AR077307A1 - Derivados de fenil(oxi/tio)alcanol sustituidos, intermediarios y metodo para su preparacion y su empleo para combatir hongos fitopatogenos - Google Patents
Derivados de fenil(oxi/tio)alcanol sustituidos, intermediarios y metodo para su preparacion y su empleo para combatir hongos fitopatogenosInfo
- Publication number
- AR077307A1 AR077307A1 ARP100102399A ARP100102399A AR077307A1 AR 077307 A1 AR077307 A1 AR 077307A1 AR P100102399 A ARP100102399 A AR P100102399A AR P100102399 A ARP100102399 A AR P100102399A AR 077307 A1 AR077307 A1 AR 077307A1
- Authority
- AR
- Argentina
- Prior art keywords
- triazol
- ylmethyl
- thio
- cyclopropyl
- phenyl
- Prior art date
Links
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical class CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 title 1
- 241000233866 Fungi Species 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 5
- 125000001559 cyclopropyl group Chemical group [H]C1([H])C([H])([H])C1([H])* 0.000 abstract 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 4
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 3
- -1 1H-1,2,4-triazol-1-ylmethyl Chemical group 0.000 abstract 3
- 150000002924 oxiranes Chemical class 0.000 abstract 3
- 125000000446 sulfanediyl group Chemical group *S* 0.000 abstract 3
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 abstract 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 abstract 2
- 125000004528 pyrimidin-5-yl group Chemical group N1=CN=CC(=C1)* 0.000 abstract 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 abstract 2
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 1
- JLTPRZCIWANJBW-UHFFFAOYSA-N 1-(3-bromo-2-chlorophenoxy)-3,3-dimethyl-2-(1,2,4-triazol-1-ylmethyl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)COC1=CC=CC(Br)=C1Cl JLTPRZCIWANJBW-UHFFFAOYSA-N 0.000 abstract 1
- CNUFDPUEKAEFED-UHFFFAOYSA-N 1-(4-bromo-2-chlorophenoxy)-3,3-dimethyl-2-(1,2,4-triazol-1-ylmethyl)butan-2-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)COC1=CC=C(Br)C=C1Cl CNUFDPUEKAEFED-UHFFFAOYSA-N 0.000 abstract 1
- ZAJWJYSRKIBMOI-UHFFFAOYSA-N 1-[3,5-bis(trifluoromethyl)phenyl]-4,4-dimethyl-3-(1,2,4-triazol-1-ylmethyl)pentan-3-ol Chemical compound C1=NC=NN1CC(O)(C(C)(C)C)CCC1=CC(C(F)(F)F)=CC(C(F)(F)F)=C1 ZAJWJYSRKIBMOI-UHFFFAOYSA-N 0.000 abstract 1
- XHPZYIUGEFSFOO-UHFFFAOYSA-N 4-(3-bromo-4-fluorophenyl)-2-(1-chlorocyclopropyl)-1-(1,2,4-triazol-1-yl)butan-2-ol Chemical compound C1=NC=NN1CC(C1(Cl)CC1)(O)CCC1=CC=C(F)C(Br)=C1 XHPZYIUGEFSFOO-UHFFFAOYSA-N 0.000 abstract 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- KPCZJLGGXRGYIE-UHFFFAOYSA-N [C]1=CC=CN=C1 Chemical group [C]1=CC=CN=C1 KPCZJLGGXRGYIE-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 125000001246 bromo group Chemical group Br* 0.000 abstract 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000011630 iodine Chemical group 0.000 abstract 1
- 150000002576 ketones Chemical class 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 244000005700 microbiome Species 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000008635 plant growth Effects 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D239/00—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings
- C07D239/02—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings
- C07D239/24—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members
- C07D239/26—Heterocyclic compounds containing 1,3-diazine or hydrogenated 1,3-diazine rings not condensed with other rings having three or more double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
- C07D249/10—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/04—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
