 WO2000059632A1 (en) 1999-04-08 2000-04-07 Process for the hydro-oxidation of olefins to olefin oxides using oxidized gold catalyst

Publications (2)

Publication Number Publication Date
BR0011184A true BR0011184A (pt) 2002-03-05
BR0011184B1 BR0011184B1 (pt) 2011-06-14

Family

ID=22435162

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0011184-8A BR0011184B1 (pt) 1999-04-08 2000-04-07 processo para a hidro-oxidaÇço de olefinas a àxidos de olefinas usando catalisador de ouro oxidado, composiÇço de catalisador e mÉtodo para preparar uma composiÇço de catalisador.

Country Status (13)

Country Link
US (1) US6255499B1 (pt)
EP (2) EP1384506A3 (pt)
JP (2) JP4646409B2 (pt)
KR (1) KR100704141B1 (pt)
CN (1) CN1122566C (pt)
AT (1) ATE259258T1 (pt)
AU (1) AU4335100A (pt)
BR (1) BR0011184B1 (pt)
DE (1) DE60008235T2 (pt)
ES (1) ES2211535T3 (pt)
ID (1) ID30342A (pt)
RU (1) RU2234369C2 (pt)
WO (1) WO2000059632A1 (pt)

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KR100704141B1 (ko) 2007-04-09
CN1122566C (zh) 2003-10-01
DE60008235D1 (de) 2004-03-18
ATE259258T1 (de) 2004-02-15
AU4335100A (en) 2000-10-23
ID30342A (id) 2001-11-22
WO2000059632A1 (en) 2000-10-12
KR20010102581A (ko) 2001-11-15
JP2011031243A (ja) 2011-02-17
US6255499B1 (en) 2001-07-03
BR0011184B1 (pt) 2011-06-14
EP1384506A9 (en) 2004-03-31
ES2211535T3 (es) 2004-07-16
JP4646409B2 (ja) 2011-03-09
EP1384506A2 (en) 2004-01-28
EP1177041B1 (en) 2004-02-11
JP5419844B2 (ja) 2014-02-19
RU2234369C2 (ru) 2004-08-20
CN1349429A (zh) 2002-05-15
JP2002541127A (ja) 2002-12-03
EP1177041A1 (en) 2002-02-06
EP1384506A3 (en) 2004-02-04

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