AR107587A1 - 2-oxiimidazolil-carboxamidas sustituidas como plaguicidas - Google Patents
2-oxiimidazolil-carboxamidas sustituidas como plaguicidasInfo
- Publication number
- AR107587A1 AR107587A1 ARP170100331A ARP170100331A AR107587A1 AR 107587 A1 AR107587 A1 AR 107587A1 AR P170100331 A ARP170100331 A AR P170100331A AR P170100331 A ARP170100331 A AR P170100331A AR 107587 A1 AR107587 A1 AR 107587A1
- Authority
- AR
- Argentina
- Prior art keywords
- optionally substituted
- alkyl
- heteroatoms
- radical
- hydrogen
- Prior art date
Links
- 239000000575 pesticide Substances 0.000 title 1
- 125000005842 heteroatom Chemical group 0.000 abstract 5
- 125000000217 alkyl group Chemical class 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- 150000002431 hydrogen Chemical class 0.000 abstract 4
- 239000001257 hydrogen Substances 0.000 abstract 4
- 125000000547 substituted alkyl group Chemical group 0.000 abstract 4
- 125000003342 alkenyl group Chemical group 0.000 abstract 3
- 125000004093 cyano group Chemical class *C#N 0.000 abstract 3
- 125000001316 cycloalkyl alkyl group Chemical group 0.000 abstract 3
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 3
- 125000003545 alkoxy group Chemical class 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 125000004438 haloalkoxy group Chemical class 0.000 abstract 2
- 125000001188 haloalkyl group Chemical class 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 125000000304 alkynyl group Chemical group 0.000 abstract 1
- 244000000054 animal parasite Species 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 125000000392 cycloalkenyl group Chemical group 0.000 abstract 1
- 239000013067 intermediate product Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 125000004426 substituted alkynyl group Chemical group 0.000 abstract 1
- 229910052717 sulfur Chemical group 0.000 abstract 1
- 239000011593 sulfur Chemical group 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/50—1,3-Diazoles; Hydrogenated 1,3-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P33/00—Antiparasitic agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
- C07D401/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
- C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
- C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D407/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00
- C07D407/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing two hetero rings
- C07D407/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D407/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00
- C07D407/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00 containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D411/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen and sulfur atoms as the only ring hetero atoms
- C07D411/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen and sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D411/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen and sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Environmental Sciences (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Veterinary Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Pharmacology & Pharmacy (AREA)
- Tropical Medicine & Parasitology (AREA)
