AR079986A1 - Metodo para preparar polietileno con alta resistencia a la fusion - Google Patents
Metodo para preparar polietileno con alta resistencia a la fusionInfo
- Publication number
- AR079986A1 AR079986A1 ARP110100080A ARP110100080A AR079986A1 AR 079986 A1 AR079986 A1 AR 079986A1 AR P110100080 A ARP110100080 A AR P110100080A AR P110100080 A ARP110100080 A AR P110100080A AR 079986 A1 AR079986 A1 AR 079986A1
- Authority
- AR
- Argentina
- Prior art keywords
- alkyl
- aryl
- ream
- hydrogen
- high fusion
- Prior art date
Links
- -1 POLYETHYLENE Polymers 0.000 title abstract 2
- 239000004698 Polyethylene Substances 0.000 title abstract 2
- 229920000573 polyethylene Polymers 0.000 title abstract 2
- 230000004927 fusion Effects 0.000 title 1
- 125000000217 alkyl group Chemical group 0.000 abstract 5
- 150000002430 hydrocarbons Chemical group 0.000 abstract 3
- 125000005262 alkoxyamine group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 2
- 239000004215 Carbon black (E152) Substances 0.000 abstract 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 1
- 239000005977 Ethylene Substances 0.000 abstract 1
- 125000002252 acyl group Chemical group 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 229920013716 polyethylene resin Polymers 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D7/00—Producing flat articles, e.g. films or sheets
- B29D7/01—Films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/32—Compounds containing nitrogen bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/11—Melt tension or melt strength
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/18—Bulk density
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/10—Chemical modification of a polymer including a reactive processing step which leads, inter alia, to morphological and/or rheological modifications, e.g. visbreaking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/26—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
- C08J2323/36—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment by reaction with nitrogen-containing compounds, e.g. by nitration
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/26—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
- C08J2423/36—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment by reaction with nitrogen-containing compounds, e.g. by nitration
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/139—Open-ended, self-supporting conduit, cylinder, or tube-type article
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Graft Or Block Polymers (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
- Processes Specially Adapted For Manufacturing Cables (AREA)
Abstract
La presente invencion consiste en un polímero a base de etileno que comprende hacer reaccionar una resma de polietileno con un derivado de alcoxiamina correspondiente a la formula: (R1) (R2)N-O-R3 donde R1 y R2 son cada uno de manera independiente uno del otro, hidrogeno, alquilo C4-42 o arilo C4-42, grupos de hidrocarbono sustituido que comprende O y/o N, y donde R1 y R2 pueden formar juntos una estructura anular; y donde R3 es hidrogeno, un hidrocarbono o un grupo hidrocarbono sustituido que comprende O y/o N. Los grupos preferidos para R3 incluyen alquilo -C1-19 arilo -C6-10 alquenilo -C2-19 -O-alquilo C1-19 -O-arilo C6-10 -NH-alquilo C1-19 -NH-arilo C6-10 -N-(alquilo C1-19)2. R3 contiene con mayor preferencia aun un grupo acilo. La resma resultante aumento la resistencia a la fusion con una mayor relacion de las viscosidades de estiramiento a 0,1 a 100 rad/s en comparacion con las resinas de polietileno sustancialmente similares que no se han hecho reaccionar con un derivado de alcoxiamina.