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AR117788A1 - Compuestos de fenilamidina 3-sustituida, preparación y uso - Google Patents

Compuestos de fenilamidina 3-sustituida, preparación y uso

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Publication number
AR117788A1
AR117788A1 ARP200100057A ARP200100057A AR117788A1 AR 117788 A1 AR117788 A1 AR 117788A1 AR P200100057 A ARP200100057 A AR P200100057A AR P200100057 A ARP200100057 A AR P200100057A AR 117788 A1 AR117788 A1 AR 117788A1
Authority
AR
Argentina
Prior art keywords
group
cycloalkyl
alkyl
ring
atoms
Prior art date
Application number
ARP200100057A
Other languages
English (en)
Inventor
Alexander G M Klausener
Hagalavadi M Venkatesha
Ruchi Garg
Sachin Nagnath Gumme
Santosh Shridhar Autkar
Kishor Singh Rathod
Sathiyamoorthi Sivakumar
Vishal A Mahajan
Maruti Naik
Original Assignee
Pi Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pi Industries Ltd filed Critical Pi Industries Ltd
Publication of AR117788A1 publication Critical patent/AR117788A1/es

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    • C07C251/04—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C251/06—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton
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    • C07C211/52—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to carbon atoms of six-membered aromatic rings of the carbon skeleton having amino groups bound to only one six-membered aromatic ring the carbon skeleton being further substituted by halogen atoms or by nitro or nitroso groups
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  • Plural Heterocyclic Compounds (AREA)

