AR109225A1 - Combinaciones de compuestos activos y métodos para proteger material propagativo vegetal - Google Patents
Combinaciones de compuestos activos y métodos para proteger material propagativo vegetalInfo
- Publication number
- AR109225A1 AR109225A1 ARP170102184A ARP170102184A AR109225A1 AR 109225 A1 AR109225 A1 AR 109225A1 AR P170102184 A ARP170102184 A AR P170102184A AR P170102184 A ARP170102184 A AR P170102184A AR 109225 A1 AR109225 A1 AR 109225A1
- Authority
- AR
- Argentina
- Prior art keywords
- methyl
- diamide
- dihydro
- phthalic acid
- phenyl
- Prior art date
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/86—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
Mezclas. Procesos para prepararlas. Composiciones que las comprenden. Su uso como compuestos biológicamente activos, especialmente en el control de microorganismos dañinos o plagas, en la protección de cultivos o materiales o como reguladores del crecimiento de las plantas. Reivindicación 1: Una composición caracterizada porque comprende (i) un compuesto de fórmula (1), donde X representa un halógeno, preferiblemente cloro, bromo o flúor, N representa 0 ó 1 y Q representa azufre o NH, y (ii) y al menos un agente para controlar plagas. Reivindicación 7: La composición de acuerdo con la reivindicación 1, caracterizada porque el compuesto de fórmula (1) es el compuesto de fórmula (2). Reivindicación 8: La composición de acuerdo con cualquiera de las reivindicaciones 1 a 7, caracterizada porque el agente para controlar plagas es un fungicida que se selecciona entre los siguientes: (1) Inhibidores de la biosíntesis de ergosterol, por ejemplo, (1.1) aldimorf, (1.2) azaconazol, (1.5) ciproconazol, (1.6) diclobutrazol, (1.7) difenoconazol, (1.8) diniconazol, (1.9) diniconazol-M, (1.10) dodemorf, (1.11) acetato de dodemorf, (1.12) epoxiconazol, (1.13) etaconazol, (1.14) fenarimol, (1.15) fenbuconazol, (1.17) fenpropidina, (1.18) fenpropimorf, (1.20) flurprimidol, (1.21) flusilazol, (1.22) flutriafole, (1.23) furconazol, (1.24) furconazol-cis, (1.25) hexaconazol, (1.26) imazalilo, (1.27) sulfato de imazalilo, (1.28) imibenconazol, (1.29) ipconazol, (1.30) metconazol, (1.31) miclobutanilo, (1.32) naftifina, (1.33) nuarimol, (1.34) oxpoconazol, (1.35) paclobutrazol, (1.36) pefurazoato, (1.37) penconazol, (1.38) piperalina, (1.40) propiconazol, (1.42) piributicarb, (1.43) pirifenox, (1.44) quinconazol, (1.45) simeconazol, (1.48) terbinafina, (1.49) tetraconazol, (1.52) tridemorf, (1.53) triflumizol, (1.54) triforina, (1.55) triticonazol, (1.56) uniconazol, (1.57) uniconazol-P, (1.58) viniconazol, (1.59) voriconazol, (1.60) 1-(4-clorofenil)-2-(1H-1,2,4-triazol-1-il)cicloheptanol, (1.61) 1-(2,2-dimetil-2,3-dihidro-1H-inden-1-il)-1H-imidazol-5-carboxilato de metilo, (1.62) N-{5-(difluorometil)-2-metil-4-[3-(trimetilsilil)propoxi]fenil}-N-etil-N-metilimidoformamida, (1.63) N-etil-N-metil-N-{2-metil-5-(trifluorometil)-4-[3-(trimetilsilil)propoxi]fenil}imidoformamida, (1.64) O-[1-(4-metoxifenoxi)-3,3-dimetilbutan-2-il]-1H-imidazol-1-carbotioato o (1.65) pirisoxazol; (2) Inhibidores de la cadena respiratoria en los complejos I o II, por ejemplo, (2.1) bixafen, (2.2) boscalida, (2.3) carboxina, (2.4) diflumetorim, (2.5) fenfuram, (2.7) flutolanilo, (2.8) fluxapiroxad, (2.9) furametpir, (2.10) furmeciclox, (2.11) mezcla de isopirazam del racemato syn-epimérico 1RS,4SR,9RS y del racemato anti-epimérico 1RS,4SR,9SR, (2.12) isopirazam (racemato anti-epimérico), (2.13) isopirazam (enantiómero anti-epimérico 1R,4S,9S), (2.14) isopirazam (enantiómero anti-epimérico 1S,4R,9R), (2.15) isopirazam (racemato syn-epimérico 1RS,4SR,9RS), (2.16) isopirazam (enantiómero syn-epimérico 1R,4S,9R), (2.17) isopirazam (enantiómero syn-epimérico 1S,4R,9S), (2.18) mepronilo, (2.19) oxicarboxina, (2.21) pentiopirad, (2.22) sedaxane, (2.23) tifluzamida, (2.24) 