- Public Health (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Medicinal Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)
Abstract
Su uso para el combate de parásitos animales. Reivindicación 1: Compuestos de la fórmula (1), caracterizado porque Q representa oxígeno o azufre; V representa un radical de la serie de hidrógeno, halógeno, alquilo, halógenoalquilo, alcoxi, halógenoalcoxi y ciano; W representa un radical de la serie de hidrógeno, halógeno, alquilo, halógenoalquilo, alcoxi, halógenoalcoxi y ciano; X representa un radical de la serie de alquilo, alquenilo o alquinilo opcionalmente sustituido, cicloalquilo o cicloalquenilo saturado o insaturado opcionalmente interrumpido por heteroátomos y opcionalmente sustituido, cicloalquilalquilo o cicloalquenilalquilo saturado o insaturado opcionalmente interrumpido por heteroátomos y opcionalmente sustituido, arilalquilo o hetarilalquilo opcionalmente sustituido; Y representa un radical de la serie de hidrógeno, ciano, alquilo, alquenilo o alquinilo opcionalmente sustituido, cicloalquilo opcionalmente interrumpido por heteroátomos y opcionalmente sustituido y cicloalquilalquilo, arilalquilo o hetarilalquilo opcionalmente interrumpido por heteroátomos y opcionalmente sustituido; A representa un radical de la serie de hidrógeno, alquilo, alquenilo o alquinilo opcionalmente sustituido y cicloalquilo opcionalmente interrumpido por heteroátomos y opcionalmente sustituido o cicloalquilalquilo; T representa oxígeno o un par de electrones; y sus sales. Reivindicación 11: Productos intermediarios, caracterizados porque poseen las fórmulas (2) y (3), en donde los radicales existentes tienen los significados de acuerdo con una de las reivindicaciones 1 a 6 y con preferencia especial, el significado de acuerdo con la reivindicación 5.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16155134 | 2016-02-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR107587A1 true AR107587A1 (es) | 2018-05-16 |
Family
ID=55345747
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP170100331A AR107587A1 (es) | 2016-02-11 | 2017-02-10 | 2-oxiimidazolil-carboxamidas sustituidas como plaguicidas |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US10647699B2 (es) |
| EP (1) | EP3414237B1 (es) |
| JP (1) | JP6892866B2 (es) |
| KR (1) | KR20180107142A (es) |
| CN (1) | CN108699045B (es) |
| AR (1) | AR107587A1 (es) |
| AU (1) | AU2017217184A1 (es) |
| BR (1) | BR112018016364A2 (es) |
| CA (1) | CA3013963A1 (es) |
| CL (1) | CL2018002298A1 (es) |
| CO (1) | CO2018008398A2 (es) |
| ES (1) | ES2845902T3 (es) |
| IL (1) | IL260640B (es) |
| MX (1) | MX2018009809A (es) |
| PH (1) | PH12018501706A1 (es) |
| RU (1) | RU2018132172A (es) |
| TW (1) | TWI721097B (es) |
| UY (1) | UY37117A (es) |
| WO (1) | WO2017137339A1 (es) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA3013962A1 (en) * | 2016-02-11 | 2017-08-17 | Bayer Cropscience Aktiengesellschaft | Substituted 2-(het)aryl-imidazolyl-carboxyamides as pest control agents |
| EP3414238B1 (de) * | 2016-02-11 | 2021-03-24 | Bayer CropScience Aktiengesellschaft | Substituierte imidazolyl-carboxamide als schädlingsbekämpfungsmittel |
| JP6892452B2 (ja) * | 2016-02-11 | 2021-06-23 | バイエル・クロップサイエンス・アクチェンゲゼルシャフト | 有害生物防除剤としての置換イミダゾリル−カルボキサミド類 |