Abstract

Reivindicación 1: Un compuesto de la fórmula (1), en la que, R¹ se selecciona a partir del grupo que consiste en hidrógeno, ciano, C₁₋₁₂-alquilo, C₂₋₁₂-alquenilo, C₂₋₁₂-alquinilo, C₁₋₁₂-haloalquilo, C₁₋₁₂-alcoxi, C₃₋₈-cicloalquilo y C₄₋₈-cicloalquilalquilo; en el que uno o más átomos de carbono en el anillo de cicloalquilo pueden reemplazarse por heteroátomos seleccionados a partir del grupo que consiste en N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O) o C(=S); R² se selecciona a partir del grupo que consiste en C₁₋₁₂-alquilo, C₂₋₁₂-alquenilo, C₂₋₁₂-alquinilo, C₁₋₁₂-haloalquilo, (C=O)-R’’ y C₃₋₈-cicloalquilo; en el que uno o más átomos de carbono en el anillo de cicloalquilo pueden reemplazarse por heteroátomos seleccionados a partir del grupo que consiste en N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O) o C(=S); o R¹ y R² junto con los átomos a los que están unidos o junto con otros átomos seleccionados a partir del grupo que consiste en C, N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O) o C(=S) puede formar un anillo no aromático de tres a siete miembros, que por su parte puede estar sustituido por uno o más grupos seleccionados a partir del grupo que consiste en X, CN, R’, OR’, SR’, N(R’)₂, COOR’ y CON(R’)₂; cada grupo de R¹ y R² puede ser opcionalmente sustituido con uno o más grupos seleccionados a partir del grupo que consiste en X, CN, R’, OR’, SR’, N(R’)₂, COOR’ y CON(R’)₂; R³ se selecciona a partir del grupo que consiste en X, ciano, C₁₋₁₂-alquilo, C₂₋₁₂-alquenilo, C₂₋₁₂-alquinilo, C₁₋₁₂-haloalquilo, N(R’R’’’), OR’’, S(O)ₙR’’’, (C=O)-R’’ y C₃₋₈-cicloalquilo; en el que uno o más átomos de carbono en el anillo de cicloalquilo pueden reemplazarse por heteroátomos seleccionados a partir del grupo que consiste en N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O) y C(=S); R⁴ se selecciona a partir del grupo que consiste en X, ciano, C₁₋₁₂-alquilo, C₂₋₁₂-alquenilo, C₂₋₁₂-alquinilo, C₁₋₁₂-haloalquilo, N(R’R’’’), OR’’, S(O)ₙR’’’, (C=O)-R’’, C₃₋₈-cicloalquilo y C₇₋₁₂-aralquilo; en el que uno o más átomos de carbono en el anillo cíclico pueden reemplazarse por heteroátomos seleccionados a partir del grupo que consiste en N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O) y C(=S); R⁴ᵃ y R⁴ᵇ se seleccionan independientemente a partir del grupo que consiste en hidrógeno, X, ciano, C₁₋₄-alquilo, C₂₋₄-alquenilo, C₂₋₄-alquinilo, C₁₋₄-haloalquilo, OR’’, S(O)ₙR’, y C₃₋₅-cicloalquilo; cada grupo de R³ y R⁴ puede ser opcionalmente sustituido con uno o más grupos seleccionados a partir del grupo que consiste en X, CN, R’, OR’, SR’, N(R’)₂, COOR’ y CON(R’)₂; A representa -{[C(R⁶R⁷)]₀₋₂-(B)₀₋₁}-, -{[B-C(R⁶R⁷)]₀₋₁-C(=Y)}-; en la que B representa O, S, NR⁵ o CR⁶R⁷; e Y representa O ó S; R⁵ se selecciona a partir del grupo que consiste en hidrógeno, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-haloalquilo, S(O)ₙR’’’, OR’’, NR’R’’, (C=O)-R’’ y C₃₋₈-cicloalquilo; en el que uno o más átomos de carbono en el anillo de cicloalquilo pueden reemplazarse por heteroátomos seleccionados a partir del grupo que consiste en N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O), C(=S); R⁶ y R⁷ se seleccionan independientemente a partir del grupo que consiste en hidrógeno, X, ciano, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-haloalquilo, N(R’’)₂, OR’’, (C=O)-R’’ y C₃₋₈-cicloalquilo; en el que uno o más átomos de carbono en el anillo de cicloalquilo pueden reemplazarse por heteroátomos seleccionados a partir del grupo que consiste en N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O) o C(=S); o R⁶ y R⁷ junto con los átomos a los que están unidos o junto con otros átomos seleccionados a partir del grupo que consiste en C, N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O) o C(=S) puede formar un anillo de tres a seis miembros, que por su parte puede estar sustituido por uno o más grupos seleccionados a partir del grupo que consiste en X, CN, R’, OR’, SR’, N(R’)₂, COOR’ y CON(R’)₂; cada grupo de R⁵, R⁶ y R⁷ puede ser opcionalmente sustituido con uno o más grupos seleccionados a partir del grupo que consiste en X, CN, R’, OR’, SR’, N(R’)₂, COOR’ y CON(R’)₂; el anillo E se selecciona a partir del grupo que consiste en C₃₋₁₈-carbociclilo y C₃₋₁₈-heterociclilo, fusionado o no fusionado, que puede ser opcionalmente sustituido por uno o más grupos de R⁸; R⁸ se selecciona a partir del grupo que consiste en hidrógeno, X, ciano, nitro, C₁₋₁₂-alquilo, C₂₋₁₂-alquenilo, C₂₋₁₂-alquinilo, C₁₋₁₂-haloalquilo, C₂₋₁₂-haloalquenilo, C₂₋₁₂-haloalquinilo, C₃₋₈-cicloalquilo, C₄₋₈-cicloalquenilo, C₄₋₈-cicloalquinilo, C₇₋₁₉-aralquilo, C₅₋₁₂-bicicloalquilo, C₆₋₁₀-arilo, C₃₋₆-heterociclilo, SCN, SF₅, N(R’R’’’), OR’’, S(O)ₙR’’’, (C=O)-R’’’, C₁₋₈-alquilo-S(O)ₙR’’, C₁₋₈-alquilo-(C=O)-R’’, CR’=NR’’, -S(R⁹)=N(R¹⁰), -S(R⁹)(O)=N(R¹⁰), S(R⁹)₂=N-, S(R⁹)₂(O)=N- y