1-metil-N-[2-(1,1,2,2-tetrafluoroetoxi)fenil]-3-(trifluorometil)-1H-pirazol-4-diamida de ácido ftálico, (2.25) 3-(difluorometil)-1-metil-N-[2-(1,1,2,2-tetrafluoroetoxi)fenil]-1H-pirazol-4-diamida de ácido ftálico, (2.26) 3-(difluorometil)-N-[4-fluoro-2-(1,1,2,3,3,3-hexafluoropropoxi)fenil]-1-metil-1H-pirazol-4-diamida de ácido ftálico, (2.27) N-[1-(2,4-diclorofenil)-1-metoxipropan-2-il]-3-(difluorometil)-1-metil-1H-pirazol-4-diamida de ácido ftálico, (2.28) 5,8-difluoro-N-[2-(2-fluoro-4-{[4-(trifluorometil)piridin-2-il]oxi}fenil)etil]quinazolin-4-amina, (2.29) benzovindiflupir, (2.30) N-[(1S,4R)-9-(diclorometilen)-1,2,3,4-tetrahidro-1,4-metanonaftalen-5-il]-3-(difluorometil)-1-metil-1H-pirazol-4-diamida de ácido ftálico y (2.31) N-[(1R,4S)-9-(diclorometilen)-1,2,3,4-tetrahidro-1,4-metanonaftalen-5-il]-3-(difluorometil)-1-metil-1H-pirazol-4-diamida de ácido ftálico, (2.32) 3-(difluorometil)-1-metil-N-(1,1,3-trimetil-2,3-dihidro-1H-inden-4-il)-1H-pirazol-4-diamida de ácido ftálico, (2.33) 1,3,5-trimetil-N-(1,1,3-trimetil-2,3-dihidro-1H-inden-4-il)-1H-pirazol-4-diamida de ácido ftálico, (2.34) 1-metil-3-(trifluorometil)-N-(1,1,3-trimetil-2,3-dihidro-1H-inden-4-il)-1H-pirazol-4-diamida de ácido ftálico, (2.35) 1-metil-3-(trifluorometil)-N-[(3R)-1,1,3-trimetil-2,3-dihidro-1H-inden-4-il]-1H-pirazol-4-diamida de ácido ftálico, (2.36) 1-metil-3-(trifluorometil)-N-[(3S)-1,1,3-trimetil-2,3-dihidro-1H-inden-4-il]-1H-pirazol-4-diamida de ácido ftálico, (2.37) 3-(difluorometil)-1-metil-N-[(3S)-1,1,3-trimetil-2,3-dihidro-1H-inden-4-il]-1H-pirazol-4-diamida de ácido ftálico, (2.38) 3-(difluorometil)-1-metil-N-[(3R)-1,1,3-trimetil-2,3-dihidro-1H-inden-4-il]-1H-pirazol-4-diamida de ácido ftálico, (2.39) 1,3,5-trimetil-N-[(3R)-1,1,3-trimetil-2,3-dihidro-1H-inden-4-il]-1H-pirazol-4-diamida de ácido ftálico, (2.40) 1,3,5-trimetil-N-[(3S)-1,1,3-trimetil-2,3-dihidro-1H-inden-4-il]-1H-pirazol-4-diamida de ácido ftálico, (2.41) benodanilo, (2.42) 2-cloro-N-(1,1,3-trimetil-2,3-dihidro-1H-inden-4-il)piridin-3-diamida de ácido ftálico, (2.43) N-[1-(4-isopropoxi-2-metilfenil)-2-metil-1-oxopropan-2-il]-3-metiltiofeno-2-diamida de ácido ftálico; (3) inhibidores de la cadena respiratoria en el complejo III, por ejemplo, (3.1) ametoctradina, (3.2) amisulbrom, (3.3) azoxistrobina, (3.4) ciazofamida, (3.5) coumetoxistrobina, (3.6) coumoxistrobina, (3.5) dimoxistrobina, (3.8) enestroburina, (3.9) famoxadona, (3.11) flufenoxistrobina, (3.13) kresoxim-metilo, (3.15) orisastrobina, (3.16) picoxistrobina, (3.17) piraclostrobina, (3.18) pirametostrobina, (3.19) piraoxistrobina, (3.20) piribencarb, (3.21) triclopiricarb, (3.23) (2E)-2-(2-{[6-(3-cloro-2-metilfenoxi)-5-fluoropirimidin-4-il]oxi}fenil)-2-(metoxiimino)-N-metiletanamida, (3.24) (2E)-2-(metoxiimino)-N-metil-2-(2-{[({(1E)-1-[3-(trifluorometil)fenil]etiliden}amino)oxi]metil}fenil)etanamida, (3.25) (2E)-2-(metoxiimino)-N-metil-2-{2-[(E)-({1-[3-(trifluorometil)fenil]etoxi}imino)metil]fenil}etanamida, (3.26) (2E)-2-{2-[({[(1E)-1-(3-{[(E)-1-fluoro-2-feniletenil]oxi}fenil)etiliden]amino}oxi)metil]fenil}-2-(metoxiimino)-N-metiletanamida, (3.27) fenaminostrobina, (3.28) 5-metoxi-2-metil-4-(2-{[({(1E)-1-[3-(trifluorometil)fenil]etiliden}amino)oxi]metil}fenil)-2,4-dihidro-3H-1,2,4-triazol-3-ona, (3.29) (2E)-2-{2-[({ciclopropil[(4-metoxifenil)imino]metil}sulfanil)metil]fenil}-3-metoxiprop-2-enoato de metilo, (3.30) N-(3-etil-3,5,5-trimetilciclohexil)-3-(formilamino)-2-hidroxibenzamida, (3.31) 2-{2-[(2,5-dimetilfenoxi)metil]fenil}-2-metoxi-N-metilacetamida o (3.32) 2-{2-[(2,5-dimetilfenoxi)metil]fenil}-2-metoxi-N-metilacetamida; (4) Inhibidores de la mitosis y la división celular, por ejemplo, (4.1) benomilo, (4.3) clorfenazol, (4.4) dietofencarb, (4.5) etaboxam, (4.7) fuberidazol, (4.9) tiabendazol, (4.10) tiofanato-metilo, (4.11) tiofanato, (4.12) zoxamida, (4.13) 