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/685,148 US8653196B2 (en) | 2010-01-11 | 2010-01-11 | Method for preparing polyethylene with high melt strength |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR079986A1 true AR079986A1 (es) | 2012-03-07 |
Family
ID=43734837
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP110100081A AR079987A1 (es) | 2010-01-11 | 2011-01-11 | Composiciones de polietileno de alta fuerza de fusion y los metodos para realizarlas |
| ARP110100080A AR079986A1 (es) | 2010-01-11 | 2011-01-11 | Metodo para preparar polietileno con alta resistencia a la fusion |
| ARP110100082A AR079988A1 (es) | 2010-01-11 | 2011-01-11 | Polietileno con alta resistencia a la fusion para uso en peliculas |
| ARP110100083A AR079989A1 (es) | 2010-01-11 | 2011-01-11 | Peliculas sopladas gruesas |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP110100081A AR079987A1 (es) | 2010-01-11 | 2011-01-11 | Composiciones de polietileno de alta fuerza de fusion y los metodos para realizarlas |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP110100082A AR079988A1 (es) | 2010-01-11 | 2011-01-11 | Polietileno con alta resistencia a la fusion para uso en peliculas |
| ARP110100083A AR079989A1 (es) | 2010-01-11 | 2011-01-11 | Peliculas sopladas gruesas |
Country Status (13)
| Country | Link |
|---|---|
| US (5) | US8653196B2 (es) |
| EP (4) | EP2523991A1 (es) |
| JP (4) | JP5643843B2 (es) |
| KR (4) | KR101886701B1 (es) |
| CN (4) | CN102985448B (es) |
| AR (4) | AR079987A1 (es) |
| BR (4) | BR112012016645A2 (es) |
| ES (1) | ES2949551T3 (es) |
| MX (4) | MX347015B (es) |
| MY (1) | MY169967A (es) |
| RU (4) | RU2012134320A (es) |
| SG (5) | SG182357A1 (es) |
| WO (4) | WO2011085379A1 (es) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8653196B2 (en) * | 2010-01-11 | 2014-02-18 | Dow Global Technologies, Llc | Method for preparing polyethylene with high melt strength |
| EP2691425B1 (en) | 2011-03-28 | 2017-04-19 | Dow Global Technologies LLC | Process to produce enhanced melt strength ethylene/alpha-olefin copolymers and articles thereof |
| WO2013006409A1 (en) * | 2011-07-06 | 2013-01-10 | Dow Global Technologies Llc | Polyethylene with high melt strength for use in extrusion coating |
| CN107266759A (zh) * | 2011-07-07 | 2017-10-20 | 陶氏环球技术有限责任公司 | 基于乙烯的聚合物组合物 |
| WO2013029223A1 (en) * | 2011-08-26 | 2013-03-07 | Dow Global Technologies Llc | Bioriented polyethylene film |
| US9340664B2 (en) | 2011-09-23 | 2016-05-17 | Exxonmobil Chemical Patents Inc. | Modified polyethylene compositions for blown film |
| US9321911B2 (en) | 2011-09-23 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Modified polyethylene compositions for cast film |
| US20160272798A1 (en) | 2011-09-23 | 2016-09-22 | Exxonmobil Chemical Patents Inc. | Modified Polyethylene Compositions with Enhanced Melt Strength |
| US11292234B2 (en) * | 2012-09-13 | 2022-04-05 | Dow Global Technologies Llc | Polyolefin based films suitable for thermoforming |
| BR112015006812B1 (pt) | 2012-09-28 | 2021-03-23 | Dow Global Technologies Llc | Composição |