Landscapes
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plural Heterocyclic Compounds (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
Derivados de fenil(oxi/tio)alcanol sustituidos a procedimientos para preparar estos compuestos, a composiciones que comprenden estos compuestos y a su uso como compuestos biologicamente activos, en particular para combatir microorganismos perjudiciales en proteccion de cultivos y en la proteccion de materiales y como reguladores del crecimiento de las plantas. Reivindicacion 1: Derivados de fenil(oxi/tio)alcanol de la formula (1) en la que X representa 5-pirimidinilo, 1H-1,2,4-triazol-1-ilmetilo, 3-pirimidilo, 1H-1,3-imidazol-1-ilmetilo o 2,4-dihidro-3H-1,2,4-triazol-3-tion-1-ilmetilo, Y representa O, S, SO, SO2 o CH2, Z1 representa bromo, yodo o trifluorometilo, Z2 y Z3, independientemente una de otra, representan halogeno, metilo o trifluorometilo, n representa 0 o 1, R representa terc-butilo, isopropilo, 1-halociclopropilo, 1-(alquil C1-4)ciclopropilo, 1-(alcoxi C1-4)ciclopropilo o 1-((alquil C1-4)-tio)ciclopropilo, y las sales agroquímicamente activas de los mismos, excepto para los compuesto 1-(3-bromo-2-clorofenoxi)-3,3-dimetil-2-(1H-1,2,4-triazol-1-ilmetil)butan-2-ol, 1-(4-bromo-2-clorofenoxi)-3,3-dimetil-2-(1H-1,2,4-triazol-1-ilmetil)butan-2-ol, 4-(3-bromo-4-fluorofenil)-2-(1-clorociclopropil)-1-(1H-1,2,4-triazol-1-il)butan-2-ol, 1-[3,5-bis(trifluorometil)fenil]-4,4-dimetil-3-(1H-1,2,4-triazol-1-ilmetil)pentan-3-ol. Reivindicacion 11: Derivados de oxirano de la formula (2) en la que Y, Z1, Z2, Z3, n y R tienen los significados dados en la reivindicacion 1, excepto para el compuesto 2-{2-[3,5-bis(trifluorometil)fenil]etil}-2-terc-butiloxirano. Reivindicacion 12: Derivados de oxirano de la formula (3) en la que Ra representa isopropilo, 1-halociclopropilo, 1-(alquil C1-4)ciclopropilo, 1-(alcoxi C1-4)cilcopropilo o 1-((alquil C1-4)-tio)ciclopropilo, A representa CH o N. Reivindicacion 13: Derivados de oxirano de la formula (4) en la que R tiene los significados dados anteriormente y A representa CH o N, donde R no representa terc-butilo si A representa CH. Reivindicacion 14: Fenil(oxi/tio)cetonas de la formula (5) en la que X4 representa 5-pirimidinilo o 3-piridinilo e Y, Z1, Z2, Z3, n y R tienen los significados dados en la reivindicacion 1.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09164930 | 2009-07-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR077307A1 true AR077307A1 (es) | 2011-08-17 |
Family
ID=41347826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP100102399A AR077307A1 (es) | 2009-07-08 | 2010-07-05 | Derivados de fenil(oxi/tio)alcanol sustituidos, intermediarios y metodo para su preparacion y su empleo para combatir hongos fitopatogenos |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US9187431B2 (es) |
| EP (1) | EP2451785A2 (es) |
| JP (2) | JP5792164B2 (es) |
| KR (1) | KR20120046242A (es) |
| CN (1) | CN102471285B (es) |
| AR (1) | AR077307A1 (es) |
| AU (1) | AU2010268838B2 (es) |
| BR (1) | BR112012000170A2 (es) |
| CA (1) | CA2775312A1 (es) |
| CL (1) | CL2012000006A1 (es) |
| CO (1) | CO6480988A2 (es) |
| EA (2) | EA023170B9 (es) |
| EC (1) | ECSP11011568A (es) |
| MX (1) | MX2012000212A (es) |
| TW (1) | TWI519525B (es) |
| WO (1) | WO2011003528A2 (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2767385A1 (en) * | 2009-07-08 | 2011-01-13 | Bayer Cropscience Ag | Phenyl(oxy/thio)alkanol derivatives |
| US9241487B2 (en) | 2010-11-30 | 2016-01-26 | Bayer Intellectual Property Gmbh | Pyrimidine derivatives and use thereof as pesticides |
| JP6657974B2 (ja) * | 2016-01-12 | 2020-03-04 | トヨタ紡織株式会社 | 金属樹脂一体成形品及びその製造方法 |