5-cloro-7-(4-metilpiperidin-1-il)-6-(2,4,6-trifluorofenil)[1,2,4]triazol[1,5-a]pirimidina o (4.14) 3-cloro-5-(6-cloropiridin-3-il)-6-metil-4-(2,4,6-trifluorofenil)piridazina; (5) Compuestos con actividad en múltiples sitios, por ejemplo, (5.1) mezcla Bordeaux, (5.2) captafol, (5.3) captano, (5.4) clorotalonilo, (5.5) preparaciones de cobre tales como hidróxido de cobre, (5.6) naftenato de cobre, (5.7) óxido de cobre, (5.8) oxicloruro de cobre, (5.9) sulfato de cobre, (5.11) ditianón, (5.12) dodina, (5.13) base libre de dodina, (5.14) ferbam, (5.15) fluorfolpet, (5.16) folpet, (5.17) guazatina, (5.18) acetato de guazatina, (5.19) iminoctadina, (5.20) albesilato de iminoctadina, (5.21) triacetato de iminoctadina, (5.22) mancobre, (5.23) mancozeb, (5.24) maneb, (5.25) metiram, (5.26) metiram cinc, (5.27) cobre-oxina, (5.28) propamidina, (5.30) azufre y preparaciones de azufre tales como, por ejemplo, polisulfuro de calcio, (5.31) tiram, (5.33) zineb, (5.34) ziram o (5.35) anilazina; (6) Compuestos capaces de inducir una defensa en el huésped, por ejemplo, acibenzolar-S-metilo, (6.3) probenazol, (6.4) tiadinilo o (6.5) laminarina; (7) inhibidores de la biosintesis de aminoácidos y proteínas, por ejemplo, (7.1), (7.2) blasticidin-S, (7.3) ciprodinilo, (7.4) kasugamicina, (7.5) clorhidrato de kasugamicina hidrato, (7.6) mepanipirim, (7.8) 3-(5-fluoro-3,3,4,4-tetrametil-3,4-dihidroisoquinolin-1-il)quinolina y (7.9) oxitetraciclina o (7.10) estreptomicina; (8) Inhibidores de la producción de ATP, por ejemplo, (8.1) acetato de fentina, (8,2) de cloruro de fentina, (8.3) de hidróxido de fentina o (8,4) siltiofam; (9) Inhibidores de la síntesis de paredes celulares, por ejemplo, (9.1) bentiavalicarb, (9.2) dimetomorf, (9.3) flumorf, (9.5) mandipropamida, (9.6) polioxinas, (9.7) polioxorim, (9.8) validamicina A, (9.9) valifenalato o (9.10) polioxina B; (10) Inhibidores de la síntesis de lípidos y membranas, por ejemplo, (10.1) bifenilo, (10.2) clorneb, (10.3) dicloran, (10.4) edifenfos, (10.5) etridiazol, (10.6) iodocarb, (10.7) iprobenfos, (10.8) isoprotiolane, (10.11) protiocarb, (10.12) pirazofos, (10.13) quintoceno, (10.14) tecnaceno o (10.15) tolclofos-metilo; (11) Inhibidores de la biosíntesis de melanina, por ejemplo, (11.1) carpropamid, (11.2) diclocimet, (11.3) fenoxanilo, (11.4) ftalida, (11.5) piroquilón, (11.6) triciclazol o (11.7) {3-metil-1-[(4-metilbencil)amino]butan-2-il}carbamato de 2,2,2-trifluoroetilo; (12) Inhibidores de la síntesis de ácidos nucleicos, por ejemplo, (12.1) benalaxilo, (12.2) benalaxil-M (kiralaxilo), (12.3) bupirimato, (12.4) clozilacona, (12.5) dimetirimol, (12.6) etirimol, (12.7) furalaxilo, (12.8) himexazol, (12.9) metalaxilo, (12.10) metalaxil-M (mefenoxam), (12.12) oxadixilo, (12.13) ácido oxolínico o (12.14) octilinona; (13) Inhibidores de la transducción de señales, por ejemplo, (13.1) clozolinato, (13.2) fenpiclonilo, (13.3) fludioxonilo, (13.5) procimidona, (13.6) quinoxifeno, (13.7) vinclozolina o (13.8) proquinazid; (14) Compuestos capaces de actuar como desacopladores, por ejemplo, (14.1) binapacrilo, (14.2) dinocap, (14.3) ferimzona, (14.4) fluazinam o (14.5) meptildinocap; (15) Otros compuestos, por ejemplo, (15.1) bentiazol, (15.2) betoxazina, (15.3) capsimicina, (15.4) carvona, (15.5) quinometionat, (15.6) piriofenona (clazafenona), (15.7) cufraneb, (15.8) ciflufenamida, (15.9) cimoxanilo, (15.10) ciprosulfamida, (15.11) dazomet, (15.12) debacarb, (15.13) diclorofeno, (15.14) diclomezina, (15.15) difenzoquat, (15.16) metilsulfato de difenzoquat, (15.17) difenilamina, (15.18) EcoMate, (15.19) fenpirazamina, (15.20) flumetover, (15.21) fluorimid, (15.22) flusulfamida, (15.23) flutianilo, (15.27) hexaclorobenceno, (15.28) irumamicina, (15.29) metasulfocarb, (15.30) isotiocianato