| JP6395804B2 (ja) * | 2013-03-28 | 2018-09-26 | ダウ グローバル テクノロジーズ エルエルシー | エチレン/アルファ−オレフィンインターポリマー組成物 |
| US9988473B2 (en) * | 2013-05-02 | 2018-06-05 | Dow Global Technologies Llc | Polyethylene composition and articles made therefrom |
| US9346897B2 (en) † | 2013-05-14 | 2016-05-24 | Chevron Phillips Chemical Company Lp | Peroxide treated metallocene-based polyolefins with improved melt strength |
| CA2955941A1 (en) * | 2014-07-25 | 2016-01-28 | Dow Global Technologies Llc | A polyethylene blend composition and film made therefrom |
| US10336893B2 (en) | 2014-12-23 | 2019-07-02 | Dow Global Technologies Llc | Process for preparing a modified ethylene-based polymer using a hydrocarbon initiator |
| ES2768878T3 (es) * | 2015-06-30 | 2020-06-23 | Dow Global Technologies Llc | Películas de polietileno con superficie mate |
| KR101924198B1 (ko) * | 2015-12-23 | 2018-11-30 | 주식회사 엘지화학 | 필름 가공성 및 투명도가 우수한 저밀도 폴리에틸렌 공중합체 |
| BR112018069347B1 (pt) * | 2016-03-31 | 2022-11-29 | Dow Global Technologies Llc | Método para aumentar a resistibilidade de fusão ou baixa viscosidade de cisalhamento de uma resina de polietileno |
| EP3238938A1 (en) | 2016-04-29 | 2017-11-01 | Borealis AG | Machine direction oriented films comprising multimodal copolymer of ethylene and at least two alpha-olefin comonomers |
| CN107880193A (zh) * | 2016-09-29 | 2018-04-06 | 中国石油化工股份有限公司 | 一种热熔胶用高熔指 ldpe 专用料的制备方法 |
| WO2018191000A1 (en) * | 2017-04-10 | 2018-10-18 | Exxonmobil Chemicl Patents Inc. | Methods for making polyolefin polymer compositions |
| US10858504B2 (en) * | 2017-07-06 | 2020-12-08 | Exxonmobil Chemical Patents Inc. | Polyethylene compositions comprising cyclic-olefin copolymers |
| ES2959311T3 (es) | 2017-09-27 | 2024-02-23 | Dow Global Technologies Llc | Composiciones de polietileno modificadas y método para preparar las mismas |
| KR102708116B1 (ko) | 2017-11-08 | 2024-09-20 | 주식회사 엘지에너지솔루션 | 세퍼레이터 및 이를 포함하는 전기화학소자 |
| TWI814848B (zh) * | 2018-06-29 | 2023-09-11 | 美商陶氏全球科技有限責任公司 | 可分配容器、分配器及操作分配器之方法 |
| KR102766176B1 (ko) * | 2018-12-11 | 2025-02-17 | 다우 글로벌 테크놀로지스 엘엘씨 | 불균일한 두께를 갖는 사일로 백 및 이의 제조 방법 |
| CN109827922B (zh) * | 2019-03-20 | 2021-08-13 | 深圳市艾科尔特检测有限公司 | 受铜离子污染水中硝酸盐氮测定时铜离子干扰的校正方法 |
| CN116648466B (zh) * | 2020-11-30 | 2025-04-18 | 株式会社Lg化学 | 聚乙烯及其制备方法 |
| WO2022114904A1 (ko) * | 2020-11-30 | 2022-06-02 | 주식회사 엘지화학 | 폴리에틸렌 및 그의 제조 방법 |
| CN117597388B (zh) * | 2021-07-08 | 2025-09-19 | 北欧化工公司 | 用于生产交联聚乙烯(pex)的聚乙烯 |
| CN119731255A (zh) | 2022-08-19 | 2025-03-28 | 巴斯夫欧洲公司 | 添加剂用于改善聚乙烯的加工的用途 |
| EP4638594A1 (en) | 2022-12-21 | 2025-10-29 | Basf Se | A method for improving the processing of polyethylene |
| WO2024137484A1 (en) * | 2022-12-21 | 2024-06-27 | Equistar Chemicals, Lp | Blend of ldpe and post-consumer recyclate content with reduced film defects |
| WO2025259663A1 (en) * | 2024-06-11 | 2025-12-18 | Dow Global Technologies Llc | Methods of producing films with improved mechanical properties |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3709853A (en) * | 1971-04-29 | 1973-01-09 | Union Carbide Corp | Polymerization of ethylene using supported bis-(cyclopentadienyl)chromium(ii)catalysts |
| US4339507A (en) * | 1980-11-26 | 1982-07-13 | Union Carbide Corporation | Linear low density ethylene hydrocarbon copolymer containing composition for extrusion coating |
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