S(R⁹)₂(O)=N-C(R⁶ᵃR⁷ᵃ)-; en el que uno o más átomos de carbono en el anillo cíclico pueden reemplazarse por heteroátomos seleccionados a partir del grupo que consiste en N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O) y C(=S); R⁶ᵃ y R⁷ᵃ se seleccionan independientemente a partir del grupo que consiste en hidrógeno, X, ciano, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₁₋₈-haloalquilo, C₂₋₈-haloalquenilo, (NR’’)₂, OR’’, S(O)ₙR’’’, (C=O)-R’’ y C₃₋₈-cicloalquilo; o R⁶ᵃ y R⁷ᵃ junto con los átomos a los que están unidos o junto con otros átomos seleccionados a partir del grupo que consiste en C, N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O) y C(=S), puede formar un anillo de tres a seis miembros, que por su parte puede ser sustituido por uno o más grupos seleccionados a partir del grupo que consiste en X, CN, R’, OR’, SR’, N(R’)₂, COOR’ y CON(R’)₂; o R⁶ᵃ y R⁷ᵃ junto con el átomo al que están unidos pueden formar un grupo de =O ó =S; R⁹ se selecciona independientemente a partir del grupo que consiste en C₁₋₈-alquilo y C₃₋₈-cicloalquilo; R¹⁰ se selecciona a partir del grupo que consiste en hidrógeno, ciano, C₁₋₈-alquilo, C₂₋₈-alquenilo, C₂₋₈-alquinilo, (C=O)-R’’, S(O)ₙR’’’ y C₃₋₈-cicloalquilo; o R⁹ y R¹⁰ junto con los átomos a los que están unidos o junto con otros átomos seleccionados a partir del grupo que consiste en C, N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O) o C(=S) puede formar un anillo de tres a siete miembros, que por su parte puede estar sustituido por uno o más grupos seleccionados a partir del grupo que consiste en X, CN, R’, OR’, SR’, N(R’)₂, COOR’ y CON(R’)₂; o R⁸ y R⁹ o R¹⁰ junto con los átomos a los que están unidos o junto con otros átomos seleccionados a partir del grupo que consiste en C, N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O) o C(=S) puede formar un anillo de tres a siete miembros, que por su parte puede estar sustituido por uno o más grupos seleccionados a partir del grupo que consiste en X, CN, R’, OR’, SR’, N(R’)₂, COOR’ y CON(R’)₂; R⁵ o R⁶ o R⁷ y R⁸ o dos R⁸ junto con los átomos a los que están unidos o junto con otros átomos seleccionados a partir del grupo que consiste en C, N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O) o C(=S), pueden formar un anillo de tres a diez miembros, que por su parte puede estar sustituido por uno o más grupos seleccionados a partir del grupo que consiste en X, CN, R’, OR’, SR’, N(R’)₂, COOR’ y CON(R’)₂; cada grupo de R⁸, R⁹ o R¹⁰ puede ser opcionalmente sustituido con uno o más grupos seleccionados a partir del grupo que consiste en X, CN, R’, OR’, SR’, N(R’R’’), COOR’ y CON(R’R’’); X representa halógeno; R’ se selecciona a partir del grupo que consiste en hidrógeno, C₁₋₈-alquilo y C₃₋₈-cicloalquilo; en el que el grupo alquilo y cicloalquilo pueden estar opcionalmente sustituidos con uno o más X; R’’ se selecciona a partir del grupo que consiste en hidrógeno, C₁₋₈-alquilo, C₁₋₈-haloalquilo, C₃₋₈-cicloalquilo, N(R’)₂, OR’ y C₆₋₁₈-arilo; en el que uno o más átomos de carbono en el anillo cíclico pueden reemplazarse por heteroátomos seleccionados a partir del grupo que consiste en N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O) o C(=S); R’’’ se selecciona a partir de los grupos que consisten en ciano, R’’, C₂₋₈-alquenilo, C₂₋₈-alquinilo, C₃₋₈-cicloalquilo, C₄₋₈-cicloalquenilo, C₄₋₈-cicloalquinilo, OR’, (C=O)-R’, COOR’, CON(R’)₂, C₆₋₁₈-arilo y C₇₋₁₉-aralquilo; en el que uno o más átomos de carbono en el anillo cíclico pueden reemplazarse por heteroátomos seleccionados a partir del grupo que consiste en N, O, S(O)ₘ y que opcionalmente incluyen de 1 a 3 miembros del anillo seleccionados a partir del grupo que consiste en C(=O) o C(=S); cada grupo de R’’ y R’’’ puede ser sustituido por uno o más grupos seleccionados a partir del grupo que consiste en X, CN, R’, OR’, SR’, N(R’)₂, COOR’ y CON(R’)₂; n representa un número entero 0, 1 ó 2; m representa un número entero 1 ó 2; o las sales, isómeros / isómeros estructurales, isómeros estereoisómeros, diastereómeros, enantiómeros, tautómeros, complejos metálicos, polimorfos o N-óxidos agrícolamente aceptables; con la condición de que los siguientes compuestos estén excluidos de la definición de compuesto de la fórmula (1): N’-(2-ciano-3-((3,3-difluoro-1-metilpiperidin-4-ilo)oxi)-5-metoxifenilo)-N,N-dimetilformimidamida y N’-(5-bromo-2-ciano-3-((2,4-dimetoxibencilo)oxi)fenilo)-N,N-dimetilformimidamida.
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