de metilo, (15.31) metrafenona, (15.32) mildiomicina, (15.33) natamicina, (15.34) dimetilditiocarbamato de níquel, (15.35) nitrotal-isopropilo, (15.36) octilinona, (15.37) oxamocarb, (15.38) oxifentiina, (15.39) pentaclorofenol y sus sales, (15.40) fenotrina, (15.41) ácido fosfórico y sus sales, (15.43) propanosina-sodio, (15.44) pirimorf, (15.45) (2E)-3-(4-ter-butilfenil)-3-(2-cloropiridin-4-il)-1-(morfolin-4-il)prop-2-en-1-ona, (15.46) (2Z)-3-(4-ter-butilfenil)-3-(2-cloropiridin-4-il)-1-(morfolin-4-il)prop-2-en-1-ona, (15.47) pirrolnitrina, (15.48) tebufloquina, (15.49) tecloftalam, (15.50) tolnifanida, (15.52) triclamida, (15.53) zarilamida, (15.54) 2-metilpropanoato de (3S,6S,7R,8R)-8-bencil-3-[({3-[(isobutiriloxi)metoxi]-4-metoxipiridin-2-il}carbonil)amino]-6-metil-4,9-dioxo-1,5-dioxonan-7-ilo, (15.55) 1-(4-{4-[(5R)-5-(2,6-difluorofenil)-4,5-dihidro-1,2-oxazol-3-il]-1,3-tiazol-2-il}piperidin-1-il)-2-[5-metil-3-(trifluorometil)-1H-pirazol-1-il]etanona, (15.56) 1-(4-{4-[(5S)-5-(2,6-difluorofenil)-4,5-dihidro-1,2-oxazol-3-il]-1,3-tiazol-2-il}piperidin-1-il)-2-[5-metil-3-(trifluorometil)-1H-pirazol-1-il]etanona, (15.57) 1-(4-{4-[5-(2,6-difluorofenil)-4,5-dihidro-1,2-oxazol-3-il]-1,3-tiazol-2-il}piperidin-1-il)-2-[5-metil-3-(trifluorometil)-1H-pirazol-1-il]etanona, (15.58) 1H-imidazol-1-carboxilato de 1-(4-metoxifenoxi)-3,3-dimetilbutan-2-ilo, (15.59) 2,3,5,6-tetracloro-4-(metilsulfonil)piridina, (15.60) 2,3-dibutil-6-clorotien[2,3-d]pirimidin-4(3H)-ona, (15.62) 2-[5-metil-3-(trifluorometil)-1H-pirazol-1-il]-1-(4-{4-[(5R)-5-fenil-4,5-dihidro-1,2-oxazol-3-il]-1,3-tiazol-2-il}piperidin-1-il)etanona, (15.63) 2-[5-metil-3-(trifluorometil)-1H-pirazol-1-il]-1-(4-{4-[(5S)-5-fenil-4,5-dihidro-1,2-oxazol-3-il]-1,3-tiazol-2-il}piperidin-1-il)etanona, (15.64) 2-[5-metil-3-(trifluorometil)-1H-pirazol-1-il]-1-{4-[4-(5-fenil-4,5-dihidro-1,2-oxazol-3-il)-1,3-tiazol-2-il]piperidin-1-il}etanona, (15.65) 2-butoxi-6-iodo-3-propil-4H-cromen-4-ona, (15.66) 2-cloro-5-[2-cloro-1-(2,6-difluoro-4-metoxifenil)-4-metil-1H-imidazol-5-il]piridina, (15.67) 2-fenilfenol y sales, (15.68) 3-(4,4,5-trifluoro-3,3-dimetil-3,4-dihidroisoquinolin-1-il)quinolina, (15.69) 3,4,5-tricloropiridin-2,6-dicarbonitrilo, (15.70) 3-cloro-5-(4-clorofenil)-4-(2.6-difluorofenil)-6-metilpiridazina, (15.71) 4-(4-clorofenil)-5-(2,6-difluorofenil)-3,6-dimetilpiridazina, (15.72) 5-amino-1,3,4-tiadiazol-2-tiol, (15.73) 5-cloro-N-fenil-N-(prop-2-in-1-il)tiofen-2-sulfonohidrazida, (15.74) 5-fluoro-2-[(4-fluorobencil)oxi]pirimidin-4-amina, (15.75) 5-fluoro-2-[(4-metilbencil)oxi]pirimidin-4-amina, (15.76) 5-metil-6-octil[1,2,4]triazol[1,5-a]pirimidin-7-amina, (15.77) (2Z)-3-amino-2-ciano-3-fenilacrilato de etilo, (15.78) N-(4-{[3-(4-clorobencil)-1,2,4-tiadiazol-5-il]oxi}-2,5-dimetilfenil)-N-etil-N-metilimidoformamida, (15.79) N-(4-clorobencil)-3-[3-metoxi-4-(prop-2-in-1-iloxi)fenil]propanamida, (15.80) N-[(4-clorofenil)(ciano)metil]-3-[3-metoxi-4-(prop-2-in-1-iloxi)fenil]propanamida, (15.81) N-[(5-bromo-3-cloropiridin-2-il)metil]-2,4-dicloronicotinamida, (15.82) N-[1-(5-bromo-3-cloropiridin-2-il)etil]-2,4-dicloronicotinamida, (15.83) N-[1-(5-bromo-3-cloropiridin-2-il)etil]-2-fluoro-4-iodonicotinamida, (15.84) N-{(E)-[(ciclopropilmetoxi)imino][6-(difluorometoxi)-2,3-difluorofenil]metil}-2-fenilacetamida, (15.85) N-{(Z)-[(ciclopropilmetoxi)imino][6-(difluorometoxi)-2,3-difluorofenil]metil}-2-fenilacetamida, (15.86) N-{4-[(3-ter-butil-4-ciano-1,2-tiazol-5-il)oxi]-2-cloro-5-metilfenil}-N-etil-N-metilimidoformamida, (15.87) N-metil-2-(1-{[5-metil-3-(trifluorometil)-1H-pirazol-1-il]acetil}piperidin-4-il)-N-(1,2,3,4-tetrahidronaftalen-1-il)-1,3-tiazol-4-diamida de ácido ftálico, (15.88) N-metil-2-(1-{[5-metil-3-(trifluorometil)-1H-pirazol-1-il]acetil}piperidin-4-il)-N-[(1R)-1,2,3,4-tetrahidronaftalen-1-il]-1,3-tiazol-4-diamida