| WO2019137995A1 (en) | 2018-01-11 | 2019-07-18 | Basf Se | Novel pyridazine compounds for controlling invertebrate pests |
| US12528798B2 (en) | 2019-10-29 | 2026-01-20 | Lg Chem, Ltd. | Compound for crop protectant |
| CN116948859B (zh) * | 2022-12-15 | 2024-03-19 | 领先生物农业股份有限公司 | 一种根瘤菌伴生菌剂及其在根瘤菌喷施中的应用 |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9424379D0 (en) * | 1994-12-02 | 1995-01-18 | Agrevo Uk Ltd | Fungicides |
| CN100352808C (zh) | 2001-03-05 | 2007-12-05 | 杜邦公司 | 杂环二酰胺无脊椎害虫控制剂 |
| GB0213715D0 (en) | 2002-06-14 | 2002-07-24 | Syngenta Ltd | Chemical compounds |
| TWI312272B (en) | 2003-05-12 | 2009-07-21 | Sumitomo Chemical Co | Pyrimidine compound and pests controlling composition containing the same |
| GB0414438D0 (en) | 2004-06-28 | 2004-07-28 | Syngenta Participations Ag | Chemical compounds |
| WO2006043635A1 (ja) | 2004-10-20 | 2006-04-27 | Kumiai Chemical Industry Co., Ltd. | ３－トリアゾリルフェニルスルフィド誘導体及びそれを有効成分として含有する殺虫・殺ダニ・殺線虫剤 |
| CA2624558C (en) | 2005-10-06 | 2011-02-22 | Nippon Soda Co., Ltd. | Cross-linked cyclic amine compounds and agents for pest control |
| TW200906396A (en) | 2007-02-14 | 2009-02-16 | Janssen Pharmaceutica Nv | LTA4H modulators and uses thereof |
| JO3240B1 (ar) * | 2007-10-17 | 2018-03-08 | Janssen Pharmaceutica Nv | c-fms مثبطات كيناز |
| JP5268461B2 (ja) | 2008-07-14 | 2013-08-21 | Ｍｅｉｊｉ Ｓｅｉｋａファルマ株式会社 | Ｐｆ１３６４物質、その製造方法、生産菌株、及び、それを有効成分とする農園芸用殺虫剤 |
| CN101337940B (zh) | 2008-08-12 | 2012-05-02 | 国家农药创制工程技术研究中心 | 具杀虫活性的含氮杂环二氯烯丙醚类化合物 |
| CN101337937B (zh) | 2008-08-12 | 2010-12-22 | 国家农药创制工程技术研究中心 | 具有杀虫活性的n-苯基-5-取代氨基吡唑类化合物 |
| CN101715774A (zh) | 2008-10-09 | 2010-06-02 | 浙江化工科技集团有限公司 | 一个具有杀虫活性化合物制备及用途 |
| EP2184273A1 (de) | 2008-11-05 | 2010-05-12 | Bayer CropScience AG | Halogen-substituierte Verbindungen als Pestizide |
| GB0820344D0 (en) | 2008-11-06 | 2008-12-17 | Syngenta Ltd | Herbicidal compositions |
| EP2236505A1 (de) | 2009-04-03 | 2010-10-06 | Bayer CropScience AG | Acylierte Aminopyridine und - pyridazine als Insektizide |
| CN102469785A (zh) * | 2009-07-24 | 2012-05-23 | 巴斯夫欧洲公司 | 防治无脊椎动物害虫的吡啶衍生物 |
| US8435976B2 (en) * | 2009-09-08 | 2013-05-07 | F. Hoffmann-La Roche | 4-substituted pyridin-3-yl-carboxamide compounds and methods of use |
| WO2011085575A1 (zh) | 2010-01-15 | 2011-07-21 | 江苏省农药研究所股份有限公司 | 邻杂环甲酰苯胺类化合物及其合成方法和应用 |
| PL2631235T3 (pl) | 2010-08-31 | 2016-05-31 | Meiji Seika Pharma Co Ltd | Środek do zwalczania szkodników |
| CN101967139B (zh) | 2010-09-14 | 2013-06-05 | 中化蓝天集团有限公司 | 一种含一氟甲氧基吡唑的邻甲酰氨基苯甲酰胺类化合物、其合成方法及应用 |
| WO2013050317A1 (en) | 2011-10-03 | 2013-04-11 | Syngenta Limited | Polymorphs of an isoxazoline derivative |
| CN102391261A (zh) | 2011-10-14 | 2012-03-28 | 上海交通大学 | 一种n-取代噁二嗪类化合物及其制备方法和应用 |
| WO2013144213A1 (en) | 2012-03-30 | 2013-10-03 | Basf Se | N-substituted pyridinylidene compounds and derivatives for combating animal pests |
| EP2647626A1 (en) | 2012-04-03 | 2013-10-09 | Syngenta Participations AG. | 1-Aza-spiro[4.5]dec-3-ene and 1,8-diaza-spiro[4.5]dec-3-ene derivatives as pesticides |
| US9282739B2 (en) | 2012-04-27 | 2016-03-15 | Dow Agrosciences Llc | Pesticidal compositions and processes related thereto |
| BR112014026746A2 (pt) | 2012-04-27 | 2017-06-27 | Dow Agrosciences Llc | composições pesticidas e processos relacionados com as mesmas |
| CN103232431B (zh) | 2013-01-25 | 2014-11-05 | 青岛科技大学 | 一种二卤代吡唑酰胺类化合物及其应用 |