Family Cites Families (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2742173A1 (de) | 1977-09-20 | 1979-03-29 | Bayer Ag | Phenoxy-pyridinyl(pyrimidinyl)-alkanole, verfahren zu ihrer herstellung sowie ihre verwendung als fungizide |
| DE2742175A1 (de) * | 1977-09-20 | 1979-03-29 | Bayer Ag | Antimikrobielle mittel |
| US4272417A (en) | 1979-05-22 | 1981-06-09 | Cargill, Incorporated | Stable protective seed coating |
| US4245432A (en) | 1979-07-25 | 1981-01-20 | Eastman Kodak Company | Seed coatings |
| DE2944850A1 (de) | 1979-11-07 | 1981-05-27 | Bayer Ag, 5090 Leverkusen | Mittel zur regulierung des pflanzenwachstums, deren herstellung und deren verwendung |
| DE3018866A1 (de) * | 1980-05-16 | 1981-11-26 | Bayer Ag, 5090 Leverkusen | 1-hydroxyethyl-azol-derivate, verfahren zu ihrer herstellung sowie ihre verwendung als pflanzenwachstumsregulatoren und fungizide |
| AU542623B2 (en) | 1980-05-16 | 1985-02-28 | Bayer Aktiengesellschaft | 1-hydroxyethyl-azole derivatives |
| JPS57165370A (en) * | 1981-03-18 | 1982-10-12 | Ici Ltd | Triazole or imidazole compounds, manufacture and fungicidal or plant growth regulant agent |
| DE3279417D1 (en) | 1981-03-18 | 1989-03-09 | Ici Plc | Triazole compounds, a process for preparing them, their use as plant fungicides and fungicidal compositions containing them |
| DE3111238A1 (de) | 1981-03-21 | 1982-10-07 | Bayer Ag, 5090 Leverkusen | Substituierte triazolylmethyl-oxirane, verfahren zu ihrer herstellung sowie ihre verwendung als zwischenprodukte |
| DE3365739D1 (en) * | 1982-01-15 | 1986-10-09 | Ciba Geigy Ag | Fungicidal and plant-growth regulating tri-azolcarbinol derivatives |
| DE3202601A1 (de) * | 1982-01-27 | 1983-08-04 | Bayer Ag, 5090 Leverkusen | Substituierte 1 -hydroxyalkyl-azolyl-derivate, verfahren zu ihrer herstellung sowie ihrer verwendung als fungizide und pflanzenwachstumsregulatoren |
| DE3325761A1 (de) * | 1983-07-16 | 1985-01-24 | Bayer Ag, 5090 Leverkusen | Aroxy-pyrimidinyl-alkanole |
| FR2561239B1 (fr) * | 1984-03-15 | 1986-09-05 | Rhone Poulenc Agrochimie | Arylthio-pyridinyl-alcanols |
| DD258163A5 (de) | 1985-10-01 | 1988-07-13 | ����`��@���k�� | Mikrobizide mittel |
| US4808430A (en) | 1987-02-27 | 1989-02-28 | Yazaki Corporation | Method of applying gel coating to plant seeds |
| DE3813129A1 (de) | 1987-07-01 | 1989-01-12 | Bayer Ag | Hydroxyethyl-azolyl-derivate |
| DE3813874A1 (de) * | 1987-07-10 | 1989-01-19 | Bayer Ag | Hydroxyalkyl-azolyl-derivate |
| EP0304171B1 (en) | 1987-08-20 | 1993-01-13 | Imperial Chemical Industries Plc | Pyrimidine derivatives |
| DE3732385A1 (de) * | 1987-09-25 | 1989-04-06 | Bayer Ag | Hydroxyalkylcyclopropyl1-1,2,4-triazolyl- oder -imidazolyl-derivate und ihre verwendung als antimykotische mittel |
| DE3811302A1 (de) * | 1988-04-02 | 1989-10-19 | Bayer Ag | Derivate des triazolylmethyl-cyclopropyl-carbinols als materialschutzmittel |
| GB8810120D0 (en) | 1988-04-28 | 1988-06-02 | Plant Genetic Systems Nv | Transgenic nuclear male sterile plants |
| GB8819308D0 (en) * | 1988-08-13 | 1988-09-14 | Pfizer Ltd | Triazole antifungal agents |
| DE3905317A1 (de) * | 1989-02-21 | 1990-08-23 | Bayer Ag | Cyclopropyl-hydroxyalkyl-azolyl-derivate |
| DE3906556A1 (de) | 1989-03-02 | 1990-09-06 | Desowag Materialschutz Gmbh | Mittel oder konzentrat zum konservieren von holz oder holzwerkstoffen |
| DE4229643A1 (de) * | 1992-09-04 | 1994-03-10 | Bayer Ag | Substituierte Hydroxyalkylpyridine |
| DE19528046A1 (de) | 1994-11-21 | 1996-05-23 | Bayer Ag | Triazolyl-Derivate |
| ATE342968T1 (de) | 1995-04-20 | 2006-11-15 | Basf Ag | Auf basis ihrer struktur entworfene herbizid resistente produkte |