de ácido ftálico, (15.89) N-metil-2-(1-{[5-metil-3-(trifluorometil)-1H-pirazol-1-il]acetil}piperidin-4-il)-N-[(1S)-1,2,3,4-tetrahidronaftalen-1-il]-1,3-tiazol-4-diamida de ácido ftálico, (15.90) {6-[({[(1-metil-1H-tetrazol-5-il)(fenil)metilen]amino}oxi)metil]piridin-2-il}carbamato de pentilo, (15.91) ácido fenazin-1-carboxílico, (15.92) quinolin-8-ol, (15.93) sulfato de quinolin-8-ol (2:1), (15.94) {6-[({[(1-metil-1H-tetrazol-5-il)(fenil)metilen]amino}oxi)metil]piridin-2-il}carbamato de ter-butilo, (15.95) 1-metil-3-(trifluorometil)-N-[2-(trifluorometil)bifenil-2-il]-1H-pirazol-4-diamida de ácido ftálico, (15.96) N-(4-clorobifenil-2-il)-3-(difluorometil)-1-metil-1H-pirazol-4-diamida de ácido ftálico, (15.97) N-(2,4-diclorobifenil-2-il)-3-(difluorometil)-1-metil-1H-pirazol-4-diamida de ácido ftálico, (15.98) 3-(difluorometil)-1-metil-N-[4-(trifluorometil)bifenil-2-il]-1H-pirazol-4-diamida de ácido ftálico, (15.99) N-(2,5-difluorobifenil-2-il)-1-metil-3-(trifluorometil)-1H-pirazol-4-diamida de ácido ftálico, (15.100) 3-(difluorometil)-1-metil-N-[4-(prop-1-in-1-il)bifenil-2-il]-1H-pirazol-4-diamida de ácido ftálico, (15.101) 5-fluoro-1,3-dimetil-N-[4-(prop-1-in-1-il)bifenil-2-il]-1H-pirazol-4-diamida de ácido ftálico, (15.102) 2-cloro-N-[4-(prop-1-in-1-il)bifenil-2-il]nicotinamida, (15.103) 3-(difluorometil)-N-[4-(3,3-dimetilbut-1-in-1-il)bifenil-2-il]-1-metil-1H-pirazol-4-diamida de ácido ftálico, (15.104) N-[4-(3,3-dimetilbut-1-in-1-il)bifenil-2-il]-5-fluoro-1,3-dimetil-1H-pirazol-4-diamida de ácido ftálico, (15.105) 3-(difluorometil)-N-(4-etinilbifenil-2-il)-1-metil-1H-pirazol-4-diamida de ácido ftálico, (15.106) N-(4-etinilbifenil-2-il)-5-fluoro-1,3-dimetil-1H-pirazol-4-diamida de ácido ftálico, (15.107) 2-cloro-N-(4-etinilbifenil-2-il)nicotinamida, (15.108) 2-cloro-N-[4-(3,3-dimetilbut-1-in-1-il)bifenil-2-il]nicotinamida, (15.109) 4-(difluorometil)-2-metil-N-[4-(trifluorometil)bifenil-2-il]-1,3-tiazol-5-diamida de ácido ftálico, (15.110) 5-fluoro-N-[4-(3-hidroxi-3-metilbut-1-in-1-il)bifenil-2-il]-1,3-dimetil-1H-pirazol-4-diamida de ácido ftálico, (15.111) 2-cloro-N-[4-(3-hidroxi-3-metilbut-1-in-1-il)bifenil-2-il]nicotinamida, (15.112) 3-(difluorometil)-N-[4-(3-metoxi-3-metilbut-1-in-1-il)bifenil-2-il]-1-metil-1H-pirazol-4-diamida de ácido ftálico, (15.113) 5-fluoro-N-[4-(3-metoxi-3-metilbut-1-in-1-il)bifenil-2-il]-1,3-dimetil-1H-pirazol-4-diamida de ácido ftálico, (15.114) 2-cloro-N-[4-(3-metoxi-3-metilbut-1-in-1-il)bifenil-2-il]nicotinamida, (15.115) (5-bromo-2-metoxi-4-metilpiridin-3-il)(2,3,4-trimetoxi-6-metilfenil)metanona, (15.116) N-[2-(4-{[3-(4-clorofenil)prop-2-in-1-il]oxi}-3-metoxifenil)etil]-N²-(metilsulfonil)valinamida, (15.117) ácido 4-oxo-4-[(2-feniletil)amino]butanoico, (15.118) {6-[({[(Z)-(1-metil-1H-tetrazol-5-il)(fenil)metilen]amino}oxi)metil]piridin-2-il}carbamato de but-3-in-1-ilo, (15.119) 4-amino-5-fluoropirimidin-2-ol (forma tautomérica: 4-amino-5-fluoropirimidin-2(1H)-ona), (15.120) 3,4,5-trihidroxibenzoato de propilo, (15.121) 1,3-dimetil-N-(1,1,3-trimetil-2,3-dihidro-1H-inden-4-il)-1H-pirazol-4-diamida de ácido ftálico, (15.122) 1,3-dimetil-N-[(3R)-1,1,3-trimetil-2,3-dihidro-1H-inden-4-il]-1H-pirazol-4-diamida de ácido ftálico, (15.123) 1,3-dimetil-N-[(3S)-1,1,3-trimetil-2,3-dihidro-1H-inden-4-il]-1H-pirazol-4-diamida de ácido ftálico, (15.124) [3-(4-cloro-2-fluorofenil)-5-(2,4-difluorofenil)-1,2-oxazol-4-il](piridin-3-il)metanol, (15.125) (S)-[3-(4-cloro-2-fluorofenil)-5-(2,4-difluorofenil)-1,2-oxazol-4-il](piridin-3-il)metanol, (15.126) (R)-[3-(4-cloro-2-fluorofenil)-5-(2,4-difluorofenil)-1,2-oxazol-4-il](piridin-3-il)metanol, (15.127) 2-{[3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-2,4-dihidro-3H-1,2,4-triazol-3-tiona, (15.128) tiocianato de 1-{[3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-1H-1,2,4-triazol-5-ilo, (15.129) 