| CN103109816B (zh) | 2013-01-25 | 2014-09-10 | 青岛科技大学 | 硫代苯甲酰胺类化合物及其应用 |
| WO2014158644A1 (en) | 2013-03-13 | 2014-10-02 | Dow Agrosciences Llc | Process for the preparation of triaryl rhamnose carbamates |
| CN103524422B (zh) | 2013-10-11 | 2015-05-27 | 中国农业科学院植物保护研究所 | 苯并咪唑衍生物及其制备方法和用途 |
| US9102654B2 (en) | 2013-10-17 | 2015-08-11 | Dow Agrosciences Llc | Processes for the preparation of pesticidal compounds |
| CA2925873A1 (en) | 2013-10-17 | 2015-04-23 | Dow Agrosciences Llc | Processes for the preparation of pesticidal compounds |
| TWI702212B (zh) * | 2015-02-09 | 2020-08-21 | 德商拜耳作物科學股份有限公司 | 作為除害劑之經取代的２－硫基咪唑基羧醯胺類 |
| JP6892452B2 (ja) * | 2016-02-11 | 2021-06-23 | バイエル・クロップサイエンス・アクチェンゲゼルシャフト | 有害生物防除剤としての置換イミダゾリル−カルボキサミド類 |
| CA3013962A1 (en) * | 2016-02-11 | 2017-08-17 | Bayer Cropscience Aktiengesellschaft | Substituted 2-(het)aryl-imidazolyl-carboxyamides as pest control agents |
-
2017
- 2017-02-06 KR KR1020187022835A patent/KR20180107142A/ko not_active Withdrawn
- 2017-02-06 CN CN201780014347.3A patent/CN108699045B/zh not_active Expired - Fee Related
- 2017-02-06 EP EP17702889.1A patent/EP3414237B1/de not_active Not-in-force
- 2017-02-06 ES ES17702889T patent/ES2845902T3/es active Active
- 2017-02-06 MX MX2018009809A patent/MX2018009809A/es unknown
- 2017-02-06 BR BR112018016364-3A patent/BR112018016364A2/pt not_active Application Discontinuation
- 2017-02-06 WO PCT/EP2017/052502 patent/WO2017137339A1/de not_active Ceased
- 2017-02-06 JP JP2018541694A patent/JP6892866B2/ja not_active Expired - Fee Related
- 2017-02-06 RU RU2018132172A patent/RU2018132172A/ru not_active Application Discontinuation
- 2017-02-06 CA CA3013963A patent/CA3013963A1/en not_active Abandoned
- 2017-02-06 US US16/076,722 patent/US10647699B2/en not_active Expired - Fee Related
- 2017-02-06 AU AU2017217184A patent/AU2017217184A1/en not_active Abandoned
- 2017-02-09 TW TW106104210A patent/TWI721097B/zh not_active IP Right Cessation
- 2017-02-10 UY UY0001037117A patent/UY37117A/es not_active Application Discontinuation
- 2017-02-10 AR ARP170100331A patent/AR107587A1/es unknown
-
2018
- 2018-07-17 IL IL260640A patent/IL260640B/en active IP Right Grant
- 2018-08-10 PH PH12018501706A patent/PH12018501706A1/en unknown
- 2018-08-10 CO CONC2018/0008398A patent/CO2018008398A2/es unknown
- 2018-08-10 CL CL2018002298A patent/CL2018002298A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| TW201741300A (zh) | 2017-12-01 |
| MX2018009809A (es) | 2018-09-10 |
| RU2018132172A (ru) | 2020-03-11 |
| EP3414237A1 (de) | 2018-12-19 |
| US20190040042A1 (en) | 2019-02-07 |
| CN108699045A (zh) | 2018-10-23 |
| KR20180107142A (ko) | 2018-10-01 |
| UY37117A (es) | 2017-09-29 |
| CN108699045B (zh) | 2021-02-12 |
| ES2845902T3 (es) | 2021-07-28 |
| CL2018002298A1 (es) | 2018-11-23 |
| EP3414237B1 (de) | 2020-12-23 |
| PH12018501706A1 (en) | 2019-05-20 |
| AU2017217184A1 (en) | 2018-08-09 |
| US10647699B2 (en) | 2020-05-12 |
| CA3013963A1 (en) | 2017-08-17 |
| TWI721097B (zh) | 2021-03-11 |
| CO2018008398A2 (es) | 2018-08-21 |
| IL260640B (en) | 2020-07-30 |
| JP2019507141A (ja) | 2019-03-14 |
| JP6892866B2 (ja) | 2021-06-23 |
| BR112018016364A2 (pt) | 2018-12-18 |
| WO2017137339A1 (de) | 2017-08-17 |
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