| US5876739A (en) | 1996-06-13 | 1999-03-02 | Novartis Ag | Insecticidal seed coating |
| US6503904B2 (en) | 1998-11-16 | 2003-01-07 | Syngenta Crop Protection, Inc. | Pesticidal composition for seed treatment |
| KR20030045673A (ko) | 2000-05-18 | 2003-06-11 | 다이이치세이야꾸 가부시끼가이샤 | 신규 벤조티오펜 유도체 |
| US6660690B2 (en) | 2000-10-06 | 2003-12-09 | Monsanto Technology, L.L.C. | Seed treatment with combinations of insecticides |
| US20020134012A1 (en) | 2001-03-21 | 2002-09-26 | Monsanto Technology, L.L.C. | Method of controlling the release of agricultural active ingredients from treated plant seeds |
| US20080234130A1 (en) | 2005-08-24 | 2008-09-25 | Pioneer Hi-Bred International, Inc. | Compositions providing tolerance to multiple herbicides and methods of use thereof |
| JP4975747B2 (ja) | 2005-08-31 | 2012-07-11 | モンサント テクノロジー エルエルシー | 殺虫性タンパク質をコードするヌクレオチド配列 |
| EP2443099A1 (en) * | 2009-06-18 | 2012-04-25 | Basf Se | Antifungal 1, 2, 4-triazolyl derivatives having a 5- sulfur substituent |
| CA2767385A1 (en) | 2009-07-08 | 2011-01-13 | Bayer Cropscience Ag | Phenyl(oxy/thio)alkanol derivatives |
-
2010
- 2010-06-25 EP EP10735188A patent/EP2451785A2/de not_active Withdrawn
- 2010-06-25 EA EA201391356A patent/EA023170B9/ru not_active IP Right Cessation
- 2010-06-25 MX MX2012000212A patent/MX2012000212A/es active IP Right Grant
- 2010-06-25 JP JP2012518789A patent/JP5792164B2/ja not_active Expired - Fee Related
- 2010-06-25 WO PCT/EP2010/003909 patent/WO2011003528A2/de not_active Ceased
- 2010-06-25 CA CA2775312A patent/CA2775312A1/en not_active Abandoned
- 2010-06-25 CN CN201080030660.4A patent/CN102471285B/zh not_active Expired - Fee Related
- 2010-06-25 KR KR1020127003306A patent/KR20120046242A/ko not_active Ceased
- 2010-06-25 EA EA201290034A patent/EA019612B1/ru not_active IP Right Cessation
- 2010-06-25 AU AU2010268838A patent/AU2010268838B2/en not_active Ceased
- 2010-06-25 BR BR112012000170A patent/BR112012000170A2/pt not_active IP Right Cessation
- 2010-07-05 AR ARP100102399A patent/AR077307A1/es unknown
- 2010-07-07 TW TW099122267A patent/TWI519525B/zh not_active IP Right Cessation
- 2010-07-08 US US12/832,558 patent/US9187431B2/en not_active Expired - Fee Related
-
2011
- 2011-12-30 EC EC2011011568A patent/ECSP11011568A/es unknown
- 2011-12-30 CO CO11181745A patent/CO6480988A2/es active IP Right Grant
-
2012
- 2012-01-03 CL CL2012000006A patent/CL2012000006A1/es unknown
-
2015
- 2015-05-11 JP JP2015096942A patent/JP2015187121A/ja active Pending
- 2015-09-03 US US14/844,518 patent/US20150376147A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| BR112012000170A2 (pt) | 2019-09-24 |
| US20110059990A1 (en) | 2011-03-10 |
| EP2451785A2 (de) | 2012-05-16 |
| AU2010268838A1 (en) | 2011-01-13 |
| CN102471285B (zh) | 2015-04-22 |
| MX2012000212A (es) | 2012-01-25 |
| AU2010268838A8 (en) | 2012-02-23 |
| JP2012532157A (ja) | 2012-12-13 |
| TW201107300A (en) | 2011-03-01 |
| EA201391356A1 (ru) | 2014-05-30 |
| CO6480988A2 (es) | 2012-07-16 |
| TWI519525B (zh) | 2016-02-01 |
| EA023170B9 (ru) | 2016-09-30 |
| EA201290034A1 (ru) | 2012-06-29 |
| CA2775312A1 (en) | 2011-01-13 |
| AU2010268838B2 (en) | 2015-06-11 |
| CL2012000006A1 (es) | 2012-10-05 |
| JP5792164B2 (ja) | 2015-10-07 |
| WO2011003528A3 (de) | 2011-08-25 |
| CN102471285A (zh) | 2012-05-23 |
| US9187431B2 (en) | 2015-11-17 |
| JP2015187121A (ja) | 2015-10-29 |
| EA023170B1 (ru) | 2016-04-29 |
| US20150376147A1 (en) | 2015-12-31 |
| KR20120046242A (ko) | 2012-05-09 |
| ECSP11011568A (es) | 2012-01-31 |
| WO2011003528A2 (de) | 2011-01-13 |
| EA019612B1 (ru) | 2014-04-30 |
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