5-(alilsulfanil)-1-{[3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-1H-1,2,4-triazol, (15.130) 2-[1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro-3H-1,2,4-triazol-3-tiona, (15.131) 2-{[rel(2R,3S)-3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-2,4-dihidro-3H-1,2,4-triazol-3-tiona, (15.132) 2-{[rel(2R,3R)-3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-2,4-dihidro-3H-1,2,4-triazol-3-tiona, (15.133) tiocianato de 1-{[rel(2R,3S)-3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-1H-1,2,4-triazol-5-ilo, (15.134) tiocianato de 1-{[rel(2R,3R)-3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-1H-1,2,4-triazol-5-ilo, (15.135) 5-(alilsulfanil)-1-{[rel(2R,3S)-3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-1H-1,2,4-triazol, (15.136) 5-(alilsulfanil)-1-{[rel(2R,3R)-3-(2-clorofenil)-2-(2,4-difluorofenil)oxiran-2-il]metil}-1H-1,2,4-triazol, (15.137) 2-[(2S,4S,5S)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro-3H-1,2,4-triazol-3-tiona, (15.138) 2-[(2R,4S,5S)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro-3H-1,2,4-triazol-3-tiona, (15.139) 2-[(2R,4R,5R)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro-3H-1,2,4-triazol-3-tiona, (15.140) 2-[(2S,4R,5R)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro-3H-1,2,4-triazol-3-tiona, (15.141) 2-[(2S,4S,5R)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro-3H-1,2,4-triazol-3-tiona, (15.142) 2-[(2R,4S,5R)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro-3H-1,2,4-triazol-3-tiona, (15.143) 2-[(2R,4R,5S)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro-3H-1,2,4-triazol-3-tiona, (15.144) 2-[(2S,4R,5S)-1-(2,4-diclorofenil)-5-hidroxi-2,6,6-trimetilheptan-4-il]-2,4-dihidro-3H-1,2,4-triazol-3-tiona, (15.145) 2-fluoro-6-(trifluorometil)-N-(1,1,3-trimetil-2,3-dihidro-1H-inden-4-il)benzamida, (15.146) 2-(6-bencilpiridin-2-il)quinazolina, (15.147) 2-[6-(3-fluoro-4-metoxifenil)-5-metilpiridin-2-il]quinazolina, (15.148) 3-(4,4-difluoro-3,3-dimetil-3,4-dihidroisoquinolin-1-il)quinolina o (15.149) ácido abscísico. Reivindicación 9: La composición de acuerdo con cualquiera de las reivindicaciones 1 a 8, caracterizada porque el agente para controlar plagas es un insecticida que se selecciona entre los siguientes. (1) Inhibidores de la acetilcolinesterasa (AChE), por ejemplo, carbamatos, por ejemplo, Alanicarb (II-1-1), Aldicarb (II-1-2), Bendiocarb (II-1-3), Benfuracarb (II-1-4), Butocarboxim (II-1-5), Butoxicarboxim (II-1-6), Carbarilo (II-1-7), Carbofuran (II-1-8), Carbosulfan (II-1-9), Etiofencarb (II-1-10), Fenobucarb (II-1-11), Formetanato (II-1-12), Furatiocarb (II-1-13), lsoprocarb (II-1-14), Metiocarb (II-1-15), Metomilo (II-1-16), Metolcarb (II-1-17), Oxamilo (II-1-18), Pirimicarb (II-1-19), Propoxur (II-1-20), Tiodicarb (II-1-21), Tiofanox (II-1-22), Triazamato (II-1-23), Trimetacarb (II-1-24), XMC (II-1-25), Xililcarb (II-1-26), organofosfatos, por ejemplo, Acefato (II-1-27), Azametifos (II-1-28), Azinfos-etilo (II-1-29), Azinfos-metilo (II-1-30), Cadusafos (II-1-31), Cloretoxifos (II-1-32), Clorfenvinfos (II-1-33), Clormefos (II-1-34), Clorpirifos (II-1-35), Clorpirifos-metilo (II-1-36), Cumafos (II-1-37), Cianofos (II-1-38), Demeton-S-metilo (II-1-39), Diazinon (II-1-40), Diclorvos / DDVP (II-1-41), Dicrotofos (II-1-42), Dimetoato (II-1-43), Dimetilvinfos (II-1-44), Disulfotón (II-1-45), EPN (II-1-46), Etión (II-1-47), Etoprofos (II-1-48), Famfur (II-1-49), Fenamifos (II-1-50), Fenitrotión (II-1-51), Fentión (II-1-52), Fostiazato (II-1-53), Heptenofos (II-1-54), lmiciafos (II-1-55), lsofenfos (II-1-56), lsopropil-O-(metoxiaminotio-fosforil) salicilato (II-1-57), lsoxatión (II-1-58), Malatión (II-1-59), Mecarbam (II-1-60), Metamidofos (II-1-61), Metidatión (II-1-62), Mevinfos (II-1-63), Monocrotofos (II-1-64), Naled (II-1-65), Ometoato (II-1-66), Óxidometon-metilo (II-1-67), Paratión (II-1-68), Paration-metilo (II-1-69), Fentoato (II-1-70), Forato (II-1-71), Fosalone (II-1-72), Fosmet (II-1-73), Fosfamidon (II-1-74), Foxim (II-1-75), Pirimifos-metilo (II-1-76), Profenofos (II-1-77), Propetamfos (II-1-78), Protiofos (II-1-79), Piraclofos (II-1-80), Piridafentión (II-1-81), Quinalfos (II-1-82), Sulfotep (II-1-83), Tebupirimfos (II-1-84), Temefos (II-1-85), Terbufos (II-1-86), Tetraclorvinfos (II-1-87), Tiometón (II-1-88), Triazofos (II-1-89), Triclorfon (II-1-90), Vamidotión (II-1-91); (2) Antagonistas de canales de cloruro bloqueados por GABA, por ejemplo, organoclorados de ciclodieno, por ejemplo, Clordano (II-2-1), Endosulfán (lI-2-2), fenilpirazoles (fiproles), por ejemplo, Etiprol (II-2-3), Fipronil (II-2-4); (3) Moduladores de canales de sodio / bloqueadores de canales de sodio dependientes del voltaje, por ejemplo, piretroides, por ejemplo, Acrinatrina (II-3-1), Aletrina (II-3-2), d-cis-trans Aletrina (II-3-3), d-trans Aletrina (II-3-4), Bifentrina (II-3-5), Bioaletrina (II-3-6), Bioaletrina S-ciclopentenilo, isómero (II-3-7), Bioresmetrina (II-3-8), Cicloprotrina (II-3-9), Ciflutrina (II-3-10), b-Ciflutrina (II-3-11), Cihalotrina (II-3-12), l-Cihalotrina (II-3-13), g-Cihalotrina (II-3-14), Cipermetrina (II-3-15), a-Cipermetrina (II-3-16), b-Cipermetrina (II-3-17), q-Cipermetrina (II-3-18), z-Cipermetrina (II-3-19), Cifenotrina [isómeros (1R)-trans] (II-3-20), Deltametrina (II-3-21), Empentrina (isómeros (EZ)-(1R)) (II-3-22), Esfenvalerato (II-3-23), Etofenprox (II-3-24), Fenpropatrina (II-3-25), Fenvalerato (II-3-26), Flucitrinato (II-3-27), Flumetrina (II-3-28), t-Fluvalinato (II-3-29), Halfenprox (II-3-30), lmiprotrina (II-3-31), Kadetrina (II-3-32), Permetrina (II-3-33), Fenotrina (isómero (1R)-trans) (II-3-34), Praletrina (II-3-35), Piretrine (piretrum) (II-3-36), Resmetrina (II-3-37), Silafluofen (II-3-38), Teflutrina (II-3-39), Tetrametrina (II-3-40), Tetrametrina [(1R), isómeros)] (II-3-41), Tralometrina (II-3-42), Transflutrina (II-3-43), DDT (II-3-44), Metoxichlor (II-3-45); (4) Agonistas de receptores de acetilcolina nicotínicos (nAChR), por ejemplo, neonicotinoides, por ejemplo, Acetamiprid (II-4-1), aClotianidin (II-4-2), Dinotefuran (II-4-3), lmidacloprid (II-4-4), Nitenpiram (II-4-5), Tiacloprid (II-4-6), Tiametoxam (II-4-7), Nicotina (II-4-8), Sulfoxaflor (II-4-9); (5) Activadores alostéricos de receptores de acetilcolina nicotínicos (nAChR), por ejemplo, las espinosinas, por ejemplo, Spinetoram (II-5-1), Spinosad (II-5-2); (6) Activadores de canales de cloruro, por ejemplo, avermectinas / milbemicinas, por ejemplo, Abamectina (II-6-1), Benzoato de Emamectina (II-6-2), Lepimectina (II-6-3), Milbemectina (II-6-4); (7) Miméticos de la hormona juvenil, por ejemplo, análogos de la hormona juvenil, por ejemplo, Hidropreno (II-7-1), Kinopreno (II-7-2), Metopreno (II-7-3), Fenoxicarb (II-7-4), Piriproxifeno (II-7-5); (8) Inhibidores no específicos (multi-sitio), por ejemplo, haluros de alquilo, por ejemplo, Bromuro de metilo (II-8-1) y otros haluros de alquilo, Cloropicrina (II-8-2), Fluoruro de sulfurilo (II-8-3), Bórax (II-8-4), Tártaro emético (II-8-5); (9) Bloqueadores de alimentación selectivos para los homópteros, por ejemplo, Pimetrozina (II-9-1), Flonicamid (II-9-2); (10) Inhibidores del crecimiento de los ácaros, por ejemplo, Clofentezina (II-10-1), Hexitiazox (II-10-2), Diflovidazina (II-10-3), Etoxazol (II-10-4); (12) Inhibidores de la ATP sintetasa mitocondrial, por ejemplo, diafentiurón (II-12-1), acaricidas orgánicos de estaño, por ejemplo, Óxido de azociclotina (II-12-2), Cihexatina (II-12-3), Fenbutatina (II-12-4), Propargita (II-12-5), Tetradifón (II-12-6); (13) Desacopladores de la fosforilación oxidativa que interrumpen el gradiente de protones, por ejemplo, Clorfenapir (II-13-1), DNOC (II-13-2), Sulfluramida (II-13-3); (14) Bloqueadores de receptores de acetilcolina nicotínicos (nAChR), por ejemplo, Bensultap (II-14-1), Clorhidrato de cartap (II-14-2), Tiociclam (II-14-3), Tiosultap-sodio (II-14-4); (15) Inhibidores de la biosíntesis de quitina tipo 0, por ejemplo, Bistriflurón (II-15-1), Clorfluazurón (II-15-2), Diflubenzurón (II-15-3), Flucicloxurón (II-15-4), Flufenoxurón (II-15-5), Hexaflumurón (II-15-6), Lufenurón (II-15-7), Novalurón (II-15-8), Noviflumurón (II-15-9), Teflubenzurón (II-15-10), Triflumurón (II-15-11); (16) Inhibidores de la biosíntesis de quitina tipo 1, por ejemplo, Buprofezina (II-16-1); (17) Disruptores de la muda, por ejemplo, ciromazina (II-17-1); (18) Agonistas de receptores de ecdisona, por ejemplo, Cromafenozida (II-18-1), Halofenozida (II-18-2), Metoxifenozida (II-18-3), Tebufenozida (II-18-4); (19) Agonistas de receptores de octopamina, por ejemplo, Amitraz (II-19-1); (20) Inhibidores del complejo III de transporte de electrones mitocondrial, por ejemplo, Hidrametilnona (II-20-1), Acequinocil (II-20-2), Fluacripirim (II-20-3); (21) Inhibidores del complejo I de transporte de electrones mitocondrial, por ejemplo, acaricidas METI, por ejemplo, Fenazaquin (II-21-1), Fenpiroximato (II-21-2), Pirimidifen (II-21-3), Piridaben (II-21-4), Tebufenpirad (II-21-5), Tolfenpirad (II-21-6), Rotenone (Derris) (II-21-7); (22) Bloqueadores de canales de sodio dependientes del voltaje, por ejemplo, lndoxacarb (II-22-1), Metaflumizona (II-22-2); (23) Inhibidores de la acetil CoA carboxilasa, por ejemplo, derivados de ácido tetrónico o tetrámico, por ejemplo, Spirodiclofen (II-23-1), Spiromesifen (II-23-2), Spirotetramat (II-23-3); (24) Inhibidores del complejo IV de transporte de electrones mitocondrial, por ejemplo, fosfinas, por ejemplo, Fosfuro de aluminio (II-24-1), Fosfuro de calcio (II-24-2), Fosfina (II-24-3), Fosfuro de cinc (II-24-4), cianuro (II-24-5); (25) Inhibidores del complejo II de transporte de electrones mitocondrial, por ejemplo, derivados de b-cetonitrilo, por ejemplo, Cienopirafeno (II-25-1), Ciflumetofeno (II-25-2); (28) Moduladores de receptores de rianodina, por ejemplo, diamidas, por ejemplo, Clorantraniliprol (II-28-1), Ciantraniliprol (II-28-2), Flubendiamida (II-28-3); (29) Ingredientes activos adicionales con modos de acción desconocidos o inciertos, por ejemplo, Amidoflumet (II-29-1), Azadiractina (II-29-2), Benclotiaz (II-29-3), Benzoximato (II-29-4), Bifenazato (II-29-5), Bromopropilato (II-29-6), Quinometionato (II-29-7), Criolita (II-29-8), Dicofol (II-29-9), Diflovidazina (II-29-10), Fluensulfone (II-29-11), Flufenerim (II-29-12), Flufiprol (II-29-13), Fluopiram (II-29-14), Fuf
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| CN105461724B (zh) * | 2014-08-11 | 2019-11-05 | 华东理工大学 | 具有杀虫活性的含氮桥环化合物及其制备和用途 |
-
2017
- 2017-07-19 CN CN201780055071.3A patent/CN109688816A/zh active Pending
- 2017-07-19 EP EP17737853.6A patent/EP3490379A1/en not_active Withdrawn
- 2017-07-19 CA CA3032030A patent/CA3032030A1/en not_active Abandoned
- 2017-07-19 WO PCT/EP2017/068216 patent/WO2018019676A1/en not_active Ceased
- 2017-07-19 BR BR112019001764A patent/BR112019001764A2/pt not_active Application Discontinuation
- 2017-07-19 RU RU2019104918A patent/RU2019104918A/ru not_active Application Discontinuation
- 2017-07-19 US US16/320,635 patent/US20190159451A1/en not_active Abandoned
- 2017-07-31 AR ARP170102184A patent/AR109225A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP3490379A1 (en) | 2019-06-05 |
| RU2019104918A (ru) | 2020-08-28 |
| BR112019001764A2 (pt) | 2019-05-07 |
| WO2018019676A1 (en) | 2018-02-01 |
| US20190159451A1 (en) | 2019-05-30 |
| CA3032030A1 (en) | 2018-02-01 |
| CN109688816A (zh) | 2019-04-26 |
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